{"assessments":[{"data_papers_used":[{"doi":"10.1149/1.2426509","evidence_class":{"experimental":4,"model":1},"id":"doi:10.1149/1.2426509","key":"pae0932f03c120aaf","n_values":5,"n_values_accepted":1,"title":"The Free Energy of Formation of Palladium Oxide","year":1967},{"doi":"10.1016/0016-7037(96)00115-9","evidence_class":{"experimental":2,"model":1},"id":"doi:10.1016/0016-7037(96)00115-9","key":"p98a7c16ef88eae21","n_values":3,"n_values_accepted":1,"title":"Gibbs free energy of formation and heat capacity of PdO: A new calibration of the PdPdO buffer to high temperatures and pressures","year":1996},{"doi":"10.1361/105497199770340545","evidence_class":{"experimental":1,"model":1},"id":"doi:10.1361/105497199770340545","key":"pf905476fc26423ba","n_values":2,"n_values_accepted":1,"title":"System Nd-Pd-O: Phase diagram and thermodynamic properties of oxides using a solid-state cell with advanced features","year":1999},{"doi":"10.1524/zpch.1970.71.1_3.142","evidence_class":{"experimental":1,"model":1},"id":"doi:10.1524/zpch.1970.71.1_3.142","key":"p6eca6f773055641f","n_values":2,"n_values_accepted":1,"title":"Freie Bildungsenthalpie von Palladiumoxid*","year":1970},{"doi":"10.1007/bf00613213","evidence_class":{"experimental":1},"id":"doi:10.1007/bf00613213","key":"p2f49fb07c29d72dc","n_values":1,"n_values_accepted":0,"title":"Measurement and regulation of oxygen content in gases using solid electrolyte cells. 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Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: roles and evidence counts derive from machine-extracted literature values and link tables; bibliographic fields are Crossref metadata as deposited (DOIs matched from printed references checked against Crossref: doi_match; mismatches dropped).","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Bibliography: papers and typed citation relations (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736021","title":"ORCHID-Bibliography: papers and typed citation relations","url":"https://doi.org/10.5281/zenodo.23736021","version":"2026.10"},"elements":["O","PD"],"papers":[{"doi":"10.1007/bf00613213","id":"doi:10.1007/bf00613213","key":"p2f49fb07c29d72dc","title":"Measurement and regulation of oxygen content in gases using solid electrolyte cells. III. 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