Al9Sr5: enthalpy of formation

2 accepted literature formation-enthalpy value(s) (DFT 2).

Systems: Al–Sr

Literature values

Enthalpy of formation of Al9Sr5 reported in the literature (2)
ValuePhase as printedT (K)ClassMethodSystemSourceLocationQuote
-29.4 kJ/mol-atomAl9Sr50DFTFirst-principlesAl–Sr[1] Zhong 2004Table 3, p. 6, row 39
report
-27.7 kJ/mol-atomAl9Sr50DFTFirst-principlesAl–Sr[1] Zhong 2004Table 3, p. 6, row 40
report

Uncertainty budget

Components kept separate, in the value's unit (literature SCHEMA.md, UNCERTAINTY_CALIBRATION.md): effective = max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter). The method floor is the robust between-study scatter of the method class in ORCHID (calibrated) or a documented prior; printed values and printed uncertainties are unchanged.

Uncertainty budget of the literature values of Al9Sr5
ValueUnitPrintedReadingMethod (class, basis)CompositionScatterConversionEffective
-29.4kJ/mol-atom0.058.395 (dft, calibrated)8.395
-27.7kJ/mol-atom0.058.395 (dft, calibrated)8.395

Sources

  1. Yu Zhong, C. Wolverton, Y. Austin Chang, Zi-Kui Liu, A combined CALPHAD/first-principles remodeling of the thermodynamics of Al–Sr: unsuspected ground state energies by “rounding up the (un)usual suspects”, Acta Materialia 52, 2739-2754 (2004). doi:10.1016/j.actamat.2004.02.022