{"assessments":[{"data_papers_used":[{"doi":"10.1016/0022-3115(61)90075-7","evidence_class":{"experimental":21},"id":"doi:10.1016/0022-3115(61)90075-7","key":"p0a3b62a91e7a06a7","n_values":21,"n_values_accepted":21,"title":"Untersuchungen in system Zirkonium-Sauerstoff teil 2 untersuchungen zur kinetik der reaktion zwischen Zirkonium und sauerstoff, sowie über die konstitution des systems Zirkonium-Sauerstoff","year":1961},{"doi":"10.1016/s0039-6028(87)80071-7","evidence_class":{"experimental":6},"id":"doi:10.1016/s0039-6028(87)80071-7","key":"p3d92d44abd6bed7d","n_values":6,"n_values_accepted":6,"title":"AES and XPS studies of oxygen stabilized alpha zirconium","year":1987}],"doi":"10.1016/s0022-3115(98)00450-4","id":"doi:10.1016/s0022-3115(98)00450-4","key":"p0e9e299d99920396","n_data_papers_used":2,"n_values_from_cited_papers":27,"reassesses":[],"tdb_files":["ZrO-98Che.tdb"],"title":"Thermodynamic modelling of the O–U–Zr system","values_reported":251,"year":1998},{"data_papers_used":[],"doi":"10.1515/ijmr-2001-0140","id":"doi:10.1515/ijmr-2001-0140","key":"p269c6ebede6c96de","n_data_papers_used":0,"n_values_from_cited_papers":0,"reassesses":["doi:10.1016/s0022-3115(98)00450-4"],"tdb_files":["ZrO-01Lia-LB.tdb"],"title":"Thermodynamic Assessment of the Zr–O Binary System","values_reported":0,"year":2001},{"data_papers_used":[],"doi":"10.1016/s0364-5916(02)00027-5","id":"doi:10.1016/s0364-5916(02)00027-5","key":"pf4ad51374e16282f","n_data_papers_used":0,"n_values_from_cited_papers":0,"reassesses":[],"tdb_files":["ZrO-02Arr.tdb"],"title":"Thermodynamic modeling of the ZrO system","values_reported":28,"year":2002},{"data_papers_used":[],"doi":"10.1016/j.calphad.2004.03.005","id":"doi:10.1016/j.calphad.2004.03.005","key":"pa70f19e4e0a48ad3","n_data_papers_used":0,"n_values_from_cited_papers":0,"reassesses":[],"tdb_files":[],"title":"Progress in the thermodynamic modelling of the O–U–Zr ternary system","values_reported":25,"year":2004},{"data_papers_used":[{"doi":"10.1007/bf02881546","evidence_class":{"model":10},"id":"doi:10.1007/bf02881546","key":"p8bc6dcbd1d529a58","n_values":10,"n_values_accepted":8,"title":"The O−Zr (Oxygen-Zirconium) system","year":1986},{"doi":"10.1016/s0364-5916(02)00027-5","evidence_class":{"model":10},"id":"doi:10.1016/s0364-5916(02)00027-5","key":"pf4ad51374e16282f","n_values":10,"n_values_accepted":6,"title":"Thermodynamic modeling of the ZrO system","year":2002},{"doi":"10.1111/j.1151-2916.1992.tb04384.x","evidence_class":{"model":6},"id":"doi:10.1111/j.1151-2916.1992.tb04384.x","key":"p30951940ad9954d2","n_values":6,"n_values_accepted":6,"title":"Thermodynamic Calculation of the Zirconia–Calcia System","year":1992},{"doi":"10.1524/zpch.1998.207.part_1_2.059","evidence_class":{"experimental":2,"model":1},"id":"doi:10.1524/zpch.1998.207.part_1_2.059","key":"p3ca4727e5017a81b","n_values":3,"n_values_accepted":3,"title":"The Energetics of Cubic Zirconia from Solution Calorimetry of Yttria- and Calcia-Stabilized Zirconia","year":1998},{"doi":"10.1557/jmr.2003.0125","evidence_class":{"experimental":2,"model":1},"id":"doi:10.1557/jmr.2003.0125","key":"p8bd855a4f91a1d7b","n_values":3,"n_values_accepted":3,"title":"Enthalpy