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Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: roles and evidence counts derive from machine-extracted literature values and link tables; bibliographic fields are Crossref metadata as deposited (DOIs matched from printed references checked against Crossref: doi_match; mismatches dropped).","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Bibliography: papers and typed citation relations (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736021","title":"ORCHID-Bibliography: papers and typed citation relations","url":"https://doi.org/10.5281/zenodo.23736021","version":"2026.10"},"elements":["CA","O","SI"],"papers":[{"doi":"10.1002/zaac.19322080102","id":"doi:10.1002/zaac.19322080102","key":"pa1c2e85864a791f6","title":"Zur Thermochemie der Metasilikate des Calciums und Magnesiums und des Diopsids","year":1932},{"doi":"10.1007/s002690050253","id":"doi:10.1007/s002690050253","key":"p9829a6014d353dbf","title":"Thermodynamics of diopside, anorthite, pseudowollastonite, CaMgGeO 4 olivine, and åkermanite up to near the melting point","year":2000},{"doi":"10.1016/j.cemconres.2023.107309","id":"doi:10.1016/j.cemconres.2023.107309","key":"p5c5110ba5b8e6c5b","title":"CaO-SiO2 assessment using 3rd generation CALPHAD models","year":2023},{"doi":"10.1021/j100826a007","id":"doi:10.1021/j100826a007","key":"p43ba5cb801802046","title":"THERMODYNAMICS OF THE SOLID SYSTEM CaO—SiO<sub>2</sub> FROM ELECTROMOTIVE FORCE DATA","year":1961},{"doi":"10.1021/ja01577a028","id":"doi:10.1021/ja01577a028","key":"p8e21fd3a20fa6285","title":"Low Temperature Heat Capacities and Entropies at 298.15°K. of Some Crystalline Silicates Containing Calcium","year":1957},{"doi":"10.1029/90jb02172","id":"doi:10.1029/90jb02172","key":"p77fdc09e2468192e","title":"High‐temperature heat capacity and premelting of minerals in the system MgO‐CaO‐Al<sub>2</sub>O<sub>3</sub>‐SiO<sub>2</sub>","year":1991},{"doi":"10.1063/1.555645","id":"doi:10.1063/1.555645","key":"ped503ab6440d07df","title":"Thermodynamic tabulations for selected phases in the system CaO-Al2O3- SiO2-H2 at 101.325 kPa (1 atm) between 273.15 and 1800 K","year":1981},{"doi":"10.2475/ajs.s4-39.229.1","id":"doi:10.2475/ajs.s4-39.229.1","key":"pcfb00f2d9f357afb","title":"The ternary system CaO-Al 2 O 3 -SiO 2 , with optical study by F. 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