{"assessments":[{"data_papers_used":[{"doi":"10.1016/0036-9748(71)90168-2","evidence_class":{"experimental":5},"id":"doi:10.1016/0036-9748(71)90168-2","key":"p9430e1267ab317ce","n_values":5,"n_values_accepted":4,"title":"Free energy of formation of Bi2O3","year":1971},{"doi":"10.1149/1.2403593","evidence_class":{"experimental":4},"id":"doi:10.1149/1.2403593","key":"p9992838188791a21","n_values":4,"n_values_accepted":3,"title":"Free Energy of Formation of Bi[sub 2]O[sub 3], Sb[sub 2]O[sub 3], and TeO[sub 2] from EMF Measurements","year":1973},{"doi":"10.2320/jinstmet1952.55.5_536","evidence_class":{"experimental":4},"id":"doi:10.2320/jinstmet1952.55.5_536","key":"p96909aed51e37321","n_values":4,"n_values_accepted":4,"title":"Activity Measurements of Liquid Ag-Bi Alloys by an EMF Method Using a Zirconia Electrolyte","year":1991},{"doi":"10.2320/jinstmet1952.56.8_900","evidence_class":{"experimental":4},"id":"doi:10.2320/jinstmet1952.56.8_900","key":"pf574094c51c356f3","n_values":4,"n_values_accepted":4,"title":"Activity of Liquid Tl-Bi Alloys Measured by an EMF Method Using Zirconia Electrolyte","year":1992},{"doi":"10.1016/0040-6031(80)87127-9","evidence_class":{"experimental":3},"id":"doi:10.1016/0040-6031(80)87127-9","key":"paa7018d5d6054571","n_values":3,"n_values_accepted":3,"title":"Diffusivity, activity and solubility of oxygen in liquid bismuth","year":1980},{"doi":"10.1021/je60035a021","evidence_class":{"experimental":2},"id":"doi:10.1021/je60035a021","key":"pc9078738178c02cb","n_values":2,"n_values_accepted":2,"title":"Enthalpy and entropy increments above 298.degree.K. for bismuth(III) bromide, bismuth(III) oxide, thallium(III) oxide, and thallium(I) oxide","year":1967},{"doi":"10.2475/ajs.s4-28.164.103","evidence_class":{"experimental":2},"id":"doi:10.2475/ajs.s4-28.164.103","key":"p21de79da315c0cfa","n_values":2,"n_values_accepted":1,"title":"Heat of formation of trisodium orthophosphate, trisodium orthoarsenate, the oxides of antimony, bismuth trioxide; and fourth paper on the heat of combination of acidic oxides with sodium oxide","year":1909},{"doi":"10.6028/jres.069a.023","evidence_class":{"experimental":2},"id":"doi:10.6028/jres.069a.023","key":"p8e9210711bead424","n_values":2,"n_values_accepted":2,"title":"Heats of transformations in bismuth oxide by differential thermal analysis","year":1965},{"doi":"10.1002/zaac.19623180307","evidence_class":{"experimental":1},"id":"doi:10.1002/zaac.19623180307","key":"p31e2063805916596","n_values":1,"n_values_accepted":1,"title":"Über Wismutoxide. III. Die Kristallstruktur der Hochtemperaturmodifikation von Wismut(III)‐oxid (δ‐Bi<sub>2</sub>O<sub>3</sub>)","year":1962},{"doi":"10.1002/zaac.19643280106","evidence_class":{"experimental":1},"id":"doi:10.1002/zaac.19643280106","key":"p68f8abe86f6ad23a","n_values":1,"n_values_accepted":1,"title":"Über Wismutoxide. VI. Überein Wismut (III)‐oxid mit höherem Sauerstoffgehalt (β‐Modifikation)","year":1964},{"doi":"10.1021/j100723a031","evidence_class":{"experimental":1},"id":"doi:10.1021/j100723a031","key":"pdb4c4b7043a480a7","n_values":1,"n_values_accepted":1,"title":"Phase transformations and electrical properties of bismuth sesquioxide","year":1969}],"doi":"10.1007/bf02667306","id":"doi:10.1007/bf02667306","key":"pb0ad97da11234547","n_data_papers_used":11,"n_values_from_cited_papers":29,"reassesses":[],"tdb_files":["BiO-95Ris-LB.tdb"],"title":"The bismuth-oxygen system","values_reported":86,"year":1995}],"cite_as":{"also_cite":["the papers themselves when you use their data (doi / citation of each bibliography record)"],"bibtex":"@misc{orchid_bibliography_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Bibliography: papers and typed citation relations}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736021},\n  url       = {https://doi.org/10.5281/zenodo.23736021},\n  note      = {Version 1, machine-extracted}\n}","dataset":"bibliography","doi":"10.5281/zenodo.23736021","licence_note":"Crossref