Al3Zr: enthalpy of formation

64 accepted literature formation-enthalpy value(s) (experimental 13, model 35, DFT 16); experimental median -48.4 kJ/mol-atom (n = 9); Materials Project -47.013 kJ/mol-atom (mp-aaaaaapf); OQMD -47.081 kJ/mol-atom (oqmd-18198).

Systems: Al–Zr

Literature values

Enthalpy of formation of Al3Zr reported in the literature (64)
Value	Phase as printed	T (K)	Class	Method	System	Source	Location
-51.6 kJ/mol-atom ± 1.2	Al3Zr	298.15	experimental		Al–Zr	[1] Long 2020 cites Macia 2018	Table 4, p. 7, row 8 report
-49 kJ/mol-atom ± 4	Al3Zr	298.15	experimental		Al–Zr	[1] Long 2020 cites Kematick 1984 doi	Table 4, p. 7, row 6 report
-49 unknown ± 4	Al3Zr	298.15	experimental		Al–Zr	[2] Tamim 2018 cites Kematick 1984 doi	Table 3, p. 9, row 85 report
-49 kJ/mol-atom	ZrAl3	298.15	experimental		Al–Zr	[3] T 2001 cites Kematick 1984	Table 2, p. 2, row 27 report
-48.4 kJ/mol-atom ± 1.3	Al3Zr	298.15	experimental		Al–Zr	[4] Fischer 2015 cites Meschel 1993 doi	Table 2, p. 4, row 2 report
-48.4 kJ/mol-atom	ZrAl3	298.15	experimental		Al–Zr	[3] T 2001 cites Meschel 1993	Table 2, p. 2, row 29 report
-48.4 kJ/mol-atom ± 1	Al3Zr	298.15	experimental		Al–Zr	[1] Long 2020 cites Meschel 1993 doi	Table 4, p. 7, row 7 report
-48.4 unknown ± 1.3	Al3Zr	298.15	experimental		Al–Zr	[2] Tamim 2018 cites Meschel 1993 doi	Table 3, p. 9, row 87 report
-48 unknown ± 4	Al3Zr	298.15	experimental		Al–Zr	[2] Tamim 2018 cites Kematick 1984 doi	Table 3, p. 9, row 22 report
-44 unknown	Al3Zr	298.15	experimental		Al–Zr	[2] Tamim 2018 cites Kubaschewski 1976	Table 3, p. 9, row 86 report
-44 kJ/mol-atom	ZrAl3	298.15	experimental		Al–Zr	[3] T 2001 cites Alcock 2001	Table 2, p. 2, row 28 report
-40.75 kJ/mol-atom	Al3Zr	298.15	experimental		Al–Zr	[5] Saunders 1986 cites ref. 36	Table 2, p. 5, row 1 report
-40.75 kJ/mol-atom	Al3Zr	298.15	experimental		Al–Zr	[4] Fischer 2015 cites Kematick 1984 doi	Table 2, p. 4, row 1 report
-187.12 unknown	Al3Zr- D023		model		Al–Zr	[6] Khvan 2018 cites Fischer 2015 doi	Table 1, p. 4, row 21 report
-52.87 kJ/mol-atom	Al3Zr		model		Al–Zr	[1] Long 2020	Table 4, p. 7, row 1 report
-51.5 unknown	Al3Zr		model	CALPHAD	Al–Zr	[2] Tamim 2018 cites Wang 2001 doi	Table 3, p. 9, row 25 report
-49.11 kJ/mol-atom	Al3Zr	298.15	model		Al–Zr	[4] Fischer 2015 cites Ghosh 2005 doi	Table 2, p. 4, row 8 report