of formation of cubic yttria-stabilized zirconia","year":2003},{"doi":"10.1006/jcht.1998.0481","evidence_class":{"experimental":2},"id":"doi:10.1006/jcht.1998.0481","key":"p7347662464d9a5c4","n_values":2,"n_values_accepted":2,"title":"Heat capacity and thermodynamic functions of zirconia and yttria-stabilized zirconia","year":1999},{"doi":"10.1016/0038-092x(66)90014-4","evidence_class":{"experimental":2},"id":"doi:10.1016/0038-092x(66)90014-4","key":"p294b620f63d88791","n_values":2,"n_values_accepted":2,"title":"Heating curves of solids obtained by a solar furnace","year":1966},{"doi":"10.1016/j.calphad.2004.03.005","evidence_class":{"model":2},"id":"doi:10.1016/j.calphad.2004.03.005","key":"pa70f19e4e0a48ad3","n_values":2,"n_values_accepted":1,"title":"Progress in the thermodynamic modelling of the O–U–Zr ternary system","year":2004},{"doi":"10.1002/zaac.19322040105","evidence_class":{"experimental":1},"id":"doi:10.1002/zaac.19322040105","key":"p187f95f6e33f063d","n_values":1,"n_values_accepted":1,"title":"Über die Schmelzpunkte des Zirkonoxydes und des Hafniumoxydes","year":1932},{"doi":"10.1007/bf01591647","evidence_class":{"experimental":1},"id":"doi:10.1007/bf01591647","key":"pd8c1b2eefd4299c2","n_values":1,"n_values_accepted":1,"title":"Der Schmelzpunkt des Hafniumoxydes","year":1925},{"doi":"10.1016/0022-3115(70)90218-7","evidence_class":{"experimental":1},"id":"doi:10.1016/0022-3115(70)90218-7","key":"p8ad557e17087c238","n_values":1,"n_values_accepted":1,"title":"The melting point of pure zirconia","year":1970},{"doi":"10.1016/s0022-3115(98)00450-4","evidence_class":{"model":1},"id":"doi:10.1016/s0022-3115(98)00450-4","key":"p0e9e299d99920396","n_values":1,"n_values_accepted":1,"title":"Thermodynamic modelling of the O–U–Zr system","year":1998},{"doi":"10.1021/j100792a052","evidence_class":{"experimental":1},"id":"doi:10.1021/j100792a052","key":"p64da8a9d5017debc","n_values":1,"n_values_accepted":1,"title":"The Heats of Formation of Zirconium Diboride and Dioxide\n                    <sup>1</sup>","year":1964},{"doi":"10.1021/ja01161a106","evidence_class":{"experimental":1},"id":"doi:10.1021/ja01161a106","key":"pc7ed6975fea56ed9","n_values":1,"n_values_accepted":1,"title":"High-Temperature Heat Contents of Some Zirconium-containing Substances\n                    <sup>1</sup>","year":1950},{"doi":"10.1111/j.1151-2916.1990.tb07619.x","evidence_class":{"experimental":1},"id":"doi:10.1111/j.1151-2916.1990.tb07619.x","key":"pcb88a8eef323e090","n_values":1,"n_values_accepted":1,"title":"Heat Capacity of Monoclinic Zirconia between 2.75 and 350 K","year":1990},{"doi":"10.1111/j.1151-2916.1995.tb08642.x","evidence_class":{"experimental":1},"id":"doi:10.1111/j.1151-2916.1995.tb08642.x","key":"p1b55b9f2f49929b1","n_values":1,"n_values_accepted":1,"title":"Tetragonal—Monoclinic Phase Transition Enthalpy and Temperature of ZrO\n                    <sub>2</sub>\n                    ‐CeO\n                    <sub>2</sub>\n                    Solid Solutions","year":1995},{"doi":"10.1557/jmr.2003.0406","evidence_class":{"experimental":1},"id":"doi:10.1557/jmr.2003.0406","key":"p530b7076363efb37","n_values":1,"n_values_accepted":1,"title":"Thermodynamics