{"assessments":[{"data_papers_used":[],"doi":null,"id":"nodoi:800c9189901884ea","key":"p22c237c36bb31134","n_data_papers_used":0,"n_values_from_cited_papers":0,"reassesses":[],"tdb_files":["SiV-98Ran-LB.tdb"],"title":"M.H. Rand, N. Saunders, COST 507, Final report round 2, 1998.","values_reported":0,"year":1998},{"data_papers_used":[{"doi":"10.1007/s10853-007-1865-6","evidence_class":{"dft":4,"model":2},"id":"doi:10.1007/s10853-007-1865-6","key":"pa51e15b94dcdba6f","n_values":6,"n_values_accepted":5,"title":"An investigation on the thermodynamic stability of V6Si5","year":2007},{"doi":"10.1016/j.calphad.2006.04.004","evidence_class":{"model":4},"id":"doi:10.1016/j.calphad.2006.04.004","key":"pd1ee03757f776b53","n_values":4,"n_values_accepted":4,"title":"Miedema’s model revisited: The parameter for Ti, Zr, and Hf","year":2006},{"doi":"10.1016/0022-5088(82)90126-6","evidence_class":{"experimental":3},"id":"doi:10.1016/0022-5088(82)90126-6","key":"p0ed40f7cba124443","n_values":3,"n_values_accepted":3,"title":"The V3Si phase: Type of formation and homogeneity range","year":1982},{"doi":"10.1016/s0925-8388(97)00528-8","evidence_class":{"experimental":2},"id":"doi:10.1016/s0925-8388(97)00528-8","key":"p61021dc9234b31e9","n_values":2,"n_values_accepted":2,"title":"Standard enthalpies of formation of some 3d transition metal silicides by high temperature direct synthesis calorimetry","year":1998},{"doi":"10.1006/jcht.1999.0579","evidence_class":{"experimental":1},"id":"doi:10.1006/jcht.1999.0579","key":"p16e45f107095288f","n_values":1,"n_values_accepted":1,"title":"Thermodynamic properties of vanadium silicides. I. Standard molar enthalpy of formation of vanadium disilicide (VSi ) at the temperature 298.15 K","year":1999},{"doi":"10.1006/jcht.1999.0612","evidence_class":{"experimental":1},"id":"doi:10.1006/jcht.1999.0612","key":"pe7582190010874f7","n_values":1,"n_values_accepted":1,"title":"Thermodynamic properties of vanadium silicides II. Standard molar enthalpy of formation (298.15 K) and reassessed thermodynamic properties of trivanadium monosilicide (V Si)","year":2000},{"doi":"10.1007/bf02873702","evidence_class":{"experimental":1},"id":"doi:10.1007/bf02873702","key":"p98ad05a8f664308f","n_values":1,"n_values_accepted":0,"title":"The Si−V (Silicon-Vanadium) system","year":1981},{"doi":"10.1007/bf02880413","evidence_class":{"experimental":1},"id":"doi:10.1007/bf02880413","key":"pce69b757e75d533a","n_values":1,"n_values_accepted":0,"title":"The Si−V (Silicon-Vanadium) system: Addendum","year":1985}],"doi":"10.1016/j.calphad.2007.12.005","id":"doi:10.1016/j.calphad.2007.12.005","key":"p2cfaa15f6ccfd42d","n_data_papers_used":8,"n_values_from_cited_papers":19,"reassesses":[],"tdb_files":["SiV-08Zha.tdb"],"title":"Thermodynamic modeling of the V–Si system supported by key experiments","values_reported":47,"year":2008},{"data_papers_used":[{"doi":"10.1016/j.jssc.2011.12.024","evidence_class":{"experimental":21},"id":"doi:10.1016/j.jssc.2011.12.024","key":"p399a3d1baf92f5f3","n_values":21,"n_values_accepted":21,"title":"The system Ta–V–Si: Crystal structure and phase