{"cite_as":{"also_cite":["the papers themselves when you use their data (doi / citation of each bibliography record)"],"bibtex":"@misc{orchid_bibliography_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Bibliography: papers and typed citation relations}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736021},\n  url       = {https://doi.org/10.5281/zenodo.23736021},\n  note      = {Version 1, machine-extracted}\n}","dataset":"bibliography","doi":"10.5281/zenodo.23736021","licence_note":"Crossref bibliographic metadata: CC0; ORCHID-derived fields (roles, evidence counts, relations): CC BY 4.0","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: roles and evidence counts derive from machine-extracted literature values and link tables; bibliographic fields are Crossref metadata as deposited (DOIs matched from printed references checked against Crossref: doi_match; mismatches dropped).","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Bibliography: papers and typed citation relations (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736021","title":"ORCHID-Bibliography: papers and typed citation relations","url":"https://doi.org/10.5281/zenodo.23736021","version":"2026.10"},"licence":"Crossref bibliographic metadata: CC0. ORCHID-derived fields (roles, evidence, relations): CC BY 4.0.","paper":{"aliases":["doi:10.1016/0021-9614(85)90069-2"],"article_number":null,"authors":[{"family":"Robie","given":"Richard A."},{"family":"Hemingway","given":"Bruce S."}],"availability":{"open_access_license":null,"pdf_redistributed":false,"read_by_orchid":"no","read_detail":["full_text_screened_for_origin"]},"candidate_systems_inferred":{},"citation":"Richard A. Robie, Bruce S. Hemingway, Low-temperature molar heat capacities and entropies of MnO2 (pyrolusite), Mn3O4 (hausmanite), and Mn2O3 (bixbyite), The Journal of Chemical Thermodynamics 17(2) (1985) 165-181, https://doi.org/10.1016/0021-9614(85)90069-2","citation_printed":null,"container_title":"The Journal of Chemical Thermodynamics","container_title_short":"The Journal of Chemical Thermodynamics","crossref":{"references_count":42,"references_deposited":42,"retrieved_at":"2026-10-23T14:11:12Z","status":"found"},"doi":"10.1016/0021-9614(85)90069-2","doi_check":{"basis":"literature_cited_source","evidence":{"author":"first","journal":"match","title":"strong","volume_page":"match","year":"ok"},"issues":[],"sources_checked":["literature_cited_source"],"status":"verified"},"doi_match":"verified","doi_url":"https://doi.org/10.1016/0021-9614(85)90069-2","evidence_summary":{"cited_as_source":{"by_evidence_class":{"experimental":2,"model":6},"by_property":{"SM":7,"TRANSITION_TEMPERATURE":1},"by_property_group":{"heat capacity / entropy / enthalpy":7,"phase transition":1},"n_citing_papers":2,"n_values":8,"n_values_accepted":7},"phase_registry_phases":["phase:mn-o:mn2o3-d53","phase:mn-o:mno2-c4"]},"id":"doi:10.1016/0021-9614(85)90069-2","id_basis":"doi","is_referenced_by_count":58,"is_referenced_by_count_retrieved":"2026-10-23","isbn":[],"issn":["0021-9614"],"issue":"2","issued":"1985-02","key":"p60948a042bfff5af","language":"en","license":[{"content_version":"tdm","delay_in_days":0,"start":"1985-02-01","url":"https://www.elsevier.com/legal/tdmrep-license"},{"content_version":"tdm","delay_in_days":0,"start":"1985-02-01","url":"https://www.elsevier.com/tdm/userlicense/1.0/"}],"metadata_source":"crossref","no_doi":false,"pages":"165-181","provenance":["orchid-data/literature/papers.json"],"publisher":"Elsevier BV","relation_counts":{"cited_by_crossref":{"in":6,"out":13},"cites":{"in":2,"out":0},"used_in_assessment":{"in":0,"out":2}},"role_details":{"cited_original_source":{"basis":"orchid-data/literature (cited source)"}},"roles":["cited_original_source"],"subtitle":null,"systems":["MN-O"],"title":"Low-temperature molar heat capacities and entropies of MnO2 (pyrolusite), Mn3O4 (hausmanite), and Mn2O3 (bixbyite)","type":"journal-article","urls":{"html":"https://data.orchid-project.org/bibliography/pages/papers/p60948a042bfff5af.html","json":"https://data.orchid-project.org/bibliography/papers/p60948a042bfff5af.json"},"volume":"17","year":1985},"relations":[{"count":null,"direction":"in","edge_id":"e34ee644300b43d4d","other":{"doi":"10.1006/jcht.1998.0479","id":"doi:10.1006/jcht.1998.0479","key":"p66b891344e77521f","title":"Molar heat capacity and thermodynamic functions of the type II