{"artifacts":{"doi:10.1007/s11664-007-0315-1/p2/text-18":{"artifact":"text_passage","label":"page 2, passage 18","page":2},"doi:10.1007/s11664-007-0315-1/p3/tab-ii":{"artifact":"table","caption":"Invariant Reactions of the Ag-Ni System","label":"II","page":3},"doi:10.1007/s11664-016-5246-2/p3/tab-ii":{"artifact":"table","caption":"Ag-Ni alloy details in the present study","label":"II","page":3},"doi:10.1007/s11664-016-5246-2/p3/text-19":{"artifact":"text_passage","label":"page 3, passage 19","page":3},"doi:10.1007/s11664-016-5246-2/p4/text-07":{"artifact":"text_passage","label":"page 4, passage 7","page":4},"doi:10.1007/s11664-016-5246-2/p5/text-05":{"artifact":"text_passage","label":"page 5, passage 5","page":5},"doi:10.1007/s11664-016-5246-2/p6/text-06":{"artifact":"text_passage","label":"page 6, passage 6","page":6},"doi:10.1007/s11664-016-5246-2/p7/tab-iii":{"artifact":"table","caption":"Gibbs energy model parameters (in SI units) and calculated invariant equilibria","label":"III","page":7}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{"doi:10.1007/s11664-016-5246-2":{"context_id":"context:source-doi-10-1007-s11664-016-5246-2","items":[{"applies_to":"the two phases, the tie-lines","extraction_accepted":false,"id":"ORC-2D3AYB67T2","instrument":"JEOL Model JXA-8500F","method":"electron probe micro-analysis (EPMA)","page":2,"quote":"The compositions of the two phases, the tie-lines, were determined by electron probe micro-analysis (EPMA) (JEOL Model JXA-8500F).","second_reader_agrees":true,"type":"measurement"},{"applies_to":"Ag-Ni alloys","calibration":"calibrated using the known temperatures of a black body (emissivity, e = 1)","extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-HPX3EP3BX2","instrument":"pyrometer (IMPAC ISR 6; Lumasense Technologies)","page":2,"quote":"The as-prepared Ag-Ni alloys were melted again in the arc melter, and their temperature profiles are/were recorded using a pyrometer (IMPAC ISR 6; Lumasense Technologies). The response time of this pyrometer was smaller than 0.01 s. The pyrometer had been calibrated using the known temperatures of a black body (emissivity, e = 1).","second_reader_agrees":true,"type":"measurement"},{"extraction_accepted":false,"id":"ORC-2NTIZX54GY","label":"Ag-Ni","page":1,"purity":"silver shots (99.9%; Alfa AesarÒ, USA) and nickel wires (99.98%; Alfa AesarÒ, USA)","quote":"Alloys of Ag-Ni were prepared with silver shots (99.9%; Alfa AesarÒ, USA) and nickel wires (99.98%; Alfa AesarÒ, USA) by using arc melting (Centorr Vacuum Industries, USA) in an argon atmosphere.","second_reader_agrees":true,"starting_materials":"silver shots (99.9%; Alfa AesarÒ, USA) and nickel wires (99.98%; Alfa AesarÒ, USA)","synthesis":"arc melting (Centorr Vacuum Industries, USA) in an argon atmosphere","type":"sample"},{"extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-N6OEY3IHAF","label":"Ag-20 at.% Ni","nominal_composition":"20 at.% Ni","page":2,"quote":"Two Ag-20 at.% Ni alloys were placed in separate quartz capsules, evacuated and sealed under vacuum.","second_reader_agrees":true,"type":"sample"},{"extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-HHJJCADHGC","nominal_composition":"80 at.% Ni","page":4,"quote":"Figure 3a shows the DTA heating curves of the three Ag-Ni alloys, Ag-20 at.%, 50 at.% and 80 at.% Ni at 2 K/min.","second_reader_agrees":true,"type":"sample"}],"paper":"doi:10.1007/s11664-016-5246-2","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash / exp-context-v2-quote","claude-opus-5.5 / exp-context-v2-quote (claude broker)"],"section_basis":null}},"elements":["AG","NI"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"M4f644600":{"catalog_entry":{"license":"CC BY 4.0","name":"AgNi-08Liu.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"X.J. Liu, F. Gao, C.P. Wang, K. Ishida, J. Electron. Mater., 37, 210-17(2008).","model_doi":"10.1007/s11664-007-0315-1","reproduced_by_calculation":true,"tdb":"AgNi-08Liu.tdb","tdb_path":"databases/sgte-binary/AgNi-08Liu.tdb","tdb_sha256":"963eadbc8f90641306464ee12739b96ea624b9b53b1ed81977396f3b82f22ef5"},"M95e7ceae":{"catalog_entry":{"license":"CC BY 4.0","name":"AgNi-17Raj.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"V.B. Rajkumar, S.