{"artifacts":{"doi:10.1007/s11664-998-0205-1/p9/text-04":{"artifact":"text_passage","label":"page 9, passage 4","page":9},"sha256:bba11faad58fcbcf/p8/tab-iv":{"artifact":"table","caption":"The Measured Liquidus Temperatures for Some Sn-Rich Alloys","label":"IV","page":8}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{"doi:10.1007/s11664-998-0205-1":{"context_id":"context:source-doi-10-1007-s11664-998-0205-1","items":[{"applies_to":"samples","extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-C47SCTU3JD","page":6,"quote":"After standard metallographic preparation, the samples were analyzed by optical microscopy and the SEM/EPMA technique.","second_reader_agrees":false,"type":"measurement"},{"applies_to":"six different Sn-rich ternary alloys","atmosphere":"dry nitrogen atmosphere","calibration":"pure indium","extraction_accepted":true,"heating_or_cooling_rate":"5°C/min","id":"ORC-EC74OUJWHR","method":"DSC","page":6,"quote":"DSC measurements were made to detect the melting temperature range of six different Sn-rich ternary alloys. The heating and cooling rate used was 5°C/min and the experiments were made under a dry nitrogen atmosphere. A reference run was made with pure indium.","second_reader_agrees":true,"type":"measurement"},{"applies_to":"specimens","extraction_accepted":false,"id":"ORC-HDV6PW3OT5","method":"optical microscopy, SEM, and qualitative energy dispersive spectroscopy (EDS)","page":6,"quote":"The specimens were aircooled and prepared for optical microscopy, SEM, and qualitative energy dispersive spectroscopy (EDS) analysis.","second_reader_agrees":false,"type":"measurement"},{"applies_to":"reaction layers at the interfacial region","extraction_accepted":false,"id":"ORC-N3WURWW5P6","method":"electron probe microanalysis (EPMA)","page":7,"quote":"The reaction layers at the interfacial region were studied by electron probe microanalysis (EPMA), and a layer of ζ-phase was found on both specimens.","second_reader_agrees":false,"type":"measurement"},{"extraction_accepted":true,"id":"ORC-XY7N7JLVE7","page":6,"purity":"at least 99.99%","quote":"The starting materials were at least 99.99% pure tin, indium, and silver. The materials were cleaned, mixed in appropriate proportions, and melted. The molten alloys were stirred regularly to ensure homogeneity.","second_reader_agrees":true,"starting_materials":"tin, indium, and silver","synthesis":"The materials were cleaned, mixed in appropriate proportions, and melted. The molten alloys were stirred regularly to ensure homogeneity.","type":"sample"},{"extraction_accepted":false,"id":"ORC-5QKTGMJXY6","nominal_composition":"nominal In contents of 2 and 8%","page":7,"quote":"To fix the liquid corner of the three-phase triangle, two diffusion couple experiments were made in Ag crucibles using SnIn alloys with nominal In contents of 2 and 8%.","second_reader_agrees":false,"type":"sample"},{"extraction_accepted":false,"id":"ORC-L7XBNRITU6","nominal_composition":"Sn33-In67 and Sn67-In33","page":7,"quote":"The interfacial reactions between Ag and SnIn were investigated with two diffusion couple experiments, where binary SnIn alloys with compositions Sn33-In67 and Sn67-In33 were held in a Ag crucible at 250°C for 100 h.","second_reader_agrees":false,"type":"sample"},{"extraction_accepted":true,"id":"ORC-TKYVLQZECB","nominal_composition":"Sn-50In-2.5Ag","page":7,"quote":"The alloy with the composition Sn-50In-2.5Ag was expected to be close to the ternary eutectic, and its microstructure was analyzed with optical microscope and the SEM.","second_reader_agrees":true,"type":"sample"},{"applies_to":"equilibrium alloys","cooling":"quenched in water","duration":"100 h","duration_parsed":{"hours":100.0,"printed":"100 h"},"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-MK2B2LZEQ2","page":6,"quote":"The equilibrium alloys were annealed at 250°C for 100 h and quenched in water.","second_reader_agrees":true,"temperature":{"T_K":523.15,"converted_in_code":true,"printed":"250°C","unit_basis":"printed_with_value","unit_printed":"°C","value_printed":250.0},"temperature_printed":"250°C","temperature_status":"parsed_from_printed","type":"treatment"},{"applies_to":"binary In-Sn alloys","atmosphere_or_container":"Small Ag crucibles","cooling":"aircooled","duration":"either 1000 min or 100 h","duration_parsed":{"alternatives_hours":[16.6667,100.0],"printed":"either 1000 min or 100 h"},"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-XYWICTNECN","page":6,"quote":"Small Ag crucibles were filled with the binary In-Sn alloys, sealed, and annealed at 250°C for either 1000 min or 100 h. The specimens were aircooled and prepared for optical microscopy, SEM, and