-48.541 kJ/mol-atom	Al3Zr		model	CALPHAD	Al–Zr	[1] Long 2020 cites Wang 2001 doi	Table 4, p. 7, row 12 report
-48.5 unknown	Al3Zr		model	CALPHAD	Al–Zr	[2] Tamim 2018 cites Wang 2001 doi	Table 3, p. 9, row 90 report
-48.5 kJ/mol-atom	Al3Zr	298.15	model	CALPHAD	Al–Zr	[4] Fischer 2015 cites Wang 2001 doi	Table 2, p. 4, row 5 report
-48.5 kJ/mol-atom	ZrAl3		model		Al–Zr	[3] T 2001	Table 2, p. 2, row 31 report
-47.17 kJ/mol-atom	Al3Zr	298.15	model		Al–Zr	[4] Fischer 2015 cites Mihalkovic 2011	Table 2, p. 4, row 10 report
-47.09 kJ/mol-atom	Al3Zr	298.15	model		Al–Zr	[4] Fischer 2015 cites Saal 2013 doi	Table 2, p. 4, row 14 report
-46.97 kJ/mol-atom	Al3Zr	298.15	model		Al–Zr	[4] Fischer 2015 cites Colinet 2013 doi	Table 2, p. 4, row 13 report
-46.78 kJ/mol-atom	Al3Zr	298.15	model	CALPHAD	Al–Zr	[4] Fischer 2015	Table 2, p. 4, row 7 report
-46.78 kJ/mol-atom	Al3Zr	298.15	model		Al–Zr	[4] Fischer 2015 cites Duan 2014 doi	Table 2, p. 4, row 15 report
-46.779 kJ/mol-atom	Al3Zr		model	CALPHAD	Al–Zr	[1] Long 2020 cites Fischer 2015 doi	Table 4, p. 7, row 13 report
-46.77 kJ/mol-atom	Al3Zr	298.15	model		Al–Zr	[4] Fischer 2015 cites Wang 2011 doi	Table 2, p. 4, row 11 report
-46.63 unknown	Al3Zr		model		Al–Zr	[2] Tamim 2018	Table 3, p. 9, row 80 report
-44.321 unknown	Al3Zr		model		Al–Zr	[2] Tamim 2018	Table 3, p. 9, row 81 report
-44.321 kJ/mol-atom	Al3Zr		model	CALPHAD	Al–Zr	[1] Long 2020 cites Tamim 2018 doi	Table 4, p. 7, row 14 report
-44.3 kJ/mol-atom	Al3Zr	298.15	model	CALPHAD	Al–Zr	[4] Fischer 2015 cites Murray 1992 doi	Table 2, p. 4, row 3 report
-44.298 unknown	Al3Zr		model	CALPHAD	Al–Zr	[2] Tamim 2018 cites Murray 1992 doi	Table 3, p. 9, row 89 report
-44.298 kJ/mol-atom	Al3Zr		model	CALPHAD	Al–Zr	[1] Long 2020 cites Murray 1992 doi	Table 4, p. 7, row 11 report
-43.012 unknown	Al3Zr		model		Al–Zr	[2] Tamim 2018	Table 3, p. 9, row 17 report
-40.63 kJ/mol-atom	Al3Zr	298.15	model	CALPHAD	Al–Zr	[4] Fischer 2015 cites Saunders 1989	Table 2, p. 4, row 4 report
-40.6 kJ/mol-atom	Al3Zr		model	CALPHAD	Al–Zr	[1] Long 2020 cites Saunders 1986 doi	Table 4, p. 7, row 9 report
-40.6 kJ/mol-atom	Al3Zr	1	model		Al–Zr	[5] Saunders 1986	Table 4, p. 8, row 8 report
-40.6 kJ/mol-atom	Al3Zr	298.15	model	CALPHAD	Al–Zr	[4] Fischer 2015 cites Harvey 2012 doi	Table 2, p. 4, row 6 report
-40.5 kJ/mol-atom	ZrAl3		model		Al–Zr	[3] T 2001 cites Saunders 1989	Table 2, p. 2, row 30 report
