{
  "counts": {
    "above_hull": 0,
    "entries": 6,
    "intervals": 5,
    "vertices": 6
  },
  "elements": [
    "MN",
    "P"
  ],
  "flags": [
    "has_intermediate_phases",
    "liquid_on_hull",
    "solution_phases"
  ],
  "isotherms": [
    {
      "element_reference": {
        "MN": {
          "energy": -9606.564518645404,
          "phase": "CBCC_A12"
        },
        "P": {
          "energy": -24276.60355812102,
          "phase": "RED_P"
        }
      },
      "intervals": [
        {
          "enthalpy": {
            "intercept": 0.0,
            "slope": -159205.94197224654
          },
          "entropy": {
            "intercept": 0.0,
            "slope": 9.365190810887682
          },
          "intercept": 0.0,
          "kind": "two_phase",
          "left": {
            "phase": "CBCC_A12",
            "x": 0.0
          },
          "mu_a_rel": 0.0,
          "mu_b_rel": -161998.17361251276,
          "right": {
            "phase": "MN3P_D0E",
            "x": 0.25
          },
          "slope": -161998.17361251276,
          "x_hi": 0.25,
          "x_lo": 0.0
        },
        {
          "enthalpy": {
            "intercept": -10555.544094116114,
            "slope": -116983.76559578208
          },
          "entropy": {
            "intercept": -2.7178756662869157,
            "slope": 20.236693476035345
          },
          "intercept": -9745.209464212712,
          "kind": "two_phase",
          "left": {
            "phase": "MN3P_D0E",
            "x": 0.25
          },
          "mu_a_rel": -9745.209464212712,
          "mu_b_rel": -132762.54521987462,
          "right": {
            "phase": "MN2P_C22",
            "x": 0.3333333333333333
          },
          "slope": -123017.33575566192,
          "x_hi": 0.3333333333333333,
          "x_lo": 0.25
        },
        {
          "enthalpy": {
            "intercept": -46303.66336579152,
            "slope": -9739.40778075585
          },
          "entropy": {
            "intercept": -0.6118077408470413,
            "slope": 13.918489699715723
          },
          "intercept": -46121.25288785799,
          "kind": "two_phase",
          "left": {
            "phase": "MN2P_C22",
            "x": 0.3333333333333333
          },
          "mu_a_rel": -46121.25288785799,
          "mu_b_rel": -60010.45837258407,
          "right": {
            "phase": "LIQUID",
            "x": 0.5434754357536221
          },
          "slope": -13889.205484726079,
          "x_hi": 0.5434754357536221,
          "x_lo": 0.3333333333333333
        },
        {
          "enthalpy": {
            "entropy_form": null,
            "hermite": [
              [
                -51596.792253420026,
                -4064.4760157432456,
                24787.51848067504,
                3804.155794075712
              ]
            ],
            "knots": [
              0.5434754357536221,
              0.8338328409357464
            ],
            "max_abs_error": 0.1826193715678528
          },
          "entropy": {
            "entropy_form": {
              "R": 8.31446261815324,
              "kind": "ideal_mixing_entropy"
            },
            "hermite": [
              [
                1.220873473545418,
                0.3204105408372168,
                5.6212917085011895,
                1.1709911768536045
              ]
            ],
            "knots": [
              0.5434754357536221,
              0.8338328409357464
            ],
            "max_abs_error": 5.558353737145083e-05
          },
          "entropy_form": {
            "RT": 2478.957029602388,
            "kind": "ideal_mixing"
          },
          "hermite": [
            [
              -51960.795679557596,
              -4160.006418494019,
              23111.530357787175,
              3455.0247746951645
            ]
          ],
          "kind": "single_phase",
          "knots": [
            0.5434754357536221,
            0.8338328409357464
          ],
          "max_abs_error": 0.16604713986453135,
          "phase": "LIQUID",
          "x_hi": 0.8338328409357464,
          "x_lo": 0.5434754357536221
        },
        {
          "enthalpy": {
            "intercept": -162905.8000801786,
            "slope": 162905.8000801786
          },
          "entropy": {
            "intercept": 72.65605072123851,
            "slope": -72.65605072123851
          },
          "intercept": -184568.2016027159,
          "kind": "two_phase",
          "left": {
            "phase": "LIQUID",