qualitative energy dispersive spectroscopy (EDS) analysis.","second_reader_agrees":true,"temperature":{"T_K":523.15,"converted_in_code":true,"printed":"250°C","unit_basis":"printed_with_value","unit_printed":"°C","value_printed":250.0},"temperature_printed":"250°C","temperature_status":"parsed_from_printed","type":"treatment"},{"applies_to":"SnIn alloys with nominal In contents of 2 and 8%","atmosphere_or_container":"Ag crucibles","duration":"1000 min","duration_parsed":{"hours":16.6667,"printed":"1000 min"},"extraction_accepted":false,"id":"ORC-2QNZZCB5MQ","page":7,"purpose":"To fix the liquid corner of the three-phase triangle","quote":"To fix the liquid corner of the three-phase triangle, two diffusion couple experiments were made in Ag crucibles using SnIn alloys with nominal In contents of 2 and 8%. The samples were held at 250°C for 1000 min.","second_reader_agrees":false,"temperature":{"T_K":523.15,"converted_in_code":true,"printed":"250°C","unit_basis":"printed_with_value","unit_printed":"°C","value_printed":250.0},"temperature_printed":"250°C","temperature_status":"parsed_from_printed","type":"treatment"},{"applies_to":"binary SnIn alloys with compositions Sn33-In67 and Sn67-In33","atmosphere_or_container":"Ag crucible","duration":"100 h","duration_parsed":{"hours":100.0,"printed":"100 h"},"extraction_accepted":false,"id":"ORC-4IFOPKACSL","page":7,"purpose":"investigated with two diffusion couple experiments","quote":"The interfacial reactions between Ag and SnIn were investigated with two diffusion couple experiments, where binary SnIn alloys with compositions Sn33-In67 and Sn67-In33 were held in a Ag crucible at 250°C for 100 h.","second_reader_agrees":false,"temperature":{"T_K":523.15,"converted_in_code":true,"printed":"250°C","unit_basis":"printed_with_value","unit_printed":"°C","value_printed":250.0},"temperature_printed":"250°C","temperature_status":"parsed_from_printed","type":"treatment"}],"paper":"doi:10.1007/s11664-998-0205-1","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash / exp-context-v2.1-quote","claude-opus-5.5 / exp-context-v2.1-quote (claude broker)"],"section_basis":"methods_heading"}},"elements":["AG","IN","SN"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/s11664-998-0205-1":{"authors":["T.-M. Korhonen","J. K. Kivilahti"],"citation":"T.-M. Korhonen, J. K. Kivilahti, Thermodynamics of the Sn-In-Ag solder system, Journal of Elec Materi 27, 149-158 (1998).","container":"Journal of Elec Materi","doi":"10.1007/s11664-998-0205-1","doi_url":"https://doi.org/10.1007/s11664-998-0205-1","id":"doi:10.1007/s11664-998-0205-1","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"bba11faad58fcbcf","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamics of the Sn-In-Ag solder system","year":1998},"doi:10.1108/eb037896":{"authors":["I. Artaki","A.M. Jackson","P.T. Vianco"],"citation":"I. Artaki, A.M. Jackson, P.T. Vianco, Fine Pitch Surface Mount Technology Assembly with Lead‐free, Low Residue Solder Paste, Soldering & Surface Mount Technology 7, 27-32 (1995).","container":"Soldering & Surface Mount Technology","doi":"10.1108/eb037896","doi_url":"https://doi.org/10.1108/eb037896","id":"doi:10.1108/eb037896","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Fine Pitch Surface Mount Technology Assembly with Lead‐free, Low Residue Solder Paste","year":1995}},"part":1,"parts":1,"records":[{"chemical_system":"AG-IN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-998-0205-1"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"id":"ORC-G2QKNPJWYN","locator":{"ref":"sha256:bba11faad58fcbcf/p8/tab-iv","row":1},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-998-0205-1","own_work_of_paper":true},"paper":"doi:10.1007/s11664-998-0205-1","paper_id":"doi:10.1007/s11664-998-0205-1","phases":[{"label":"liquidus"}],"pid":"sha256:bba11faad58fcbcf/p8/tab-iv/r01#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"1, 1b","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-IN-SN","system":"AG-IN-SN","temperature_K":463.15,"temperature_basis":"printed","temperature_printed":"190","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":463.15},{"chemical_system":"AG-IN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-998-0205-1"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"id":"ORC-DHCLHDQE2N","locator":{"ref":"sha256:bba11faad58fcbcf/p8/tab-iv","row":2},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-998-0205-1","own_work_of_paper":true},"paper":"doi:10.1007/s11664-998-0205-1","paper_id":"doi:10.1007/s11664-998-0205-1","phases":[{"label":"liquidus"}],"pid":"sha256:bba11faad58fcbcf/p8/tab-iv/r02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