-W. Chen, J. Electron. Mater., 46, 2282-89(2017).","model_doi":"10.1007/s11664-016-5246-2","reproduced_by_calculation":false,"tdb":"AgNi-17Raj.tdb","tdb_path":"databases/sgte-binary/AgNi-17Raj.tdb","tdb_sha256":"d8845da8400c41e90c61c86cbf914c0b4ee53d9072306121abd62c539048cf9d"},"Mede673f8":{"catalog_entry":{"license":"CC BY 4.0","name":"AgNi-17Raj.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"V.B. Rajkumar, S.-W. Chen, J. Electron. Mater., 46, 2282-89(2017).","model_doi":"10.1007/s11664-016-5246-2","reproduced_by_calculation":true,"tdb":"AgNi-17Raj.tdb","tdb_path":"databases/sgte-binary/AgNi-17Raj.tdb","tdb_sha256":"d8845da8400c41e90c61c86cbf914c0b4ee53d9072306121abd62c539048cf9d"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/bf02873194":{"authors":["M. Singleton","P. Nash"],"citation":"M. Singleton, P. Nash, The Ag−Ni (Silver-Nickel) system, JPE 8, 119-121 (1987).","container":"JPE","doi":"10.1007/bf02873194","doi_url":"https://doi.org/10.1007/bf02873194","id":"doi:10.1007/bf02873194","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The Ag−Ni (Silver-Nickel) system","year":1987},"doi:10.1007/s11664-007-0315-1":{"authors":["Xing Jun Liu","Feng Gao","Cui Ping Wang","Kiyohito Ishida"],"citation":"Xing Jun Liu, Feng Gao, Cui Ping Wang, Kiyohito Ishida, Thermodynamic Assessments of the Ag-Ni Binary and Ag-Cu-Ni Ternary Systems, Journal of Elec Materi 37, 210-217 (2008).","container":"Journal of Elec Materi","doi":"10.1007/s11664-007-0315-1","doi_url":"https://doi.org/10.1007/s11664-007-0315-1","id":"doi:10.1007/s11664-007-0315-1","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"d60cd8372810e876","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic Assessments of the Ag-Ni Binary and Ag-Cu-Ni Ternary Systems","year":2008},"doi:10.1007/s11664-016-5246-2":{"authors":["V. B. Rajkumar","Sinn-wen Chen"],"citation":"V. B. Rajkumar, Sinn-wen Chen, Thermodynamic Modeling of Ag-Ni System Combining Experiments and Molecular Dynamic Simulation, Journal of Elec Materi 46, 2282-2289 (2017).","container":"Journal of Elec Materi","doi":"10.1007/s11664-016-5246-2","doi_url":"https://doi.org/10.1007/s11664-016-5246-2","id":"doi:10.1007/s11664-016-5246-2","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"fdcf1066babfe900","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic Modeling of Ag-Ni System Combining Experiments and Molecular Dynamic Simulation","year":2017},"doi:10.1557/jmr.2006.0157":{"authors":["Usman Saeed","Hans Flandorfer","Herbert Ipser"],"citation":"Usman Saeed, Hans Flandorfer, Herbert Ipser, Lead-free solders: Enthalpies of mixing of liquid alloys in the Ag–Ni and Ag–Ni–Sn systems, J. Mater. Res. 21, 1294-1304 (2006).","container":"J. Mater. Res.","doi":"10.1557/jmr.2006.0157","doi_url":"https://doi.org/10.1557/jmr.2006.0157","id":"doi:10.1557/jmr.2006.0157","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Lead-free solders: Enthalpies of mixing of liquid alloys in the Ag–Ni and Ag–Ni–Sn systems","year":2006}},"part":1,"parts":1,"records":[{"chemical_system":"AG-NI","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-016-5246-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-Y34QJQ4CT7","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p3/tab-ii","row":4},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-016-5246-2","own_work_of_paper":true},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":0.9771,"NI":0.0229},"composition_source":"printed","phase":"L1"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":0.0024,"NI":0.9976},"composition_source":"printed","phase":"(Ni)"}],"phases":[{"label":"L1","model_phase":"LIQUID"},{"label":"(Ni)"}],"pid":"doi:10.1007/s11664-016-5246-2/p3/tab-ii/r04#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-NI","system":"AG-NI","temperature_K":1473.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AG-NI","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-016-5246-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":0,"fold_lso":0,"id":"ORC-IMMB7R3YHC","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p3/tab-ii","row":5},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-016-5246-2","own_work_of_paper":true},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":0.0121,"NI":0.9879},"composition_source":"printed","phase":"(Ni)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":0.9879,"NI":0.0121},"composition_source":"printed","phase":"(Ag)"}],"phases":[{"label":"(Ni)"},{"label":"(Ag)"}],"pid":"doi:10.1007/s11664-016-5246-2/p3/tab-ii/r05#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-NI","system":"AG-NI","temperature_K":1023.