equilibria","year":2012},{"doi":"10.1016/j.calphad.2007.12.005","evidence_class":{"model":13,"unspecified":5},"id":"doi:10.1016/j.calphad.2007.12.005","key":"p2cfaa15f6ccfd42d","n_values":18,"n_values_accepted":18,"title":"Thermodynamic modeling of the V–Si system supported by key experiments","year":2008},{"doi":"10.1016/j.calphad.2006.04.004","evidence_class":{"model":5},"id":"doi:10.1016/j.calphad.2006.04.004","key":"pd1ee03757f776b53","n_values":5,"n_values_accepted":5,"title":"Miedema’s model revisited: The parameter for Ti, Zr, and Hf","year":2006},{"doi":"10.1007/bf00682295","evidence_class":{"unspecified":4},"id":"doi:10.1007/bf00682295","key":"paea03834006cc409","n_values":4,"n_values_accepted":4,"title":"Low temperature specific heat of VSi2, NbSi2, and TaSi2","year":1993},{"doi":"10.1016/s0925-8388(97)00528-8","evidence_class":{"experimental":4},"id":"doi:10.1016/s0925-8388(97)00528-8","key":"p61021dc9234b31e9","n_values":4,"n_values_accepted":4,"title":"Standard enthalpies of formation of some 3d transition metal silicides by high temperature direct synthesis calorimetry","year":1998},{"doi":"10.1007/s10853-007-1865-6","evidence_class":{"model":3},"id":"doi:10.1007/s10853-007-1865-6","key":"pa51e15b94dcdba6f","n_values":3,"n_values_accepted":3,"title":"An investigation on the thermodynamic stability of V6Si5","year":2007},{"doi":"10.3406/bulmi.1970.6423","evidence_class":{"model":3},"id":"doi:10.3406/bulmi.1970.6423","key":"p125b3689ac7d786a","n_values":3,"n_values_accepted":3,"title":"Structure des phases binaires V6Si5 et Ti6Ge5","year":1970},{"doi":"10.2320/matertrans1960.27.225","evidence_class":{"model":1},"id":"doi:10.2320/matertrans1960.27.225","key":"p11215ad71c349788","n_values":1,"n_values_accepted":1,"title":"Stability of Crystal Structure of (Fe, V)&lt;SUB&gt;3&lt;/SUB&gt;M and (Fe, Ni)&lt;SUB&gt;3&lt;/SUB&gt;M (M=Si, Ge, Sn) and Its Analysis Based on Rigid Band Model","year":1986}],"doi":"10.1016/j.jssc.2012.12.003","id":"doi:10.1016/j.jssc.2012.12.003","key":"p8e3e6605817f2973","n_data_papers_used":8,"n_values_from_cited_papers":59,"reassesses":["doi:10.1016/j.calphad.2007.12.005"],"tdb_files":["SiV-13Bro.tdb"],"title":"The system Ta–V–Si: Thermodynamic modeling","values_reported":157,"year":2013},{"data_papers_used":[{"doi":"10.1016/j.calphad.2007.12.005","evidence_class":{"model":6},"id":"doi:10.1016/j.calphad.2007.12.005","key":"p2cfaa15f6ccfd42d","n_values":6,"n_values_accepted":6,"title":"Thermodynamic modeling of the V–Si system supported by key experiments","year":2008},{"doi":"10.1016/j.jssc.2012.12.003","evidence_class":{"dft":6},"id":"doi:10.1016/j.jssc.2012.12.003","key":"p8e3e6605817f2973","n_values":6,"n_values_accepted":6,"title":"The system Ta–V–Si: Thermodynamic modeling","year":2013},{"doi":"10.1016/s0925-8388(97)00528-8","evidence_class":{"experimental":1},"id":"doi:10.1016/s0925-8388(97)00528-8","key":"p61021dc9234b31e9","n_values":1,"n_values_accepted":1,"title":"Standard enthalpies of formation of some 3d transition metal silicides by high temperature direct synthesis