AlNi8Pr3: enthalpy of formation

3 accepted literature formation-enthalpy value(s) (model 2, DFT 1).

Systems: Al–Ni–Pr

Literature values

Enthalpy of formation of AlNi8Pr3 reported in the literature (3)
ValuePhase as printedT (K)ClassMethodSystemSourceLocationQuote
-38.59 kJ/mol-atomNi₈AlPr₃modelAl–Ni–Pr[1] Liao 2019Table 4, p. 6, row 20
report
-37.18 kJ/mol-atomNi₈AlPr₃modelAl–Ni–Pr[1] Liao 2019Table 4, p. 6, row 18
report
-30.96 kJ/mol-atomNi8AlPr3DFTAl–Ni–Pr[1] Liao 2019
cites Jain 2013		Table 4, p. 6, row 19
report

Uncertainty budget

Components kept separate, in the value's unit (literature SCHEMA.md, UNCERTAINTY_CALIBRATION.md): effective = max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter). The method floor is the robust between-study scatter of the method class in ORCHID (calibrated) or a documented prior; printed values and printed uncertainties are unchanged.

Uncertainty budget of the literature values of AlNi8Pr3
ValueUnitPrintedReadingMethod (class, basis)CompositionScatterConversionEffective
-38.59kJ/mol-atom0.0053.9 (model_calculated, calibrated)3.9
-37.18kJ/mol-atom0.0053.9 (model_calculated, calibrated)3.9
-30.96kJ/mol-atom0.0053.929 (dft, calibrated)3.929

Sources

  1. Jinfa Liao, Yuehui Liao, Hang Wang, Ligang Zhang, Yue Ma, Thermodynamic optimization of the Ni–Al–Pr ternary system, Mater. Res. Express 6, 086512 (2019). doi:10.1088/2053-1591/ab19fa