-40.5 unknown	Al3Zr		model	CALPHAD	Al–Zr	[2] Tamim 2018 cites Saunders 1988	Table 3, p. 9, row 88 report
-40.5 kJ/mol-atom	Al3Zr		model	CALPHAD	Al–Zr	[1] Long 2020 cites Saunders 1989	Table 4, p. 7, row 10 report
-39.973 unknown	Al3Zr		model		Al–Zr	[2] Tamim 2018	Table 3, p. 9, row 18 report
-39.59 kJ/mol-atom	Al3Zr	298.15	model		Al–Zr	[4] Fischer 2015 cites Zhang 2010 doi	Table 2, p. 4, row 9 report
-39.52 kJ/mol-atom	Al3Zr		model		Al–Zr	[5] Saunders 1986	Table 2, p. 5, row 2 report
-39 unknown	Al3Zr		model	CALPHAD	Al–Zr	[2] Tamim 2018 cites Murray 1992 doi	Table 3, p. 9, row 24 report
-37.8 kJ/mol-atom	Al3Zr	298.15	model		Al–Zr	[4] Fischer 2015 cites Harvey 2012 doi	Table 2, p. 4, row 12 report
-36.2 unknown	Al3Zr		model	CALPHAD	Al–Zr	[2] Tamim 2018 cites Saunders 1988	Table 3, p. 9, row 23 report
-188.5 eV/kJ mol−1	Al3Zr- D023	0	DFT		Al–Zr	[6] Khvan 2018	Table 1, p. 4, row 5 report
-178.5 eV/kJ mol−1	Al3Zr_L12	0	DFT	ab-initio	Al–Zr	[6] Khvan 2018	Table 1, p. 4, row 15 report
-178.4 eV/kJ mol−1	Al3Zr- D022	0	DFT		Al–Zr	[6] Khvan 2018	Table 1, p. 4, row 4 report
-49.106 unknown	Al3Zr		DFT	ab initio	Al–Zr	[2] Tamim 2018 cites Ghosh 2005 doi	Table 3, p. 9, row 84 report
-49.106 kJ/mol-atom	Al3Zr		DFT	Ab-initio	Al–Zr	[1] Long 2020 cites Ghosh 2005 doi	Table 4, p. 7, row 4 report
-46.78 kJ/mol-atom	Al3Zr		DFT	Ab-initio	Al–Zr	[1] Long 2020 cites Duan 2013	Table 4, p. 7, row 2 report
-46.78 unknown	Al3Zr		DFT	ab initio	Al–Zr	[2] Tamim 2018 cites Duan 2014 doi	Table 3, p. 9, row 82 report
-46.77 kJ/mol-atom	Al3Zr		DFT	Ab-initio	Al–Zr	[1] Long 2020 cites Wang 2011 doi	Table 4, p. 7, row 3 report
-46.77 unknown	Al3Zr		DFT	ab initio	Al–Zr	[2] Tamim 2018 cites Wang 2011 doi	Table 3, p. 9, row 83 report
-39.593 kJ/mol-atom	Al3Zr		DFT	Ab-initio	Al–Zr	[1] Long 2020 cites Zhang 2010 doi	Table 4, p. 7, row 5 report
-37.599 unknown	Al3Zr		DFT	ab initio	Al–Zr	[2] Tamim 2018 cites Ghosh 2005 doi	Table 3, p. 9, row 21 report
-36.02 unknown	Al3Zr		DFT	ab initio	Al–Zr	[2] Tamim 2018 cites Wang 2011 doi	Table 3, p. 9, row 20 report
-35.308 unknown	Al3Zr		DFT	ab initio	Al–Zr	[2] Tamim 2018 cites Duan 2014 doi	Table 3, p. 9, row 19 report
-1.954 eV/f.u.	Al3Zr- D023	0	DFT		Al–Zr	[6] Khvan 2018	Table 1, p. 4, row 5 report
-1.85 eV/f.u.	Al3Zr_L12	0	DFT	ab-initio	Al–Zr	[6] Khvan 2018	Table 1, p. 4, row 15 report
-1.849 eV/f.u.	Al3Zr- D022	0	DFT		Al–Zr	[6] Khvan 2018	Table 1, p. 4, row 4 report

