{"artifacts":{"doi:10.1007/s11669-020-00827-z/p4/text-02":{"artifact":"text_passage","label":"page 4, passage 2","page":4},"doi:10.1007/s11669-020-00827-z/p5/tab-3":{"artifact":"table","caption":"Invariant reactions as compared to literature information in Al-Li binary system","label":"3","page":5},"doi:10.1016/j.calphad.2010.11.006/p10/text-27":{"artifact":"text_passage","label":"page 10, passage 27","page":10},"doi:10.1016/j.calphad.2011.09.003/p3/tab-1":{"artifact":"table","caption":"Crystallographic data for the solid phases in the Al–Li–Mg system [17–19].","label":"1","page":3},"doi:10.1016/j.calphad.2011.09.003/p7/text-08":{"artifact":"text_passage","label":"page 7, passage 8","page":7},"sha256:85fd53a1a176b694/p58/tab-i":{"artifact":"table","caption":" Invariant Reactions.","label":"I","page":58},"sha256:8ee5c169b908262e/p2/tab-1":{"artifact":"table","caption":"Crystallographic data of the phases in the Al-Zr, [28–33] Al-Li [9,53,57,58] and Al-Li-Zr [10] system","label":"1","page":2},"sha256:8ee5c169b908262e/p7/tab-4":{"artifact":"table","caption":"Enthalpies of formation of the stable Al-Zr and Al-Li system (kJ/mol)","label":"4","page":7}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n author = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n title = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n version = {2026.10},\n publisher = {Zenodo},\n year = {2026},\n doi = {10.5281/zenodo.23735569},\n url = {https://doi.org/10.5281/zenodo.23735569},\n note = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n author = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n title = {{ORCHID data: umbrella record of the ORCHID datasets}},\n version = {2026.10},\n publisher = {Zenodo},\n year = {2026},\n doi = {10.5281/zenodo.23736065},\n url = {https://doi.org/10.5281/zenodo.23736065},\n note = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["AL","LI"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"Mb4ef1200":{"catalog_entry":{"license":"CC BY 4.0","name":"AlLi-20Lon.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"J. Phase Equilib. Diffus., 41, 623-41(2020).","model_doi":"10.1007/s11669-020-00827-z","reproduced_by_calculation":true,"tdb":"AlLi-20Lon.tdb","tdb_path":"databases/sgte-binary/AlLi-20Lon.tdb","tdb_sha256":"936c9bbf5ba6a80591c009adb7f6d302de6cc8d07a2f57b2f26edc3efe340e7e"},"Mca4c82bc":{"catalog_entry":{"license":"CC BY 4.0","name":"AlLi-20Lon.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"J. Phase Equilib. Diffus., 41, 623-41(2020).","model_doi":"10.1007/s11669-020-00827-z","reproduced_by_calculation":false,"tdb":"AlLi-20Lon.tdb","tdb_path":"databases/sgte-binary/AlLi-20Lon.tdb","tdb_sha256":"936c9bbf5ba6a80591c009adb7f6d302de6cc8d07a2f57b2f26edc3efe340e7e"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/bf02647619":{"authors":["R. J. Pulham","P. Hubberstey","P. Hemptenmacher"],"citation":"R. J. Pulham, P. Hubberstey, P. Hemptenmacher, Solutions of aluminum in liquid lithium: contribution to the Li-Al phase diagram, JPE 15, 587-590 (1994).","container":"JPE","doi":"10.1007/bf02647619","doi_url":"https://doi.org/10.1007/bf02647619","id":"doi:10.1007/bf02647619","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Solutions of aluminum in liquid lithium: contribution to the Li-Al phase diagram","year":1994},"doi:10.1007/bf02892377":{"citation":"A.J. McAlister, Bull. Alloy Phase Diagrams 3 (1982) 177–183.","doi":"10.1007/bf02892377","doi_url":"https://doi.org/10.1007/bf02892377","id":"doi:10.1007/bf02892377","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"]},"doi:10.1007/s11669-020-00827-z":{"authors":["Zhaohui Long","Dongyu Cui","Hongxing Hu","Zhi Li","Fucheng Yin","Touwen Fan"],"citation":"Zhaohui Long, Dongyu Cui, Hongxing Hu, Zhi Li, Fucheng Yin, Touwen Fan, Thermodynamic Modeling of the Al-Li-Zr Ternary System, J. Phase Equilib. Diffus. 