Ge3Se7: enthalpy of formation

2 accepted literature formation-enthalpy value(s) (model 2).

Systems: Ge–Se

Literature values

Enthalpy of formation of Ge3Se7 reported in the literature (2)
ValuePhase as printedT (K)ClassMethodSystemSourceLocationQuote
-23.92 kJ/mol-atomGe3Se70modelFirst–principlesGe–Se[1] Chen 2022
cites Saal 2013		Table II, p. 3, row 28
report
-22.065 kJ/mol-atomGe3Se7298.15modelCALPHADGe–Se[1] Chen 2022Table II, p. 3, row 29
report

Uncertainty budget

Components kept separate, in the value's unit (literature SCHEMA.md, UNCERTAINTY_CALIBRATION.md): effective = max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter). The method floor is the robust between-study scatter of the method class in ORCHID (calibrated) or a documented prior; printed values and printed uncertainties are unchanged.

Uncertainty budget of the literature values of Ge3Se7
ValueUnitPrintedReadingMethod (class, basis)CompositionScatterConversionEffective
-23.92kJ/mol-atom0.0053.9 (model_calculated, calibrated)3.9
-22.065kJ/mol-atom5.000e-43.9 (model_calculated, calibrated)3.9

Sources

  1. Shanxiong Chen, Jiong Wang, Shangzhao Yu, Biao Hu, Qing Wu, Yong Du, Thermodynamic Modeling of the Ge-X (X = As, Se, S, P) Systems, J. Electron. Mater. 51, 2114-2130 (2022). doi:10.1007/s11664-022-09474-1