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AG-NI","cited_sources":[{"first_author":"Sinoleton","kind":"assessment","label":"13","reference":"M. Sinoleton and P. Nash, Phase Diagrams of Binary Nickel Alloys 1, 1 (1991).","status":"resolved","year":"1991"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["reaction_liquid_count_inconsistent_as_printed","reaction_class_conflicts_printed_reaction"],"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"reaction_liquid_count_inconsistent_as_printed","detail":"eutectic with 2 liquid phase(s); the page prints it so","effect":"not_espei_ready","gate":"G6","visual_check":{"checked":"2026-10-24","image_sha256":"ca3bd1cca483ac8ec4e718040f30168ec2ed68bf50664074c503b7318ac1d22d","page":3,"pdf_sha256_prefix":"d60cd8372810e876","seen":"Table II Ag-Ni: 'L1 → fcc(Ni) + L2 | Eutectic | 1435 (13), 1435 (This work)'; 'L → fcc(Ni) + fcc(Ag) | Monotectic | 960 (13), 959 (This work)' (°C).","verdict":"checked"}},{"code":"reaction_class_conflicts_printed_reaction","detail":"class 'eutectic' but the printed reaction 'L1 -> fcc (Ni) + L2' reads 'monotectic'","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-ANAJ7HFOBG","locator":{"ref":"doi:10.1007/s11664-007-0315-1/p3/tab-ii","row":1},"observation_type":"invariant_reaction","origin":{"basis":"cited_evaluation_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11664-007-0315-1","paper_id":"doi:10.1007/s11664-007-0315-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":0.03},"composition_source":"printed","phase":"L1"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":0.01},"composition_source":"printed","phase":"fcc (Ni)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":0.9611},"composition_source":"printed","phase":"L2"}],"phases":[{"label":"L1","model_phase":"LIQUID"},{"label":"fcc (Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"L2","model_phase":"LIQUID"}],"pid":"doi:10.1007/s11664-007-0315-1/p3/tab-ii/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L1 -> fcc (Ni) + L2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AG-NI","system":"AG-NI","temperature_K":1708.15,"temperature_printed":"1435","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1708.15},{"chemical_system":"AG-NI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["reaction_liquid_count_inconsistent_as_printed","reaction_class_conflicts_printed_reaction"],"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"reaction_liquid_count_inconsistent_as_printed","detail":"eutectic with 2 liquid phase(s); the page prints it so","effect":"not_espei_ready","gate":"G6","visual_check":{"checked":"2026-10-24","image_sha256":"ca3bd1cca483ac8ec4e718040f30168ec2ed68bf50664074c503b7318ac1d22d","page":3,"pdf_sha256_prefix":"d60cd8372810e876","seen":"Table II Ag-Ni: 'L1 → fcc(Ni) + L2 | Eutectic | 1435 (13), 1435 (This work)'; 'L → fcc(Ni) + fcc(Ag) | Monotectic | 960 (13), 959 (This work)' (°C).","verdict":"checked"}},{"code":"reaction_class_conflicts_printed_reaction","detail":"class 'eutectic' but the printed reaction 'L1 -> fcc (Ni) + L2' reads 'monotectic'","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-YMICACAANB","locator":{"ref":"doi:10.1007/s11664-007-0315-1/p3/tab-ii","row":2},"model":"M4f644600","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1007/s11664-007-0315-1","own_work_of_paper":true},"paper":"doi:10.1007/s11664-007-0315-1","paper_id":"doi:10.1007/s11664-007-0315-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":0.031},"composition_source":"printed","phase":"L1"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":0.014},"composition_source":"printed","phase":"fcc (Ni)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":0.958},"composition_source":"printed","phase":"L2"}],"phases":[{"label":"L1","model_phase":"LIQUID"},{"label":"fcc (Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"L2","model_phase":"LIQUID"}],"pid":"doi:10.1007/s11664-007-0315-1/p3/tab-ii/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L1 -> fcc (Ni) + L2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AG-NI","system":"AG-NI","temperature_K":1708.15,"temperature_printed":"1435","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1708.15},{"chemical_system":"AG-NI","cited_sources":[{"first_author":"Sinoleton","kind":"assessment","label":"13","reference":"M. Sinoleton and