{"artifacts":{"doi:10.1007/bf02869269/p4/tab-4":{"artifact":"table","caption":"Ag-Pt Lattice Parameter Data","label":"4","page":4},"doi:10.1007/bf02873021/p2/tab-1":{"artifact":"table","caption":"Ag-lr Crystal Structure and Lattice Parameter Data (25 ~","label":"1","page":2},"doi:10.1007/bf02873022/p1/tab-1":{"artifact":"table","caption":"Ag-lr Crystal Structure and Lattice Parameter Data (25 ~","label":"1","page":1},"doi:10.1007/bf02873022/p2/tab-1":{"artifact":"table","caption":"Ag-Os Crystal Structure and Lattice Parameter Data (25 ~","label":"1","page":2},"doi:10.1007/bf02873023/p2/tab-1":{"artifact":"table","caption":"Ag-Rh Crystal Structure and Lattice Parameter Data (25 ~","label":"1","page":2},"doi:10.1007/bf02873024/p2/tab-1":{"artifact":"table","caption":"Ag-Ru Crystal Structure and Lattice Parameter Data (25 ~","label":"1","page":2},"doi:10.1007/bf02881270/p3/tab-3":{"artifact":"table","caption":"Ag-P Lattice Parameter Data","label":"3","page":3},"doi:10.1007/bf02898263/p5/tab-3":{"artifact":"table","caption":"Ag-Mn Lattice Parameter Data at 21 ~","label":"3","page":5},"doi:10.1007/s11669-018-0683-7/p6/tab-4":{"artifact":"table","caption":"Relative energy (DE, kJ/mole-atom) with respect to fcc-Ag and trigonal-Se estimated from DFT calculations","label":"4","page":6},"doi:10.1016/j.jallcom.2004.04.126/p4/tab-2":{"artifact":"table","caption":"Experimental data obtained by high temperature isoperibolic calorimetry of liquid Ag–Al alloys","label":"2","page":4},"doi:10.1111/j.1151-2916.1997.tb03232.x/p2/tab-i":{"artifact":"table","caption":"Gibbs Energy of Dissolution of Oxygen in Liquid Silver and First-Order Interaction Parameter e O O","label":"I","page":2},"sha256:152dffd3ba088bc9/p5/tab-1":{"artifact":"table","caption":"Enthalpy of formation for the NaSi and Ag 2 Na compounds and the crystal structures of the Na–X (X = Si, Ag) systems","label":"1","page":5},"sha256:6016e175ce77feba/p3/tab-1":{"artifact":"table","caption":"Crystal structures and formation enthalpies of the compounds in Ag–Dy and Ag–Er systems by first-principles calculations.","label":"1","page":3},"sha256:614bc096ebddac3a/p4/tab-2":{"artifact":"table","caption":"Ag-Bi Lattice Parameter Data","label":"2","page":4}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{"doi:10.1016/j.jallcom.2004.04.126":{"context_id":"context:source-doi-10-1016-j-jallcom-2004-04-126","items":[{"extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-VXUWIRULQB","page":4,"quote":"Both methods of analysis give the composition of the coexisting phases in the eutectic with maximal deviation of about 0.6 at.%.","second_reader_agrees":false,"stated_uncertainty":"maximal deviation of about 0.6 at.%","type":"measurement"},{"applies_to":"liquid Ag-Al alloys","atmosphere":"argon 4.8 gas at atmospheric pressure","crucible":"alumina crucible","extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-DEWMKWRGI7","instrument":"high temperature isoperibolic calorimeter","page":6,"quote":"The partial enthalpies of mixing of the liquid components and thereby the integral enthalpy of formation of liquid Ag-Al alloys were measured using a high temperature isoperibolic calorimeter and the method described in [15,16]. The experiments were carried out in alumina crucible at 1373±3 K under argon 4.8 gas at atmospheric pressure.","second_reader_agrees":false,"stated_uncertainty":"±3 K","type":"measurement"},{"composition_basis":"at.%","extraction_accepted":true,"id":"ORC-MY2BBGXABK","label":"hypo-eutectic Ag-38.8 at.% of Al","nominal_composition":"Ag-38.8 at.% of Al","page":4,"purity":"99.9998 wt.%","quote":"For these measurements hypo-eutectic Ag-38.8 at.% of Al and hyper-eutectic Ag-69.2 at.% Al samples of about 30 g each were prepared by melting in argon environment in a high-temperature vacuum furnace. The Ag and Al with purity of 99.9998 wt.% were procured from Goodfellow Cambridge Ltd.","second_reader_agrees":true,"starting_materials":"Ag and Al","synthesis":"melting in argon environment in a high-temperature vacuum furnace","type":"sample"},{"composition_basis":"at.%","extraction_accepted":true,"id":"ORC-MY2BBGXABK","label":"hyper-eutectic Ag-69.2 at.% Al","nominal_composition":"Ag-69.2 at.% Al","page":4,"purity":"99.9998 wt.%","quote":"For these measurements hypo-eutectic Ag-38.8 at.% of Al and hyper-eutectic Ag-69.2 at.% Al samples of about 30 g each were prepared by melting in argon environment in a high-temperature vacuum furnace. The Ag and Al with purity of 99.9998 wt.% were procured from Goodfellow Cambridge Ltd.","second_reader_agrees":true,"starting_materials":"Ag and Al","synthesis":"melting in argon environment in a high-temperature vacuum furnace","type":"sample"},{"cooling":"quenched in cold water","duration":"about 117 h","duration_parsed":{"hours":117.0,"printed":"117 h"},"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-R5ULKQ4VLP","page":4,"quote":"After that, two pieces from these three ones were separately annealed further for about 117 h at 565 and 400 ◦ C, respectively, and quenched in cold water.","second_reader_agrees":true,"temperature":{"T_K":838.15,"converted_in_code":true,"printed":"565","unit_basis":"shared_unit_in_quote","unit_printed":"°C","unit_source_text":"565 and 400 ° C","value_printed":565.0},"temperature_printed":"565","temperature_status":"parsed_from_printed","type":"treatment"},{"cooling":"quenched in cold water","duration":"about 117 h","duration_parsed":{"hours":117.0,"printed":"117 h"},"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-R5ULKQ4VLP","page":4,"quote":"After that, two pieces from these three ones were separately annealed further for about 117 h at 565 and 400 ◦ C, respectively, and quenched in cold water.","second_reader_agrees":true,"temperature":{"T_K":673.15,"converted_in_code":true,"printed":"400 ◦ C","unit_basis":"printed_with_value","unit_printed":"°C","value_printed":400.0},"temperature_printed":"400 ◦ C","temperature_status":"parsed_from_printed","type":"treatment"},{"applies_to":"hypo-eutectic ingot","atmosphere_or_container":"argon","cooling":"quenched in cold water","duration":"191 h","duration_parsed":{"hours":191.0,"printed":"191 h"},"extraction_accepted":true,"id":"ORC-XS4MRBTIZZ","page":4,"quote":"Two other parts of the hypo-eutectic ingot were separately annealed for 191 h in argon at 502 ◦ C and for 305 h at 317 ◦ C, respectively, and quenched in cold water.","second_reader_agrees":true,"temperature":{"T_K":775.15,"converted_in_code":true,"printed":"502 ◦ C","unit_basis":"printed_with_value","unit_printed":"°C","value_printed":502.0},"temperature_printed":"502 ◦ C","temperature_status":"parsed_from_printed","type":"treatment"},{"applies_to":"hypo-eutectic ingot","atmosphere_or_container":"argon","cooling":"quenched in cold water","duration":"305 h","duration_parsed":{"hours":305.0,"printed":"305 h"},"extraction_accepted":true,"id":"ORC-XS4MRBTIZZ","page":4,"quote":"Two other parts of the hypo-eutectic ingot were separately annealed for 191 h in argon at 502 ◦ C and for 305 h at 317 ◦ C, respectively, and quenched in cold water.","second_reader_agrees":true,"temperature":{"T_K":590.15,"converted_in_code":true,"printed":"317 ◦ C","unit_basis":"printed_with_value","unit_printed":"°C","value_printed":317.0},"temperature_printed":"317 ◦ C","temperature_status":"parsed_from_printed","type":"treatment"},{"applies_to":"hyper-eutectic ingot","cooling":"subsequently quenched in cold water as well","duration":"117 h","duration_parsed":{"hours":117.0,"printed":"117 h"},"extraction_accepted":true,"id":"ORC-YNYBTVKDS6","page":4,"quote":"Three other parts of the hyper-eutectic ingot were annealed together for 117 h at a temperature of 500 ◦ C and subsequently quenched in cold water as well.","second_reader_agrees":true,"temperature":{"T_K":773.15,"converted_in_code":true,"printed":"500 ◦ C","unit_basis":"printed_with_value","unit_printed":"°C","value_printed":500.0},"temperature_printed":"500 ◦ C","temperature_status":"parsed_from_printed","type":"treatment"}],"paper":"doi:10.1016/j.jallcom.2004.04.126","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash / exp-context-v2.1-quote","claude-opus-5.5 / exp-context-v2.1-quote (claude broker)"],"section_basis":"own_work_method_cues"}},"elements":["AG"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/bf02671975":{"authors":["I. Karakaya","W. T. Thompson"],"citation":"I. Karakaya, W. T. Thompson, The Ag-Bi (Silver-Bismuth) System, JPE 14, 525-530 (1993).","container":"JPE","doi":"10.1007/bf02671975","doi_url":"https://doi.org/10.1007/bf02671975","id":"doi:10.1007/bf02671975","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"614bc096ebddac3a","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"The