Fe3Ho: enthalpy of formation

2 accepted literature formation-enthalpy value(s) (model 2).

Systems: Fe–Ho

Literature values

Enthalpy of formation of Fe3Ho reported in the literature (2)
ValuePhase as printedT (K)ClassMethodSystemSourceLocationQuote
-2.52 kJ/mol (basis unstated)Fe3Ho298.15modelOptimizationFe–Ho[1] Kardellass 2014Table 3, p. 3, row 10
report
-2 kJ/mol (basis unstated)Fe3Ho298.15modelPredictionFe–Ho[1] Kardellass 2014
cites Kardellass 2013
Table 3, p. 3, row 9
report

Uncertainty budget

Components kept separate, in the value's unit (literature SCHEMA.md, UNCERTAINTY_CALIBRATION.md): effective = max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter). The method floor is the robust between-study scatter of the method class in ORCHID (calibrated) or a documented prior; printed values and printed uncertainties are unchanged.

Uncertainty budget of the literature values of Fe3Ho
ValueUnitPrintedReadingMethod (class, basis)CompositionScatterConversionEffective
-2.52kJ/mol (basis unstated)0.00515.6 (model_calculated, calibrated)15.6
-2kJ/mol (basis unstated)0.0515.6 (model_calculated, calibrated)15.6

Sources

  1. S. Kardellass, C. Servant, N. Selhaoui, A. Iddaoudi, M. Ait Amar, L. Bouirden, A thermodynamic assessment of the Iron+Holmium phase diagram, The Journal of Chemical Thermodynamics 74, 78-84 (2014). doi:10.1016/j.jct.2013.11.037