Uncertainty budget

Components kept separate, in the value's unit (literature SCHEMA.md, UNCERTAINTY_CALIBRATION.md): effective = max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter). The method floor is the robust between-study scatter of the method class in ORCHID (calibrated) or a documented prior; printed values and printed uncertainties are unchanged.

Uncertainty budget of the literature values of Al3Zr
Value	Unit	Printed	Reading	Method (class, basis)	Effective
-51.6	kJ/mol-atom	1.2	0.05	3.5 (unknown, calibrated)	3.5
-49	kJ/mol-atom	4	0.05	3.5 (unknown, calibrated)	4
-49	unknown	4	0.05	unit 'unknown' not convertible to kJ/mol-atom	4
-49	kJ/mol-atom		0.5	3.5 (unknown, calibrated)	3.5
-48.4	kJ/mol-atom	1.3	0.05	3.5 (unknown, calibrated)	3.5
-48.4	kJ/mol-atom		0.05	3.5 (unknown, calibrated)	3.5
-48.4	kJ/mol-atom	1	0.05	3.5 (unknown, calibrated)	3.5
-48.4	unknown	1.3	0.05	unit 'unknown' not convertible to kJ/mol-atom	1.3
-48	unknown	4	0.05	unit 'unknown' not convertible to kJ/mol-atom	4
-44	unknown		0.05	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-44	kJ/mol-atom		0.5	3.5 (unknown, calibrated)	3.5
-40.75	kJ/mol-atom		0.005	3.5 (unknown, calibrated)	3.5
-40.75	kJ/mol-atom		0.005	3.5 (unknown, calibrated)	3.5
-187.12	unknown		0.005	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-52.87	kJ/mol-atom		0.005	3.9 (model_calculated, calibrated)	3.9
-51.5	unknown		0.05	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-49.11	kJ/mol-atom		0.005	3.9 (model_calculated, calibrated)	3.9
-48.541	kJ/mol-atom		5.000e-4	3.9 (model_calculated, calibrated)	3.9
-48.5	unknown		0.05	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-48.5	kJ/mol-atom		0.05	3.9 (model_calculated, calibrated)	3.9
-48.5	kJ/mol-atom		0.05	3.9 (model_calculated, calibrated)	3.9
-47.17	kJ/mol-atom		0.005	3.9 (model_calculated, calibrated)	3.9
-47.09	kJ/mol-atom		0.005	3.9 (model_calculated, calibrated)	3.9
-46.97	kJ/mol-atom		0.005	3.9 (model_calculated, calibrated)	3.9
-46.78	kJ/mol-atom		0.005	3.9 (model_calculated, calibrated)	3.9
-46.78	kJ/mol-atom		0.005	3.9 (model_calculated, calibrated)	3.9
-46.779	kJ/mol-atom		5.000e-4	3.9 (model_calculated, calibrated)	3.9
-46.77	kJ/mol-atom		0.005	3.9 (model_calculated, calibrated)	3.9
-46.63	unknown		0.005	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-44.321	unknown		5.000e-4	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-44.321	kJ/mol-atom		5.000e-4	3.9 (model_calculated, calibrated)	3.9
-44.3	kJ/mol-atom		0.05	3.9 (model_calculated, calibrated)	3.9
-44.298	unknown		5.000e-4	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-44.298	kJ/mol-atom		5.000e-4	3.9 (model_calculated, calibrated)	3.9
-43.012	unknown		5.000e-4	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-40.63	kJ/mol-atom		0.005	3.9 (model_calculated, calibrated)	3.9
-40.6	kJ/mol-atom		0.05	3.9 (model_calculated, calibrated)	3.9
-40.6	kJ/mol-atom		5.000e-4	3.9 (model_calculated, calibrated)	3.9
-40.6	kJ/mol-atom		0.05	3.9 (model_calculated, calibrated)	3.9
-40.5	kJ/mol-atom		0.05	3.9 (model_calculated, calibrated)	3.9
-40.5	unknown		0.05	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-40.5	kJ/mol-atom		0.05	3.9 (model_calculated, calibrated)	3.9
-39.973	unknown		5.000e-4	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-39.59	kJ/mol-atom		0.005	3.9 (model_calculated, calibrated)	3.9
-39.52	kJ/mol-atom		0.005	3.9 (model_calculated, calibrated)	3.9
-39	unknown		0.05	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-37.8	kJ/mol-atom		0.05	3.9 (model_calculated, calibrated)	3.9
-36.2	unknown		0.05	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-188.5	eV/kJ mol−1		0.05	0.348 (dft, calibrated)	0.348
-178.5	eV/kJ mol−1		0.05	0.348 (dft, calibrated)	0.348
-178.4	eV/kJ mol−1		0.05	0.348 (dft, calibrated)	0.348
-49.106	unknown		5.000e-4	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-49.106	kJ/mol-atom		5.000e-4	8.395 (dft, calibrated)	8.395
-46.78	kJ/mol-atom		0.005	8.395 (dft, calibrated)	8.395
-46.78	unknown		0.005	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-46.77	kJ/mol-atom		0.005	8.395 (dft, calibrated)	8.395
-46.77	unknown		0.005	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-39.593	kJ/mol-atom		5.000e-4	8.395 (dft, calibrated)	8.395
-37.599	unknown		5.000e-4	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-36.02	unknown		0.005	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-35.308	unknown		5.000e-4	unit 'unknown' not convertible to kJ/mol-atom	unit 'unknown' not convertible to kJ/mol-atom
-1.954	eV/f.u.		5.000e-4	0.348 (dft, calibrated)	0.348
-1.85	eV/f.u.		0.005	0.348 (dft, calibrated)	0.348
-1.849	eV/f.u.		5.000e-4	0.348 (dft, calibrated)	0.348