Ag-Bi (Silver-Bismuth) System","year":1993},"doi:10.1007/bf02869269":{"authors":["I. Karakaya","W. T. Thompson"],"citation":"I. Karakaya, W. T. Thompson, The Ag-Pt (Silver-Platinum) system, Bulletin of Alloy Phase Diagrams 8, 334-340 (1987).","container":"Bulletin of Alloy Phase Diagrams","doi":"10.1007/bf02869269","doi_url":"https://doi.org/10.1007/bf02869269","id":"doi:10.1007/bf02869269","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"4c202b6095f2d505","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"The Ag-Pt (Silver-Platinum) system","year":1987},"doi:10.1007/bf02873021":{"authors":["I. Karakaya","W. T. Thompson"],"citation":"I. Karakaya, W. T. Thompson, The Ag−Ir (Silver-Iridium) system, Bulletin of Alloy Phase Diagrams 7, 359-360 (1986).","container":"Bulletin of Alloy Phase Diagrams","doi":"10.1007/bf02873021","doi_url":"https://doi.org/10.1007/bf02873021","id":"doi:10.1007/bf02873021","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"24979687498e262a","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"The Ag−Ir (Silver-Iridium) system","year":1986},"doi:10.1007/bf02873022":{"authors":["I. Karakaya","W. T. Thompson"],"citation":"I. Karakaya, W. T. Thompson, The Ag−Os (Silver-Osmium) system, Bulletin of Alloy Phase Diagrams 7, 360-362 (1986).","container":"Bulletin of Alloy Phase Diagrams","doi":"10.1007/bf02873022","doi_url":"https://doi.org/10.1007/bf02873022","id":"doi:10.1007/bf02873022","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"5bb70d074d2ae988","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"The Ag−Os (Silver-Osmium) system","year":1986},"doi:10.1007/bf02873023":{"authors":["I. Karakaya","W. T. Thompson"],"citation":"I. Karakaya, W. T. Thompson, The Ag−Rh (Silver-Rhodium) system, Bulletin of Alloy Phase Diagrams 7, 362-365 (1986).","container":"Bulletin of Alloy Phase Diagrams","doi":"10.1007/bf02873023","doi_url":"https://doi.org/10.1007/bf02873023","id":"doi:10.1007/bf02873023","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"b761655da50cf54a","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"The Ag−Rh (Silver-Rhodium) system","year":1986},"doi:10.1007/bf02873024":{"authors":["I. Karakaya","W. T. Thompson"],"citation":"I. Karakaya, W. T. Thompson, The Ag−Ru (Silver-Ruthenium) system, Bulletin of Alloy Phase Diagrams 7, 365-368 (1986).","container":"Bulletin of Alloy Phase Diagrams","doi":"10.1007/bf02873024","doi_url":"https://doi.org/10.1007/bf02873024","id":"doi:10.1007/bf02873024","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"ce9b1b7bf7bc6136","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"The Ag−Ru (Silver-Ruthenium) system","year":1986},"doi:10.1007/bf02881270":{"authors":["I. Karakaya","W. T. Thompson"],"citation":"I. Karakaya, W. T. Thompson, The Ag−P (Silver-Phosphorus) system, Bulletin of Alloy Phase Diagrams 9, 232-236 (1988).","container":"Bulletin of Alloy Phase Diagrams","doi":"10.1007/bf02881270","doi_url":"https://doi.org/10.1007/bf02881270","id":"doi:10.1007/bf02881270","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"1908efa11ede3d54","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"The Ag−P (Silver-Phosphorus) system","year":1988},"doi:10.1007/bf02898263":{"authors":["I. Karakaya","W. T. Thompson"],"citation":"I. Karakaya, W. T. Thompson, The Ag-Mn (Silver-Manganese) system, Bulletin of Alloy Phase Diagrams 11, 480-486 (1990).","container":"Bulletin of Alloy Phase Diagrams","doi":"10.1007/bf02898263","doi_url":"https://doi.org/10.1007/bf02898263","id":"doi:10.1007/bf02898263","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"91702cad0a1b48c8","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"The Ag-Mn (Silver-Manganese) system","year":1990},"doi:10.1007/s11669-018-0683-7":{"authors":["Zhi Li","Shun-Li Shang","Jianyun Shen","Po-Hsien Liao","Zi-Kui Liu","Timothy J. Anderson"],"citation":"Zhi Li, Shun-Li Shang, Jianyun Shen, Po-Hsien Liao, Zi-Kui Liu, Timothy J. Anderson, Thermodynamic Assessment of the Ag-Se System Aided by First-Principles Calculations, J. Phase Equilib. Diffus. 39, 870-881 (2018).","container":"J. Phase Equilib. Diffus.","doi":"10.1007/s11669-018-0683-7","doi_url":"https://doi.org/10.1007/s11669-018-0683-7","id":"doi:10.1007/s11669-018-0683-7","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"017b6a6adcb3cb9e","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic Assessment of the Ag-Se System Aided by First-Principles Calculations","year":2018},"doi:10.1016/j.calphad.2004.05.002":{"authors":["Yi Wang"],"citation":"Yi Wang, Ab initio lattice stability in comparison with CALPHAD lattice stability, Calphad (2004).","container":"Calphad","doi":"10.1016/j.calphad.2004.05.002","doi_url":"https://doi.org/10.1016/j.calphad.2004.05.002","id":"doi:10.1016/j.calphad.2004.05.002","kind":"cited_work","metadata_source":"openalex/crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Ab initio lattice stability in comparison with CALPHAD lattice stability","year":2004},"doi:10.1016/j.jallcom.2004.04.126":{"authors":["V.T. Witusiewicz","U. Hecht","S.G. Fries","S. Rex"],"citation":"V.T. Witusiewicz, U. Hecht, S.G. Fries, S. Rex, The Ag–Al–Cu system, Journal of Alloys and Compounds 385, 133-143 (2004).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2004.04.126","doi_url":"https://doi.org/10.1016/j.jallcom.2004.04.126","id":"doi:10.1016/j.jallcom.2004.04.126","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"025e779fcef6ccfb","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"The Ag–Al–Cu system","year":2004},"doi:10.1016/j.jallcom.2009.09.036":{"authors":["Z.H. Long","Y.J. Yang","S. Jin","H.S. Liu","F. Zheng","Z.P. Jin"],"citation":"Z.H. Long, Y.J. Yang, S. Jin, H.S. Liu, F. Zheng, Z.P. Jin, Thermodynamic assessments of Ag–Dy and Ag–Er binary systems, Journal of Alloys and Compounds 489, 146-151 (2010).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2009.09.036","doi_url":"https://doi.org/10.1016/j.jallcom.2009.09.036","id":"doi:10.1016/j.jallcom.2009.09.036","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"6016e175ce77feba","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic assessments of Ag–Dy and Ag–Er binary systems","year":2010},"doi:10.1111/j.1151-2916.1997.tb03232.x":{"authors":["Jérôme Assal","Bengt Hallstedt","Ludwig J. Gauckler"],"citation":"Jérôme Assal, Bengt Hallstedt, Ludwig J. Gauckler, Thermodynamic Assessment of the Silver–Oxygen System, Journal of the American Ceramic Society 80, 3054-3060 (1997).","container":"Journal of the American Ceramic Society","doi":"10.1111/j.1151-2916.1997.tb03232.x","doi_url":"https://doi.org/10.1111/j.1151-2916.1997.tb03232.x","id":"doi:10.1111/j.1151-2916.1997.tb03232.x","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"3ef4d8a52f994c6c","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic Assessment of the Silver–Oxygen System","year":1997},"doi:10.2298/jmmb120113024h":{"authors":["D. Hao","M. Bu","Y. Wang","Y. Tang","Q. Gao","M. Wang","B. Hu","Y. Du"],"citation":"D. Hao, M. Bu, Y. Wang, Y. Tang, Q. Gao, M. Wang et al., Thermodynamic modeling of the Na-X (X = Si, Ag, Cu, Cr) systems, J min metall B Metall 48, 273-282 (2012).","container":"J min metall B Metall","doi":"10.2298/jmmb120113024h","doi_url":"https://doi.org/10.2298/jmmb120113024h","id":"doi:10.2298/jmmb120113024h","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"152dffd3ba088bc9","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic modeling of the Na-X (X = Si, Ag, Cu, Cr) systems","year":2012},"ref:d2b09f5b98dc6107":{"citation":"A. Sieverts and J. Hagenacker, ‘‘Solubilities of Hydrogen and Oxygen in Solid and Liquid Silver’’ (in Ger.), Z. Phys. Chem. (Munich), 68 [1] 115–28 (1909).","id":"ref:d2b09f5b98dc6107","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1909}},"part":1,"parts":1,"records":[{"chemical_system":"AG","cited_sources":[{"kind":"unknown","label":"1","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AG","before":"AG-PT","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["(Ag)"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":"ORC-YYVN2DF6OA.780394","before":null,"evidence":{"class":"temperature","decision":"same printed cell (single 'Lattice parameter, nm' column) stored as LATTICE_UNSPECIFIED_AXIS and LATTICE_A; keep LATTICE_A (fcc/cubic lattice parameter)","decision_file":"temperature_t080.json","doi":"10.1007/bf02869269","kept_id":"ORC-YYVN2DF6OA.780394","pdf_page":4,"pdf_sha256":"4c202b6095f2d50594aea757c4de0f40f6f66abd6e890049128bdc0ac66db279","printed":"","rationale":"Same