{"assessments":[{"data_papers_used":[],"doi":"10.1016/0364-5916(89)90007-2","id":"doi:10.1016/0364-5916(89)90007-2","key":"pb5631d18c1b7834c","n_data_papers_used":0,"n_values_from_cited_papers":0,"reassesses":[],"tdb_files":["SiTa-89Vah.tdb"],"title":"A thermodynamic evaluation of four Si-M (M = Mo, Ta, Ti, W) binary systems","values_reported":54,"year":1989},{"data_papers_used":[],"doi":null,"id":"nodoi:137c496847b2d3fe","key":"p455e4eb1c4a40c79","n_data_papers_used":0,"n_values_from_cited_papers":0,"reassesses":[],"tdb_files":["SiTa-03Che-LB.tdb"],"title":"P.-Y. Chevalier, E. Fischer, unpublished, 2003.","values_reported":0,"year":2003},{"data_papers_used":[],"doi":"10.1007/s11669-009-9579-x","id":"doi:10.1007/s11669-009-9579-x","key":"pe49d749cd0752ddf","n_data_papers_used":0,"n_values_from_cited_papers":0,"reassesses":["doi:10.1016/0364-5916(89)90007-2"],"tdb_files":["SiTa-09Guo.tdb"],"title":"Thermodynamic Assessment of the Si-Ta and Si-W Systems","values_reported":35,"year":2009},{"data_papers_used":[{"doi":"10.1021/ja01560a007","evidence_class":{"experimental":9},"id":"doi:10.1021/ja01560a007","key":"p9a89c36ee484622e","n_values":9,"n_values_accepted":9,"title":"The Dissociation Pressures of the Tantalum Silicides<sup>1,2</sup>","year":1957},{"doi":"10.1007/bf02667688","evidence_class":{"experimental":5},"id":"doi:10.1007/bf02667688","key":"p8a843a6eff0dc412","n_values":5,"n_values_accepted":0,"title":"The Si-Ta (silicon-tantalum) system","year":1994},{"doi":"10.1149/1.2411545","evidence_class":{"experimental":5},"id":"doi:10.1149/1.2411545","key":"pc07c0cb3a235b669","n_values":5,"n_values_accepted":5,"title":"The Free Energy of Formation of Tantalum Silicides Using Solid Oxide Electrolytes","year":1969},{"doi":"10.1016/0001-6160(55)90120-6","evidence_class":{"experimental":2},"id":"doi:10.1016/0001-6160(55)90120-6","key":"p92be8b34320bf97d","n_values":2,"n_values_accepted":2,"title":"The heats of formation of some transition metal silicides","year":1955},{"doi":"10.1016/s0925-8388(98)00747-6","evidence_class":{"experimental":2},"id":"doi:10.1016/s0925-8388(98)00747-6","key":"pb644c317dbccda22","n_values":2,"n_values_accepted":2,"title":"Standard enthalpies of formation of some 5d transition metal silicides by high temperature direct synthesis calorimetry","year":1998},{"doi":"10.1103/physrevb.80.104103","evidence_class":{"dft":1,"model":1},"id":"doi:10.1103/physrevb.80.104103","key":"pa8aa80f1af9afe1f","n_values":2,"n_values_accepted":2,"title":"Phase stability and physical properties of<mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\"><mml:mrow><mml:msub><mml:mrow><mml:mtext>Ta</mml:mtext></mml:mrow><mml:mn>5</mml:mn></mml:msub><mml:msub><mml:mrow><mml:mtext>Si</mml:mtext></mml:mrow><mml:mn>3</mml:mn></mml:msub></mml:mrow></mml:math>compounds from first-principles calculations","year":2009},{"doi":"10.1007/bf00902640","evidence_class":{"experimental":1},"id":"doi:10.1007/bf00902640","key":"p193a7f403625dbbe","n_values":1,"n_values_accepted":1,"title":"Das Verhalten metallreicher, hochschmelzender Silizide gegen�ber Bor, Kohlenstoff, Stickstoff und Sauerstoff","year":1956}],"doi":"10.1016/j.jallcom.2012.09.148","id":"doi:10.1016/j.jallcom.2012.09.148","key":"pe70a42420157b3d6","n_data_papers_used":7,"n_values_from_cited_papers":26,"reassesses":["doi:10.1007/s11669-009-9579-x","doi:10.1016/0364-5916(89)90007-2"],"tdb_files":["SiTa-13Dro.tdb"],"title":"Thermodynamic assessment of the Si–Ta