{"artifacts":{"doi:10.1016/0364-5916(92)90009-m/p3/text-03":{"artifact":"text_passage","label":"page 3, passage 3","page":3},"doi:10.1016/j.jnucmat.2017.11.037/p2/text-03":{"artifact":"text_passage","label":"page 2, passage 3","page":2},"doi:10.1016/s0364-5916(01)00004-9/p6/text-05":{"artifact":"text_passage","label":"page 6, passage 5","page":6},"sha256:ea4a93d4322c86c9/p3/tab-1":{"artifact":"table","caption":"Reported crystallographic and stability data of the unary and binary phases encountered in the U-Al-Ga ternary system.","label":"1","page":3}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["AL","GA"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/0364-5916(92)90009-m":{"authors":["A. Watson"],"citation":"A. Watson, Re-assessment of phase diagram and thermodynamic properties of the Al-Ga system, Calphad 16, 207-217 (1992).","container":"Calphad","doi":"10.1016/0364-5916(92)90009-m","doi_url":"https://doi.org/10.1016/0364-5916(92)90009-m","id":"doi:10.1016/0364-5916(92)90009-m","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"7046ac97ce0eb162","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Re-assessment of phase diagram and thermodynamic properties of the Al-Ga system","year":1992},"doi:10.1016/j.jnucmat.2017.11.037":{"authors":["Chantal Moussa","Alexandre Berche","José Barbosa","Mathieu Pasturel","Bertrand Stepnik","Olivier Tougait"],"citation":"Chantal Moussa, Alexandre Berche, José Barbosa, Mathieu Pasturel, Bertrand Stepnik, Olivier Tougait, Experimental investigation of the phase equilibria and thermodynamic assessment in the U-Ga and U-Al-Ga systems, Journal of Nuclear Materials 499, 361-371 (2018).","container":"Journal of Nuclear Materials","doi":"10.1016/j.jnucmat.2017.11.037","doi_url":"https://doi.org/10.1016/j.jnucmat.2017.11.037","id":"doi:10.1016/j.jnucmat.2017.11.037","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"ea4a93d4322c86c9","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Experimental investigation of the phase equilibria and thermodynamic assessment in the U-Ga and U-Al-Ga systems","year":2018},"doi:10.1016/s0364-5916(01)00004-9":{"authors":["M. Mathon","K. Jardet","E. Aragon","P. Satre","A. Sebaoun"],"citation":"M. Mathon, K. Jardet, E. Aragon, P. Satre, A. Sebaoun, Al-Ga-Zn System: Reassessments of the Three Binary Systems and Discussion on Possible Estimations and on Optimisation of the Ternary System, Calphad 24, 253-284 (2000).","container":"Calphad","doi":"10.1016/s0364-5916(01)00004-9","doi_url":"https://doi.org/10.1016/s0364-5916(01)00004-9","id":"doi:10.1016/s0364-5916(01)00004-9","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"c46c88913192a2ac","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Al-Ga-Zn System: Reassessments of the Three Binary Systems and Discussion on Possible Estimations and on Optimisation of the Ternary System","year":2000}},"part":1,"parts":1,"records":[{"chemical_system":"AL-GA","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"7","reference":"T.B. Massalski, H. Okamoto, P.R. Subramanian, L. Kacprzak, Binary Alloy Phase Diagrams, second ed., vols. 1e3, ASM International, 1990.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":null,"before":933.0,"evidence":{"printed":null},"field":"temperature_K","gate":"page","rule":"stability_range_not_lattice_measurement_temperature","visual_check":{"checked":"2026-10-25","image_sha256":"336199237adedb4ec549c372a6eb0b2cf285df39a87613f0e7458661232a9c87","page":3,"pdf_sha256_prefix":"ea4a93d4322c86c9","seen":"Table 1 separates lattice parameters from Stability range (K); the compiled lattice measurements have no single stated measurement temperature.","verdict":"corrected"}},{"after":"page_checked_phase_stability_not_measurement","before":"printed_bound","evidence":{"printed":null},"field":"temperature_basis","gate":"page","rule":"stability_range_not_lattice_measurement_temperature","visual_check":{"checked":"2026-10-25","image_sha256":"336199237adedb4ec549c372a6eb0b2cf285df39a87613f0e7458661232a9c87","page":3,"pdf_sha256_prefix":"ea4a93d4322c86c9","seen":"Table 1 separates lattice parameters from Stability range (K); the compiled lattice measurements have no single stated measurement temperature.","verdict":"corrected"}},{"after":"AL-GA","before":"AL-GA-U","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["Al"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["measurement_temperature_not_stated"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"measurement_temperature_not_stated","detail":"Table 1 separates lattice parameters from Stability range (K); the compiled lattice measurements have no single stated measurement temperature.