printed cell as ORC-YYVN2DF6OA.780394; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"4","table_key":"t080"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"6cc8e464c34f60b0c2a05b7e17bde911dcff198fdbb2ec9a817f050dc1f56f8e","page":4,"pdf_sha256_prefix":"4c202b6095f2d505","seen":"row 1, lattice parameter column","verdict":"confirmed"}}],"duplicate_of":"ORC-YYVN2DF6OA.780394","evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"gate_failures":["duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"duplicate_source_row","detail":"same printed cell (single 'Lattice parameter, nm' column) stored as LATTICE_UNSPECIFIED_AXIS and LATTICE_A; keep LATTICE_A (fcc/cubic lattice parameter)","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (temperature, t080)","image_sha256":"6cc8e464c34f60b0c2a05b7e17bde911dcff198fdbb2ec9a817f050dc1f56f8e","page":4,"pdf_sha256_prefix":"4c202b6095f2d505","seen":"row 1, lattice parameter column","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-YYVN2DF6OA.780394 (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-YYVN2DF6OA.308f06","locator":{"ref":"doi:10.1007/bf02869269/p4/tab-4","row":1},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/bf02869269","paper_id":"doi:10.1007/bf02869269","phase_compositions":[{"basis":"mole_fraction","composition":{"AG":1.0},"composition_source":"printed","composition_stored":{"AG":1.0,"PT":0.0},"phase":"(Ag)"}],"phases":[{"label":"(Ag)"}],"pid":"doi:10.1007/bf02869269/p4/tab-4/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_UNSPECIFIED_AXIS","property_code_raw":"LATTICE_LATTICE_PARAMETER","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-PT","system":"AG","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008989,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008989},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.0861,"value_stored":0.40861},{"chemical_system":"AG","cited_sources":[{"kind":"unknown","label":"1","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AG","before":"AG-PT","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["(Ag)"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":null,"before":298.15,"evidence":{"paper":"doi:10.1007/bf02869269","pdf_page":4,"pdf_sha256":"4c202b6095f2d50594aea757c4de0f40f6f66abd6e890049128bdc0ac66db279","rationale":"Clear a temperature taken from an annealing or adjacent experimental column; retain the record as already excluded from ESPEI fitting.","report_id":"ORCHID-Y10-20261027-v1"},"field":"temperature_K","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"2026-10-27; Codex rendered-page recheck at 220 dpi with OCR assistance; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"4c202b6095f2d505","page":4,"pdf_sha256_prefix":"4c202b6095f2d505","seen":"The pure Ag row leaves Annealing °C blank; 298.15 K is an assumption, not a printed measurement temperature.","verdict":"confirmed"}},{"after":"not_printed","before":"assumed_room_temperature","evidence":{"paper":"doi:10.1007/bf02869269","pdf_page":4,"pdf_sha256":"4c202b6095f2d50594aea757c4de0f40f6f66abd6e890049128bdc0ac66db279","rationale":"Clear a temperature taken from an annealing or adjacent experimental column; retain the record as already excluded from ESPEI fitting.","report_id":"ORCHID-Y10-20261027-v1"},"field":"temperature_basis","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"2026-10-27; Codex rendered-page recheck at 220 dpi with OCR assistance; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"4c202b6095f2d505","page":4,"pdf_sha256_prefix":"4c202b6095f2d505","seen":"The pure Ag row leaves Annealing °C blank; 298.15 K is an assumption, not a printed measurement temperature.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"gate_failures":["measurement_temperature_not_stated","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["independent_check_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"measurement_temperature_not_stated","detail":"stored T=298.15 (assumed_room_temperature) is not printed: annealing temperature cell is '...' and no measurement T is stated on the page","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (temperature, t080)","image_sha256":"6cc8e464c34f60b0c2a05b7e17bde911dcff198fdbb2ec9a817f050dc1f56f8e","page":4,"pdf_sha256_prefix":"4c202b6095f2d505","seen":"(Ag) 0 at.% Pt '...' 0.40861 [King1]; γ '...' '...' 0.3890 [Pearson2]","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"The source may permit a separately modeled annealing condition, but it does not support that temperature as the measurement temperature.","effect":"not_espei_ready","gate":"CX20261028"}],"id":"ORC-YYVN2DF6OA.780394","locator":{"ref":"doi:10.1007/bf02869269/p4/tab-4","row":1},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/bf02869269","paper_id":"doi:10.1007/bf02869269","phase_compositions":[{"basis":"mole_fraction","composition":{"AG":1.0},"composition_source":"printed","composition_stored":{"AG":1.0,"PT":0.0},"phase":"(Ag)"}],"phases":[{"label":"(Ag)"}],"pid":"doi:10.1007/bf02869269/p4/tab-4/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-PT","system":"AG","temperature_K":null,"temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008989,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008989},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.0861,"value_stored":0.40861},{"chemical_system":"AG","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AG","before":"AG-IR","evidence":{"basis":"printed_overall_composition","overall_composition":{"AG":1.0,"IR":0.0},"phases":["Ag(s)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-Z4GYAM2GXT","locator":{"ref":"doi:10.1007/bf02873021/p2/tab-1","row":1},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02873021","own_work_of_paper":true},"overall_composition":{"AG":1.0},"overall_composition_stored":{"AG":1.0,"IR":0.0},"paper":"doi:10.1007/bf02873021","paper_id":"doi:10.1007/bf02873021","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":1.0},"composition_source":"printed","composition_stored":{"AG":1.0,"IR":0.0},"phase":"Ag(s)"}],"phases":[{"label":"Ag(s)"}],"pid":"doi:10.1007/bf02873021/p2/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-IR","structure":{"pearson_symbol":"cF4","prototype":"Cu","strukturbericht":"A1"},"system":"AG","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008989,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008989},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.0861,"value_stored":0.40861},{"chemical_system":"AG","cited_sources":[{"kind":"unknown","label":"1","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AG","before":"AG-IR","evidence":{"basis":"printed_overall_composition","overall_composition":{"AG":1.0,"IR":0.0},"phases":["Ag(s)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-RNABF3L75O.610bc5","locator":{"ref":"doi:10.1007/bf02873022/p1/tab-1","row":1},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"AG":1.0},"overall_composition_stored":{"AG":1.0,"IR":0.0},"paper":"doi:10.1007/bf02873022","paper_id":"doi:10.1007/bf02873022","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":1.0},"composition_source":"printed","composition_stored":{"AG":1.0,"IR":0.0},"phase":"Ag(s)"}],"phases":[{"label":"Ag(s)"}],"pid":"doi:10.1007/bf02873022/p1/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_UNSPECIFIED_AXIS","property_code_raw":"LATTICE_LATTICE_PARAMETER","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-IR","structure":{"pearson_symbol":"cF4","prototype":"Cu","space_group":"Fm3m","strukturbericht":"A1"},"system":"AG","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"25","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008989,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008989},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.0861,"value_stored":0.40861},{"chemical_system":"AG","cited_sources":[{"kind":"unknown","label":"1","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AG","before":"AG-IR","evidence":{"basis":"printed_overall_composition","overall_composition":{"AG":1.0,"IR":0.0},"phases":["Ag(s)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-RNABF3L75O.ed80ac","locator":{"ref":"doi:10.1007/bf02873022/p1/tab-1","row":1},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"AG":1.0},"overall_composition_stored":{"AG":1.0,"IR":0.0},"paper":"doi:10.1007/bf02873022","paper_id":"doi:10.1007/bf02873022","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":1.0},"composition_source":"printed","composition_stored":{"AG":1.0,"IR":0.0},"phase":"Ag(s)"}],"phases":[{"label":"Ag(s)"}],"pid":"doi:10.1007/bf02873022/p1/