"2","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-IN-SN","system":"AG-IN-SN","temperature_K":423.15,"temperature_basis":"printed","temperature_printed":"150","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":423.15},{"chemical_system":"AG-IN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-998-0205-1"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"id":"ORC-JT45VEKNZF","locator":{"ref":"sha256:bba11faad58fcbcf/p8/tab-iv","row":3},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-998-0205-1","own_work_of_paper":true},"paper":"doi:10.1007/s11664-998-0205-1","paper_id":"doi:10.1007/s11664-998-0205-1","phases":[{"label":"liquidus"}],"pid":"sha256:bba11faad58fcbcf/p8/tab-iv/r03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"3","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-IN-SN","system":"AG-IN-SN","temperature_K":478.15,"temperature_basis":"printed","temperature_printed":"205","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":478.15},{"chemical_system":"AG-IN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-998-0205-1"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":2,"id":"ORC-P2PXE2ZV6X","locator":{"ref":"sha256:bba11faad58fcbcf/p8/tab-iv","row":4},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-998-0205-1","own_work_of_paper":true},"overall_composition":{"IN":0.5},"paper":"doi:10.1007/s11664-998-0205-1","paper_id":"doi:10.1007/s11664-998-0205-1","phases":[{"label":"liquidus"}],"pid":"sha256:bba11faad58fcbcf/p8/tab-iv/r04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"4,4b","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-IN-SN","system":"AG-IN-SN","temperature_K":399.15,"temperature_basis":"printed","temperature_printed":"126","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":399.15},{"chemical_system":"AG-IN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-998-0205-1"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"id":"ORC-VBJPTPXIDO","locator":{"ref":"sha256:bba11faad58fcbcf/p8/tab-iv","row":5},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-998-0205-1","own_work_of_paper":true},"paper":"doi:10.1007/s11664-998-0205-1","paper_id":"doi:10.1007/s11664-998-0205-1","phases":[{"label":"liquidus"}],"pid":"sha256:bba11faad58fcbcf/p8/tab-iv/r05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"5","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-IN-SN","system":"AG-IN-SN","temperature_K":480.15,"temperature_basis":"printed","temperature_printed":"207","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":480.15},{"chemical_system":"AG-IN-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-998-0205-1"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":2,"id":"ORC-X72KVHTNLB","locator":{"ref":"sha256:bba11faad58fcbcf/p8/tab-iv","row":6},"observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-998-0205-1","own_work_of_paper":true},"paper":"doi:10.1007/s11664-998-0205-1","paper_id":"doi:10.1007/s11664-998-0205-1","phases":[{"label":"liquidus"}],"pid":"sha256:bba11faad58fcbcf/p8/tab-iv/r06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"6","type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-IN-SN","system":"AG-IN-SN","temperature_K":449.15,"temperature_basis":"printed","temperature_printed":"176","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":449.15},{"chemical_system":"AG-IN-SN","citations_printed":["34"],"cited_sources":[{"doi":"10.1108/eb037896","first_author":"Artaki","kind":"unknown","label":"34","paper":"doi:10.1108/eb037896","reference":"I. Artaki, A.M. Jackson and P.T. Vianco, Soldering and Surface Mount Technology 20, 27 (1995).","status":"resolved","year":"1995"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-7AH2T2YW4B","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-998-0205-1/p9/text-04"},"method":"DSC","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11664-998-0205-1","paper_id":"doi:10.1007/s11664-998-0205-1","pid":"doi:10.1007/s11664-998-0205-1/p9/text-04/s09#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"A similar extra peak has also been reported34 for a commercial Sn-In-Ag solder. The DSC graph showed a very sharp peak at about 114°C, due to melting at the eutectic temperature, and another peak with a maximum at the liquidus temperature.","quote_page":9,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AG-IN-SN","system":"AG-IN-SN","temperature_K":387.15,"temperature_printed":"about 114°C","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"thermal_analysis","entry":"value_types/T_INVARIANT/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":387.15}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"AG-IN-SN"}