P. Nash, Phase Diagrams of Binary Nickel Alloys 1, 1 (1991).","status":"resolved","year":"1991"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["reaction_liquid_count_inconsistent_as_printed","reaction_class_conflicts_printed_reaction"],"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"reaction_liquid_count_inconsistent_as_printed","detail":"monotectic with 1 liquid phase(s); the page prints it so","effect":"not_espei_ready","gate":"G6","visual_check":{"checked":"2026-10-24","image_sha256":"ca3bd1cca483ac8ec4e718040f30168ec2ed68bf50664074c503b7318ac1d22d","page":3,"pdf_sha256_prefix":"d60cd8372810e876","seen":"Table II Ag-Ni: 'L1 → fcc(Ni) + L2 | Eutectic | 1435 (13), 1435 (This work)'; 'L → fcc(Ni) + fcc(Ag) | Monotectic | 960 (13), 959 (This work)' (°C).","verdict":"checked"}},{"code":"reaction_class_conflicts_printed_reaction","detail":"class 'monotectic' but the printed reaction 'L -> fcc (Ni) + fcc (Ag)' reads 'eutectic'","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-Z6AYM4OAC7","locator":{"ref":"doi:10.1007/s11664-007-0315-1/p3/tab-ii","row":3},"observation_type":"invariant_reaction","origin":{"basis":"cited_evaluation_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11664-007-0315-1","paper_id":"doi:10.1007/s11664-007-0315-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":0.9968},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":0.998},"composition_source":"printed","phase":"fcc (Ag)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"fcc (Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"fcc (Ag)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11664-007-0315-1/p3/tab-ii/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> fcc (Ni) + fcc (Ag)","type":"monotectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AG-NI","system":"AG-NI","temperature_K":1233.15,"temperature_printed":"960","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"monotectic","transition_kind_printed":"Monotectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1233.15},{"chemical_system":"AG-NI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["reaction_liquid_count_inconsistent_as_printed","reaction_class_conflicts_printed_reaction"],"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"reaction_liquid_count_inconsistent_as_printed","detail":"monotectic with 1 liquid phase(s); the page prints it so","effect":"not_espei_ready","gate":"G6","visual_check":{"checked":"2026-10-24","image_sha256":"ca3bd1cca483ac8ec4e718040f30168ec2ed68bf50664074c503b7318ac1d22d","page":3,"pdf_sha256_prefix":"d60cd8372810e876","seen":"Table II Ag-Ni: 'L1 → fcc(Ni) + L2 | Eutectic | 1435 (13), 1435 (This work)'; 'L → fcc(Ni) + fcc(Ag) | Monotectic | 960 (13), 959 (This work)' (°C).","verdict":"checked"}},{"code":"reaction_class_conflicts_printed_reaction","detail":"class 'monotectic' but the printed reaction 'L -> fcc (Ni) + fcc (Ag)' reads 'eutectic'","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-CYJUQMWWTM","locator":{"ref":"doi:10.1007/s11664-007-0315-1/p3/tab-ii","row":4},"model":"M4f644600","observation_type":"invariant_reaction","origin":{"basis":"this_work_uncited_beside_cited_rows+title_modelling","class":"model_value","measured_in":"doi:10.1007/s11664-007-0315-1","own_work_of_paper":true},"paper":"doi:10.1007/s11664-007-0315-1","paper_id":"doi:10.1007/s11664-007-0315-1","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":0.995},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":0.0045},"composition_source":"printed","phase":"fcc (Ni)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":0.998},"composition_source":"printed","phase":"fcc (Ag)"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"fcc (Ni)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"fcc (Ag)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11664-007-0315-1/p3/tab-ii/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> fcc (Ni) + fcc (Ag)","type":"monotectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AG-NI","system":"AG-NI","temperature_K":1232.15,"temperature_printed":"959","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"monotectic","transition_kind_printed":"Monotectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1232.15},{"chemical_system":"AG-NI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.942,"dx":{"L1":-0.0018,"L2":0.9432},"fail_reason":"composition","model":"AgNi-17Raj.