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-25","image_sha256":"336199237adedb4ec549c372a6eb0b2cf285df39a87613f0e7458661232a9c87","page":3,"pdf_sha256_prefix":"ea4a93d4322c86c9","seen":"Table 1 separates lattice parameters from Stability range (K); the compiled lattice measurements have no single stated measurement temperature.","verdict":"confirmed"}}],"id":"ORC-7XIFBP6AVB.2051ef","locator":{"ref":"sha256:ea4a93d4322c86c9/p3/tab-1","row":4},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.11.037","paper_id":"doi:10.1016/j.jnucmat.2017.11.037","phase_compositions":[{"basis":"mole_fraction","composition":{"GA":0.01},"composition_source":"printed","phase":"Al"}],"phases":[{"label":"Al"}],"pid":"sha256:ea4a93d4322c86c9/p3/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-GA-U","structure":{"prototype":"Cu","strukturbericht":"Fm3̄m"},"system":"AL-GA","temperature_K":null,"temperature_K_stored":933.0,"temperature_basis":"page_checked_phase_stability_not_measurement","temperature_basis_stored":"printed_bound","temperature_bound":{"op":"<","printed":"<933","value_K":933.0},"temperature_printed":"<933","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03112,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.03112},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.041,"value_stored":4.041},{"chemical_system":"AL-GA","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"7","reference":"T.B. Massalski, H. Okamoto, P.R. Subramanian, L. Kacprzak, Binary Alloy Phase Diagrams, second ed., vols. 1e3, ASM International, 1990.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":null,"before":933.0,"evidence":{"printed":null},"field":"temperature_K","gate":"page","rule":"stability_range_not_lattice_measurement_temperature","visual_check":{"checked":"2026-10-25","image_sha256":"336199237adedb4ec549c372a6eb0b2cf285df39a87613f0e7458661232a9c87","page":3,"pdf_sha256_prefix":"ea4a93d4322c86c9","seen":"Table 1 separates lattice parameters from Stability range (K); the compiled lattice measurements have no single stated measurement temperature.","verdict":"corrected"}},{"after":"page_checked_phase_stability_not_measurement","before":"printed_bound","evidence":{"printed":null},"field":"temperature_basis","gate":"page","rule":"stability_range_not_lattice_measurement_temperature","visual_check":{"checked":"2026-10-25","image_sha256":"336199237adedb4ec549c372a6eb0b2cf285df39a87613f0e7458661232a9c87","page":3,"pdf_sha256_prefix":"ea4a93d4322c86c9","seen":"Table 1 separates lattice parameters from Stability range (K); the compiled lattice measurements have no single stated measurement temperature.","verdict":"corrected"}},{"after":"AL-GA","before":"AL-GA-U","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["Al"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["measurement_temperature_not_stated"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"measurement_temperature_not_stated","detail":"Table 1 separates lattice parameters from Stability range (K); the compiled lattice measurements have no single stated measurement temperature.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-25","image_sha256":"336199237adedb4ec549c372a6eb0b2cf285df39a87613f0e7458661232a9c87","page":3,"pdf_sha256_prefix":"ea4a93d4322c86c9","seen":"Table 1 separates lattice parameters from Stability range (K); the compiled lattice measurements have no single stated measurement temperature.","verdict":"confirmed"}}],"id":"ORC-7XIFBP6AVB.61adca","locator":{"ref":"sha256:ea4a93d4322c86c9/p3/tab-1","row":4},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.11.037","paper_id":"doi:10.1016/j.jnucmat.2017.11.037","phase_compositions":[{"basis":"mole_fraction","composition":{"GA":0.01},"composition_source":"printed","phase":"Al"}],"phases":[{"label":"Al"}],"pid":"sha256:ea4a93d4322c86c9/p3/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-GA-U","structure":{"prototype":"Cu","strukturbericht":"Fm3̄m"},"system":"AL-GA","temperature_K":null,"temperature_K_stored":933.0,"temperature_basis":"page_checked_phase_stability_not_measurement","temperature_basis_stored":"printed_bound","temperature_bound":{"op":"<","printed":"<933","value_K":933.0},"temperature_printed":"<933","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03112,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.03112},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.041,"value_stored":4.041},{"chemical_system":"AL-GA","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"7","reference":"T.B. Massalski, H. Okamoto, P.R. Subramanian, L. Kacprzak, Binary Alloy Phase Diagrams, second ed., vols. 1e3, ASM International, 1990.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":null,"before":933.0,"evidence":{"printed":null},"field":"temperature_K","gate":"page","rule":"stability_range_not_lattice_measurement_temperature","visual_check":{"checked":"2026-10-25","image_sha256":"336199237adedb4ec549c372a6eb0b2cf285df39a87613f0e7458661232a9c87","page":3,"pdf_sha256_prefix":"ea4a93d4322c86c9","seen":"Table 1 separates lattice parameters from Stability range (K); the compiled lattice measurements have no single stated measurement temperature.","verdict":"corrected"}},{"after":"page_checked_phase_stability_not_measurement","before":"printed_bound","evidence":{"printed":null},"field":"temperature_basis","gate":"page","rule":"stability_range_not_lattice_measurement_temperature","visual_check":{"checked":"2026-10-25","image_sha256":"336199237adedb4ec549c372a6eb0b2cf285df39a87613f0e7458661232a9c87","page":3,"pdf_sha256_prefix":"ea4a93d4322c86c9","seen":"Table 1 separates lattice parameters from Stability range (K); the compiled lattice