DFT formation energies

Lowest-energy entries at this composition. Materials Project and OQMD use different energy references and are never averaged. 1 eV/atom = 96.485 kJ/mol-atom.

DFT formation energy of Al3Zr
Source	Entry	kJ/mol-atom	eV/atom	Space group	E above hull (kJ/mol-atom)	E above hull (eV/atom)	Theoretical
Materials Project	mp-aaaaaapf	-47.013	-0.487257	I4/mmm	0	0	no
OQMD	oqmd-18198	-47.081	-0.487957	I4/mmm	0	0	no

DFT sources: A. Jain et al., Commentary: The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002. doi:10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501-1509; S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010. doi:10.1007/s11837-013-0755-4 (CC BY 4.0);

Sources

Zhaohui Long, Dongyu Cui, Hongxing Hu, Zhi Li, Fucheng Yin, Touwen Fan, Thermodynamic Modeling of the Al-Li-Zr Ternary System, J. Phase Equilib. Diffus. 41, 623-641 (2020). doi:10.1007/s11669-020-00827-z
Rkia Tamim, Kamal Mahdouk, Thermodynamic reassessment of the Al–Zr binary system, J Therm Anal Calorim 131, 1187-1200 (2018). doi:10.1007/s10973-017-6635-3
T. Wang, Z. Jin, J.-C. Zhao, J. Phase Equilib., 22, 544-51(2001). doi:10.1007/s12385-001-0072-4
Evelyne Fischer, Catherine Colinet, An Updated Thermodynamic Modeling of the Al-Zr System, J. Phase Equilib. Diffus. 36, 404-413 (2015). doi:10.1007/s11669-015-0398-y
N. Saunders, V. G. Rivlin, Thermodynamic characterization of Al–Cr, Al–Zr, and Al–Cr–Zr alloy systems, Materials Science and Technology 2, 520-527 (1986). doi:10.1179/mst.1986.2.6.520
A.V. Khvan, D.G. Eskin, K.F. Starodub, A.T. Dinsdale, F. Wang, C. Fang et al., New insights into solidification and phase equilibria in the Al-Al3Zr system: Theoretical and experimental investigations, Journal of Alloys and Compounds 743, 626-638 (2018). doi:10.1016/j.jallcom.2018.02.023

Please cite

R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735569
R. Arróyave, J. Saal, D. Shin, ORCHID-Parity: DFT-vs-experiment formation-enthalpy benchmark (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23735943
R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). doi:10.5281/zenodo.23736065

Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); G. Kim, S. V. Meschel, P. Nash, W. Chen, Experimental formation enthalpies for intermetallic phases and other inorganic compounds, Scientific Data 4 (2017) 170162, https://doi.org/10.1038/sdata.2017.162; B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file. Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.

@misc{orchid_literature_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735569},
  url       = {https://doi.org/10.5281/zenodo.23735569},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_dft_benchmark_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID-Parity: DFT-vs-experiment formation-enthalpy benchmark}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23735943},
  url       = {https://doi.org/10.5281/zenodo.23735943},
  note      = {Version 1, machine-extracted}
}

@misc{orchid_data_2026,
  author    = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon},
  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},
  version   = {2026.10},
  publisher = {Zenodo},
  year      = {2026},
  doi       = {10.5281/zenodo.23736065},
  url       = {https://doi.org/10.5281/zenodo.23736065},
  note      = {Version 1, machine-extracted}
}