Pd9Si2: enthalpy of formation

2 accepted literature formation-enthalpy value(s) (DFT 2).

Systems: Pd–Si

Literature values

Enthalpy of formation of Pd9Si2 reported in the literature (2)
ValuePhase as printedT (K)ClassMethodSystemSourceLocationQuote
-42.7 kJ/mol (basis unstated)Pd9Si2-α0DFTfirst-principlesPd–Si[1] Zhou 2016Table I, p. 3, row 8
report
-42.7 kJ/mol (basis unstated)Pd9Si2-αDFTfirst-principlesPd–Si[1] Zhou 2016Table I, p. 3, row 8
report

Uncertainty budget

Components kept separate, in the value's unit (literature SCHEMA.md, UNCERTAINTY_CALIBRATION.md): effective = max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter). The method floor is the robust between-study scatter of the method class in ORCHID (calibrated) or a documented prior; printed values and printed uncertainties are unchanged.

Uncertainty budget of the literature values of Pd9Si2
ValueUnitPrintedReadingMethod (class, basis)CompositionScatterConversionEffective
-42.7kJ/mol (basis unstated)0.0549.83 (dft, calibrated)49.83
-42.7kJ/mol (basis unstated)0.0549.83 (dft, calibrated)49.83

Sources

  1. S. H. Zhou, Y. Huo, Ralph E. Napolitano, Phase Stability for the Pd-Si System: First-Principles, Experiments, and Solution-Based Modeling, Metall Mater Trans A 47, 194-208 (2016). doi:10.1007/s11661-015-3206-8