{"artifacts":{"doi:10.1007/bf02881270/p2/tab-1":{"artifact":"table","caption":"Ag-P Invariant Reactions (at P = 101.3 kPa)","label":"1","page":2},"doi:10.1007/bf02881270/p3/tab-2":{"artifact":"table","caption":"Ag-P Crystal Structure Data","label":"2","page":3},"doi:10.1007/bf02881270/p3/tab-3":{"artifact":"table","caption":"Ag-P Lattice Parameter Data","label":"3","page":3}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["AG","P"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/bf02881270":{"authors":["I. Karakaya","W. T. Thompson"],"citation":"I. Karakaya, W. T. Thompson, The Ag−P (Silver-Phosphorus) system, Bulletin of Alloy Phase Diagrams 9, 232-236 (1988).","container":"Bulletin of Alloy Phase Diagrams","doi":"10.1007/bf02881270","doi_url":"https://doi.org/10.1007/bf02881270","id":"doi:10.1007/bf02881270","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"1908efa11ede3d54","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"The Ag−P (Silver-Phosphorus) system","year":1988}},"part":1,"parts":1,"records":[{"chemical_system":"AG-P","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":{"crystal_system":"Monoclinic","phase":"AgP2"},"before":null,"evidence":{"batch":"table_context_batch_14","doi":"10.1007/bf02881270","pdf_page":3,"pdf_sha256":"1908efa11ede3d54f2faf386bafda403f1e5dc167605d841f0342c867f20ce47","printed":"AgP2 | 66.7 | (a) | ... | ... | ... ; footnote (a) Monoclinic structure with β = 113.48°","rationale":"Printed table context for this group supplies crystal_system; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[2],"table":"2","table_key":"t277"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 14","image_sha256":"4d6198580e2a40c906e16136a764d8206547e8d12fc88936d573bc5d2789bceb","page":3,"pdf_sha256_prefix":"1908efa11ede3d54","seen":"single row; the crystal system comes from the table footnote attached to the row's Pearson cell (the record is the β = 113.48° value from that footnote)","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":4,"id":"ORC-ZUOSO3M3C5","locator":{"ref":"doi:10.1007/bf02881270/p3/tab-2","row":2},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02881270","own_work_of_paper":true},"paper":"doi:10.1007/bf02881270","paper_id":"doi:10.1007/bf02881270","phase_compositions":[{"basis":"mole_fraction","composition":{"AG":0.333,"P":0.667},"composition_source":"printed","phase":"AgP2"}],"phases":[{"label":"AgP2","model_phase":"AGP2"}],"pid":"doi:10.1007/bf02881270/p3/tab-2/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-P","structure":{"crystal_system":"Monoclinic","phase":"AgP2"},"system":"AG-P","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":113.48},{"chemical_system":"AG-P","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-HTZ6ZOBZ5F","locator":{"ref":"doi:10.1007/bf02881270/p3/tab-2","row":3},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02881270","own_work_of_paper":true},"paper":"doi:10.1007/bf02881270","paper_id":"doi:10.1007/bf02881270","phase_compositions":[{"basis":"mole_fraction","composition":{"AG":0.216,"P":0.784},"composition_source":"printed","phase":"Ag3P11"}],"phases":[{"label":"Ag3P11","model_phase":"AG3P11"}],"pid":"doi:10.1007/bf02881270/p3/tab-2/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-P","structure":{"space_group":"Cm"},"system":"AG-P","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/LATTICE_ANGLE/classes/unknown","floor":0.05,"floor_unit":"degree","n_pairs":2,"prior_source":"orchid_assumed","value":0.05},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":118.84},{"chemical_system":"AG-P","cited_sources":[{"kind":"unknown","label":"65Olo","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-E2DVDWYLVG.7833b7","locator":{"ref":"doi:10.1007/bf02881270/p3/tab-3","row":2},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1007/bf02881270","paper_id":"doi:10.1007/bf02881270","phase_compositions":[{"basis":"mole_fraction","composition":{"AG":0.333,"P":0.667},"composition_source":"printed","phase":"AgP2"}],"phases":[{"label":"AgP2","model_phase":"AGP2"}],"pid":"doi:10.1007/bf02881270/p3/tab-3/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-P","system":"AG-P","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01368,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01368},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.218,"value_stored":0.6218},{"chemical_system":"AG-P","cited_sources":[{"kind":"unknown","label":"65Olo","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-E2DVDWYLVG.7d1793","locator":{"ref":"doi:10.1007/bf02881270/p3/tab-3","row":2},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1007/bf02881270","paper_id":"doi:10.1007/bf02881270","phase_compositions":[{"basis":"mole_fraction","composition":{"AG":0.333,"P":0.667},"composition_source":"printed","phase":"AgP2"}],"phases":[{"label":"AgP2","model_phase":"AGP2"}],"pid":"doi:10.1007/bf02881270/p3/tab-3/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-P","system":"AG-P","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01717,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01717},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.804,"value_stored":0.7804},{"chemical_system":"AG-P","cited_sources