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-NQQH6UHVQL","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p7/tab-iii","row":2},"model":"Mede673f8","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-016-5246-2","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.9836},"composition_source":"printed","phase":"L2"},{"basis":"mole_fraction","composition":{"NI":0.0386},"composition_source":"printed","phase":"L1"},{"basis":"mole_fraction","composition":{"NI":0.9992},"composition_source":"printed","phase":"(Ni)"}],"phases":[{"label":"L2","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"L1","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"(Ni)","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11664-016-5246-2/p7/tab-iii/r-unplaced-3a9a85ba#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L2 -> L1 + (Ni)","type":"monotectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"AG-NI","system":"AG-NI","temperature_K":1708,"temperature_printed":"1708","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1708},{"chemical_system":"AG-NI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-ZWW2KGKXJZ","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p7/tab-iii","row":1},"model":"M95e7ceae","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-016-5246-2","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.0158},"composition_source":"printed","phase":"G"},{"basis":"mole_fraction","composition":{"NI":0.8199},"composition_source":"printed","phase":"L2"},{"basis":"mole_fraction","composition":{"NI":0.1904},"composition_source":"printed","phase":"L1"}],"phases":[{"label":"G"},{"label":"L2"},{"label":"L1"}],"pid":"doi:10.1007/s11664-016-5246-2/p7/tab-iii/r01#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"G + L2 -> L1"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AG-NI","system":"AG-NI","temperature_K":2460,"temperature_printed":"2460","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2460},{"chemical_system":"AG-NI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.659,"dx":{"(Ag)":-0.9961,"L1":-0.0002},"fail_reason":"composition_pure_element_label","model":"AgNi-17Raj.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-L3FAZXVINP","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p7/tab-iii","row":3},"model":"Mede673f8","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-016-5246-2","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","phase_compositions":[{"basis":"mole_fraction","composition":{"NI":0.0051},"composition_source":"printed","phase":"L1"},{"basis":"mole_fraction","composition":{"NI":0.0038},"composition_source":"printed","phase":"(Ag)"},{"basis":"mole_fraction","composition":{"NI":0.9999},"composition_source":"printed","phase":"(Ni)"}],"phases":[{"label":"L1","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"(Ag)","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"(Ni)","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11664-016-5246-2/p7/tab-iii/r02#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L1 -> (Ag) + (Ni)","type":"eutectic","type_basis":"derived_from_printed_reaction"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AG-NI","system":"AG-NI","temperature_K":1234,"temperature_printed":"1234","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1234},{"chemical_system":"AG-NI","citations_printed":["13"],"cited_sources":[{"first_author":"Sinoleton","kind":"assessment","label":"13","reference":"M. Sinoleton and P. Nash, Phase Diagrams of Binary Nickel Alloys 1, 1 (1991).","status":"resolved","year":"1991"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-3ZZCA2XVBT.255411","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-007-0315-1/p2/text-18"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1007/s11664-007-0315-1","paper_id":"doi:10.1007/s11664-007-0315-1","pid":"doi:10.1007/s11664-007-0315-1/p2/text-18/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"There is a eutectic reaction [L fi fcc (Ni) + fcc (Ag)] at 960C and a monotectic reaction [L1 fi fcc (Ni) + L2] at 1435C.","quote_page":2,"reaction":{"printed":"L -> fcc (Ni) + fcc (Ag)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AG-NI","system":"AG-NI","temperature_K":1233.15,"temperature_printed":"960","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1233.15},{"chemical_system":"AG-NI","citations_printed":["13"],"cited_sources":[{"first_author":"Sinoleton","kind":"assessment","label":"13","reference":"M. Sinoleton