system","values_reported":79,"year":2013},{"data_papers_used":[{"doi":"10.1007/s11669-009-9579-x","evidence_class":{"model":5,"unspecified":10},"id":"doi:10.1007/s11669-009-9579-x","key":"pe49d749cd0752ddf","n_values":15,"n_values_accepted":15,"title":"Thermodynamic Assessment of the Si-Ta and Si-W Systems","year":2009},{"doi":"10.1007/bf00682295","evidence_class":{"unspecified":4},"id":"doi:10.1007/bf00682295","key":"paea03834006cc409","n_values":4,"n_values_accepted":4,"title":"Low temperature specific heat of VSi2, NbSi2, and TaSi2","year":1993},{"doi":"10.1016/s0925-8388(97)00528-8","evidence_class":{"experimental":4},"id":"doi:10.1016/s0925-8388(97)00528-8","key":"p61021dc9234b31e9","n_values":4,"n_values_accepted":4,"title":"Standard enthalpies of formation of some 3d transition metal silicides by high temperature direct synthesis calorimetry","year":1998},{"doi":"10.1016/0001-6160(55)90120-6","evidence_class":{"experimental":3},"id":"doi:10.1016/0001-6160(55)90120-6","key":"p92be8b34320bf97d","n_values":3,"n_values_accepted":2,"title":"The heats of formation of some transition metal silicides","year":1955},{"doi":"10.1149/1.2411545","evidence_class":{"experimental":2},"id":"doi:10.1149/1.2411545","key":"pc07c0cb3a235b669","n_values":2,"n_values_accepted":2,"title":"The Free Energy of Formation of Tantalum Silicides Using Solid Oxide Electrolytes","year":1969}],"doi":"10.1016/j.jssc.2012.12.003","id":"doi:10.1016/j.jssc.2012.12.003","key":"p8e3e6605817f2973","n_data_papers_used":5,"n_values_from_cited_papers":28,"reassesses":[],"tdb_files":[],"title":"The system Ta–V–Si: Thermodynamic modeling","values_reported":157,"year":2013}],"cite_as":{"also_cite":["the papers themselves when you use their data (doi / citation of each bibliography record)"],"bibtex":"@misc{orchid_bibliography_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Bibliography: papers and typed citation relations}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736021},\n  url       = {https://doi.org/10.5281/zenodo.23736021},\n  note      = {Version 1, machine-extracted}\n}","dataset":"bibliography","doi":"10.5281/zenodo.23736021","licence_note":"Crossref bibliographic metadata: CC0; ORCHID-derived fields (roles, evidence counts, relations): CC BY 4.0","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: roles and evidence counts derive from machine-extracted literature values and link tables; bibliographic fields are Crossref metadata as deposited (DOIs matched from printed references checked against Crossref: doi_match; mismatches dropped).","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Bibliography: papers and typed citation relations (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736021","title":"ORCHID-Bibliography: papers and typed citation relations","url":"https://doi.org/10.5281/zenodo.23736021","version":"2026.10"},"elements":["SI","TA"],"papers":[{"doi":"10.1007/bf00682295","id":"doi:10.1007/bf00682295","key":"paea03834006cc409","title":"Low temperature specific heat of VSi2, NbSi2, and TaSi2","year":1993},{"doi":"10.1007/bf00902640","id":"doi:10.1007/bf00902640","key":"p193a7f403625dbbe","title":"Das Verhalten metallreicher, hochschmelzender Silizide gegen�ber Bor, Kohlenstoff, Stickstoff und Sauerstoff","year":1956},{"doi":"10.1007/bf02648373","id":"doi:10.1007/bf02648373","key":"p90ce35a582fabe9a","title":"The O-Ta (Oxygen-Tantalum) system","year":1996},{"doi":"10.1007/bf02667688","id":"doi:10.1007/bf02667688","key":"p8a843a6eff0dc412","title":"The Si-Ta (silicon-tantalum) system","year":1994},{"doi":"10.1007/s11669-009-9579-x","id":"doi:10.1007/s11669-009-9579-x","key":"pe49d749cd0752ddf","title":"Thermodynamic