Co2Ti: enthalpy of formation

2 accepted literature formation-enthalpy value(s) (experimental 1, model 1).

Systems: Co–Ti

Literature values

Enthalpy of formation of Co2Ti reported in the literature (2)
ValuePhase as printedT (K)ClassMethodSystemSourceLocationQuote
-34.1 kJ/mol (basis unstated)Co2Ti298.15experimentalCo–Ti[1] Wu 2020
cites Gachon 1981 doi
Table 7, p. 9, row 4
report
-32.2062 kJ/mol (basis unstated)Co2Ti298.15modelCo–Ti[1] Wu 2020Table 7, p. 9, row 3
report

Uncertainty budget

Components kept separate, in the value's unit (literature SCHEMA.md, UNCERTAINTY_CALIBRATION.md): effective = max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter). The method floor is the robust between-study scatter of the method class in ORCHID (calibrated) or a documented prior; printed values and printed uncertainties are unchanged.

Uncertainty budget of the literature values of Co2Ti
ValueUnitPrintedReadingMethod (class, basis)CompositionScatterConversionEffective
-34.1kJ/mol (basis unstated)5.000e-410.5 (unknown, calibrated)10.5
-32.2062kJ/mol (basis unstated)5.000e-511.7 (model_calculated, calibrated)11.7

Sources

  1. Liying Wu, Yinping Zeng, Yafei Pan, Yong Du, Yingbiao Peng, Han Li et al., Thermodynamic description and simulation of solidification microstructure in the Co-Ti system, The Journal of Chemical Thermodynamics 142, 105995 (2020). doi:10.1016/j.jct.2019.105995