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-IR","structure":{"pearson_symbol":"cF4","prototype":"Cu","space_group":"Fm3m","strukturbericht":"A1"},"system":"AG","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"25","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008989,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008989},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.0861,"value_stored":0.40861},{"chemical_system":"AG","cited_sources":[{"kind":"unknown","label":"1","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AG","before":"AG-OS","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["Ag(s)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":0,"fold_lso":0,"id":"ORC-LJIGBSRBAQ.3876f5","locator":{"ref":"doi:10.1007/bf02873022/p2/tab-1","row":1},"merged_ids":["ORC-LJIGBSRBAQ.42bc6e"],"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/bf02873022","paper_id":"doi:10.1007/bf02873022","phase_compositions":[{"basis":"mole_fraction","composition":{"AG":1.0},"composition_source":"printed","composition_stored":{"AG":1.0,"OS":0.0},"phase":"Ag(s)"}],"phases":[{"label":"Ag(s)"}],"pid":"doi:10.1007/bf02873022/p2/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_code_raw":"LATTICE_LATTICE_PARAMETER_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-OS","structure":{"pearson_symbol":"cF4","prototype":"Cu","space_group":"Fm3m","strukturbericht":"A1"},"system":"AG","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"25","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008989,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008989},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.0861,"value_stored":0.40861},{"chemical_system":"AG","cited_sources":[{"kind":"unknown","label":"1","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AG","before":"AG-RH","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["Ag(s)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-TNYUDAOXB4.ba77be","locator":{"ref":"doi:10.1007/bf02873023/p2/tab-1","row":1},"merged_ids":["ORC-TNYUDAOXB4.d1612b"],"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1007/bf02873023","paper_id":"doi:10.1007/bf02873023","phase_compositions":[{"basis":"mole_fraction","composition":{"AG":1.0},"composition_source":"printed","composition_stored":{"AG":1.0,"RH":0.0},"phase":"Ag(s)"}],"phases":[{"label":"Ag(s)"}],"pid":"doi:10.1007/bf02873023/p2/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-RH","structure":{"pearson_symbol":"cF4","prototype":"Cu","space_group":"Fm3m","strukturbericht":"A1"},"system":"AG","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"25","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008989,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008989},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.0861,"value_stored":0.40861},{"chemical_system":"AG","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AG","before":"AG-RU","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["Ag(s)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-TL6RWRZFVX.2f2b4c","locator":{"ref":"doi:10.1007/bf02873024/p2/tab-1","row":1},"merged_ids":["ORC-TL6RWRZFVX.71a805"],"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02873024","own_work_of_paper":true},"paper":"doi:10.1007/bf02873024","paper_id":"doi:10.1007/bf02873024","phase_compositions":[{"basis":"mole_fraction","composition":{"AG":1.0},"composition_source":"printed","composition_stored":{"AG":1.0,"RU":0.0},"phase":"Ag(s)"}],"phases":[{"label":"Ag(s)"}],"pid":"doi:10.1007/bf02873024/p2/tab-1/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-RU","structure":{"pearson_symbol":"cF4","prototype":"Cu","strukturbericht":"A1"},"system":"AG","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"25","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008989,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008989},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.0861,"value_stored":0.40861},{"chemical_system":"AG","cited_sources":[{"kind":"unknown","label":"1","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AG","before":"AG-P","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["Ag(s)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-TGUNKV43RG","locator":{"ref":"doi:10.1007/bf02881270/p3/tab-3","row":1},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1007/bf02881270","paper_id":"doi:10.1007/bf02881270","phase_compositions":[{"basis":"mole_fraction","composition":{"AG":1.0},"composition_source":"printed","composition_stored":{"AG":1.0,"P":0.0},"phase":"Ag(s)"}],"phases":[{"label":"Ag(s)"}],"pid":"doi:10.1007/bf02881270/p3/tab-3/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-P","system":"AG","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008989,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008989},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.0861,"value_stored":0.40861},{"chemical_system":"AG","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AG","before":"AG-MN","evidence":{"basis":"printed_overall_composition","overall_composition":{"AG":1.0,"MN":0.0},"phases":["Ag"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-CNN4FAK62S.44ae1c","locator":{"ref":"doi:10.1007/bf02898263/p5/tab-3","row":1},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02898263","own_work_of_paper":true},"overall_composition":{"AG":1.0},"overall_composition_stored":{"AG":1.0,"MN":0.0},"paper":"doi:10.1007/bf02898263","paper_id":"doi:10.1007/bf02898263","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":1.0},"composition_source":"printed","composition_stored":{"AG":1.0,"MN":0.0},"phase":"Ag"}],"phases":[{"label":"Ag"}],"pid":"doi:10.1007/bf02898263/p5/tab-3/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-MN","system":"AG","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"25","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008989,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008989},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.0861,"value_stored":0.40861},{"chemical_system":"AG","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AG","before":"AG-MN","evidence":{"basis":"printed_overall_composition","overall_composition":{"AG":1.0,"MN":0.0},"phases":["Ag"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-CNN4FAK62S.e85f87","locator":{"ref":"doi:10.1007/bf02898263/p5/tab-3","row":1},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02898263","own_work_of_paper":true},"overall_composition":{"AG":1.0},"overall_composition_stored":{"AG":1.0,"MN":0.0},"paper":"doi:10.1007/bf02898263","paper_id":"doi:10.1007/bf02898263","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":1.0},"composition_source":"printed","composition_stored":{"AG":1.0,"MN":0.0},"phase":"Ag"}],"phases":[{"label":"Ag"}],"pid":"doi:10.1007/bf02898263/p5/tab-3/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_UNSPECIFIED_AXIS","property_code_raw":"LATTICE_LATTICE_PARAMETERS","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-MN","system":"AG","temperature_K":298.15,"temperature_basis":"printed","temperature_printed":"25","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008989,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008989},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.0861,"value_stored":0.40861},{"chemical_system":"AG","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AG","before":"AG-MN","evidence":{"basis":"printed_overall_composition","overall_composition":{"AG":1.0,"MN":0.0},"phases":["(Ag)"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":294.15,"before":848.15,"evidence":{"class":"temperature","decision_file":"temperature_t081.json","doi":"10.1007/bf02898263","pdf_page":5,"pdf_sha256":"91702cad0a1b48c8f63c99746ca9e73e3b5c1da317db120cd37f6c4fc844a71a","printed":"Table 3 Ag-Mn Lattice Parameter Data at 21 °C ... (Ag) 0 0.408612 Annealed at 575 °C [62Cal]","rationale":"caption states the lattice parameters are at 21 °C; only rows marked (a) have unknown measurement T; 575 °C is the anneal temperature","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t081"},"field":"temperature_K","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"5af97c5117b9bf01041974039e0c06a0945ca02b83306df0ee6fba8427742b39","page":5,"pdf_sha256_prefix":"91702cad0a1b48c8","seen":"(Ag) rows 0, 2.08, 4.59, 4.89 at.