of the tetragonal-to-monoclinic phase transformation in fine and nanocrystalline yttria-stabilized zirconia powders","year":2003}],"doi":"10.1016/j.calphad.2004.09.002","id":"doi:10.1016/j.calphad.2004.09.002","key":"p01e8363fd6eea0bc","n_data_papers_used":17,"n_values_from_cited_papers":47,"reassesses":["doi:10.1016/j.ssi.2004.02.017","doi:10.1016/s0022-3115(98)00450-4","doi:10.1016/s0364-5916(02)00027-5"],"tdb_files":["ZrO-04Wan.tdb"],"title":"On the thermodynamic modeling of the Zr–O system","values_reported":93,"year":2004},{"data_papers_used":[],"doi":"10.1016/j.ssi.2004.02.017","id":"doi:10.1016/j.ssi.2004.02.017","key":"p9b897dffc64a1d2e","n_data_papers_used":0,"n_values_from_cited_papers":0,"reassesses":[],"tdb_files":["ZrO-04Che.tdb"],"title":"Thermodynamic modeling of the ZrO2–YO1.5 system","values_reported":45,"year":2004},{"data_papers_used":[],"doi":null,"id":"nodoi:b1c27cbf8c370705","key":"pc955337829aecc2d","n_data_papers_used":0,"n_values_from_cited_papers":0,"reassesses":[],"tdb_files":["ZrO-06Wan.tdb"],"title":"C. Wang, PhD Thesis, Stuttgart, 2006.","values_reported":0,"year":2006},{"data_papers_used":[],"doi":"10.1016/j.jnucmat.2006.10.008","id":"doi:10.1016/j.jnucmat.2006.10.008","key":"p54136e6daa6ed3c1","n_data_papers_used":0,"n_values_from_cited_papers":0,"reassesses":[],"tdb_files":[],"title":"Thermodynamic evaluation of the Nb–O–Zr system","values_reported":19,"year":2007},{"data_papers_used":[],"doi":"10.1016/j.jnucmat.2022.154180","id":"doi:10.1016/j.jnucmat.2022.154180","key":"pe783eff05dbdc942","n_data_papers_used":0,"n_values_from_cited_papers":0,"reassesses":["doi:10.1515/ijmr-2001-0140"],"tdb_files":["ZrO-23Jia.tdb"],"title":"Thermodynamic analysis for molten corium stratification with U-Zr-O-Fe database","values_reported":1,"year":2023}],"cite_as":{"also_cite":["the papers themselves when you use their data (doi / citation of each bibliography record)"],"bibtex":"@misc{orchid_bibliography_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Bibliography: papers and typed citation relations}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736021},\n  url       = {https://doi.org/10.5281/zenodo.23736021},\n  note      = {Version 1, machine-extracted}\n}","dataset":"bibliography","doi":"10.5281/zenodo.23736021","licence_note":"Crossref bibliographic metadata: CC0; ORCHID-derived fields (roles, evidence counts, relations): CC BY 4.0","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: roles and evidence counts derive from machine-extracted literature values and link tables; bibliographic fields are Crossref metadata as deposited (DOIs matched from printed references checked against Crossref: doi_match; mismatches dropped).","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Bibliography: papers and typed citation relations (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736021","title":"ORCHID-Bibliography: papers and typed citation relations","url":"https://doi.org/10.5281/zenodo.23736021","version":"2026.10"},"elements":["O","ZR"],"papers":[{"doi":"10.1002/zaac.19322040105","id":"doi:10.1002/zaac.19322040105","key":"p187f95f6e33f063d","title":"Über die Schmelzpunkte des Zirkonoxydes und