41, 623-641 (2020).","container":"J. Phase Equilib. Diffus.","doi":"10.1007/s11669-020-00827-z","doi_url":"https://doi.org/10.1007/s11669-020-00827-z","id":"doi:10.1007/s11669-020-00827-z","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"8ee5c169b908262e","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic Modeling of the Al-Li-Zr Ternary System","year":2020},"doi:10.1016/j.calphad.2010.11.006":{"authors":["Cuiping Guo","Yu Liang","Changrong Li","Zhenmin Du"],"citation":"Cuiping Guo, Yu Liang, Changrong Li, Zhenmin Du, Thermodynamic description of the Al–Li–Zn system, Calphad 35, 54-65 (2011).","container":"Calphad","doi":"10.1016/j.calphad.2010.11.006","doi_url":"https://doi.org/10.1016/j.calphad.2010.11.006","id":"doi:10.1016/j.calphad.2010.11.006","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"ec58ec9506c20051","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic description of the Al–Li–Zn system","year":2011},"doi:10.1016/j.calphad.2011.09.003":{"authors":["Peisheng Wang","Yong Du","Shuhong Liu"],"citation":"Peisheng Wang, Yong Du, Shuhong Liu, Thermodynamic optimization of the Li–Mg and Al–Li–Mg systems, Calphad 35, 523-532 (2011).","container":"Calphad","doi":"10.1016/j.calphad.2011.09.003","doi_url":"https://doi.org/10.1016/j.calphad.2011.09.003","id":"doi:10.1016/j.calphad.2011.09.003","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"68271a4400e98726","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic optimization of the Li–Mg and Al–Li–Mg systems","year":2011},"doi:10.1016/j.jssc.2010.08.029":{"authors":["Kati Puhakainen","Magnus Boström","Thomas L. Groy","Ulrich Häussermann"],"citation":"Kati Puhakainen, Magnus Boström, Thomas L. Groy, Ulrich Häussermann, A new phase in the system lithium–aluminum: Characterization of orthorhombic Li2Al, Journal of Solid State Chemistry 183, 2528-2533 (2010).","container":"Journal of Solid State Chemistry","doi":"10.1016/j.jssc.2010.08.029","doi_url":"https://doi.org/10.1016/j.jssc.2010.08.029","id":"doi:10.1016/j.jssc.2010.08.029","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"A new phase in the system lithium–aluminum: Characterization of orthorhombic Li2Al","year":2010},"doi:10.1088/0953-8984/6/18/015":{"authors":["A Arya","G P Das","H G Salunke","S Banerjee"],"citation":"A Arya, G P Das, H G Salunke, S Banerjee, Cohesive and electronic properties of ordered Li-Al intermetallic compounds, J. Phys.: Condens. Matter 6, 3389-3402 (1994).","container":"J. Phys.: Condens. Matter","doi":"10.1088/0953-8984/6/18/015","doi_url":"https://doi.org/10.1088/0953-8984/6/18/015","id":"doi:10.1088/0953-8984/6/18/015","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Cohesive and electronic properties of ordered Li-Al intermetallic compounds","year":1994},"doi:10.1103/physrevb.32.207":{"authors":["N. E. Christensen"],"citation":"N. E. Christensen, Structural phase stability ofB2andB32intermetallic compounds, Phys. Rev. B 32, 207-228 (1985).","container":"Phys. Rev. B","doi":"10.1103/physrevb.32.207","doi_url":"https://doi.org/10.1103/physrevb.32.207","id":"doi:10.1103/physrevb.32.207","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Structural phase stability ofB2andB32intermetallic compounds","year":1985},"doi:10.1103/physrevb.42.10912":{"authors":["X.-Q. Guo","R. Podloucky","A. J. Freeman"],"citation":"X.-Q. Guo, R. Podloucky, A. J. Freeman, Phase stability and bonding characteristics of Li-rich Al-Li intermetallic compounds:Al2Li3andAl4Li9, Phys. Rev. B 42, 10912-10923 (1990).","container":"Phys. Rev. B","doi":"10.1103/physrevb.42.10912","doi_url":"https://doi.org/10.1103/physrevb.42.10912","id":"doi:10.1103/physrevb.42.10912","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Phase stability and bonding characteristics of Li-rich Al-Li intermetallic compounds:Al2Li3andAl4Li9","year":1990},"doi:10.1103/physrevb.53.6137":{"authors":["Marcel H. F. Sluiter","Y. Watanabe","D. de Fontaine","Y. Kawazoe"],"citation":"Marcel H. F. Sluiter, Y. Watanabe, D. de Fontaine, Y. Kawazoe, First-principles calculation of the pressure dependence of phase equilibria in the Al-Li system, Phys. Rev. B 53, 6137-6151 (1996).","container":"Phys. Rev. B","doi":"10.1103/physrevb.53.6137","doi_url":"https://doi.org/10.1103/physrevb.53.6137","id":"doi:10.1103/physrevb.53.6137","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"First-principles calculation of the pressure dependence of phase equilibria in the Al-Li system","year":1996},"doi:10.1149/1.2408242":{"authors":["N. P. Yao","L. A. Herédy","R. C. Saunders"],"citation":"N. P. Yao, L. A. Herédy, R. C. Saunders, Emf Measurements of Electrochemically Prepared Lithium-Aluminum Alloy, J. Electrochem. Soc. 118, 1039 (1971).","container":"J. Electrochem. Soc.","doi":"10.1149/1.2408242","doi_url":"https://doi.org/10.1149/1.2408242","id":"doi:10.1149/1.2408242","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Emf Measurements of Electrochemically Prepared Lithium-Aluminum Alloy","year":1971},"doi:10.3139/146.101553":{"authors":["Bengt Hallstedt","Olga