% Mn, comment 'Annealed at 575 °C' (no footnote a); stored T 848.15 = 575 °C anneal","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-FK6CDRNCKY.98f875","locator":{"ref":"doi:10.1007/bf02898263/p5/tab-3","row":2},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02898263","own_work_of_paper":true},"overall_composition":{"AG":1.0},"overall_composition_stored":{"AG":1.0,"MN":0.0},"paper":"doi:10.1007/bf02898263","paper_id":"doi:10.1007/bf02898263","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":1.0},"composition_source":"printed","composition_stored":{"AG":1.0,"MN":0.0},"phase":"(Ag)"}],"phases":[{"label":"(Ag)"}],"pid":"doi:10.1007/bf02898263/p5/tab-3/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_UNSPECIFIED_AXIS","property_code_raw":"LATTICE_LATTICE_PARAMETERS","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-MN","system":"AG","temperature_K":294.15,"temperature_basis":"printed","temperature_printed":"575","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-06},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008989,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008989},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.08612,"value_stored":0.408612},{"chemical_system":"AG","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AG","before":"AG-MN","evidence":{"basis":"printed_overall_composition","overall_composition":{"AG":1.0,"MN":0.0},"phases":["(Ag)"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":294.15,"before":848.15,"evidence":{"class":"temperature","decision_file":"temperature_t081.json","doi":"10.1007/bf02898263","pdf_page":5,"pdf_sha256":"91702cad0a1b48c8f63c99746ca9e73e3b5c1da317db120cd37f6c4fc844a71a","printed":"Table 3 Ag-Mn Lattice Parameter Data at 21 °C ... (Ag) 0 0.408612 Annealed at 575 °C [62Cal]","rationale":"caption states the lattice parameters are at 21 °C; only rows marked (a) have unknown measurement T; 575 °C is the anneal temperature","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t081"},"field":"temperature_K","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"5af97c5117b9bf01041974039e0c06a0945ca02b83306df0ee6fba8427742b39","page":5,"pdf_sha256_prefix":"91702cad0a1b48c8","seen":"(Ag) rows 0, 2.08, 4.59, 4.89 at.% Mn, comment 'Annealed at 575 °C' (no footnote a); stored T 848.15 = 575 °C anneal","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-FK6CDRNCKY.f19f53","locator":{"ref":"doi:10.1007/bf02898263/p5/tab-3","row":2},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02898263","own_work_of_paper":true},"overall_composition":{"AG":1.0},"overall_composition_stored":{"AG":1.0,"MN":0.0},"paper":"doi:10.1007/bf02898263","paper_id":"doi:10.1007/bf02898263","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AG":1.0},"composition_source":"printed","composition_stored":{"AG":1.0,"MN":0.0},"phase":"(Ag)"}],"phases":[{"label":"(Ag)"}],"pid":"doi:10.1007/bf02898263/p5/tab-3/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-MN","system":"AG","temperature_K":294.15,"temperature_basis":"printed","temperature_printed":"575","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-06},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008989,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008989},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.08612,"value_stored":0.408612},{"calculation_settings":{"functional":"PBE + D3"},"chemical_system":"AG","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AG","before":"AG-SE","evidence":{"basis":"phase_formula","overall_composition":{"SE":0.0},"phases":["α-Ag"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-536MYGGDN3","locator":{"ref":"doi:10.1007/s11669-018-0683-7/p6/tab-4","row":3},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-018-0683-7","own_work_of_paper":true},"overall_composition":{},"overall_composition_basis":"from_formula","overall_composition_stored":{"SE":0.0},"paper":"doi:10.1007/s11669-018-0683-7","paper_id":"doi:10.1007/s11669-018-0683-7","phases":[{"label":"α-Ag"}],"pid":"doi:10.1007/s11669-018-0683-7/p6/tab-4/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔE","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"AG":{"phase":"printed:fcc-Ag and trigonal-Se"}},"reference_state_stored":{"AG":{"phase":"printed:fcc-Ag and trigonal-Se"},"SE":{"phase":"printed:fcc-Ag and trigonal-Se"}},"source_system":"AG-SE","system":"AG","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (the quantity is defined at 0 K)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.0259},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":0.518,"value_printed":0.518,"value_stored":518.0},{"calculation_settings":{"functional":"PBEsol"},"chemical_system":"AG","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AG","before":"AG-SE","evidence":{"basis":"phase_formula","overall_composition":{"SE":0.0},"phases":["α-Ag"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":0,"id":"ORC-L7YW7KOMQ3","locator":{"ref":"doi:10.1007/s11669-018-0683-7/p6/tab-4","row":4},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-018-0683-7","own_work_of_paper":true},"overall_composition":{},"overall_composition_basis":"from_formula","overall_composition_stored":{"SE":0.0},"paper":"doi:10.1007/s11669-018-0683-7","paper_id":"doi:10.1007/s11669-018-0683-7","phases":[{"label":"α-Ag"}],"pid":"doi:10.1007/s11669-018-0683-7/p6/tab-4/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔE","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"AG":{"phase":"printed:fcc-Ag and trigonal-Se"}},"reference_state_stored":{"AG":{"phase":"printed:fcc-Ag and trigonal-Se"},"SE":{"phase":"printed:fcc-Ag and trigonal-Se"}},"source_system":"AG-SE","system":"AG","temperature_K":0.0,"temperature_basis":"quantity_label","temperature_printed":"0 K (the quantity is defined at 0 K)","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.02805},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"caption","unit_printed":"kJ/mole-atom","unit_stored":"J/mol-atom","value":0.561,"value_printed":0.561,"value_stored":561.0},{"chemical_system":"AG","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2004.04.126"},"corrections":[{"after":"AG","before":"AG-AL","evidence":{"basis":"printed_overall_composition","overall_composition":{"AG":1.0,"AL":0.0},"phases":["liquid"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-D4UB6MT7XP.e066d2","locator":{"ref":"doi:10.1016/j.jallcom.2004.04.126/p4/tab-2","row":2},"merged_ids":["ORC-UABTJFL75R.698dba"],"merged_pids":["doi:10.1016/j.jallcom.2004.04.126/p4/tab-2/r01#equilibrium_property"],"method":"high temperature isoperibolic calorimetry","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2004.04.126","own_work_of_paper":true},"overall_composition":{"AG":1.0},"overall_composition_stored":{"AG":1.0,"AL":0.0},"paper":"doi:10.1016/j.jallcom.2004.04.126","paper_id":"doi:10.1016/j.jallcom.2004.04.126","phases":[{"label":"liquid","model_phase":"LIQUID"}],"pid":"doi:10.1016/j.jallcom.2004.04.126/p4/tab-2/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AG":{"phase":"LIQUID"}},"reference_state_stored":{"AG":{"phase":"LIQUID"},"AL":{"phase":"LIQUID"}},"source_system":"AG-AL","system":"AG","temperature_K":1373.0,"temperature_basis":"printed","temperature_uncertainty":{"basis":"printed","value":3.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1e-09},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.5,"sigma_method":{"basis":"prior","ci95":null,"class":"solution_reaction_calorimetry","entry":"value_types/H_MIX_PARTIAL/classes/solution_reaction_calorimetry","floor":0.5,"floor_unit":"kJ/mol","n_pairs":0,"prior_source":"espei","value":0.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"kJ mol^-1","unit_stored":"J/mol (basis unstated)","value":0.0,"value_printed":0,"value_stored":0.0},{"chemical_system":"AG","cited_sources":[{"first_author":"Donnan","kind":"unknown","label":"20","reference":"F. G. Donnan and T. W. A. Shaw, ‘‘The Solubility of Oxygen in Molten Silver,’’ J. Soc. Chem. Ind., London, 29 [16] 987–89 (1910).","status":"resolved","year":"1910"}],"component":"O","conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AG","before":"AG-O","evidence":{"basis":"printed_overall_composition","overall_composition":{"O":0.0},"phases":["liquid Ag"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-XB4OBER4ZF.674d93","locator":{"ref":"doi:10.1111/j.1151-2916.1997.tb03232.x/p2/tab-i","row":2},"method":"Absorption","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{},"overall_composition_stored":{"O":0.0},"paper":"doi:10.1111/j.1151-2916.1997.tb03232.x","paper_id":"doi:10.1111/j.1151-2916.1997.tb03232.x","phases":[{"label":"liquid Ag"}],"pid":"doi:10.1111/j.1151-2916.1997.tb03232.x/p2/tab-i/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GIBBS_ENERGY","property_group":"activity / EMF / Gibbs energy","property_printed":"Δ°G","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-O","system":"AG","temperature_K":1348.0,"temperature_basis":"printed","temperature_printed":"1348","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":348.75},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1000.0,"sigma_method":{"basis":"prior","ci95":null,"class":"experimental_unspecified","entry":"value_types/G_MIX_PARTIAL/classes/experimental_unspecified","floor":1.0,"floor_unit":"kJ/mol","n_pairs":0,"prior_source":"kubaschewski","value":1000.