{"assessments":[{"data_papers_used":[],"doi":null,"id":"nodoi:5d91ecf9c7d70aaa","key":"pca87013cf3049cb4","n_data_papers_used":0,"n_values_from_cited_papers":0,"reassesses":[],"tdb_files":["TiB-94Bat-LB.tdb"],"title":"C. Baetzner, PhD thesis, Univ. Stuttgart, Germany, 1994.","values_reported":0,"year":1994},{"data_papers_used":[{"doi":"10.1107/s0567740875004268","evidence_class":{"experimental":4},"id":"doi:10.1107/s0567740875004268","key":"p559821fa71c96e28","n_values":4,"n_values_accepted":4,"title":"Struktur des tetragonalen (B<sub>12</sub>)<sub>4</sub>B<sub>2</sub>Ti<sub>1,3...2,0</sub>","year":1975}],"doi":"10.1007/bf02646248","id":"doi:10.1007/bf02646248","key":"p6de580cb51c7681b","n_data_papers_used":1,"n_values_from_cited_papers":4,"reassesses":[],"tdb_files":[],"title":"A critical assessment and thermodynamic calculation of the boron-carbon-titanium (B-C-Ti) ternary system","values_reported":183,"year":1995},{"data_papers_used":[],"doi":"10.1007/bf02646757","id":"doi:10.1007/bf02646757","key":"pf0d52c25235f74b8","n_data_papers_used":0,"n_values_from_cited_papers":0,"reassesses":[],"tdb_files":[],"title":"Critical assessment and thermodynamic calculation of the ternary system boron-hafnium-titanium (B-Hf-Ti)","values_reported":92,"year":1997},{"data_papers_used":[],"doi":null,"id":"nodoi:485a6c7bb39c92ba","key":"paaee7588859f6f54","n_data_papers_used":0,"n_values_from_cited_papers":0,"reassesses":[],"tdb_files":[],"title":"COST 507: Thermochemical database for light metal alloys, Volume 2","values_reported":379,"year":1998},{"data_papers_used":[{"doi":"10.1007/bf00899796","evidence_class":{"model":3},"id":"doi:10.1007/bf00899796","key":"peb589df2fb373f80","n_values":3,"n_values_accepted":3,"title":"Ein Beitrag zum Dreistoff Titan-Molybd�n-Bor","year":1960},{"doi":"10.1021/j100814a027","evidence_class":{"experimental":3},"id":"doi:10.1021/j100814a027","key":"pc0d9475d7e019873","n_values":3,"n_values_accepted":3,"title":"MASS SPECTROMETRIC STUDY OF THE VAPORIZATION OF THE TITANIUM-BORON SYSTEM<sup>1</sup>","year":1962},{"doi":"10.1107/s0365110x5400014x","evidence_class":{"experimental":3},"id":"doi:10.1107/s0365110x5400014x","key":"p211b5e3b06e5df7b","n_values":3,"n_values_accepted":3,"title":"The crystal structure of TiB","year":1954},{"doi":"10.1111/j.1151-2916.1986.tb04701.x","evidence_class":{"experimental":3},"id":"doi:10.1111/j.1151-2916.1986.tb04701.x","key":"p9c7ab5f96b5e7fcf","n_values":3,"n_values_accepted":3,"title":"Experimental Evidence for the Existence of the Ti\n                    <sub>3</sub>\n                    B\n                    <sub>4</sub>\n                    Phase","year":1986},{"doi":"10.1002/zaac.19522680308","evidence_class":{"experimental":1},"id":"doi:10.1002/zaac.19522680308","key":"pebe662c557fcabf9","n_values":1,"n_values_accepted":1,"title":"Über ein neues Verfahren zur Herstellung von Metallboriden der Übergangsmetalle, insbesondere von Titan‐und Zirkonborid","year":1952},{"doi":"10.1016/0001-6160(54)90090-5","evidence_class":{"experimental":1},"id":"doi:10.1016/0001-6160(54)90090-5","key":"pc82982bd02011c4c","n_values":1,"n_values_accepted":1,"title":"Transition metal diborides","year":1954},{"doi":"10.1016/0042-207x(95)00080-1","evidence_class":{"experimental":1},"id":"doi:10.1016/0042-207x(95)00080-1","key":"pe0a274df3a4bfcd1","n_values":1,"n_values_accepted":1,"title":"Phase formation in the N-B-Ti system","year":1995},{"doi":"10.1021/j100829a025","evidence_class":{"experimental":1},"id":"doi:10.1021/j100829a025","key":"p32d82cd96224f1c7","n_values":1,"n_values_accepted":1,"title":"THE HEAT OF FORMATION OF TITANIUM DIBORIDE: EXPERIMENTAL