and P. Nash, Phase Diagrams of Binary Nickel Alloys 1, 1 (1991).","status":"resolved","year":"1991"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-3ZZCA2XVBT.2c104e","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-007-0315-1/p2/text-18"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1007/s11664-007-0315-1","paper_id":"doi:10.1007/s11664-007-0315-1","pid":"doi:10.1007/s11664-007-0315-1/p2/text-18/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"There is a eutectic reaction [L fi fcc (Ni) + fcc (Ag)] at 960C and a monotectic reaction [L1 fi fcc (Ni) + L2] at 1435C.","quote_page":2,"reaction":{"printed":"L1 -> fcc (Ni) + L2","type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AG-NI","system":"AG-NI","temperature_K":1708.15,"temperature_printed":"1435","tool_release":"release v2 + tools dev copy record build","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1708.15},{"chemical_system":"AG-NI","citations_printed":["6"],"cited_sources":[{"doi":"10.1007/bf02873194","first_author":"Singleton","kind":"unknown","label":"6","paper":"doi:10.1007/bf02873194","reference":"M. Singleton and P. Nash, J. Phase Equilib. 8, 119 (1987).","status":"resolved","year":"1987"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-YI7SJ56SEY","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p3/text-19"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","pid":"doi:10.1007/s11664-016-5246-2/p3/text-19/s10#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The monotectic at 1708 K6 is taken as internal reference.","quote_page":3,"reaction":{"type":"monotectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AG-NI","system":"AG-NI","temperature_K":1708.0,"temperature_printed":"1708 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"monotectic","transition_kind_printed":"monotectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1708.0},{"chemical_system":"AG-NI","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-016-5246-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-AZ6QQAX5CJ.4ac78e","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p4/text-07"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11664-016-5246-2","own_work_of_paper":true},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","pid":"doi:10.1007/s11664-016-5246-2/p4/text-07/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The measured temperature (average of two values) was 2442 K, 2624 K and 2451 K for Ag-20 at.%, 50 at.%, and 80 at.% Ni, respectively.","quote_page":4,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AG-NI","system":"AG-NI","temperature_K":2442.0,"temperature_printed":"2442 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2442.0},{"chemical_system":"AG-NI","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-016-5246-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-AZ6QQAX5CJ.60255e","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p4/text-07"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11664-016-5246-2","own_work_of_paper":true},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","pid":"doi:10.1007/s11664-016-5246-2/p4/text-07/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The measured temperature (average of two values) was 2442 K, 2624 K and 2451 K for Ag-20 at.%, 50 at.%, and 80 at.% Ni, respectively.","quote_page":4,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AG-NI","system":"AG-NI","temperature_K":2624.0,"temperature_printed":"2624 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2624.0},{"chemical_system":"AG-NI","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-016-5246-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-AZ6QQAX5CJ.909ad6","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p4/text-07"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11664-016-5246-2","own_work_of_paper":true},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","pid":"doi:10.1007/s11664-016-5246-2/p4/text-07/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The measured temperature (average of two values) was 2442 K, 2624 K and 2451 K for Ag-20 at.%, 50 at.%, and 80 at.