Critical assessment of the Si-P system: P solubility in the Si-rich region and refining by phosphorus distillation

Simon Favre, Ioana Nuta (ORCID 0000-0002-1255-2289), Guy Chichignoud, Evelyne Fischer, Christian Chatillon

Calphad 87 102758 (2024) · Elsevier BV

DOI: 10.1016/j.calphad.2024.102758

Data: JSON record · id doi:10.1016/j.calphad.2024.102758 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 34 released values
• assessment behind a TDB file: SiP-24Fav.tdb (P–Si)

Systems

P–Si

Evidence in ORCHID

34 values read from this paper (27 accepted), from 4 tables and 10 text passages.

Phase-registry phases citing it: phase:p-si:a4-diamond, phase:p-si:bcc-a2, phase:p-si:fcc-a1, phase:p-si:gas, phase:p-si:hcp-a3, phase:p-si:liquid, phase:p-si:p-red, phase:p-si:p-white, phase:p-si:sip, phase:p-si:sip2

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 1 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (1)

• The SGTE collection of binary datasets (2025) [crossref_reference_list]

References (Crossref, publisher-deposited) (9)

• Dampfdruckuntersuchungen im System ZnSiP (1976) [crossref_reference_list]
• The P−Si (Phosphorus-Silicon) system (1985) [crossref_reference_list]
• Calculation of Phase Diagrams and First-Principles Study of Germanium Impacts on Phosphorus Distribution in Czochralski Silicon (2021) [crossref_reference_list]
• Modeling of Thermodynamic Properties and Phase Equilibria of the Si-P System (2013) [crossref_reference_list]
• Über Struktur und Eigenschaften der Halbmetalle. XXII. Die Kristallstruktur des Hittorfschen Phosphors (1969) [crossref_reference_list]
• Analysis of thermodynamic properties and phase equilibria in the Si-P system (2011) [crossref_reference_list]
• Phase diagram study of the Si–P system in Si-rich region (2011) [crossref_reference_list]
• Critical Evaluation and Thermodynamic Re-Optimization of the Si–P and Si–Fe–P Systems (2023) [crossref_reference_list]
• The Crystal Structures of SiP2, SiAs2, and GeP. (1967) [crossref_reference_list]

TDB files modelling its system (2)

• tdb:SiP-24Fav.tdb [orchid_literature_model_link]
• tdb:SiP-24Fav.tdb [sgte_tdb_header]

Reassesses (cites an earlier assessment of the same system) (2)

• Calculation of Phase Diagrams and First-Principles Study of Germanium Impacts on Phosphorus Distribution in Czochralski Silicon (2021) [citation+same-system]
• Modeling of Thermodynamic Properties and Phase Equilibria of the Si-P System (2013) [citation+same-system]