# Au51Ce14: enthalpy of formation > Enthalpy of formation of Au51Ce14: 9 literature value(s) with sources, pages and quotes, from ORCHID. HTML: https://data.orchid-project.org/compounds/Au51Ce14.html · Markdown: https://data.orchid-project.org/compounds/Au51Ce14.md 9 accepted literature formation-enthalpy value(s) (experimental 5, model 4); experimental median -49.5 kJ/mol-atom (n = 5). Systems: [Au–Ce](https://data.orchid-project.org/systems/AU-CE.html) ## Literature values Table: Enthalpy of formation of Au51Ce14 reported in the literature (9) | Value | Phase as printed | T (K) | Class | Method | System | Source | Location | Quote | |---:|---|---:|---|---|---|---|---|---| | -55 kJ/mol-atom ± 1.7 | αCe14Au51 | 1123 | experimental | Calorimetry | [Au–Ce](https://data.orchid-project.org/systems/AU-CE.html) | [1] Moustaine 2016; _cites Janghorban 1994_ | Table 2, p. 3, row 22; `ORC-QJDXXXFN2P` | | | -53.2 kJ/mol-atom ± 1.9 | αCe14Au51 | 298.15 | experimental | Calorimetry | [Au–Ce](https://data.orchid-project.org/systems/AU-CE.html) | [1] Moustaine 2016; _cites Janghorban 1994_ | Table 2, p. 3, row 24; `ORC-3EJL3XSNS3` | | | -49.5 kJ/mol-atom ± 2.2 | Au51Ce14 | 298.15 | experimental | calorimetry | [Au–Ce](https://data.orchid-project.org/systems/AU-CE.html) | [2] Dong 2013; _cites Fitzner 1993_ | Table 4, p. 4, row 13; `ORC-XMEGCVQUVQ.0e8da6` | | | -49.5 kJ/mol-atom ± 2.2 | αCe14Au51 | 298.15 | experimental | Calorimetry | [Au–Ce](https://data.orchid-project.org/systems/AU-CE.html) | [1] Moustaine 2016; _cites Fitzner 1993_ [doi](https://doi.org/10.1007/bf02657857) | Table 2, p. 3, row 25; `ORC-YWV2PVBMJG` | | | -44 kJ/mol-atom ± 5 | αCe14Au51 | 1223 | experimental | Calorimetry | [Au–Ce](https://data.orchid-project.org/systems/AU-CE.html) | [1] Moustaine 2016; _cites LomelloeTafin 2006_ | Table 2, p. 3, row 23; `ORC-BTF2MJDJVD` | | | -57.71 kJ/mol-atom | αCe14Au51 | 298.15 | model | Optimization | [Au–Ce](https://data.orchid-project.org/systems/AU-CE.html) | [1] Moustaine 2016; _cites Dong 2013_ [doi](https://doi.org/10.1016/j.calphad.2013.07.013) | Table 2, p. 3, row 26; `ORC-623GB6EO3D.fc5d45` | | | -57.71 kJ/mol-atom | Au51Ce14 | 289 | model | | [Au–Ce](https://data.orchid-project.org/systems/AU-CE.html) | [2] Dong 2013 | Table 4, p. 4, row 14; `ORC-HB4FDN2SJV.7027a3` | | | -55.99 kJ/mol-atom | αCe14Au51 | 298.15 | model | Optimization | [Au–Ce](https://data.orchid-project.org/systems/AU-CE.html) | [1] Moustaine 2016 | Table 2, p. 3, row 27; `ORC-GTQ3UJBWPM.418ac2` | | | -53.1 kJ/mol-atom | βCe14Au51 | 298.15 | model | Optimization | [Au–Ce](https://data.orchid-project.org/systems/AU-CE.html) | [1] Moustaine 2016 | Table 2, p. 3, row 28; `ORC-LWJM5JSKV7.8b5cfd` | | ### Uncertainty budget Components kept separate, in the value's unit (literature [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md), [UNCERTAINTY_CALIBRATION.md](https://data.orchid-project.org/literature/UNCERTAINTY_CALIBRATION.md)): effective = max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter). The method floor is the robust between-study scatter of the method class in ORCHID (calibrated) or a documented prior; printed values and printed uncertainties are unchanged. Table: Uncertainty budget of the literature values of Au51Ce14 | Value | Unit | Printed | Reading | Method (class, basis) | Composition | Scatter | Conversion | Effective | |---:|---|---:|---:|---|---:|---:|---:|---:| | -55 | kJ/mol-atom | 1.7 | 0.5 | 3.2 (solution_reaction_calorimetry, calibrated) | | | | 3.2 | | -53.2 | kJ/mol-atom | 1.9 | 0.05 | 3.2 (solution_reaction_calorimetry, calibrated) | | | | 3.2 | | -49.5 | kJ/mol-atom | 2.2 | 0.05 | 3.2 (solution_reaction_calorimetry, calibrated) | | | | 3.2 | | -49.5 | kJ/mol-atom | 2.2 | 0.05 | 3.2 (solution_reaction_calorimetry, calibrated) | | | | 