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol","value_type":"G_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol","unit_printed":"J/mol","value":-6975.0,"value_printed":-6975},{"chemical_system":"AG","cited_sources":[{"first_author":"Sieverts","kind":"unknown","label":"15","reference":"A. Sieverts and J. Hagenacker, ‘‘Solubilities of Hydrogen and Oxygen in Solid and Liquid Silver’’ (in Ger.), Z. Phys. Chem. (Munich), 68 [1] 115–28 (1909).","status":"resolved","year":"1909"}],"component":"O","conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"max":1398.0,"min":1348.0},"before":null,"evidence":{"printed":"1348, 1398"},"field":"temperature_range_K","gate":"R3","rule":"temperature_range_printed_not_stored","visual_check":{"checked":"2026-10-24","image_sha256":"3156734fb3bdea77b293312c911cb2bba59f6a7b7caacff186601073c42ca856","page":6,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Row temperature printed (CrN at 1173 K; SiP at melting 1443 K) but not stored.","verdict":"rule_confirmed"}},{"after":"AG","before":"AG-O","evidence":{"basis":"printed_overall_composition","overall_composition":{"O":0.0},"phases":["liquid Ag"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":"ORC-HE7LQKN7Y4.35385c","before":null,"evidence":{"class":"dup2","decision":"Natural alias would be the r1 placeholder (EXCL), but ORC-XNG6K44SHM is clearly worse: its locator row 13 does not exist (table has 12 rows); the only printed -6887 is in row 1. Kept r1 record has the correct locator and is getting liquid Ag via the table-context batch.","decision_file":"dup2_t251.json","doi":"10.1111/j.1151-2916.1997.tb03232.x","kept_id":"ORC-HE7LQKN7Y4.35385c","pdf_page":2,"pdf_sha256":"3ef4d8a52f994c6c2628d817ae64b9af53a095a61be97436dbcf3f3ace72e497","printed":"","rationale":"Same printed cell as ORC-HE7LQKN7Y4.35385c; not an independent observation.","report_id":"ORCHID-TD-20261028-v1","table":"I","table_key":"t251"},"field":"duplicate_of","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"b6800c007f918c5eb4dda62f7f0b082f1b0cc83c7d016f4dc7550d19e7eaa423","page":2,"pdf_sha256_prefix":"3ef4d8a52f994c6c","seen":"row 1 ΔG° '-7028, -6887' (J/mol), T '1348, 1398'","verdict":"confirmed"}}],"duplicate_of":"ORC-HE7LQKN7Y4.35385c","evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["no_single_temperature","duplicate_source_row","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["state:T_K","state:reference_state","temperature not stated","table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"gate_failures":[{"code":"no_single_temperature","detail":"printed for a temperature range 1348-1398 K","effect":"not_espei_ready","gate":"R3","visual_check":{"checked":"2026-10-24","image_sha256":"3156734fb3bdea77b293312c911cb2bba59f6a7b7caacff186601073c42ca856","page":6,"pdf_sha256_prefix":"20c4aebfdd28e7fc","seen":"Row temperature printed (CrN at 1173 K; SiP at melting 1443 K) but not stored.","verdict":"rule_confirmed"}},{"code":"duplicate_source_row","detail":"Natural alias would be the r1 placeholder (EXCL), but ORC-XNG6K44SHM is clearly worse: its locator row 13 does not exist (table has 12 rows); the only printed -6887 is in row 1. Kept r1 record has the correct locator and is getting liquid A","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (dup2, t251)","image_sha256":"b6800c007f918c5eb4dda62f7f0b082f1b0cc83c7d016f4dc7550d19e7eaa423","page":2,"pdf_sha256_prefix":"3ef4d8a52f994c6c","seen":"row 1 ΔG° '-7028, -6887' (J/mol), T '1348, 1398'","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"Duplicate of ORC-HE7LQKN7Y4.35385c (same printed cell); not independent evidence: exclude from fitting, counts and calibration.","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-XNG6K44SHM","locator":{"ref":"doi:10.1111/j.1151-2916.1997.tb03232.x/p2/tab-i","row":13},"method":"Absorption","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:d2b09f5b98dc6107","own_work_of_paper":false},"overall_composition":{},"overall_composition_stored":{"O":0.0},"paper":"doi:10.1111/j.1151-2916.1997.tb03232.x","paper_id":"doi:10.1111/j.1151-2916.1997.tb03232.x","phases":[{"label":"liquid Ag"}],"pid":"doi:10.1111/j.1151-2916.1997.tb03232.x/p2/tab-i/r13#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GIBBS_ENERGY","property_group":"activity / EMF / Gibbs energy","property_printed":"Δ°G","reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AG-O","system":"AG","temperature_basis":"row_temperature_range_printed","temperature_printed":"1348, 1398","temperature_range_K":{"max":1398.0,"min":1348.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":344.35},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1000.0,"sigma_method":{"basis":"prior","ci95":null,"class":"experimental_unspecified","entry":"value_types/G_MIX_PARTIAL/classes/experimental_unspecified","floor":1.0,"floor_unit":"kJ/mol","n_pairs":0,"prior_source":"kubaschewski","value":1000.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"J/mol","value_type":"G_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol","unit_printed":"J/mol","value":-6887.0,"value_printed":-6887},{"chemical_system":"AG","cited_sources":[{"first_author":"Spreadborough","kind":"unknown","label":"29","reference":"J. Spreadborough and J.W. Christian, J. Sci. Instrum., 36 (1959) 116-118.","status":"resolved","year":"1959"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"Ag","label_source":"printed_source_page","pearson_symbol":"cF4","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_08","doi":"10.2298/jmmb120113024h","pdf_page":5,"pdf_sha256":"152dffd3ba088bc9e5bd86fb8389755335de9306f4fbcd7d7998ed269cfd66f9","printed":"Ag | cF4 | Fm-3m | 4.085 [29] / 4.149 TW","rationale":"Printed table context for this group supplies phase, pearson_symbol, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[7,8],"table":"1","table_key":"t144"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"601c9132ac6ddf90707697f49d5b7b93d6501b0cc3ad3d66e9d75526111f4b07","page":5,"pdf_sha256_prefix":"152dffd3ba088bc9","seen":"merged cells span both Ag rows; records carry composition {NA0,SI0} (Ag not encoded)","verdict":"confirmed"}},{"after":{"pearson_symbol":"cF4","phase":"Ag","space_group":"Fm-3m"},"before":null,"evidence":{"batch":"table_context_batch_08","doi":"10.2298/jmmb120113024h","pdf_page":5,"pdf_sha256":"152dffd3ba088bc9e5bd86fb8389755335de9306f4fbcd7d7998ed269cfd66f9","printed":"Ag | cF4 | Fm-3m | 4.085 [29] / 4.149 TW","rationale":"Printed table context for this group supplies phase, pearson_symbol, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[7,8],"table":"1","table_key":"t144"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"601c9132ac6ddf90707697f49d5b7b93d6501b0cc3ad3d66e9d75526111f4b07","page":5,"pdf_sha256_prefix":"152dffd3ba088bc9","seen":"merged cells span both Ag rows; records carry composition {NA0,SI0} (Ag not encoded)","verdict":"confirmed"}},{"after":"AG","before":"AG-NA-SI","evidence":{"basis":"phase_formula","overall_composition":{"NA":0.0,"SI":0.0},"phases":["Ag"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-B76QT27NQU","locator":{"ref":"sha256:152dffd3ba088bc9/p5/tab-1","row":7},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{},"overall_composition_basis":"from_formula","overall_composition_stored":{"NA":0.0,"SI":0.0},"paper":"doi:10.2298/jmmb120113024h","paper_id":"doi:10.2298/jmmb120113024h","phases":[{"label":"Ag","label_source":"printed_source_page","pearson_symbol":"cF4","structure_basis":"printed_source_page"}],"pid":"sha256:152dffd3ba088bc9/p5/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-NA-SI","structure":{"pearson_symbol":"cF4","phase":"Ag","space_group":"Fm-3m"},"system":"AG","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008987,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008987},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.085,"value_stored":4.085},{"chemical_system":"AG","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":[{"label":"Ag","label_source":"printed_source_page","pearson_symbol":"cF4","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_08","doi":"10.2298/jmmb120113024h","pdf_page":5,"pdf_sha256":"152dffd3ba088bc9e5bd86fb8389755335de9306f4fbcd7d7998ed269cfd66f9","printed":"Ag | cF4 | Fm-3m | 4.085 [29] / 4.149 TW","rationale":"Printed table context for this group supplies phase, pearson_symbol, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[7,8],"table":"1","table_key":"t144"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"601c9132ac6ddf90707697f49d5b7b93d6501b0cc3ad3d66e9d75526111f4b07","page":5,"pdf_sha256_prefix":"152dffd3ba088bc9","seen":"merged cells span both Ag rows; records carry composition {NA0,SI0} (Ag not encoded)","verdict":"confirmed"}},{"after":{"pearson_symbol":"cF4","phase":"Ag","space_group":"Fm-3m"},"before":null,"evidence":{"batch":"table_context_batch_08","doi":"10.2298/jmmb120113024h","pdf_page":5,"pdf_sha256":"152dffd3ba088bc9e5bd86fb8389755335de9306f4fbcd7d7998ed269cfd66f9","printed":"Ag | cF4 | Fm-3m | 4.085 [29] / 4.149 TW","rationale":"Printed table context for this group supplies phase, pearson_symbol, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[7,8],"table":"1","table_key":"t144"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 08","image_sha256":"601c9132ac6ddf90707697f49d5b7b93d6501b0cc3ad3d66e9d75526111f4b07","page":5,"pdf_sha256_prefix":"152dffd3ba088bc9","seen":"merged cells span both Ag rows; records carry composition {NA0,SI0} (Ag not encoded)","verdict":"confirmed"}},{"after":"AG","before":"AG-NA-SI","evidence":{"basis":"phase_formula","overall_composition":{"NA":0.0,"SI":0.0},"phases":["Ag"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-JUS2FDGFF3","locator":{"ref":"sha256:152dffd3ba088bc9/p5/tab-1","row":8},"method":"first-principles calculation","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.2298/jmmb120113024h","own_work_of_paper":true},"overall_composition":{},"overall_composition_basis":"from_formula","overall_composition_stored":{"NA":0.0,"SI":0.0},"paper":"doi:10.2298/jmmb120113024h","paper_id":"doi:10.2298/jmmb120113024h","phases":[{"label":"Ag","label_source":"printed_source_page","pearson_symbol":"cF4","structure_basis":"printed_source_page"}],"pid":"sha256:152dffd3ba088bc9/p5/tab-1/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-NA-SI","structure":{"pearson_symbol":"cF4","phase":"Ag","space_group":"Fm-3m"},"system":"AG","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04149,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04149},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.149,"value_stored":4.149},{"chemical_system":"AG","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":298.15,"before":298.0,"evidence":{"printed":"298 K"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"},{"after":"AG","before":"AG-DY-ER","evidence":{"basis":"phase_formula","overall_composition":{"DY":0.0,"ER":0.0},"phases":["Ag"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":{"pearson_symbol":"cF4","phase":"Ag","prototype":"Cu","space_group":"Fm-3m"},"before":null,"evidence":{"batch":"table_context_batch_04","doi":"10.1016/j.jallcom.2009.09.036","pdf_page":3,"pdf_sha256":"6016e175ce77feba1b15386897f50990d5dc73c60019c0420be9287259c55ca0","printed":"Ag | cF4 | Fm-3m | Cu (Phase | Person symbol | Space group | Prototype, printed on the group's first line)","rationale":"Printed table context for this group supplies pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":null,"table":"1","table_key":"t071"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 04","image_sha256":"964ce105253109e6b38505f46d4d330d7a4c0f4e760a9c5f0151d91d1a16d4b6","page":3,"pdf_sha256_prefix":"6016e175ce77feba","seen":"Ag group: lattice lines for This work and refs; extraction rows [22, 23, 24]; ends at next Phase entry","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-HTZ3J7KHVO","locator":{"ref":"sha256:6016e175ce77feba/p3/tab-1","row":22},"method":"first-principles (VASP PAW-GGA)","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.jallcom.2009.09.036","own_work_of_paper":true},"overall_composition":{},"overall_composition_basis":"from_formula","overall_composition_stored":{"DY":0.0,"ER":0.0},"paper":"doi:10.1016/j.jallcom.2009.09.036","paper_id":"doi:10.1016/j.jallcom.2009.09.036","phases":[{"label":"Ag"}],"pid":"sha256:6016e175ce77feba/p3/tab-1/r22#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"AG-DY-ER","structure":{"pearson_symbol":"cF4","phase":"Ag","prototype":"Cu","space_group":"Fm-3m"},"system":"AG","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_basis":"printed","temperature_printed":"298 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.2077},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04154,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04154},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":4.154,"value_printed":4.154,"value_stored":4.154},{"chemical_system":"AG","cited_sources":[{"doi":"10.1016/j.calphad.2004.05.002","first_author":"Wang","kind":"assessment","label":"29","paper":"doi:10.1016/j.calphad.2004.05.002","reference":"Y. Wang, S. Curtarolo, C. Jiang, R. Arroyave, T. Wang, G. Ceder, L.Q. Chen, Z.K. Liu, CALPHAD 28 (2004) 79–90.","status":"resolved","year":"2004"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AG","before":"AG-DY-ER","evidence":{"basis":"phase_formula","overall_composition":{"DY":0.0,"ER":0.0},"phases":["Ag"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":{"pearson_symbol":"cF4","phase":"Ag","prototype":"Cu","space_group":"Fm-3m"},"before":null,"evidence":{"batch":"table_context_batch_04","doi":"10.1016/j.jallcom.2009.09.036","pdf_page":3,"pdf_sha256":"6016e175ce77feba1b15386897f50990d5dc73c60019c0420be9287259c55ca0","printed":"Ag | cF4 | Fm-3m | Cu (Phase | Person symbol | Space group | Prototype, printed on the group's first line)","rationale":"Printed table context for this group supplies pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":null,"table":"1","table_key":"t071"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 04","image_sha256":"964ce105253109e6b38505f46d4d330d7a4c0f4e760a9c5f0151d91d1a16d4b6","page":3,"pdf_sha256_prefix":"6016e175ce77feba","seen":"Ag group: lattice lines for This work and refs; extraction rows [22, 23, 24]; ends at next Phase entry","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-PNP62ZBLT2","locator":{"ref":"sha256:6016e175ce77feba/p3/tab-1","row":23},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"caption_names_calculation_only","class":"model_value","own_work_of_paper":false},"overall_composition":{},"overall_composition_basis":"from_formula","overall_composition_stored":{"DY":0.0,"ER":0.0},"paper":"doi:10.1016/j.jallcom.2009.09.036","paper_id":"doi:10.1016/j.jallcom.2009.09.036","phases":[{"label":"Ag"}],"pid":"sha256:6016e175ce77feba/p3/tab-1/r23#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"AG-DY-ER","structure":{"pearson_symbol":"cF4","phase":"Ag","prototype":"Cu","space_group":"Fm-3m"},"system":"AG","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.20775},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03199,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.03199},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":4.155,"value_printed":4.155,"value_stored":4.155},{"chemical_system":"AG","cited_sources":[{"first_author":"Straumanis","kind":"assessment","label":"30","reference":"M.E. Straumanis, S.M. Riad, Trans. Metall. Soc. AIME 233 (1965) 964–967.","status":"resolved","year":"1965"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AG","before":"AG-DY-ER","evidence":{"basis":"phase_formula","overall_composition":{"DY":0.0,"ER":0.0},"phases":["Ag"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":{"pearson_symbol":"cF4","phase":"Ag","prototype":"Cu","space_group":"Fm-3m"},"before":null,"evidence":{"batch":"table_context_batch_04","doi":"10.1016/j.jallcom.2009.09.036","pdf_page":3,"pdf_sha256":"6016e175ce77feba1b15386897f50990d5dc73c60019c0420be9287259c55ca0","printed":"Ag | cF4 | Fm-3m | Cu (Phase | Person symbol | Space group | Prototype, printed on the group's first line)","rationale":"Printed table context for this group supplies pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":null,"table":"1","table_key":"t071"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 04","image_sha256":"964ce105253109e6b38505f46d4d330d7a4c0f4e760a9c5f0151d91d1a16d4b6","page":3,"pdf_sha256_prefix":"6016e175ce77feba","seen":"Ag group: lattice lines for This work and refs; extraction rows [22, 23, 24]; ends at next Phase entry","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-WYRMRAX6IY","locator":{"ref":"sha256:6016e175ce77feba/p3/tab-1","row":24},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"caption_names_calculation_only","class":"model_value","own_work_of_paper":false},"overall_composition":{},"overall_composition_basis":"from_formula","overall_composition_stored":{"DY":0.0,"ER":0.0},"paper":"doi:10.1016/j.jallcom.2009.09.036","paper_id":"doi:10.1016/j.jallcom.2009.09.036","phases":[{"label":"Ag"}],"pid":"sha256:6016e175ce77feba/p3/tab-1/r24#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","source_system":"AG-DY-ER","structure":{"pearson_symbol":"cF4","phase":"Ag","prototype":"Cu","space_group":"Fm-3m"},"system":"AG","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.2043},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03146,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.03146},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":4.086,"value_printed":4.086,"value_stored":4.086},{"chemical_system":"AG","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AG","before":"AG-BI","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["Ag"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":{"AG":1.0},"before":null,"evidence":{"class":"composition","decision_file":"composition_t065.json","doi":"10.1007/bf02671975","pdf_page":4,"pdf_sha256":"614bc096ebddac3a58a01a705880b7971f3a2db6846597ff3ac986324f71380a","printed":"Ag | 0 | 0.40861 [King1]; 0 | 0.40782 [40Chi]; 0 | 0.40857 [Massalski2]","rationale":"Pure Ag (0 at.