{"artifacts":{"sha256:152dffd3ba088bc9/p5/tab-1":{"artifact":"table","caption":"Enthalpy of formation for the NaSi and Ag 2 Na compounds and the crystal structures of the Na–X (X = Si, Ag) systems","label":"1","page":5}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["AG","NA"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.2298/jmmb120113024h":{"authors":["D. Hao","M. Bu","Y. Wang","Y. Tang","Q. Gao","M. Wang","B. Hu","Y. Du"],"citation":"D. Hao, M. Bu, Y. Wang, Y. Tang, Q. Gao, M. Wang et al., Thermodynamic modeling of the Na-X (X = Si, Ag, Cu, Cr) systems, J min metall B Metall 48, 273-282 (2012).","container":"J min metall B Metall","doi":"10.2298/jmmb120113024h","doi_url":"https://doi.org/10.2298/jmmb120113024h","id":"doi:10.2298/jmmb120113024h","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"152dffd3ba088bc9","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic modeling of the Na-X (X = Si, Ag, Cu, Cr) systems","year":2012}},"part":1,"parts":1,"records":[{"chemical_system":"AG-NA","cited_sources":[{"first_author":"Kienast","kind":"unknown","label":"16","reference":"G. Kienast and J. Verma, Z. Anorg. [28] W.L. Bond and W. Kaiser, J. Phys. Chem., 310 (1961) 143-169. Chem. Solids, 16 (1960) 44-45. 282 D. Hao / JMM 48 (2) B (2012) 273 - 282","status":"resolved","year":"2012"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"Ag2Na","label_source":"printed_source_page","pearson_symbol":"cF24","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_08","doi":"10.2298/jmmb120113024h","pdf_page":5,"pdf_sha256":"152dffd3ba088bc9e5bd86fb8389755335de9306f4fbcd7d7998ed269cfd66f9","printed":"Ag2Na | cF24 | Fd-3m | 7.923 [16] / 8.019 TW","rationale":"Printed table context for this group supplies phase, pearson_symbol, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[9,10],"table":"1","table_key":"t144"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"601c9132ac6ddf90707697f49d5b7b93d6501b0cc3ad3d66e9d75526111f4b07","page":5,"pdf_sha256_prefix":"152dffd3ba088bc9","seen":"merged cells span both Ag2Na rows; records carry composition {NA0.333,SI0} (Ag not encoded)","verdict":"confirmed"}},{"after":{"pearson_symbol":"cF24","phase":"Ag2Na","space_group":"Fd-3m"},"before":null,"evidence":{"batch":"table_context_batch_08","doi":"10.2298/jmmb120113024h","pdf_page":5,"pdf_sha256":"152dffd3ba088bc9e5bd86fb8389755335de9306f4fbcd7d7998ed269cfd66f9","printed":"Ag2Na | cF24 | Fd-3m | 7.923 [16] / 8.019 TW","rationale":"Printed table context for this group supplies phase, pearson_symbol, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[9,10],"table":"1","table_key":"t144"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"601c9132ac6ddf90707697f49d5b7b93d6501b0cc3ad3d66e9d75526111f4b07","page":5,"pdf_sha256_prefix":"152dffd3ba088bc9","seen":"merged cells span both Ag2Na rows; records carry composition {NA0.333,SI0} (Ag not encoded)","verdict":"confirmed"}},{"after":"AG-NA","before":"AG-NA-SI","evidence":{"basis":"phase_formula","overall_composition":{"NA":0.333333,"SI":0.0},"phases":["Ag2Na"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-OIO2IBAHQZ","locator":{"ref":"sha256:152dffd3ba088bc9/p5/tab-1","row":9},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"NA":0.333333},"overall_composition_basis":"from_formula","overall_composition_stored":{"NA":0.333333,"SI":0.0},"paper":"doi:10.2298/jmmb120113024h","paper_id":"doi:10.2298/jmmb120113024h","phases":[{"label":"Ag2Na","label_source":"printed_source_page","pearson_symbol":"cF24","structure_basis":"printed_source_page"}],"pid":"sha256:152dffd3ba088bc9/p5/tab-1/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-NA-SI","structure":{"pearson_symbol":"cF24","phase":"Ag2Na","space_group":"Fd-3m"},"system":"AG-NA","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01743,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01743},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":7.923,"value_stored":7.923},{"chemical_system":"AG-NA","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":[{"label":"Ag2Na","label_source":"printed_source_page","pearson_symbol":"cF24","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_08","doi":"10.2298/jmmb120113024h","pdf_page":5,"pdf_sha256":"152dffd3ba088bc9e5bd86fb8389755335de9306f4fbcd7d7998ed269cfd66f9","printed":"Ag2Na | cF24 | Fd-3m | 7.923 [16] / 8.019 TW","rationale":"Printed table context for this group supplies phase, pearson_symbol, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[9,10],"table":"1","table_key":"t144"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"601c9132ac6ddf90707697f49d5b7b93d6501b0cc3ad3d66e9d75526111f4b07","page":5,"pdf_sha256_prefix":"152dffd3ba088bc9","seen":"merged cells span both Ag2Na rows; records carry composition {NA0.333,SI0} (Ag not encoded)","verdict":"confirmed"}},{"after":{"pearson_symbol":"cF24","phase":"Ag2Na","space_group":"Fd-3m"},"before":null,"evidence":{"batch":"table_context_batch_08","doi":"10.2298/jmmb120113024h","pdf_page":5,"pdf_sha256":"152dffd3ba088bc9e5bd86fb8389755335de9306f4fbcd7d7998ed269cfd66f9","printed":"Ag2Na | cF24 | Fd-3m | 7.923 [16] / 8.019 TW","rationale":"Printed table context for this group supplies phase, pearson_symbol, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[9,10],"table":"1","table_key":"t144"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"601c9132ac6ddf90707697f49d5b7b93d6501b0cc3ad3d66e9d75526111f4b07","page":5,"pdf_sha256_prefix":"152dffd3ba088bc9","seen":"merged cells span both Ag2Na rows; records carry composition {NA0.333,SI0} (Ag not encoded)","verdict":"confirmed"}},{"after":"AG-NA","before":"AG-NA-SI","evidence":{"basis":"phase_formula","overall_composition":{"NA":0.333333,"SI":0.0},"phases":["Ag2Na"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-B3IYKX5BW7","locator":{"ref":"sha256:152dffd3ba088bc9/p5/tab-1","row":10},"method":"first-principles calculation","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.2298/jmmb120113024h","own_work_of_paper":true},"overall_composition":{"NA":0.333333},"overall_composition_basis":"from_formula","overall_composition_stored":{"NA":0.333333,"SI":0.0},"paper":"doi:10.2298/jmmb120113024h","paper_id":"doi:10.2298/jmmb120113024h","phases":[{"label":"Ag2Na","label_source":"printed_source_page","pearson_symbol":"cF24","structure_basis":"printed_source_page"}],"pid":"sha256:152dffd3ba088bc9/p5/tab-1/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-NA-SI","structure":{"pearson_symbol":"cF24","phase":"Ag2Na","space_group":"Fd-3m"},"system":"AG-NA","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.08019,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.08019},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":8.019,"value_stored":8.019}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"AG-NA"}