antiferromagnet MnO","year":1999},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"in","edge_id":"e11a6086a85ca033b","other":{"doi":"10.1007/bf01046534","id":"doi:10.1007/bf01046534","key":"p3fb4780f7f51fffd","title":"Thermodynamic data from redox reactions at high temperatures. II. The MnO-0Mn3O4 oxygen buffer, and implications for the thermodynamic properties of MnO and Mn3O4","year":1993},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"in","edge_id":"ed2b23d2a43cd4a05","other":{"doi":"10.1007/bf02665468","id":"doi:10.1007/bf02665468","key":"pf663f0439089af7a","title":"Phase relations and gibbs energies in the system Mn-Rh-O","year":1994},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"in","edge_id":"e9a0ce4e1b3241a8f","other":{"doi":"10.1007/s11669-003-0004-6","id":"doi:10.1007/s11669-003-0004-6","key":"p8bbb0a4b49a65084","title":"Assessment of the Mn-O system","year":2003},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"in","edge_id":"ec0d65ff649d9a9b5","other":{"doi":"10.1007/s11669-009-9643-6","id":"doi:10.1007/s11669-009-9643-6","key":"pa146cac250606511","title":"Thermodynamic Assessment of the Fe-Mn-O System","year":2010},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"in","edge_id":"e8e2d136dc3ad44bd","other":{"doi":"10.1016/0021-9614(86)90047-9","id":"doi:10.1016/0021-9614(86)90047-9","key":"p4547566a000343b9","title":"Heat capacity and thermodynamic behaviour of Mn3O4 and ZnMn2O4 at low temperatures","year":1986},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"out","edge_id":"eb256395988bca3e4","other":{"doi":"10.1002/jctb.5010170905","id":"doi:10.1002/jctb.5010170905","key":"p4400d3ea9183f4b1","title":"Equilibria and hysteresis in the system Mn<sub>2</sub>O<sub>3</sub>Mn<sub>3</sub>O<sub>4</sub>O<sub>2</sub>","year":1967},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"out","edge_id":"e9550841e300e4c79","other":{"doi":"10.1016/0013-4686(67)85035-7","id":"doi:10.1016/0013-4686(67)85035-7","key":"p28bcd5ce0247bdf9","title":"Thermodynamic study of the manganese/ manganous-oxide system by the use of solid oxide electrolytes","year":1967},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"out","edge_id":"ed9a770639931c996","other":{"doi":"10.1021/ja01245a015","id":"doi:10.1021/ja01245a015","key":"p3a46586b112c5ea6","title":"Specific Heats at Low Temperatures of Manganese Carbide and Manganese Dioxide<sup>1</sup>","year":1943},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"out","edge_id":"e53a88c6b4b195db6","other":{"doi":"10.1021/ja01245a016","id":"doi:10.1021/ja01245a016","key":"p80448434748845d4","title":"Heats of Formation of Manganomanganic Oxide and Manganese Dioxide<sup>1</sup>","year":1943},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"out","edge_id":"e68ec449ee60073f1","other":{"doi":"10.1021/ja01260a007","id":"doi:10.1021/ja01260a007","key":"pa8e4f0bf4bdd5807","title":"High-temperature Heat Content of Mn<sub>3</sub>O<sub>4</sub>, MnSiO<sub>3</sub> and Mn<sub>3</sub>C<sup>1</sup>","year":1942},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"out","edge_id":"e3f44377db7d7bb56","other":{"doi":"10.1021/ja01641a063","id":"doi:10.1021/ja01641a063","key":"p9a0ddc9313314d52","title":"Low-temperature Heat Capacities and Entropies at 298.16°K. of Manganese Sesquioxide and Niobium Pentoxide","year":1954},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"out","edge_id":"e5e927259e136f487","other":{"doi":"10.1103/physrevb.1.3763","id":"doi:10.1103/physrevb.1.3763","key":"p47db3ebf8b6535a6","title":"Magnetic and Crystallographic Transitions in<mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\"><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant=\"normal\">Sc</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>,<mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\"><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant=\"normal\">Cr</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>, and<mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\"><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant=\"normal\">Ga</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>Substituted<mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=\"normal\">Mn</mml:mi></mml:mrow><mml:mrow><mml:mn>2</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\"><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=\"normal\">O</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>","year":1970},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"out","edge_id":"ea139dd2c98f78b01","other":{"doi":"10.1111/j.1151-2916.1960.tb13630.x","id":"doi:10.1111/j.1151-2916.1960.tb13630.x","key":"p55406a63930e38d7","title":"Solid‐Solid