% Ni, respectively.","quote_page":4,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AG-NI","system":"AG-NI","temperature_K":2451.0,"temperature_printed":"2451 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2451.0},{"chemical_system":"AG-NI","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-016-5246-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-ERFAHNALYO.615bb5","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p4/text-07"},"merged_ids":["ORC-ERFAHNALYO.cd6a7e"],"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11664-016-5246-2","own_work_of_paper":true},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","pid":"doi:10.1007/s11664-016-5246-2/p4/text-07/s08#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"According to the heating curve, the eutectic reaction temperature measured is 1228 K, 1231 K, 1228 K for Ag-20 at.%, 50 at.% and 80 at.% Ni respectively.","quote_page":4,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AG-NI","system":"AG-NI","temperature_K":1228.0,"temperature_printed":"1228 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1228.0},{"chemical_system":"AG-NI","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-016-5246-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-ERFAHNALYO.b15ba9","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p4/text-07"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11664-016-5246-2","own_work_of_paper":true},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","pid":"doi:10.1007/s11664-016-5246-2/p4/text-07/s08#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"According to the heating curve, the eutectic reaction temperature measured is 1228 K, 1231 K, 1228 K for Ag-20 at.%, 50 at.% and 80 at.% Ni respectively.","quote_page":4,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AG-NI","system":"AG-NI","temperature_K":1231.0,"temperature_printed":"1231 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1231.0},{"chemical_system":"AG-NI","citations_printed":["6"],"cited_sources":[{"doi":"10.1007/bf02873194","first_author":"Singleton","kind":"unknown","label":"6","paper":"doi:10.1007/bf02873194","reference":"M. Singleton and P. Nash, J. Phase Equilib. 8, 119 (1987).","status":"resolved","year":"1987"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-7LLUIVYRKL.3f3ed9","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p4/text-07"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","pid":"doi:10.1007/s11664-016-5246-2/p4/text-07/s09#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The eutectic temperature measured in the present work (average, 1229 K) is in accordance with the value (1233 K) reported by Singleton and Nash.6","quote_page":4,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AG-NI","system":"AG-NI","temperature_K":1233.0,"temperature_printed":"1233 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1233.0},{"chemical_system":"AG-NI","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-016-5246-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-7LLUIVYRKL.9d6c09","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p4/text-07"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11664-016-5246-2","own_work_of_paper":true},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","pid":"doi:10.1007/s11664-016-5246-2/p4/text-07/s09#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The eutectic temperature measured in the present work (average, 1229 K) is in accordance with the value (1233 K) reported by Singleton and Nash.6","quote_page":4,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AG-NI","system":"AG-NI","temperature_K":1229.0,"temperature_printed":"1229 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1229.0},{"chemical_system":"AG-NI","citations_printed":["20"],"cited_sources":[{"doi":"10.1557/jmr.2006.0157","first_author":"Saeed","kind":"unknown","label":"20","paper":"doi:10.1557/jmr.2006.0157","reference":"U. Saeed, H. Flandorfer, and H. Ipser, J. Mater. Res. 21, 1294 (2006).","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-3GHR27LY5E","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p5/text-05"},"observation_type":"equilibrium_property","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","pid":"doi:10.1007/s11664-016-5246-2/p5/text-05/s02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_MIX","property_group":"mixing / partial","property_printed":"enthalpy of mixing","quote":"The enthalpy of mixing of the liquid at 1773 K by Saeed et al.20 shows a kink at about 4.5 and 98.5 at.