Si5U3: enthalpy of formation

2 accepted literature formation-enthalpy value(s) (model 2).

Systems: Si–U

Literature values

Enthalpy of formation of Si5U3 reported in the literature (2)
ValuePhase as printedT (K)ClassMethodSystemSourceLocationQuote
-44.26 kJ/mol-atomU3Si5298.15modelEstimationSi–U[1] Berche 2009
cites Rand 2009		Table 2, p. 2, row 11
report
-42.9 kJ/mol-atomU3Si5298.15modelModellingSi–U[1] Berche 2009Table 2, p. 2, row 12
report

Uncertainty budget

Components kept separate, in the value's unit (literature SCHEMA.md, UNCERTAINTY_CALIBRATION.md): effective = max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter). The method floor is the robust between-study scatter of the method class in ORCHID (calibrated) or a documented prior; printed values and printed uncertainties are unchanged.

Uncertainty budget of the literature values of Si5U3
ValueUnitPrintedReadingMethod (class, basis)CompositionScatterConversionEffective
-44.26kJ/mol-atom0.0053.9 (model_calculated, calibrated)3.9
-42.9kJ/mol-atom0.053.9 (model_calculated, calibrated)3.9

Sources

  1. A. Berche, C. Rado, O. Rapaud, C. Guéneau, J. Rogez, Thermodynamic study of the U–Si system, Journal of Nuclear Materials 389, 101-107 (2009). doi:10.1016/j.jnucmat.2009.01.014