calorimetry","year":1998}],"doi":"10.1016/j.jmst.2018.01.004","id":"doi:10.1016/j.jmst.2018.01.004","key":"pe648c5342bcd2202","n_data_papers_used":3,"n_values_from_cited_papers":13,"reassesses":["doi:10.1016/j.calphad.2007.12.005","doi:10.1016/j.jssc.2012.12.003"],"tdb_files":["SiV-18Luo.tdb"],"title":"Thermodynamic investigation of phase equilibria in Al–Si–V system","values_reported":86,"year":2018}],"cite_as":{"also_cite":["the papers themselves when you use their data (doi / citation of each bibliography record)"],"bibtex":"@misc{orchid_bibliography_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Bibliography: papers and typed citation relations}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736021},\n  url       = {https://doi.org/10.5281/zenodo.23736021},\n  note      = {Version 1, machine-extracted}\n}","dataset":"bibliography","doi":"10.5281/zenodo.23736021","licence_note":"Crossref bibliographic metadata: CC0; ORCHID-derived fields (roles, evidence counts, relations): CC BY 4.0","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: roles and evidence counts derive from machine-extracted literature values and link tables; bibliographic fields are Crossref metadata as deposited (DOIs matched from printed references checked against Crossref: doi_match; mismatches dropped).","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Bibliography: papers and typed citation relations (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736021","title":"ORCHID-Bibliography: papers and typed citation relations","url":"https://doi.org/10.5281/zenodo.23736021","version":"2026.10"},"elements":["SI","V"],"papers":[{"doi":"10.1006/jcht.1999.0579","id":"doi:10.1006/jcht.1999.0579","key":"p16e45f107095288f","title":"Thermodynamic properties of vanadium silicides. I. Standard molar enthalpy of formation of vanadium disilicide (VSi ) at the temperature 298.15 K","year":1999},{"doi":"10.1006/jcht.1999.0612","id":"doi:10.1006/jcht.1999.0612","key":"pe7582190010874f7","title":"Thermodynamic properties of vanadium silicides II. Standard molar enthalpy of formation (298.15 K) and reassessed thermodynamic properties of trivanadium monosilicide (V Si)","year":2000},{"doi":"10.1007/bf00682295","id":"doi:10.1007/bf00682295","key":"paea03834006cc409","title":"Low temperature specific heat of VSi2, NbSi2, and TaSi2","year":1993},{"doi":"10.1007/bf02873702","id":"doi:10.1007/bf02873702","key":"p98ad05a8f664308f","title":"The Si−V (Silicon-Vanadium) system","year":1981},{"doi":"10.1007/bf02880413","id":"doi:10.1007/bf02880413","key":"pce69b757e75d533a","title":"The Si−V (Silicon-Vanadium) system: Addendum","year":1985},{"doi":"10.1007/s10853-007-1865-6","id":"doi:10.1007/s10853-007-1865-6","key":"pa51e15b94dcdba6f","title":"An investigation on the thermodynamic stability of V6Si5","year":2007},{"doi":"10.1007/s11669-010-9733-5","id":"doi:10.1007/s11669-010-9733-5","key":"pffbef0c42c7d4848","title":"Si-V (Silicon-Vanadium)","year":2010},{"doi":"10.1016/0022-5088(82)90126-6","id":"doi:10.1016/0022-5088(82)90126-6","key":"p0ed40f7cba124443","title":"The V3Si phase: Type of formation and homogeneity