Phase diagram, thermodynamic studies, and ab-initio calculations of the Ge-Li system

W. Gierlotka, A. Dębski, M. Zabrocki, A. Góral, W. Gąsior

The Journal of Chemical Thermodynamics 175 106883 (2022) · Elsevier BV

DOI: 10.1016/j.jct.2022.106883

Data: JSON record · id doi:10.1016/j.jct.2022.106883 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 283 released values
• assessment behind a TDB file: GeLi-22Gie.tdb (Ge–Li)

Systems

Ge–Li, Ge–Sn, Li–Sn

Evidence in ORCHID

283 values read from this paper (279 accepted), from 7 tables and 3 text passages.

ESPEI datasets derived: 18 (dft/literature/GE-LI/GeLi-18Wan.GE12LI7.json …).

Phase-registry phases citing it: phase:ge-li:a4-diamond, phase:ge-li:bcc-a2, phase:ge-li:fcc-a1, phase:ge-li:ge12li7, phase:ge-li:ge2li7, phase:ge-li:ge3li7, phase:ge-li:ge4li15-d86, phase:ge-li:ge4li17, phase:ge-li:ge4li9, phase:ge-li:ge7li12, phase:ge-li:geli, phase:ge-li:geli4, phase:ge-li:hcp-a3, phase:ge-li:liquid

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 1 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (1)

• The SGTE collection of binary datasets (2025) [crossref_reference_list]

References (Crossref, publisher-deposited) (12)

• The Ge- Li (Germanium-Lithium) system (1997) [crossref_reference_list]
• Phase Equilibria of Sn-Sb-Ag Ternary System (II): Calculation (2008) [crossref_reference_list]
• Thermodynamic Description of the Quaternary Ag-Cu-In-Sn System (2011) [crossref_reference_list]
• A Thermodynamic Assessment of the Li-Ge System (2018) [crossref_reference_list]
• Heat of formation of the solid solutions of zinc, gallium and germanium in copper (1962) [crossref_reference_list]
• Solubility of Lithium in germanium (1957) [crossref_reference_list]
• Enthalpy of formation of the CaLi2 phase (2012) [crossref_reference_list]
• Phase equilibria and solidification of ternary Sn–Bi–Ag alloys (2010) [crossref_reference_list]
• Enthalpy of formation for CoGe, CoSn, Ni3.14Sn4, Ni3.50Sn4, AuCo1.66Sn4, AuNi2Sn4 and Au1.17Pt1.82Sn4 (2000) [crossref_reference_list]
• Structural and thermodynamic similarities of phases in the Li–Tt (Tt = Si, Ge) systems: redetermination of the lithium-rich side of the Li–Ge phase diagram and crystal structures of Li ₁₇ Si _4.0−x Ge _x for <i>x</i> = 2.3, 3.1, 3.5, and 4 as well as Li _4.1 Ge (2014) [crossref_reference_list]
• Generalized Gradient Approximation Made Simple (1996) [crossref_reference_list]
• Thermodynamische Analyse der binären Systeme des Germaniums mit Kupfer, Silber und Gold (1971) [crossref_reference_list]

Cites (values carry this citation) (3)

• Solubility of Lithium in germanium (1957) — 1 values [orchid_extraction]
• Enthalpy of formation of the CaLi2 phase (2012) — 1 values [orchid_extraction]
• Structural and thermodynamic similarities of phases in the Li–Tt (Tt = Si, Ge) systems: redetermination of the lithium-rich side of the Li–Ge phase diagram and crystal structures of Li ₁₇ Si _4.0−x Ge _x for <i>x</i> = 2.3, 3.1, 3.5, and 4 as well as Li _4.1 Ge (2014) — 1 values [orchid_extraction]

TDB files modelling its system (2)

• tdb:GeLi-22Gie.tdb [orchid_literature_model_link]
• tdb:GeLi-22Gie.tdb [sgte_tdb_header]

Reassesses (cites an earlier assessment of the same system) (1)

• A Thermodynamic Assessment of the Li-Ge System (2018) [citation+same-system]

Data papers used (3)

• Solubility of Lithium in germanium (1957) — 1 values [orchid_extraction]
• Enthalpy of formation of the CaLi2 phase (2012) — 1 values [orchid_extraction]
• Structural and thermodynamic similarities of phases in the Li–Tt (Tt = Si, Ge) systems: redetermination of the lithium-rich side of the Li–Ge phase diagram and crystal structures of Li ₁₇ Si _4.0−x Ge _x for <i>x</i> = 2.3, 3.1, 3.5, and 4 as well as Li _4.1 Ge (2014) — 1 values [orchid_extraction]