and Solid‐Vapor Reactions and a New Phase in the System Mn‐O","year":1960},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"out","edge_id":"e32f01ff6f02e6517","other":{"doi":"10.1149/1.2411434","id":"doi:10.1149/1.2411434","key":"pf82fc4c3c37a9ee1","title":"Thermodynamic Properties of the Oxides of Fe, Ni, Pb, Cu, and Mn, by EMF Measurements","year":1968},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"out","edge_id":"e05b8e818b5736b81","other":{"doi":"10.1149/1.2423551","id":"doi:10.1149/1.2423551","key":"p3176934b8b1530a3","title":"Equilibrium Pressures of Oxygen over MnO[sub 2]-Mn[sub 2]O[sub 3] at Various Temperatures","year":1965},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"out","edge_id":"e770aa4fecdae9251","other":{"doi":"10.1179/cmq.1966.5.2.109","id":"doi:10.1179/cmq.1966.5.2.109","key":"p9df7d12f665b85d0","title":"Thermodynamics of the Mn-S-O System Between 1000° K and 1250° K","year":1966},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"out","edge_id":"eb0515d1d7e44bc99","other":{"doi":"10.1179/cmq.1967.6.1.71","id":"doi:10.1179/cmq.1967.6.1.71","key":"p9bbe69cb9db464ec","title":"Use of Thermal Conductivity Gas Analysis for Thermodynamic Measurements on the Dissociation of CuO, Mn<sub>2</sub>O<sub>3</sub>and MnO<sub>2</sub>","year":1967},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"count":null,"direction":"out","edge_id":"e85be94b5ed957aa9","other":{"doi":"10.2475/ajs.258.1.66","id":"doi:10.2475/ajs.258.1.66","key":"p53f38913e436e1ee","title":"Studies in the system Mn-O--The Mn 2 O 3 -Mn 3 O 4 and Mn 3 O 4 -MnO equilibria","year":1960},"provenance":{"source":"crossref_reference_list"},"type":"cited_by_crossref"},{"attrs":{"citation_status":{"resolved":7},"evidence_class":{"experimental":1,"model":6},"n_values":7,"n_values_accepted":6,"property":{"SM":6,"TRANSITION_TEMPERATURE":1},"systems":["MN-O"]},"count":7,"direction":"in","edge_id":"ea4a95ff907c61193","other":{"doi":"10.1007/s11669-003-0004-6","id":"doi:10.1007/s11669-003-0004-6","key":"p8bbb0a4b49a65084","title":"Assessment of the Mn-O system","year":2003},"provenance":{"dataset":"orchid-data/literature/orchid-literature.jsonl.gz","method":"record.cited_sources (reference printed for the value in the containing paper)","source":"orchid_extraction"},"type":"cites"},{"attrs":{"citation_status":{"resolved":1},"evidence_class":{"experimental":1},"n_values":1,"n_values_accepted":1,"property":{"SM":1},"systems":["MN-O"]},"count":1,"direction":"in","edge_id":"e809403053d226a56","other":{"doi":"10.1007/s11669-009-9643-6","id":"doi:10.1007/s11669-009-9643-6","key":"pa146cac250606511","title":"Thermodynamic Assessment of the Fe-Mn-O System","year":2010},"provenance":{"dataset":"orchid-data/literature/orchid-literature.jsonl.gz","method":"record.cited_sources (reference printed for the value in the containing paper)","source":"orchid_extraction"},"type":"cites"},{"attrs":{"citation_status":{"resolved":7},"evidence_class":{"experimental":1,"model":6},"n_values":7,"n_values_accepted":6,"property":{"SM":6,"TRANSITION_TEMPERATURE":1},"systems":["MN-O"]},"count":7,"direction":"out","edge_id":"efc9732165c26163e","other":{"doi":"10.1007/s11669-003-0004-6","id":"doi:10.1007/s11669-003-0004-6","key":"p8bbb0a4b49a65084","title":"Assessment of the Mn-O system","year":2003},"provenance":{"dataset":"orchid-data/literature/orchid-literature.jsonl.gz","method":"record.cited_sources (reference printed for the value in the containing paper)","source":"orchid_extraction"},"type":"used_in_assessment"},{"attrs":{"citation_status":{"resolved":1},"evidence_class":{"experimental":1},"n_values":1,"n_values_accepted":1,"property":{"SM":1},"systems":["MN-O"]},"count":1,"direction":"out","edge_id":"e8365e4fd59e65edc","other":{"doi":"10.1007/s11669-009-9643-6","id":"doi:10.1007/s11669-009-9643-6","key":"pa146cac250606511","title":"Thermodynamic Assessment of the Fe-Mn-O System","year":2010},"provenance":{"dataset":"orchid-data/literature/orchid-literature.jsonl.gz","method":"record.cited_sources (reference printed for the value in the containing paper)","source":"orchid_extraction"},"type":"used_in_assessment"}]}