Kim"],"citation":"Bengt Hallstedt, Olga Kim, Thermodynamic assessment of the Al–Li system, International Journal of Materials Research 98, 961-969 (2007).","container":"International Journal of Materials Research","doi":"10.3139/146.101553","doi_url":"https://doi.org/10.3139/146.101553","id":"doi:10.3139/146.101553","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Thermodynamic assessment of the Al–Li system","year":2007},"ref:1fa019436d752c75":{"citation":"A. Müller, The Al-Li Phase Diagram, Z. Metallkd., 1926, 18, p 231","id":"ref:1fa019436d752c75","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1926},"ref:232ba85e4082a28c":{"citation":"A. Grube, L. Mohr, and W. Breuning, Elektrische Leitfähigkeit und Zustandsdiagramm bei binären Legierungen. 17. Mitteilung. Das System Lithium–Aluminium, Z. Elektrochem., 1935, 41, p 880-883. https://doi.org/10.1002/bbpc.19350411213","id":"ref:232ba85e4082a28c","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1935},"ref:639878ea89f3392b":{"citation":"F.I. Shamray and P.Ya. Saldau, Equilibrium Diagram of the System Al-Li, Izv. Akad. Nauk SSSR, Otd. Khim., 1937, 3, p 631640","id":"ref:639878ea89f3392b","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1937},"ref:c1884defdae4ec20":{"citation":"E. Schürmann and H.J. Voss, Investigation of the Melting Equilibria of Mg-Li-Al Alloys, Giessereiforschung, 1981, 33, p 33","id":"ref:c1884defdae4ec20","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1981},"ref:c9e6d1b0a02f9ff9":{"citation":"K.M. Myles, F.C. Mrazek, J.A. Smaga and J.L. Settle, in Advanced Battery Research and Design, U.S. ERDA Report ANL76-8, Proceedings of Symposium and Workshop, Argonne National Laboratory, B50 (cited from [7]), 1976 J. Phase Equilib. Diffus. (2020) 41:623–641","id":"ref:c9e6d1b0a02f9ff9","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":2020},"sha256:85fd53a1a176b694":{"authors":["I. Ansara (ed.)","A. T. Dinsdale (ed.)","M. H. Rand (ed.)"],"citation":"I. Ansara, A. T. Dinsdale, M. H. Rand (eds.), COST 507: Thermochemical database for light metal alloys, Volume 2, EUR 18499 EN, Office for Official Publications of the European Communities, Luxembourg (1998), ISBN 92-828-3902-8.","container":"EUR 18499 EN","doi_not_used":"10.1016/s0364-5916(98)00037-6","id":"sha256:85fd53a1a176b694","kind":"corpus_paper","metadata_source":"pdf_title_page","pdf_sha256_prefix":"85fd53a1a176b694","roles":["cited_source","reporting_paper"],"source_kinds":["journal_article"],"title":"COST 507: Thermochemical database for light metal alloys, Volume 2","year":1998}},"part":1,"parts":1,"records":[{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1007/bf02892377","first_author":"McAlister","kind":"assessment","label":"18","paper":"doi:10.1007/bf02892377","reference":"A.J. McAlister, Bull. Alloy Phase Diagrams 3 (1982) 177–183.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-MG","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"MG":0.0},"phases":["AlLi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-SUIS5XQTTI","locator":{"ref":"doi:10.1016/j.calphad.2011.09.003/p3/tab-1","row":4},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"MG":0.0},"paper":"doi:10.1016/j.calphad.2011.09.003","paper_id":"doi:10.1016/j.calphad.2011.09.003","phases":[{"label":"AlLi"}],"pid":"doi:10.1016/j.calphad.2011.09.003/p3/tab-1/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-LI-MG","structure":{"pearson_symbol":"cF16","prototype":"NaTl","space_group":"Fd3 m"},"system":"AL-LI","temperature_K":973.15,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","printed":"≤ 700","value_K":973.15},"temperature_printed":"≤ 700","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04905,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.04905},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":6.37,"value_stored":637.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1007/bf02892377","first_author":"McAlister","kind":"assessment","label":"18","paper":"doi:10.1007/bf02892377","reference":"A.J. McAlister, Bull. Alloy Phase Diagrams 3 (1982) 177–183.