Gibbs free energy of formation and heat capacity of PdO: A new calibration of the PdPdO buffer to high temperatures and pressures

J. Nell, H.St.C. O'Neill

Geochimica et Cosmochimica Acta 60 (14) 2487-2493 (1996) · Elsevier BV

DOI: 10.1016/0016-7037(96)00115-9

Data: JSON record · id doi:10.1016/0016-7037(96)00115-9 · metadata: crossref

Roles in ORCHID

• cited as the original source of values

Systems

O–Pd

Evidence in ORCHID

3 values in 1 other papers cite this work as their source.

Phase-registry phases citing it: phase:o-pd:pdo-b17

Availability

Read by ORCHID: no (full_text_screened_for_origin). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 39 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (4)

• The metallic palladium-rhodium solution in interaction with oxygen: The Pd-Rh-O phase diagram and thermodynamics (2022) [crossref_reference_list]
• The Gibbs free energy of formation and heat capacity of β-Rh2O3 and MgRh2O4, the MgORhO phase diagram, and constraints on the stability of Mg2Rh 4+O4 (1997) [crossref_reference_list]
• High-temperature heat capacity of palladinite PdO(c) (2011) [crossref_reference_list]
• System Nd-Pd-O: Phase diagram and thermodynamic properties of oxides using a solid-state cell with advanced features (1999) [crossref_reference_list]

References (Crossref, publisher-deposited) (7)

• Measurement and regulation of oxygen content in gases using solid electrolyte cells. III. Oxygen pump-gauge (1975) [crossref_reference_list]
• Thermodynamic data from redox reactions at high temperatures. I. An experimental and theoretical assessment of the electrochemical method using stabilized zirconia electrolytes, with revised values for the Fe-?FeO?, Co-CoO, Ni-NiO and Cu-Cu2O oxygen buffers, and new data for the W-WO2 buffer (1993) [crossref_reference_list]
• Determination of the standard free energy of formation of PdO(s) from the solid oxide electrolyte e.m.f. (1983) [crossref_reference_list]
• Formation, dissociation and expansion behavior of platinum group metal oxides (PdO, RuO2, IrO2) (1975) [crossref_reference_list]
• Dissociation of Palladium Oxide¹ (1966) [crossref_reference_list]
• The Free Energy of Formation of Palladium Oxide (1967) [crossref_reference_list]
• Freie Bildungsenthalpie von Palladiumoxid* (1970) [crossref_reference_list]

Cited for values by (1)

• The metallic palladium-rhodium solution in interaction with oxygen: The Pd-Rh-O phase diagram and thermodynamics (2022) — 3 values [orchid_extraction]

Used in (assessments / papers that took values from it) (1)

• The metallic palladium-rhodium solution in interaction with oxygen: The Pd-Rh-O phase diagram and thermodynamics (2022) — 3 values [orchid_extraction]