measurements have no single stated measurement temperature.","verdict":"corrected"}},{"after":"AL-GA","before":"AL-GA-U","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["Al"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["measurement_temperature_not_stated"],"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"measurement_temperature_not_stated","detail":"Table 1 separates lattice parameters from Stability range (K); the compiled lattice measurements have no single stated measurement temperature.","effect":"not_espei_ready","gate":"page","visual_check":{"checked":"2026-10-25","image_sha256":"336199237adedb4ec549c372a6eb0b2cf285df39a87613f0e7458661232a9c87","page":3,"pdf_sha256_prefix":"ea4a93d4322c86c9","seen":"Table 1 separates lattice parameters from Stability range (K); the compiled lattice measurements have no single stated measurement temperature.","verdict":"confirmed"}}],"id":"ORC-7XIFBP6AVB.e4fe4e","locator":{"ref":"sha256:ea4a93d4322c86c9/p3/tab-1","row":4},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.11.037","paper_id":"doi:10.1016/j.jnucmat.2017.11.037","phase_compositions":[{"basis":"mole_fraction","composition":{"GA":0.01},"composition_source":"printed","phase":"Al"}],"phases":[{"label":"Al"}],"pid":"sha256:ea4a93d4322c86c9/p3/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-GA-U","structure":{"prototype":"Cu","strukturbericht":"Fm3̄m"},"system":"AL-GA","temperature_K":null,"temperature_K_stored":933.0,"temperature_basis":"page_checked_phase_stability_not_measurement","temperature_basis_stored":"printed_bound","temperature_bound":{"op":"<","printed":"<933","value_K":933.0},"temperature_printed":"<933","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03112,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.03112},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.041,"value_stored":4.041},{"chemical_system":"AL-GA","citations_printed":["5","6","7","8","9","11","12","13"],"cited_sources":[{"kind":"unknown","label":"5","status":"unresolved"},{"kind":"unknown","label":"6","status":"unresolved"},{"kind":"unknown","label":"7","status":"unresolved"},{"kind":"unknown","label":"8","status":"unresolved"},{"kind":"unknown","label":"9","status":"unresolved"},{"kind":"unknown","label":"11","status":"unresolved"},{"kind":"unknown","label":"12","status":"unresolved"},{"kind":"unknown","label":"13","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-6TXQW2E3T6","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/0364-5916(92)90009-m/p3/text-03"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/0364-5916(92)90009-m","paper_id":"doi:10.1016/0364-5916(92)90009-m","pid":"doi:10.1016/0364-5916(92)90009-m/p3/text-03/s20#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The experimental determinations of the eutectic point 5-9 11-13 at around 300 K and at a gallium content of approxtmately 97 at% are in very close agreement wtt *b* each otbcr.","quote_page":3,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-GA","system":"AL-GA","temperature_K":300.0,"temperature_printed":"300 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":300.0},{"chemical_system":"AL-GA","citations_printed":["7"],"cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"7","reference":"T.B. Massalski, H. Okamoto, P.R. Subramanian, L. Kacprzak, Binary Alloy Phase Diagrams, second ed., vols. 1e3, ASM International, 1990.","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-IAFJ2YE5TL","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jnucmat.2017.11.037/p2/text-03"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.11.037","paper_id":"doi:10.1016/j.jnucmat.2017.11.037","pid":"doi:10.1016/j.jnucmat.2017.11.037/p2/text-03/s18#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"It is characterized by a rather limited solubility of Ga into solid Al to a maximum of about 9 at.% and an eutectic reaction at 303 K.","quote_page":2,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-GA","system":"AL-GA","temperature_K":303.0,"temperature_printed":"303 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":303.0},{"chemical_system":"AL-GA","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1016/s0364-5916(01)00004-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":0,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-O6G26UJICD.1424f2","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/s0364-5916(01)00004-9/p6/text-05"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1016/s0364-5916(01)00004-9","own_work_of_paper":true},"paper":"doi:10.1016/s0364-5916(01)00004-9","paper_id":"doi:10.1016/s0364-5916(01)00004-9","pid":"doi:10.1016/s0364-5916(01)00004-9/p6/text-05/s13#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The melting temperature of Ga at 303 K and the Al-Ga binary eutectic at 298.5 K and the Ga-Zn eutectic at 297.3 K, lead to the appearance of two-phases and three-phases fields.","quote_page":6,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-GA","system":"AL-GA","temperature_K":298.5,"temperature_printed":"298.5 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":298.5}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"AL-GA"}