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-MG","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.6,"MG":0.0},"phases":["Al2Li3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-E5FYDCKCVJ.cec90e","locator":{"ref":"doi:10.1016/j.calphad.2011.09.003/p3/tab-1","row":5},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"LI":0.6},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.6,"MG":0.0},"paper":"doi:10.1016/j.calphad.2011.09.003","paper_id":"doi:10.1016/j.calphad.2011.09.003","phases":[{"label":"Al2Li3"}],"pid":"doi:10.1016/j.calphad.2011.09.003/p3/tab-1/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-LI-MG","structure":{"pearson_symbol":"hR15","prototype":"Bi2Te3","space_group":"Fd3 m"},"system":"AL-LI","temperature_K":793.15,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","printed":"≤ 520","value_K":793.15},"temperature_printed":"≤ 520","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03471,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.03471},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.508,"value_stored":450.8},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1007/bf02892377","first_author":"McAlister","kind":"assessment","label":"18","paper":"doi:10.1007/bf02892377","reference":"A.J. McAlister, Bull. Alloy Phase Diagrams 3 (1982) 177–183.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-MG","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.6,"MG":0.0},"phases":["Al2Li3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-E5FYDCKCVJ.fbe4b7","locator":{"ref":"doi:10.1016/j.calphad.2011.09.003/p3/tab-1","row":5},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"LI":0.6},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.6,"MG":0.0},"paper":"doi:10.1016/j.calphad.2011.09.003","paper_id":"doi:10.1016/j.calphad.2011.09.003","phases":[{"label":"Al2Li3"}],"pid":"doi:10.1016/j.calphad.2011.09.003/p3/tab-1/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-LI-MG","structure":{"pearson_symbol":"hR15","prototype":"Bi2Te3","space_group":"Fd3 m"},"system":"AL-LI","temperature_K":793.15,"temperature_basis":"printed_bound","temperature_bound":{"op":"<","printed":"≤ 520","value_K":793.15},"temperature_printed":"≤ 520","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1098,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.1098},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":14.26,"value_stored":1426.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1007/bf02892377","first_author":"McAlister","kind":"assessment","label":"18","paper":"doi:10.1007/bf02892377","reference":"A.J. McAlister, Bull. Alloy Phase Diagrams 3 (1982) 177–183.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-MG","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.692308,"MG":0.0},"phases":["Al4Li9"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-UE6CGWEO7A.3194e7","locator":{"ref":"doi:10.1016/j.calphad.2011.09.003/p3/tab-1","row":6},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"LI":0.692308},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.692308,"MG":0.0},"paper":"doi:10.1016/j.calphad.2011.09.003","paper_id":"doi:10.1016/j.calphad.2011.09.003","phases":[{"label":"Al4Li9"}],"pid":"doi:10.1016/j.calphad.2011.09.003/p3/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_BETA","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-LI-MG","structure":{"pearson_symbol":"mC26","prototype":"Al4Li9","space_group":"C2/m"},"system":"AL-LI","temperature_K":302.5,"temperature_basis":"printed_range","temperature_range_K":{"max":330.0,"min":275.0},"temperature_uncertainty":{"basis":"printed_range","value":27.5},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/LATTICE_ANGLE","floor":0.1,"floor_unit":"degree","n_pairs":1,"value":0.1},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"°","value_type":"LATTICE_ANGLE"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"°","value":107.67},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1007/bf02892377","first_author":"McAlister","kind":"assessment","label":"18","paper":"doi:10.1007/bf02892377","reference":"A.J. McAlister, Bull. Alloy Phase Diagrams 3 (1982) 177–183.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-MG","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.692308,"MG":0.0},"phases":["Al4Li9"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-UE6CGWEO7A.ad8fcd","locator":{"ref":"doi:10.1016/j.calphad.2011.09.003/p3/tab-1","row":6},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"LI":0.692308},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.692308,"MG":0.0},"paper":"doi:10.1016/j.calphad.2011.09.003","paper_id":"doi:10.1016/j.calphad.2011.09.003","phases":[{"label":"Al4Li9"}],"pid":"doi:10.1016/j.calphad.2011.09.003/p3/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-LI-MG","structure":{"pearson_symbol":"mC26","prototype":"Al4Li9","space_group":"C2/m"},"system":"AL-LI","temperature_K":302.5,"temperature_basis":"printed_range","temperature_range_K":{"max":330.0,"min":275.0},"temperature_uncertainty":{"basis":"printed_range","value":27.5},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0418,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.0418},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":5.4288,"value_stored":542.88},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1007/bf02892377","first_author":"McAlister","kind":"assessment","label":"18","paper":"doi:10.1007/bf02892377","reference":"A.J. McAlister, Bull. Alloy Phase Diagrams 3 (1982) 177–183.