Y13Zn58: enthalpy of formation

3 accepted literature formation-enthalpy value(s) (experimental 1, model 2); experimental median -37 kJ/mol-atom (n = 1).

Systems: Y–Zn

Literature values

Enthalpy of formation of Y13Zn58 reported in the literature (3)
ValuePhase as printedT (K)ClassMethodSystemSourceLocationQuote
-37 kJ/mol-atom ± 2Y13Zn58298.15experimentalY–Zn[1] Shao 2006
cites Mason 1976 doi		Table 2, p. 4, row 17
report
-36 kJ/mol-atomY13Zn58modelCALPHADY–Zn[1] Shao 2006Table 2, p. 4, row 16
report
-32 kJ/mol-atomY13Zn58modelY–Zn[1] Shao 2006
cites F 1988		Table 2, p. 4, row 18
report

Uncertainty budget

Components kept separate, in the value's unit (literature SCHEMA.md, UNCERTAINTY_CALIBRATION.md): effective = max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter). The method floor is the robust between-study scatter of the method class in ORCHID (calibrated) or a documented prior; printed values and printed uncertainties are unchanged.

Uncertainty budget of the literature values of Y13Zn58
ValueUnitPrintedReadingMethod (class, basis)CompositionScatterConversionEffective
-37kJ/mol-atom20.53.5 (unknown, calibrated)3.5
-36kJ/mol-atom0.053.9 (model_calculated, calibrated)3.9
-32kJ/mol-atom0.53.9 (model_calculated, calibrated)3.9

Sources

  1. G. Shao, V. Varsani, Z. Fan, Thermodynamic modelling of the Y–Zn and Mg–Zn–Y systems, Calphad 30, 286-295 (2006). doi:10.1016/j.calphad.2006.03.005