CALPHAD-Based Thermodynamic Reassessment of Tb-Ni Binary System Supported by Ab-Initio Calculations

Z. Rahou, D. Moustaine, Y. Ben-Ali, A. Hallaoui

Journal of Phase Equilibria and Diffusion 45 (1) 75-85 (2024) · Springer Science and Business Media LLC

DOI: 10.1007/s11669-024-01089-9

Data: JSON record · id doi:10.1007/s11669-024-01089-9 · metadata: crossref

Roles in ORCHID

• read by ORCHID (values extracted): 126 released values
• assessment behind a TDB file: NiTb-24Rah.tdb (Ni–Tb)

Systems

Tb, Ni–Tb

Evidence in ORCHID

126 values read from this paper (122 accepted), from 3 tables and 2 text passages.

ESPEI datasets derived: 33 (derived/invariant-brackets/NI-TB/NiTb-04Ron.zpf-00.json …).

Phase-registry phases citing it: phase:ni-tb:bcc-a2, phase:ni-tb:fcc-a1, phase:ni-tb:hcp-a3, phase:ni-tb:liquid, phase:ni-tb:ni17tb2, phase:ni-tb:ni2tb-c15, phase:ni-tb:ni2tb3, phase:ni-tb:ni3tb, phase:ni-tb:ni5tb-d2d, phase:ni-tb:ni7tb2, phase:ni-tb:nitb, phase:ni-tb:nitb3-d011

Availability

Read by ORCHID: yes (values_extracted). Open-access licence (Crossref license field): none deposited. Crossref is-referenced-by count: 1 (retrieved 2026-10-23).

Relations

Cited by (Crossref reference lists) (1)

• The SGTE collection of binary datasets (2025) [crossref_reference_list]

References (Crossref, publisher-deposited) (17)

• Study of the enthalpies of formation in the Gd-Ni system (1986) [crossref_reference_list]
• guidelines for binary phase diagram assessment (1993) [crossref_reference_list]
• Phase equilibria and thermodynamic properties in the RE-Ni (RE = rare earth metals) binary systems (2022) [crossref_reference_list]
• The crystal structure and magnetic properties of the rare-earth nickel (RNi) compounds (1964) [crossref_reference_list]
• The crystal structures of the rare-earth compounds of the form R2Ni17, R2Co17 and R2Fe17 (1966) [crossref_reference_list]
• Model predictions for the enthalpy of formation of transition metal alloys II (1983) [crossref_reference_list]
• Cohesion in alloys — fundamentals of a semi-empirical model (1980) [crossref_reference_list]
• Standard enthalpies of formation of terbium alloys, Tb + Me (Me  Ni, Ru, Rh, Pd, Ir, Pt), by high-temperature direct synthesis calorimetry (1995) [crossref_reference_list]
• Thermodynamic reassessment of Gd–Ni system (2015) [crossref_reference_list]
• Thermodynamic stability of RNi2 Laves phases (2013) [crossref_reference_list]
• Design of the rare-earth-containing materials based on the micro-alloying phase equilibria, phase diagrams and phase transformations (2023) [crossref_reference_list]
• On the constitution and thermodynamics of Ni–Tb alloys (2004) [crossref_reference_list]
• Standard enthalpies of formation of CeNi5 and of RENi (RE=Ce, Pr, Nd, Sm, Gd, Tb, Ho, Tm and Lu), determined by high-temperature direct synthesis calorimetry (1998) [crossref_reference_list]
• Intermetallic compounds of rare-earth and 3d transition metals (1977) [crossref_reference_list]
• Special points for Brillouin-zone integrations (1976) [crossref_reference_list]
• The monoclinic, CrB-related, crystal structure of Tb3Ni2, Dy3Ni2 and Ho3Ni2 (1974) [crossref_reference_list]
• Mixing enthalpies in liquid alloys of manganese with the lanthanides (2011) [crossref_reference_list]

Cites (values carry this citation) (9)

• On the constitution and thermodynamics of Ni–Tb alloys (2004) — 22 values [orchid_extraction]
• Model predictions for the enthalpy of formation of transition metal alloys II (1983) — 8 values [orchid_extraction]
• The crystal structure and magnetic properties of the rare-earth nickel (RNi) compounds (1964) — 3 values [orchid_extraction]
• The monoclinic, CrB-related, crystal structure of Tb3Ni2, Dy3Ni2 and Ho3Ni2 (1974) — 3 values [orchid_extraction]
• The crystal structures of the rare-earth compounds of the form R2Ni17, R2Co17 and R2Fe17 (1966) — 2 values [orchid_extraction]
• Intermetallic compounds of rare-earth and 3d transition metals (1977) — 2 values [orchid_extraction]
• Standard enthalpies of formation of terbium alloys, Tb + Me (Me  Ni, Ru, Rh, Pd, Ir, Pt), by high-temperature direct synthesis calorimetry (1995) — 1 values [orchid_extraction]
• Thermodynamic stability of RNi2 Laves phases (2013) — 1 values [orchid_extraction]
• Standard enthalpies of formation of CeNi5 and of RENi (RE=Ce, Pr, Nd, Sm, Gd, Tb, Ho, Tm and Lu), determined by high-temperature direct synthesis calorimetry (1998) — 1 values [orchid_extraction]

TDB files modelling its system (2)

• tdb:NiTb-24Rah.tdb [sgte_tdb_header]
• tdb:NiTb-24Rah.tdb [orchid_literature_model_link]

Reassesses (cites an earlier assessment of the same system) (2)

• Phase equilibria and thermodynamic properties in the RE-Ni (RE = rare earth metals) binary systems (2022) [citation+same-system]
• On the constitution and thermodynamics of Ni–Tb alloys (2004) [citation+same-system]

Data papers used (9)

• On the constitution and thermodynamics of Ni–Tb alloys (2004) — 22 values [orchid_extraction]
• Model predictions for the enthalpy of formation of transition metal alloys II (1983) — 8 values [orchid_extraction]
• The crystal structure and magnetic properties of the rare-earth nickel (RNi) compounds (1964) — 3 values [orchid_extraction]
• The monoclinic, CrB-related, crystal structure of Tb3Ni2, Dy3Ni2 and Ho3Ni2 (1974) — 3 values [orchid_extraction]
• The crystal structures of the rare-earth compounds of the form R2Ni17, R2Co17 and R2Fe17 (1966) — 2 values [orchid_extraction]
• Intermetallic compounds of rare-earth and 3d transition metals (1977) — 2 values [orchid_extraction]
• Standard enthalpies of formation of terbium alloys, Tb + Me (Me  Ni, Ru, Rh, Pd, Ir, Pt), by high-temperature direct synthesis calorimetry (1995) — 1 values [orchid_extraction]
• Thermodynamic stability of RNi2 Laves phases (2013) — 1 values [orchid_extraction]
• Standard enthalpies of formation of CeNi5 and of RENi (RE=Ce, Pr, Nd, Sm, Gd, Tb, Ho, Tm and Lu), determined by high-temperature direct synthesis calorimetry (1998) — 1 values [orchid_extraction]