AND ANALYTICAL RESOLUTION OF LITERATURE CONFLICT","year":1961},{"doi":"10.1116/1.573700","evidence_class":{"experimental":1},"id":"doi:10.1116/1.573700","key":"p8339aa56a8848960","n_values":1,"n_values_accepted":1,"title":"Material selection for hard coatings","year":1986},{"doi":"10.1149/1.2430108","evidence_class":{"experimental":1},"id":"doi:10.1149/1.2430108","key":"p022b3d6ba493685b","n_values":1,"n_values_accepted":1,"title":"The Thermodynamic Stability of Refractory Borides","year":1955}],"doi":"10.1016/j.jallcom.2003.09.017","id":"doi:10.1016/j.jallcom.2003.09.017","key":"pa2147ea36149ae8f","n_data_papers_used":10,"n_values_from_cited_papers":18,"reassesses":[],"tdb_files":["TiB-04Ma.tdb"],"title":"Thermodynamic assessment of the Ti–B system","values_reported":65,"year":2004},{"data_papers_used":[{"doi":"10.1016/j.jallcom.2003.09.017","evidence_class":{"model":6},"id":"doi:10.1016/j.jallcom.2003.09.017","key":"pa2147ea36149ae8f","n_values":6,"n_values_accepted":6,"title":"Thermodynamic assessment of the Ti–B system","year":2004},{"doi":"10.1002/zaac.19522680308","evidence_class":{"experimental":1},"id":"doi:10.1002/zaac.19522680308","key":"pebe662c557fcabf9","n_values":1,"n_values_accepted":1,"title":"Über ein neues Verfahren zur Herstellung von Metallboriden der Übergangsmetalle, insbesondere von Titan‐und Zirkonborid","year":1952},{"doi":"10.1016/0001-6160(54)90090-5","evidence_class":{"experimental":1},"id":"doi:10.1016/0001-6160(54)90090-5","key":"pc82982bd02011c4c","n_values":1,"n_values_accepted":1,"title":"Transition metal diborides","year":1954}],"doi":"10.1016/j.jallcom.2006.10.034","id":"doi:10.1016/j.jallcom.2006.10.034","key":"p3e009bfe214286ec","n_data_papers_used":3,"n_values_from_cited_papers":8,"reassesses":["doi:10.1016/j.jallcom.2003.09.017"],"tdb_files":["TiB-08Wit.tdb"],"title":"The Al–B–Nb–Ti system","values_reported":72,"year":2008},{"data_papers_used":[{"doi":"10.1016/j.jallcom.2007.02.030","evidence_class":{"model":20},"id":"doi:10.1016/j.jallcom.2007.02.030","key":"pa5212a78d3ea2892","n_values":20,"n_values_accepted":20,"title":"The Al–B–Nb–Ti system","year":2008}],"doi":"10.2320/matertrans.mc200820","id":"doi:10.2320/matertrans.mc200820","key":"pfa717b52f41e70d2","n_data_papers_used":1,"n_values_from_cited_papers":20,"reassesses":["doi:10.1016/j.jallcom.2006.10.034"],"tdb_files":["TiB-09Nak.tdb"],"title":"Thermodynamic Analysis of the Nb&amp;ndash;Ti&amp;ndash;B Ternary Phase Diagram","values_reported":84,"year":2009},{"data_papers_used":[],"doi":"10.1016/j.calphad.2011.10.003","id":"doi:10.1016/j.calphad.2011.10.003","key":"p5418ef98e6d539e4","n_data_papers_used":0,"n_values_from_cited_papers":0,"reassesses":["doi:10.1016/j.jallcom.2003.09.017","doi:10.1016/j.jallcom.2006.10.034"],"tdb_files":["TiB-11Cac.tdb"],"title":"Equilibrium between MB2 (M=Ti,Zr,Hf) UHTC and Ni: A thermodynamic database for the B–Hf–Ni–Ti–Zr system","values_reported":146,"year":2011},{"data_papers_used":[],"doi":"10.1016/j.jallcom.2015.09.158","id":"doi:10.1016/j.jallcom.2015.09.158","key":"pee3968ff9043ef8d","n_data_papers_used":0,"n_values_from_cited_papers":0,"reassesses":["doi:10.1016/j.jallcom.2006.10.034"],"tdb_files":["TiB-16Wit.tdb"],"title":"Thermodynamic modelling of the ternary B–Mo–Ti system with refined B–Mo description","values_reported":91,"year":2016},{"data_papers_used":[],"doi":"10.1016/j.jallcom.2019.05.341","id":"doi:10.1016/j.jallcom.2019.05.341","key":"pf3538e517ecb4dba","n_data_papers_used":0,"n_values_from_cited_papers":0,"reassesses":["doi:10.1016/j.jallcom.2006.10.034","doi:10.1016/j.jallcom.2015.09.158"],"tdb_files":["TiB-19Wit.tdb"],"title":"Experimental