bibliographic metadata: CC0; ORCHID-derived fields (roles, evidence counts, relations): CC BY 4.0","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: roles and evidence counts derive from machine-extracted literature values and link tables; bibliographic fields are Crossref metadata as deposited (DOIs matched from printed references checked against Crossref: doi_match; mismatches dropped).","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Bibliography: papers and typed citation relations (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736021","title":"ORCHID-Bibliography: papers and typed citation relations","url":"https://doi.org/10.5281/zenodo.23736021","version":"2026.10"},"elements":["BI","O"],"papers":[{"doi":"10.1002/zaac.19623180307","id":"doi:10.1002/zaac.19623180307","key":"p31e2063805916596","title":"Über Wismutoxide. III. Die Kristallstruktur der Hochtemperaturmodifikation von Wismut(III)‐oxid (δ‐Bi<sub>2</sub>O<sub>3</sub>)","year":1962},{"doi":"10.1002/zaac.19643280106","id":"doi:10.1002/zaac.19643280106","key":"p68f8abe86f6ad23a","title":"Über Wismutoxide. VI. 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Schaefer, \"Electrochemical Determination of Thermodynamic Properties of Bismuth Sesquioxide and Stannic Oxide,\" U.S. Bureau of Mines RI, 8906 (1984). 85Hih M. Hillert, B. Jansson, B. Sundman, andJ. Agren, \"ATwo-Sublattice Model for Molten Solutions with Different Tendency for lonization,\" Metall. Trans. A, 16, 261-266 (1985).","year":1985},{"doi":null,"id":"nodoi:1ea882563cefa59c","key":"pb631abae7a650b99","title":"B. lsecke and J. Osterwald, \"Equilibria Study in the BismuthOxygen System,\" Z. Phys. Chem. Neue Folge, 115, 17-24 (1979) in German.","year":1979},{"doi":null,"id":"nodoi:3c1df37f8076e4d0","key":"pca0e01d9a2459b4a","title":"A.V. Korobeinikova, V.A. Kholmov, and L.A. Rezmitskii, Vest. Mosk. Univ. Khim., 17(3), 381 (1976) in Russian.","year":1976},{"doi":null,"id":"nodoi:4cd7244852c26ef9","key":"pf68290e990fb580d","title":"G.M. Mehrotra, M.G. Frohberg, and M.L. Kapoor, \"Standard Free Energy of Formation of Bi203,\" Z Phys. Chem. Neue Folge, 99, 304-307 (1976). Journal of Phase Equilibria Vol. 16 No. 3 1995 233 S e c t i o n I: B a s i c a n d A p p l i e d R e s e a r c h","year":1995},{"doi":null,"id":"nodoi:6611a7d14589d217","key":"p1122d0f573268984","title":"Binary Alloy Phase Diagrams, 2nd ed., T.B. Massalski, H. Okamoto, P.R. Subramanian, and L. Kacprzak, ed., ASM International, Materials Park, OH, 770 (1990)","year":1990},{"doi":null,"id":"nodoi:66f309fdab45c1db","key":"pb484c8204033992b","title":"S. ltoh and T. Azakami, \"Activity Measurements of Liquid Bi-Sb Alloys by the EMF Method using Solid Electrolytes,\" J. Jpn. Inst. Met., 48, 293-301 (1984) in Japanese.","year":1984},{"doi":null,"id":"nodoi:869016ac21751a41","key":"p85df201fc275734f","title":"A.V.R. Rao and V.B. Tare, \"Determination of the Melting Point and Heat of Fusion of Bi203 by the Solid Electrolyte Technique,\" J. Electrochem. Soc. India, 22, 20-22 (1973). 7b'Med: J.W. Medernach, \"On the Structure of Evaporated Bismuth Oxide Thin Films,\" J. SolidState Chem., 15, 352-359 (1975).","year":1975}],"papers_by_role":{"cited_original_source":["doi:10.1002/zaac.19623180307","doi:10.1002/zaac.19643280106","doi:10.1016/0036-9748(71)90168-2","doi:10.1016/0040-6031(80)87127-9","doi:10.1021/j100723a031","doi:10.1021/je60035a021","doi:10.1149/1.2403593","doi:10.2320/jinstmet1952.55.5_536","doi:10.2320/jinstmet1952.56.8_900","doi:10.2475/ajs.s4-28.164.103","doi:10.6028/jres.069a.023","nodoi:059eeb95d3d100c6","nodoi:1ea882563cefa59c","nodoi:3c1df37f8076e4d0","nodoi:4cd7244852c26ef9","nodoi:66f309fdab45c1db","nodoi:869016ac21751a41"],"corpus_assessment_read":["doi:10.1007/bf02667306"],"handbook_diagram_source":["doi:10.1007/bf02667306","nodoi:6611a7d14589d217"],"tdb_source_assessment":["doi:10.1007/bf02667306"]},"system":"BI-O"}