% Ni which confirms the immiscibility. These experimental values were fitted by Saeed et al.20 to give a maximum value of +13.5 kJ mol\u00021 at Ag-60 at.% Ni.","quote_page":5,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AG-NI","system":"AG-NI","temperature_K":1773.0,"temperature_printed":"1773 K","tool_release":"release v2 + tools dev copy record build","uncertainty":{"basis":"stated_default","note":"10% placeholder; none printed","value":1.35},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_stored":"kJ mol 1","value":13.5,"value_stored":13.5},{"chemical_system":"AG-NI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-SYLS5ZCRUG","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p5/text-05"},"method":"MD simulation","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"equilibrium_property","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/s11664-016-5246-2","own_work_of_paper":true},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","pid":"doi:10.1007/s11664-016-5246-2/p5/text-05/s08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_MIX","property_group":"mixing / partial","property_printed":"enthalpy of mixing","quote":"In the present work, the enthalpy of mixing of Ag-59.9\n\nat.% Ni at 1773 K is maximum with a value of 16.77 kJ mol\u00021.","quote_page":5,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AG-NI","system":"AG-NI","temperature_K":1773.0,"temperature_printed":"1773 K","tool_release":"release v2 + tools dev copy record build","uncertainty":{"basis":"stated_default","note":"10% placeholder; none printed","value":1.677},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/H_MIX_PARTIAL","floor":1.0,"floor_unit":"kJ/mol","n_pairs":133,"value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_stored":"kJ mol 1","value":16.77,"value_stored":16.77},{"chemical_system":"AG-NI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-OHAFLWXY6D.6f895f","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p6/text-06"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/s11664-016-5246-2","own_work_of_paper":true},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","pid":"doi:10.1007/s11664-016-5246-2/p6/text-06/s06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"According to the present Gibbs energy model parameters, the liquid critical temperature (Tc) is  2753 K at Ag-50 at.% Ni and the Tc of metastable (Ag,Ni) is  5173 K at Ag-65 at.% Ni.","quote_page":6,"reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AG-NI","system":"AG-NI","temperature_K":5173.0,"temperature_printed":"5173 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":5173.0},{"chemical_system":"AG-NI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-OHAFLWXY6D.f3176a","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p6/text-06"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/s11664-016-5246-2","own_work_of_paper":true},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","pid":"doi:10.1007/s11664-016-5246-2/p6/text-06/s06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"According to the present Gibbs energy model parameters, the liquid critical temperature (Tc) is  2753 K at Ag-50 at.% Ni and the Tc of metastable (Ag,Ni) is  5173 K at Ag-65 at.% Ni.","quote_page":6,"reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AG-NI","system":"AG-NI","temperature_K":2753.0,"temperature_printed":"2753 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2753.0},{"chemical_system":"AG-NI","citations_printed":["18"],"cited_sources":[{"first_author":"Colinet","kind":"unknown","label":"18","reference":"C. Colinet and A. Pasturel, Z. Metallkd. 89, 863 (1998).","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-GMVI6P3QJ7","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-016-5246-2/p6/text-06"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1007/s11664-016-5246-2","paper_id":"doi:10.1007/s11664-016-5246-2","pid":"doi:10.1007/s11664-016-5246-2/p6/text-06/s07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The Tc of the liquid is in accordance with the present experimental measurement, whereas the Tc of (Ag,Ni) is higher than the value calculated by Colinet and Pasturel (Tc   4000 K18).","quote_page":6,"reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AG-NI","system":"AG-NI","temperature_K":4000.0,"temperature_printed":"4000 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":4000.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"AG-NI"}