Assessment of the Si-Ta and Si-W Systems","year":2009},{"doi":"10.1016/0001-6160(55)90120-6","id":"doi:10.1016/0001-6160(55)90120-6","key":"p92be8b34320bf97d","title":"The heats of formation of some transition metal silicides","year":1955},{"doi":"10.1016/0364-5916(89)90007-2","id":"doi:10.1016/0364-5916(89)90007-2","key":"pb5631d18c1b7834c","title":"A thermodynamic evaluation of four Si-M (M = Mo, Ta, Ti, W) binary systems","year":1989},{"doi":"10.1016/j.jallcom.2012.09.148","id":"doi:10.1016/j.jallcom.2012.09.148","key":"pe70a42420157b3d6","title":"Thermodynamic assessment of the Si–Ta system","year":2013},{"doi":"10.1016/j.jssc.2012.12.003","id":"doi:10.1016/j.jssc.2012.12.003","key":"p8e3e6605817f2973","title":"The system Ta–V–Si: Thermodynamic modeling","year":2013},{"doi":"10.1016/s0925-8388(97)00528-8","id":"doi:10.1016/s0925-8388(97)00528-8","key":"p61021dc9234b31e9","title":"Standard enthalpies of formation of some 3d transition metal silicides by high temperature direct synthesis calorimetry","year":1998},{"doi":"10.1016/s0925-8388(98)00747-6","id":"doi:10.1016/s0925-8388(98)00747-6","key":"pb644c317dbccda22","title":"Standard enthalpies of formation of some 5d transition metal silicides by high temperature direct synthesis calorimetry","year":1998},{"doi":"10.1021/ja01560a007","id":"doi:10.1021/ja01560a007","key":"p9a89c36ee484622e","title":"The Dissociation Pressures of the Tantalum Silicides<sup>1,2</sup>","year":1957},{"doi":"10.1103/physrevb.80.104103","id":"doi:10.1103/physrevb.80.104103","key":"pa8aa80f1af9afe1f","title":"Phase stability and physical properties of<mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\" display=\"inline\"><mml:mrow><mml:msub><mml:mrow><mml:mtext>Ta</mml:mtext></mml:mrow><mml:mn>5</mml:mn></mml:msub><mml:msub><mml:mrow><mml:mtext>Si</mml:mtext></mml:mrow><mml:mn>3</mml:mn></mml:msub></mml:mrow></mml:math>compounds from first-principles calculations","year":2009},{"doi":"10.1149/1.2411545","id":"doi:10.1149/1.2411545","key":"pc07c0cb3a235b669","title":"The Free Energy of Formation of Tantalum Silicides Using Solid Oxide Electrolytes","year":1969},{"doi":null,"id":"nodoi:137c496847b2d3fe","key":"p455e4eb1c4a40c79","title":"P.-Y. Chevalier, E. Fischer, unpublished, 2003.","year":2003},{"doi":null,"id":"nodoi:1a2dbe3297e1a467","key":"p0e414df0bcb399a9","title":"T.D. Massalski, Si–Ta (Silicium-Tantalum), in: T.D. Massalski (Ed.), Binary Alloys Phase Diagrams, second ed., vol. 3, ASM International, Metals Park, Ohio, 1990, pp. 3364–3366.","year":1990}],"papers_by_role":{"cited_original_source":["doi:10.1007/bf00682295","doi:10.1007/bf00902640","doi:10.1007/bf02648373","doi:10.1007/bf02667688","doi:10.1007/s11669-009-9579-x","doi:10.1016/0001-6160(55)90120-6","doi:10.1016/0364-5916(89)90007-2","doi:10.1016/j.jssc.2012.12.003","doi:10.1016/s0925-8388(97)00528-8","doi:10.1016/s0925-8388(98)00747-6","doi:10.1021/ja01560a007","doi:10.1103/physrevb.80.104103","doi:10.1149/1.2411545","nodoi:1a2dbe3297e1a467"],"corpus_assessment_read":["doi:10.1007/s11669-009-9579-x","doi:10.1016/0364-5916(89)90007-2","doi:10.1016/j.jallcom.2012.09.148","doi:10.1016/j.jssc.2012.12.003"],"discovery_lead":["doi:10.1016/j.jallcom.2012.09.148","doi:10.1016/j.jssc.2012.12.003"],"handbook_diagram_source":["doi:10.1007/bf02648373"],"tdb_source_assessment":["doi:10.1007/s11669-009-9579-x","doi:10.1016/0364-5916(89)90007-2","doi:10.1016/j.jallcom.2012.09.148","doi:10.1016/j.jssc.2012.12.003","nodoi:137c496847b2d3fe"]},"system":"SI-TA"}