":[{"kind":"unknown","label":"65Olo","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-E2DVDWYLVG.a1d6b4","locator":{"ref":"doi:10.1007/bf02881270/p3/tab-3","row":2},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1007/bf02881270","paper_id":"doi:10.1007/bf02881270","phase_compositions":[{"basis":"mole_fraction","composition":{"AG":0.333,"P":0.667},"composition_source":"printed","phase":"AgP2"}],"phases":[{"label":"AgP2","model_phase":"AGP2"}],"pid":"doi:10.1007/bf02881270/p3/tab-3/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-P","system":"AG-P","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01112,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01112},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.056,"value_stored":0.5056},{"chemical_system":"AG-P","cited_sources":[{"first_author":"Moller","kind":"assessment","label":"81Mol","reference":"M.H. Moller and W. Jeitschko, \"Preparation and Crystal Structure of Trisilver Undecaphosphide, Ag.~Pll, an Unusual Defect Tetrahedral Compound,\" Inorg. Chem., 20, 828-833 (1981). (Equi Diagram, Crys Structure; Experimental ) 8 4 O k a : H. Okamoto and T.B. Massalski, \"The Au-P (GoldPhosphorus) System,\" Bull. Alloy Phase Diagrams, 5(5), 490-491 (1984). (Thermo; Compilation)","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-QHXJSRRKR4.20bbd9","locator":{"ref":"doi:10.1007/bf02881270/p3/tab-3","row":3},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1007/bf02881270","paper_id":"doi:10.1007/bf02881270","phase_compositions":[{"basis":"mole_fraction","composition":{"AG":0.216,"P":0.784},"composition_source":"printed","phase":"Ag3P11"}],"phases":[{"label":"Ag3P11","model_phase":"AG3P11"}],"pid":"doi:10.1007/bf02881270/p3/tab-3/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-P","system":"AG-P","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1001,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.1001},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":12.999,"value_stored":1.2999},{"chemical_system":"AG-P","cited_sources":[{"first_author":"Moller","kind":"assessment","label":"81Mol","reference":"M.H. Moller and W. Jeitschko, \"Preparation and Crystal Structure of Trisilver Undecaphosphide, Ag.~Pll, an Unusual Defect Tetrahedral Compound,\" Inorg. Chem., 20, 828-833 (1981). (Equi Diagram, Crys Structure; Experimental ) 8 4 O k a : H. Okamoto and T.B. Massalski, \"The Au-P (GoldPhosphorus) System,\" Bull. Alloy Phase Diagrams, 5(5), 490-491 (1984). (Thermo; Compilation)","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-QHXJSRRKR4.c92762","locator":{"ref":"doi:10.1007/bf02881270/p3/tab-3","row":3},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1007/bf02881270","paper_id":"doi:10.1007/bf02881270","phase_compositions":[{"basis":"mole_fraction","composition":{"AG":0.216,"P":0.784},"composition_source":"printed","phase":"Ag3P11"}],"phases":[{"label":"Ag3P11","model_phase":"AG3P11"}],"pid":"doi:10.1007/bf02881270/p3/tab-3/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-P","system":"AG-P","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05091,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.05091},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.612,"value_stored":0.6612},{"chemical_system":"AG-P","cited_sources":[{"first_author":"Moller","kind":"assessment","label":"81Mol","reference":"M.H. Moller and W. Jeitschko, \"Preparation and Crystal Structure of Trisilver Undecaphosphide, Ag.~Pll, an Unusual Defect Tetrahedral Compound,\" Inorg. Chem., 20, 828-833 (1981). (Equi Diagram, Crys Structure; Experimental ) 8 4 O k a : H. Okamoto and T.B. Massalski, \"The Au-P (GoldPhosphorus) System,\" Bull. Alloy Phase Diagrams, 5(5), 490-491 (1984). (Thermo; Compilation)","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":4,"id":"ORC-QHXJSRRKR4.ffa2ba","locator":{"ref":"doi:10.1007/bf02881270/p3/tab-3","row":3},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1007/bf02881270","paper_id":"doi:10.1007/bf02881270","phase_compositions":[{"basis":"mole_fraction","composition":{"AG":0.216,"P":0.784},"composition_source":"printed","phase":"Ag3P11"}],"phases":[{"label":"Ag3P11","model_phase":"AG3P11"}],"pid":"doi:10.1007/bf02881270/p3/tab-3/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-P","system":"AG-P","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05817,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.05817},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.555,"value_stored":0.7555},{"chemical_system":"AG-P","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-X25KZY6TRV","locator":{"ref":"doi:10.1007/bf02881270/p2/tab-1","row":1},"observation_type":"invariant_reaction","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02881270","own_work_of_paper":true},"paper":"doi:10.1007/bf02881270","paper_id":"doi:10.1007/bf02881270","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"P":0.0},"composition_source":"printed","phase":"L1"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"P":0.097},"composition_source":"printed","phase":"(Ag)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"P":1.0},"composition_source":"printed","phase":"g"}],"phases":[{"label":"L1","model_phase":"LIQUID"},{"label":"(Ag)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"g"}],"pid":"doi:10.1007/bf02881270/p2/tab-1/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L1 <-> (Ag) + g"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AG-P","system":"AG-P","temperature_K":1153.15,"temperature_printed":"880","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1153.15},{"chemical_system":"AG-P","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-LFIGMSMDAB","locator":{"ref":"doi:10.1007/bf02881270/p2/tab-1","row":2},"observation_type":"invariant_reaction","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02881270","own_work_of_paper":true},"paper":"doi:10.1007/bf02881270","paper_id":"doi:10.1007/bf02881270","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"P":0.0},"composition_source":"printed","phase":"(Ag)"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"P":1.0},"composition_source":"printed","phase":"g"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"P":0.667},"composition_source":"printed","phase":"AgP2"}],"phases":[{"label":"(Ag)","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"g"},{"label":"AgP2","model_phase":"AGP2","pearson_symbol":"mP12","prototype":"CuP2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/bf02881270/p2/tab-1/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"(Ag) + g <-> AgP2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AG-P","system":"AG-P","temperature_K":827.15,"temperature_printed":"554","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":827.15},{"chemical_system":"AG-P","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-HXWZDRV6TD","locator":{"ref":"doi:10.1007/bf02881270/p2/tab-1","row":3},"observation_type":"invariant_reaction","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02881270","own_work_of_paper":true},"paper":"doi:10.1007/bf02881270","paper_id":"doi:10.1007/bf02881270","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"P":0.667},"composition_source":"printed","phase":"AgP2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"P":1.0},"composition_source":"printed","phase":"g"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"P":0.784},"composition_source":"printed","phase":"Ag3P11"}],"phases":[{"label":"AgP2","model_phase":"AGP2","pearson_symbol":"mP12","prototype":"CuP2","structure_basis":"mapped_model_phase"},{"label":"g"},{"label":"Ag3P11","model_phase":"AG3P11","pearson_symbol":"mC28","prototype":"Ag3P11","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/bf02881270/p2/tab-1/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"AgP2 + g <-> Ag3P11"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AG-P","system":"AG-P","temperature_K":731.15,"temperature_printed":"458","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":731.15},{"chemical_system":"AG-P","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-WQYAI6I3AN","locator":{"ref":"doi:10.1007/bf02881270/p2/tab-1","row":4},"observation_type":"invariant_reaction","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02881270","own_work_of_paper":true},"paper":"doi:10.1007/bf02881270","paper_id":"doi:10.1007/bf02881270","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"P":1.0},"composition_source":"printed","phase":"g"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"P":0.784},"composition_source":"printed","phase":"Ag3P11"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"P":1.0},"composition_source":"printed","phase":"L2"}],"phases":[{"label":"g"},{"label":"Ag3P11","model_phase":"AG3P11","pearson_symbol":"mC28","prototype":"Ag3P11","structure_basis":"mapped_model_phase"},{"label":"L2","model_phase":"LIQUID"}],"pid":"doi:10.1007/bf02881270/p2/tab-1/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"g <-> Ag3P11 + L2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AG-P","system":"AG-P","temperature_K":553.15,"temperature_printed":"280","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":553.15},{"chemical_system":"AG-P","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":4,"id":"ORC-IXRDQ3VT42","locator":{"ref":"doi:10.1007/bf02881270/p2/tab-1","row":5},"observation_type":"invariant_reaction","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02881270","own_work_of_paper":true},"paper":"doi:10.1007/bf02881270","paper_id":"doi:10.1007/bf02881270","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"P":1.0},"composition_source":"printed","phase":"L2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"P":0.784},"composition_source":"printed","phase":"Ag3P11"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"P":1.0},"composition_source":"printed","phase":"P(white)"}],"phases":[{"label":"L2","model_phase":"LIQUID"},{"label":"Ag3P11","model_phase":"AG3P11","pearson_symbol":"mC28","prototype":"Ag3P11","structure_basis":"mapped_model_phase"},{"label":"P(white)"}],"pid":"doi:10.1007/bf02881270/p2/tab-1/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L2 <-> Ag3P11 + P(white)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AG-P","system":"AG-P","temperature_K":317.25,"temperature_printed":"44.1","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":317.25}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"AG-P"}