study and thermodynamic re-modelling of the constituent binaries and ternary B–Fe–Ti system","values_reported":322,"year":2019}],"cite_as":{"also_cite":["the papers themselves when you use their data (doi / citation of each bibliography record)"],"bibtex":"@misc{orchid_bibliography_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Bibliography: papers and typed citation relations}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736021},\n  url       = {https://doi.org/10.5281/zenodo.23736021},\n  note      = {Version 1, machine-extracted}\n}","dataset":"bibliography","doi":"10.5281/zenodo.23736021","licence_note":"Crossref bibliographic metadata: CC0; ORCHID-derived fields (roles, evidence counts, relations): CC BY 4.0","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: roles and evidence counts derive from machine-extracted literature values and link tables; bibliographic fields are Crossref metadata as deposited (DOIs matched from printed references checked against Crossref: doi_match; mismatches dropped).","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Bibliography: papers and typed citation relations (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736021","title":"ORCHID-Bibliography: papers and typed citation relations","url":"https://doi.org/10.5281/zenodo.23736021","version":"2026.10"},"elements":["B","TI"],"papers":[{"doi":"10.1002/zaac.19522680308","id":"doi:10.1002/zaac.19522680308","key":"pebe662c557fcabf9","title":"Über ein neues Verfahren zur Herstellung von Metallboriden der Übergangsmetalle, insbesondere von Titan‐und Zirkonborid","year":1952},{"doi":"10.1007/bf00899796","id":"doi:10.1007/bf00899796","key":"peb589df2fb373f80","title":"Ein Beitrag zum Dreistoff Titan-Molybd�n-Bor","year":1960},{"doi":"10.1007/bf02646248","id":"doi:10.1007/bf02646248","key":"p6de580cb51c7681b","title":"A critical assessment and thermodynamic calculation of the boron-carbon-titanium (B-C-Ti) ternary system","year":1995},{"doi":"10.1007/bf02646757","id":"doi:10.1007/bf02646757","key":"pf0d52c25235f74b8","title":"Critical assessment and thermodynamic calculation of the ternary system boron-hafnium-titanium (B-Hf-Ti)","year":1997},{"doi":"10.1016/0001-6160(54)90090-5","id":"doi:10.1016/0001-6160(54)90090-5","key":"pc82982bd02011c4c","title":"Transition metal diborides","year":1954},{"doi":"10.1016/0042-207x(95)00080-1","id":"doi:10.1016/0042-207x(95)00080-1","key":"pe0a274df3a4bfcd1","title":"Phase formation in the N-B-Ti system","year":1995},{"doi":"10.1016/j.calphad.2011.10.003","id":"doi:10.1016/j.calphad.2011.10.003","key":"p5418ef98e6d539e4","title":"Equilibrium between MB2 (M=Ti,Zr,Hf) UHTC and Ni: A thermodynamic database for the B–Hf–Ni–Ti–Zr system","year":2011},{"doi":"10.1016/j.jallcom.2003.09.017","id":"doi:10.1016/j.jallcom.2003.09.017","key":"pa2147ea36149ae8f","title":"Thermodynamic assessment of the Ti–B system","year":2004},{"doi":"10.1016/j.jallcom.2006.10.034","id":"doi:10.1016/j.jallcom.2006.10.034","key":"p3e009bfe214286ec","title":"The Al–B–Nb–Ti system","year":2008},{"doi":"10.1016/j.jallcom.2007.02.030","id":"doi:10.1016/j.jallcom.2007.02.030","key":"pa5212a78d3ea2892","title":"The Al–B–Nb–Ti system","year":2008},{"doi":"10.1016/j.jallcom.2015.09.158","id":"doi:10.1016/j.jallcom.2015.09.158","key":"pee3968ff9043ef8d","title":"Thermodynamic modelling of the ternary B–Mo–Ti system with refined B–Mo description","year":2016},{"doi":"10.1016/j.jallcom.2019.05.341","id":"doi:10.1016/j.jallcom.2019.05.341","key":"pf3538e517ecb4dba","title":"Experimental study and thermodynamic re-modelling of the constituent binaries and ternary B–Fe–Ti