Ni19Sm5: enthalpy of formation

2 accepted literature formation-enthalpy value(s) (model 2).

Systems: Ni–Sm

Literature values

Enthalpy of formation of Ni19Sm5 reported in the literature (2)
ValuePhase as printedT (K)ClassMethodSystemSourceLocationQuote
-36.5 kJ/mol-atomSm5Ni19modelOptimizationNi–Sm[1] Rahou 2016
cites Su 1998 doi		Table 5, p. 6, row 21
report
-34.5 kJ/mol-atomSm5Ni19300modelOptimizationNi–Sm[1] Rahou 2016Table 5, p. 6, row 20
report

Uncertainty budget

Components kept separate, in the value's unit (literature SCHEMA.md, UNCERTAINTY_CALIBRATION.md): effective = max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter). The method floor is the robust between-study scatter of the method class in ORCHID (calibrated) or a documented prior; printed values and printed uncertainties are unchanged.

Uncertainty budget of the literature values of Ni19Sm5
ValueUnitPrintedReadingMethod (class, basis)CompositionScatterConversionEffective
-36.5kJ/mol-atom0.053.9 (model_calculated, calibrated)3.9
-34.5kJ/mol-atom0.053.9 (model_calculated, calibrated)3.9

Sources

  1. Z. Rahou, K. Mahdouk, Thermodynamic reassessment of the Sm–Ni binary system, Journal of Alloys and Compounds 664, 469-475 (2016). doi:10.1016/j.jallcom.2015.12.215