% Bi printed); unary convention {X:1.0} as used by the majority of unary records in the release.","report_id":"ORCHID-TD-20261028-v1","table":"2","table_key":"t065"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"80ff3b4eb2114e2f331d569c9940186058b05628bb134fe32223e0167f9fbecd","page":4,"pdf_sha256_prefix":"614bc096ebddac3a","seen":"first three Ag rows, composition 0 at.% Bi","verdict":"confirmed"}},{"after":"from_formula","before":null,"evidence":{"class":"composition","decision_file":"composition_t065.json","doi":"10.1007/bf02671975","pdf_page":4,"pdf_sha256":"614bc096ebddac3a58a01a705880b7971f3a2db6846597ff3ac986324f71380a","printed":"Ag | 0 | 0.40861 [King1]; 0 | 0.40782 [40Chi]; 0 | 0.40857 [Massalski2]","rationale":"Pure Ag (0 at.% Bi printed); unary convention {X:1.0} as used by the majority of unary records in the release.","report_id":"ORCHID-TD-20261028-v1","table":"2","table_key":"t065"},"field":"overall_composition_basis","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"80ff3b4eb2114e2f331d569c9940186058b05628bb134fe32223e0167f9fbecd","page":4,"pdf_sha256_prefix":"614bc096ebddac3a","seen":"first three Ag rows, composition 0 at.% Bi","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-ND4LVX627P","locator":{"ref":"sha256:614bc096ebddac3a/p4/tab-2","row":1},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02671975","own_work_of_paper":true},"overall_composition":{"AG":1.0},"overall_composition_basis":"from_formula","paper":"doi:10.1007/bf02671975","paper_id":"doi:10.1007/bf02671975","phase_compositions":[{"basis":"mole_fraction","composition":{"AG":1.0},"composition_source":"printed","composition_stored":{"AG":1.0,"BI":0.0},"phase":"Ag"}],"phases":[{"label":"Ag"}],"pid":"sha256:614bc096ebddac3a/p4/tab-2/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-BI","system":"AG","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008989,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008989},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.0861,"value_stored":0.40861},{"chemical_system":"AG","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AG","before":"AG-BI","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["Ag"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":{"AG":1.0},"before":null,"evidence":{"class":"composition","decision_file":"composition_t065.json","doi":"10.1007/bf02671975","pdf_page":4,"pdf_sha256":"614bc096ebddac3a58a01a705880b7971f3a2db6846597ff3ac986324f71380a","printed":"Ag | 0 | 0.40861 [King1]; 0 | 0.40782 [40Chi]; 0 | 0.40857 [Massalski2]","rationale":"Pure Ag (0 at.% Bi printed); unary convention {X:1.0} as used by the majority of unary records in the release.","report_id":"ORCHID-TD-20261028-v1","table":"2","table_key":"t065"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"80ff3b4eb2114e2f331d569c9940186058b05628bb134fe32223e0167f9fbecd","page":4,"pdf_sha256_prefix":"614bc096ebddac3a","seen":"first three Ag rows, composition 0 at.% Bi","verdict":"confirmed"}},{"after":"from_formula","before":null,"evidence":{"class":"composition","decision_file":"composition_t065.json","doi":"10.1007/bf02671975","pdf_page":4,"pdf_sha256":"614bc096ebddac3a58a01a705880b7971f3a2db6846597ff3ac986324f71380a","printed":"Ag | 0 | 0.40861 [King1]; 0 | 0.40782 [40Chi]; 0 | 0.40857 [Massalski2]","rationale":"Pure Ag (0 at.% Bi printed); unary convention {X:1.0} as used by the majority of unary records in the release.","report_id":"ORCHID-TD-20261028-v1","table":"2","table_key":"t065"},"field":"overall_composition_basis","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"80ff3b4eb2114e2f331d569c9940186058b05628bb134fe32223e0167f9fbecd","page":4,"pdf_sha256_prefix":"614bc096ebddac3a","seen":"first three Ag rows, composition 0 at.% Bi","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-CVEBKSJBEX","locator":{"ref":"sha256:614bc096ebddac3a/p4/tab-2","row":2},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02671975","own_work_of_paper":true},"overall_composition":{"AG":1.0},"overall_composition_basis":"from_formula","paper":"doi:10.1007/bf02671975","paper_id":"doi:10.1007/bf02671975","phase_compositions":[{"basis":"mole_fraction","composition":{"AG":1.0},"composition_source":"printed","composition_stored":{"AG":1.0,"BI":0.0},"phase":"Ag"}],"phases":[{"label":"Ag"}],"pid":"sha256:614bc096ebddac3a/p4/tab-2/r02#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-BI","system":"AG","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008972,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008972},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.0782,"value_stored":0.40782},{"chemical_system":"AG","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AG","before":"AG-BI","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["Ag"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":{"AG":1.0},"before":null,"evidence":{"class":"composition","decision_file":"composition_t065.json","doi":"10.1007/bf02671975","pdf_page":4,"pdf_sha256":"614bc096ebddac3a58a01a705880b7971f3a2db6846597ff3ac986324f71380a","printed":"Ag | 0 | 0.40861 [King1]; 0 | 0.40782 [40Chi]; 0 | 0.40857 [Massalski2]","rationale":"Pure Ag (0 at.% Bi printed); unary convention {X:1.0} as used by the majority of unary records in the release.","report_id":"ORCHID-TD-20261028-v1","table":"2","table_key":"t065"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"80ff3b4eb2114e2f331d569c9940186058b05628bb134fe32223e0167f9fbecd","page":4,"pdf_sha256_prefix":"614bc096ebddac3a","seen":"first three Ag rows, composition 0 at.% Bi","verdict":"confirmed"}},{"after":"from_formula","before":null,"evidence":{"class":"composition","decision_file":"composition_t065.json","doi":"10.1007/bf02671975","pdf_page":4,"pdf_sha256":"614bc096ebddac3a58a01a705880b7971f3a2db6846597ff3ac986324f71380a","printed":"Ag | 0 | 0.40861 [King1]; 0 | 0.40782 [40Chi]; 0 | 0.40857 [Massalski2]","rationale":"Pure Ag (0 at.% Bi printed); unary convention {X:1.0} as used by the majority of unary records in the release.","report_id":"ORCHID-TD-20261028-v1","table":"2","table_key":"t065"},"field":"overall_composition_basis","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"80ff3b4eb2114e2f331d569c9940186058b05628bb134fe32223e0167f9fbecd","page":4,"pdf_sha256_prefix":"614bc096ebddac3a","seen":"first three Ag rows, composition 0 at.% Bi","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"from_evaluation_paper":true,"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-MG75L7CKXK","locator":{"ref":"sha256:614bc096ebddac3a/p4/tab-2","row":3},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02671975","own_work_of_paper":true},"overall_composition":{"AG":1.0},"overall_composition_basis":"from_formula","paper":"doi:10.1007/bf02671975","paper_id":"doi:10.1007/bf02671975","phase_compositions":[{"basis":"mole_fraction","composition":{"AG":1.0},"composition_source":"printed","composition_stored":{"AG":1.0,"BI":0.0},"phase":"Ag"}],"phases":[{"label":"Ag"}],"pid":"sha256:614bc096ebddac3a/p4/tab-2/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AG-BI","system":"AG","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.008989,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.008989},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.0857,"value_stored":0.40857}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"AG"}