system","year":2019},{"doi":"10.1021/j100814a027","id":"doi:10.1021/j100814a027","key":"pc0d9475d7e019873","title":"MASS SPECTROMETRIC STUDY OF THE VAPORIZATION OF THE TITANIUM-BORON SYSTEM<sup>1</sup>","year":1962},{"doi":"10.1021/j100829a025","id":"doi:10.1021/j100829a025","key":"p32d82cd96224f1c7","title":"THE HEAT OF FORMATION OF TITANIUM DIBORIDE: EXPERIMENTAL AND ANALYTICAL RESOLUTION OF LITERATURE CONFLICT","year":1961},{"doi":"10.1107/s0365110x5400014x","id":"doi:10.1107/s0365110x5400014x","key":"p211b5e3b06e5df7b","title":"The crystal structure of TiB","year":1954},{"doi":"10.1107/s0567740875004268","id":"doi:10.1107/s0567740875004268","key":"p559821fa71c96e28","title":"Struktur des tetragonalen (B<sub>12</sub>)<sub>4</sub>B<sub>2</sub>Ti<sub>1,3...2,0</sub>","year":1975},{"doi":"10.1111/j.1151-2916.1986.tb04701.x","id":"doi:10.1111/j.1151-2916.1986.tb04701.x","key":"p9c7ab5f96b5e7fcf","title":"Experimental Evidence for the Existence of the Ti\n                    <sub>3</sub>\n                    B\n                    <sub>4</sub>\n                    Phase","year":1986},{"doi":"10.1116/1.573700","id":"doi:10.1116/1.573700","key":"p8339aa56a8848960","title":"Material selection for hard coatings","year":1986},{"doi":"10.1149/1.2430108","id":"doi:10.1149/1.2430108","key":"p022b3d6ba493685b","title":"The Thermodynamic Stability of Refractory Borides","year":1955},{"doi":"10.1361/154770306x109953","id":"doi:10.1361/154770306x109953","key":"p8ef8c29e000a8228","title":"B−Ti (Boron-Titanium)","year":2006},{"doi":"10.2320/matertrans.mc200820","id":"doi:10.2320/matertrans.mc200820","key":"pfa717b52f41e70d2","title":"Thermodynamic Analysis of the Nb&amp;ndash;Ti&amp;ndash;B Ternary Phase Diagram","year":2009},{"doi":null,"id":"nodoi:485a6c7bb39c92ba","key":"paaee7588859f6f54","title":"COST 507: Thermochemical database for light metal alloys, Volume 2","year":1998},{"doi":null,"id":"nodoi:5d91ecf9c7d70aaa","key":"pca87013cf3049cb4","title":"C. Baetzner, PhD thesis, Univ. Stuttgart, Germany, 1994.","year":1994},{"doi":null,"id":"nodoi:7cf86a7d49ed0b9a","key":"pe12432e81fb7d4e9","title":"C. Baetzner, Thesis, Max Planck Institut--PML Stuttgart, Germany (1994).","year":1994}],"papers_by_role":{"cited_original_source":["doi:10.1002/zaac.19522680308","doi:10.1007/bf00899796","doi:10.1007/bf02646757","doi:10.1016/0001-6160(54)90090-5","doi:10.1016/0042-207x(95)00080-1","doi:10.1016/j.jallcom.2003.09.017","doi:10.1016/j.jallcom.2007.02.030","doi:10.1021/j100814a027","doi:10.1021/j100829a025","doi:10.1107/s0365110x5400014x","doi:10.1107/s0567740875004268","doi:10.1111/j.1151-2916.1986.tb04701.x","doi:10.1116/1.573700","doi:10.1149/1.2430108","nodoi:485a6c7bb39c92ba","nodoi:7cf86a7d49ed0b9a"],"corpus_assessment_read":["doi:10.1007/bf02646248","doi:10.1007/bf02646757","doi:10.1016/j.calphad.2011.10.003","doi:10.1016/j.jallcom.2003.09.017","doi:10.1016/j.jallcom.2006.10.034","doi:10.1016/j.jallcom.2015.09.158","doi:10.1016/j.jallcom.2019.05.341","doi:10.2320/matertrans.mc200820","nodoi:485a6c7bb39c92ba"],"discovery_lead":["doi:10.1016/j.calphad.2011.10.003","doi:10.1016/j.jallcom.2006.10.034","doi:10.1016/j.jallcom.2007.02.030","doi:10.1016/j.jallcom.2015.09.158","doi:10.1016/j.jallcom.2019.05.341","doi:10.2320/matertrans.mc200820"],"handbook_diagram_source":["doi:10.1361/154770306x109953"],"tdb_source_assessment":["doi:10.1007/bf02646248","doi:10.1007/bf02646757","doi:10.1016/j.calphad.2011.10.003","doi:10.1016/j.jallcom.2003.09.017","doi:10.1016/j.jallcom.2006.10.034","doi:10.1016/j.jallcom.2015.09.158","doi:10.1016/j.jallcom.2019.05.341","doi:10.2320/matertrans.mc200820","nodoi:5d91ecf9c7d70aaa"]},"system":"B-TI"}