range","year":1982},{"doi":"10.1016/j.calphad.2006.04.004","id":"doi:10.1016/j.calphad.2006.04.004","key":"pd1ee03757f776b53","title":"Miedema’s model revisited: The parameter for Ti, Zr, and Hf","year":2006},{"doi":"10.1016/j.calphad.2007.12.005","id":"doi:10.1016/j.calphad.2007.12.005","key":"p2cfaa15f6ccfd42d","title":"Thermodynamic modeling of the V–Si system supported by key experiments","year":2008},{"doi":"10.1016/j.jmst.2018.01.004","id":"doi:10.1016/j.jmst.2018.01.004","key":"pe648c5342bcd2202","title":"Thermodynamic investigation of phase equilibria in Al–Si–V system","year":2018},{"doi":"10.1016/j.jssc.2011.12.024","id":"doi:10.1016/j.jssc.2011.12.024","key":"p399a3d1baf92f5f3","title":"The system Ta–V–Si: Crystal structure and phase equilibria","year":2012},{"doi":"10.1016/j.jssc.2012.12.003","id":"doi:10.1016/j.jssc.2012.12.003","key":"p8e3e6605817f2973","title":"The system Ta–V–Si: Thermodynamic modeling","year":2013},{"doi":"10.1016/s0925-8388(97)00528-8","id":"doi:10.1016/s0925-8388(97)00528-8","key":"p61021dc9234b31e9","title":"Standard enthalpies of formation of some 3d transition metal silicides by high temperature direct synthesis calorimetry","year":1998},{"doi":"10.2320/matertrans1960.27.225","id":"doi:10.2320/matertrans1960.27.225","key":"p11215ad71c349788","title":"Stability of Crystal Structure of (Fe, V)&lt;SUB&gt;3&lt;/SUB&gt;M and (Fe, Ni)&lt;SUB&gt;3&lt;/SUB&gt;M (M=Si, Ge, Sn) and Its Analysis Based on Rigid Band Model","year":1986},{"doi":"10.3406/bulmi.1970.6423","id":"doi:10.3406/bulmi.1970.6423","key":"p125b3689ac7d786a","title":"Structure des phases binaires V6Si5 et Ti6Ge5","year":1970},{"doi":null,"id":"nodoi:0b753560c62f459b","key":"pbfb128b3dc8863f3","title":"Yu.A. Kocherzhinskii, O.G. Kulik, E. Shishkin, Dokl. Akad. Nauk SSSR 209 (6) (1973) 1347–1349.","year":1973},{"doi":null,"id":"nodoi:34c4014872fe280d","key":"p0cd034c5c0db792a","title":"G.I. Kalishevich, P.V. Gel’d, Yu.V. Putinsev, High Temp. (USSR) 6 (1968) 959–962.","year":1968},{"doi":null,"id":"nodoi:800c9189901884ea","key":"p22c237c36bb31134","title":"M.H. Rand, N. Saunders, COST 507, Final report round 2, 1998.","year":1998}],"papers_by_role":{"cited_original_source":["doi:10.1006/jcht.1999.0579","doi:10.1006/jcht.1999.0612","doi:10.1007/bf00682295","doi:10.1007/bf02873702","doi:10.1007/bf02880413","doi:10.1007/s10853-007-1865-6","doi:10.1016/0022-5088(82)90126-6","doi:10.1016/j.calphad.2006.04.004","doi:10.1016/j.calphad.2007.12.005","doi:10.1016/j.jssc.2011.12.024","doi:10.1016/j.jssc.2012.12.003","doi:10.1016/s0925-8388(97)00528-8","doi:10.2320/matertrans1960.27.225","doi:10.3406/bulmi.1970.6423","nodoi:0b753560c62f459b","nodoi:34c4014872fe280d"],"corpus_assessment_read":["doi:10.1016/j.calphad.2007.12.005","doi:10.1016/j.jmst.2018.01.004","doi:10.1016/j.jssc.2012.12.003"],"discovery_lead":["doi:10.1016/j.jmst.2018.01.004","doi:10.1016/j.jssc.2011.12.024","doi:10.1016/j.jssc.2012.12.003"],"handbook_diagram_source":["doi:10.1007/s11669-010-9733-5"],"tdb_source_assessment":["doi:10.1016/j.calphad.2007.12.005","doi:10.1016/j.jmst.2018.01.004","doi:10.1016/j.jssc.2012.12.003","nodoi:800c9189901884ea"]},"system":"SI-V"}
