AlLi2Zr: enthalpy of formation

2 accepted literature formation-enthalpy value(s) (model 1, DFT 1).

Systems: Al–Li–Zr

Literature values

Enthalpy of formation of AlLi2Zr reported in the literature (2)
ValuePhase as printedT (K)ClassMethodSystemSourceLocationQuote
-3.8946 kJ/mol (basis unstated)AlLi2ZrmodelAl–Li–Zr[1] Long 2020Table 6, p. 15, row 1
report
-3.4662 kJ/mol (basis unstated)AlLi2ZrDFTAl–Li–Zr[1] Long 2020Table 6, p. 15, row 1
report

Uncertainty budget

Components kept separate, in the value's unit (literature SCHEMA.md, UNCERTAINTY_CALIBRATION.md): effective = max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter). The method floor is the robust between-study scatter of the method class in ORCHID (calibrated) or a documented prior; printed values and printed uncertainties are unchanged.

Uncertainty budget of the literature values of AlLi2Zr
ValueUnitPrintedReadingMethod (class, basis)CompositionScatterConversionEffective
-3.8946kJ/mol (basis unstated)5.000e-515.6 (model_calculated, calibrated)15.6
-3.4662kJ/mol (basis unstated)5.000e-533.58 (dft, calibrated)33.58

Sources

  1. Zhaohui Long, Dongyu Cui, Hongxing Hu, Zhi Li, Fucheng Yin, Touwen Fan, Thermodynamic Modeling of the Al-Li-Zr Ternary System, J. Phase Equilib. Diffus. 41, 623-641 (2020). doi:10.1007/s11669-020-00827-z