des Hafniumoxydes","year":1932},{"doi":"10.1006/jcht.1998.0481","id":"doi:10.1006/jcht.1998.0481","key":"p7347662464d9a5c4","title":"Heat capacity and thermodynamic functions of zirconia and yttria-stabilized zirconia","year":1999},{"doi":"10.1007/bf01591647","id":"doi:10.1007/bf01591647","key":"pd8c1b2eefd4299c2","title":"Der Schmelzpunkt des Hafniumoxydes","year":1925},{"doi":"10.1007/bf02881546","id":"doi:10.1007/bf02881546","key":"p8bc6dcbd1d529a58","title":"The O−Zr (Oxygen-Zirconium) system","year":1986},{"doi":"10.1007/s11669-007-9154-2","id":"doi:10.1007/s11669-007-9154-2","key":"p6c1ce0e3cb2477ab","title":"O-Zr (Oxygen-Zirconium)","year":2007},{"doi":"10.1016/0022-3115(61)90075-7","id":"doi:10.1016/0022-3115(61)90075-7","key":"p0a3b62a91e7a06a7","title":"Untersuchungen in system Zirkonium-Sauerstoff teil 2 untersuchungen zur kinetik der reaktion zwischen Zirkonium und sauerstoff, sowie über die konstitution des systems Zirkonium-Sauerstoff","year":1961},{"doi":"10.1016/0022-3115(70)90218-7","id":"doi:10.1016/0022-3115(70)90218-7","key":"p8ad557e17087c238","title":"The melting point of pure zirconia","year":1970},{"doi":"10.1016/0038-092x(66)90014-4","id":"doi:10.1016/0038-092x(66)90014-4","key":"p294b620f63d88791","title":"Heating curves of solids obtained by a solar furnace","year":1966},{"doi":"10.1016/j.calphad.2004.03.005","id":"doi:10.1016/j.calphad.2004.03.005","key":"pa70f19e4e0a48ad3","title":"Progress in the thermodynamic modelling of the O–U–Zr ternary system","year":2004},{"doi":"10.1016/j.calphad.2004.09.002","id":"doi:10.1016/j.calphad.2004.09.002","key":"p01e8363fd6eea0bc","title":"On the thermodynamic modeling of the Zr–O system","year":2004},{"doi":"10.1016/j.jnucmat.2006.10.008","id":"doi:10.1016/j.jnucmat.2006.10.008","key":"p54136e6daa6ed3c1","title":"Thermodynamic evaluation of the Nb–O–Zr system","year":2007},{"doi":"10.1016/j.jnucmat.2022.154180","id":"doi:10.1016/j.jnucmat.2022.154180","key":"pe783eff05dbdc942","title":"Thermodynamic analysis for molten corium stratification with U-Zr-O-Fe database","year":2023},{"doi":"10.1016/j.ssi.2004.02.017","id":"doi:10.1016/j.ssi.2004.02.017","key":"p9b897dffc64a1d2e","title":"Thermodynamic modeling of the ZrO2–YO1.5 system","year":2004},{"doi":"10.1016/s0022-3115(98)00450-4","id":"doi:10.1016/s0022-3115(98)00450-4","key":"p0e9e299d99920396","title":"Thermodynamic modelling of the O–U–Zr system","year":1998},{"doi":"10.1016/s0039-6028(87)80071-7","id":"doi:10.1016/s0039-6028(87)80071-7","key":"p3d92d44abd6bed7d","title":"AES and XPS studies of oxygen stabilized alpha zirconium","year":1987},{"doi":"10.1016/s0364-5916(02)00027-5","id":"doi:10.1016/s0364-5916(02)00027-5","key":"pf4ad51374e16282f","title":"Thermodynamic modeling of the ZrO system","year":2002},{"doi":"10.1021/j100792a052","id":"doi:10.1021/j100792a052","key":"p64da8a9d5017debc","title":"The Heats of Formation of Zirconium Diboride and Dioxide\n                    <sup>1</sup>","year":1964},{"doi":"10.1021/ja01161a106","id":"doi:10.1021/ja01161a106","key":"pc7ed6975fea56ed9","title":"High-Temperature Heat Contents of Some Zirconium-containing Substances\n                    <sup>1</sup>","year":1950},{"doi":"10.1111/j.1151-2916.1990.tb07619.x","id":"doi:10.1111/j.1151-2916.1990.tb07619.x","key":"pcb88a8eef323e090","title":"Heat Capacity of Monoclinic Zirconia between 2.75 and 350 K","year":1990},{"doi":"10.1111/j.1151-2916.1992.tb04384.x","id":"doi:10.1111/j.1151-2916.1992.tb04384.x","key":"p30951940ad9954d2","title":"Thermodynamic Calculation of the Zirconia–Calcia System","year":1992},{"doi":"10.1111/j.1151-2916.1995.tb08642.x","id":"doi:10.1111/j.1151-2916.1995.tb08642.x","key":"p1b55b9f2f49929b1","title":"Tetragonal—Monoclinic Phase Transition Enthalpy and Temperature of ZrO\n                    <sub>2</sub>\n                    ‐CeO\n                    <sub>2</sub>\n                    Solid Solutions","year":1995},{"doi":"10.1515/ijmr-2001-0140","id":"doi:10.1515/ijmr-2001-0140","key":"p269c6ebede6c96de","title":"Thermodynamic Assessment of the Zr–O Binary System","year":2001},{"doi":"10.1524/zpch.1998.207.part_1_2.059","id":"doi:10.1524/zpch.1998.207.part_1_2.059","key":"p3ca4727e5017a81b","title":"The Energetics of Cubic Zirconia from Solution Calorimetry of Yttria- and Calcia-Stabilized Zirconia","year":1998},{"doi":"10.1557/jmr.2003.0125","id":"doi:10.1557/jmr.2003.0125","key":"p8bd855a4f91a1d7b","title":"Enthalpy of formation of cubic yttria-stabilized zirconia","year":2003},{"doi":"10.1557/jmr.2003.0406","id":"doi:10.1557/jmr.2003.0406","key":"p530b7076363efb37","title":"Thermodynamics of the tetragonal-to-monoclinic phase transformation in fine and nanocrystalline yttria-stabilized zirconia powders","year":2003},{"doi":null,"id":"nodoi:b1c27cbf8c370705","key":"pc955337829aecc2d","title":"C. Wang, PhD Thesis, Stuttgart, 2006.","year":2006}],"papers_by_role":{"cited_original_source":["doi:10.1002/zaac.19322040105","doi:10.1006/jcht.1998.0481","doi:10.1007/bf01591647","doi:10.1007/bf02881546","doi:10.1016/0022-3115(61)90075-7","doi:10.1016/0022-3115(70)90218-7","doi:10.1016/0038-092x(66)90014-4","doi:10.1016/j.calphad.2004.03.005","doi:10.1016/s0022-3115(98)00450-4","doi:10.1016/s0039-6028(87)80071-7","doi:10.1016/s0364-5916(02)00027-5","doi:10.1021/j100792a052","doi:10.1021/ja01161a106","doi:10.1111/j.1151-2916.1990.tb07619.x","doi:10.1111/j.1151-2916.1992.tb04384.x","doi:10.1111/j.1151-2916.1995.tb08642.x","doi:10.1524/zpch.1998.207.part_1_2.059","doi:10.1557/jmr.2003.0125","doi:10.1557/jmr.2003.0406"],"corpus_assessment_read":["doi:10.1016/j.calphad.2004.03.005","doi:10.1016/j.calphad.2004.09.002","doi:10.1016/j.jnucmat.2006.10.008","doi:10.1016/j.jnucmat.2022.154180","doi:10.1016/j.ssi.2004.02.017","doi:10.1016/s0022-3115(98)00450-4","doi:10.1016/s0364-5916(02)00027-5"],"discovery_lead":["doi:10.1016/j.calphad.2004.03.005","doi:10.1016/j.calphad.2004.09.002","doi:10.1016/j.jnucmat.2022.154180","doi:10.1016/s0022-3115(98)00450-4"],"handbook_diagram_source":["doi:10.1007/s11669-007-9154-2"],"tdb_source_assessment":["doi:10.1016/j.calphad.2004.03.005","doi:10.1016/j.calphad.2004.09.002","doi:10.1016/j.jnucmat.2006.10.008","doi:10.1016/j.jnucmat.2022.154180","doi:10.1016/j.ssi.2004.02.017","doi:10.1016/s0022-3115(98)00450-4","doi:10.1016/s0364-5916(02)00027-5","doi:10.1515/ijmr-2001-0140","nodoi:b1c27cbf8c370705"]},"system":"O-ZR"}