3.2 | | -44 | kJ/mol-atom | 5 | 0.5 | 3.2 (solution_reaction_calorimetry, calibrated) | | | | 5 | | -57.71 | kJ/mol-atom | | 0.005 | 3.9 (model_calculated, calibrated) | | | | 3.9 | | -57.71 | kJ/mol-atom | | 0.005 | 3.9 (model_calculated, calibrated) | | | | 3.9 | | -55.99 | kJ/mol-atom | | 0.005 | 3.9 (model_calculated, calibrated) | | | | 3.9 | | -53.1 | kJ/mol-atom | | 0.05 | 3.9 (model_calculated, calibrated) | | | | 3.9 | ## Sources 1. D. Moustaine, K. Mahdouk, Thermodynamic reassessment of the cerium gold binary system, Journal of Alloys and Compounds 683, 599-609 (2016). [doi:10.1016/j.jallcom.2016.05.116](https://doi.org/10.1016/j.jallcom.2016.05.116) 2. H.Q. Dong, X.M. Tao, T. Laurila, V. Vuorinen, M. Paulasto-Kröckel, Thermodynamic modeling of Au–Ce–Sn ternary system, Calphad 42, 38-50 (2013). [doi:10.1016/j.calphad.2013.07.013](https://doi.org/10.1016/j.calphad.2013.07.013) ## Please cite - R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569 - R. Arróyave, J. Saal, D. Shin, ORCHID-Parity: DFT-vs-experiment formation-enthalpy benchmark (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735943 - R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065 Also cite the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work); A. Jain et al., The Materials Project: A materials genome approach to accelerating materials innovation, APL Materials 1 (2013) 011002, https://doi.org/10.1063/1.4812323 (CC BY 4.0); J. E. Saal et al., JOM 65 (2013) 1501, https://doi.org/10.1007/s11837-013-0755-4 and S. Kirklin et al., npj Comput. Mater. 1 (2015) 15010, https://doi.org/10.1038/npjcompumats.2015.10 (CC BY 4.0); G. Kim, S. V. Meschel, P. Nash, W. Chen, Experimental formation enthalpies for intermetallic phases and other inorganic compounds, Scientific Data 4 (2017) 170162, https://doi.org/10.1038/sdata.2017.162; B. Hallstedt, The SGTE collection of binary datasets, Calphad 89 (2025) 102833, https://doi.org/10.1016/j.calphad.2025.102833 (CC BY 4.0), and the original assessment named in each file. Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes. ```bibtex @misc{orchid_literature_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23735569}, url = {https://doi.org/10.5281/zenodo.23735569}, note = {Version 1, machine-extracted} } @misc{orchid_dft_benchmark_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID-Parity: DFT-vs-experiment formation-enthalpy benchmark}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23735943}, url = {https://doi.org/10.5281/zenodo.23735943}, note = {Version 1, machine-extracted} } @misc{orchid_data_2026, author = {Arr{\'o}yave, Raymundo and Saal, James and Shin, Dongwon}, title = {{ORCHID data: umbrella record of the ORCHID datasets}}, version = {2026.10}, publisher = {Zenodo}, year = {2026}, doi = {10.5281/zenodo.23736065}, url = {https://doi.org/10.5281/zenodo.23736065}, note = {Version 1, machine-extracted} } ``` --- Derived data CC BY 4.0 ([licence](https://creativecommons.org/licenses/by/4.0/)): cite ORCHID ([CITATION.cff](https://data.orchid-project.org/CITATION.cff)) and the original sources. Quotes are short excerpts kept so that each value can be checked; they remain under the publishers' copyright and are not relicensed. Source papers, page images and full text are not redistributed. Field reference: [SCHEMA.md](https://data.orchid-project.org/literature/SCHEMA.md). Machine-readable guide: [llms.txt](https://data.orchid-project.org/llms.txt). Found an error? The report link of a value (Markdown: its id, ORC-..., in the Location column) opens a pre-filled GitHub issue, https://github.com/orchid-calphad/orchid-data/issues/new?template=report-value-error.yml&record_id=\, carrying only the record id, source and value; [how to contribute](https://orchid-project.org/contribute/).