            "x": 0.8338328409357464
          },
          "mu_a_rel": -184568.2016027159,
          "mu_b_rel": 0.0,
          "right": {
            "phase": "RED_P",
            "x": 1.0
          },
          "slope": 184568.2016027159,
          "x_hi": 1.0,
          "x_lo": 0.8338328409357464
        }
      ],
      "temperature_K": 298.15,
      "vertices": [
        {
          "collinear": false,
          "degenerate": [],
          "energy": 0.0,
          "energy_per_atom": 0.0,
          "enthalpy": 0.0,
          "entries_at_x": 1,
          "entropy": 0.0,
          "formula": "",
          "nsites": null,
          "phase": "CBCC_A12",
          "phase_kind": "solution",
          "spacegroup_number": null,
          "spacegroup_symbol": "",
          "theoretical": false,
          "x": 0.0
        },
        {
          "collinear": false,
          "degenerate": [],
          "energy": -40499.54340312819,
          "energy_per_atom": -40499.54340312819,
          "enthalpy": -39801.485493061635,
          "entries_at_x": 1,
          "entropy": 2.3412977027219206,
          "formula": "",
          "nsites": null,
          "phase": "MN3P_D0E",
          "phase_kind": "solution",
          "spacegroup_number": null,
          "spacegroup_symbol": "",
          "theoretical": false,
          "x": 0.25
        },
        {
          "collinear": false,
          "degenerate": [],
          "energy": -50750.98804943335,
          "energy_per_atom": -50750.98804943335,
          "enthalpy": -49550.13262604347,
          "entries_at_x": 1,
          "entropy": 4.027688825724866,
          "formula": "",
          "nsites": null,
          "phase": "MN2P_C22",
          "phase_kind": "solution",
          "spacegroup_number": null,
          "spacegroup_symbol": "",
          "theoretical": false,
          "x": 0.3333333333333333
        },
        {
          "collinear": false,
          "degenerate": [],
          "energy": -53669.69489094109,
          "energy_per_atom": -53669.69489094109,
          "enthalpy": -51596.792253420026,
          "entries_at_x": 1,
          "entropy": 6.952549513738262,
          "formula": "",
          "nsites": null,
          "phase": "LIQUID",
          "phase_kind": "solution",
          "spacegroup_number": null,
          "spacegroup_symbol": "",
          "theoretical": false,
          "x": 0.5434754357536221
        },
        {
          "collinear": false,
          "degenerate": [],
          "energy": -30669.173713921722,
          "energy_per_atom": -30669.173713921722,
          "enthalpy": -27069.593994412535,
          "entries_at_x": 1,
          "entropy": 12.07304953717652,
          "formula": "",
          "nsites": null,
          "phase": "LIQUID",
          "phase_kind": "solution",
          "spacegroup_number": null,
          "spacegroup_symbol": "",
          "theoretical": false,
          "x": 0.8338328409357464
        },
        {
          "collinear": false,
          "degenerate": [],
          "energy": 0.0,
          "energy_per_atom": 0.0,
          "enthalpy": 0.0,
          "entries_at_x": 1,
          "entropy": 0.0,
          "formula": "",
          "nsites": null,
          "phase": "RED_P",
          "phase_kind": "solution",
          "spacegroup_number": null,
          "spacegroup_symbol": "",
          "theoretical": false,
          "x": 1.0
        }
      ]
    }
  ],
  "mp_agreement": {
    "comparable": false,
    "comparable_note": "CALPHAD isotherms have no upstream stability flag to compare against",
    "max_abs_delta_energy_above_hull": 0.0,
    "only_mp_stable": [],
    "only_ours_stable": [],
    "stable_sets_match": true
  },
  "provenance": {
    "assessment": "MnP-01Mie",
    "builder_version": 1,
    "engine": {
      "numpy": "2.5.1",
      "pycalphad": "0.11.2",
      "python": "3.13.15"
    },
    "fit_tol": 1.0,
    "observed_at": "2026-09-03T00:48:40Z",
    "phase_families": {},
    "sample_conditions": {
      "endpoint_tol": 1.0,
      "fit_samples": 65,
      "order_tol": 0.0001,
      "pressure_Pa": 101325.0,
      "redundant_tol": 1.0,
      "refine_tol": 1e-07,
      "step": 0.002,
      "temperature_K": 298.15
    },
    "source_path": "databases/sgte-binary/MnP-01Mie.tdb",
    "source_sha256": "10848464fabd372b159aec2be51469aac815cc9abdb7e443954efd4646612aea"
  },
  "reference": {
    "kind": "calphad_formation_T",
    "per": "mole_atoms",
    "temperature_K": 298.15,
    "units": "J/mol-atoms"
  },
  "schema_version": 1,
  "system_id": "MN-P",
  "x_element": "P"
}