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-MG","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.692308,"MG":0.0},"phases":["Al4Li9"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-UE6CGWEO7A.f6eef5","locator":{"ref":"doi:10.1016/j.calphad.2011.09.003/p3/tab-1","row":6},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"LI":0.692308},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.692308,"MG":0.0},"paper":"doi:10.1016/j.calphad.2011.09.003","paper_id":"doi:10.1016/j.calphad.2011.09.003","phases":[{"label":"Al4Li9"}],"pid":"doi:10.1016/j.calphad.2011.09.003/p3/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-LI-MG","structure":{"pearson_symbol":"mC26","prototype":"Al4Li9","space_group":"C2/m"},"system":"AL-LI","temperature_K":302.5,"temperature_basis":"printed_range","temperature_range_K":{"max":330.0,"min":275.0},"temperature_uncertainty":{"basis":"printed_range","value":27.5},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03464,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.03464},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":4.4988,"value_stored":449.88},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1007/bf02892377","first_author":"McAlister","kind":"assessment","label":"18","paper":"doi:10.1007/bf02892377","reference":"A.J. McAlister, Bull. Alloy Phase Diagrams 3 (1982) 177–183.","status":"resolved","year":"1982"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-MG","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.692308,"MG":0.0},"phases":["Al4Li9"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":2,"id":"ORC-UE6CGWEO7A.f9acba","locator":{"ref":"doi:10.1016/j.calphad.2011.09.003/p3/tab-1","row":6},"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"structural_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"LI":0.692308},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.692308,"MG":0.0},"paper":"doi:10.1016/j.calphad.2011.09.003","paper_id":"doi:10.1016/j.calphad.2011.09.003","phases":[{"label":"Al4Li9"}],"pid":"doi:10.1016/j.calphad.2011.09.003/p3/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-LI-MG","structure":{"pearson_symbol":"mC26","prototype":"Al4Li9","space_group":"C2/m"},"system":"AL-LI","temperature_K":302.5,"temperature_basis":"printed_range","temperature_range_K":{"max":330.0,"min":275.0},"temperature_uncertainty":{"basis":"printed_range","value":27.5},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1475,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.1475},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"pm","value":19.1551,"value_stored":1915.51},{"chemical_system":"AL-LI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-TPZBLBWLIB","locator":{"ref":"sha256:8ee5c169b908262e/p2/tab-1","row":14},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi"}],"pid":"sha256:8ee5c169b908262e/p2/tab-1/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-LI-ZR","structure":{"prototype":"NaTi","space_group":"Fd 3̄m","strukturbericht":"cF16"},"system":"AL-LI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01399,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01399},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":6.36,"value_stored":6.36},{"chemical_system":"AL-LI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.6,"ZR":0.0},"phases":["Al2Li3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-QE24O4MH7Z.a1ae91","locator":{"ref":"sha256:8ee5c169b908262e/p2/tab-1","row":15},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.6},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.6,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al2Li3"}],"pid":"sha256:8ee5c169b908262e/p2/tab-1/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-LI-ZR","structure":{"prototype":"Bi2Te3","space_group":"R 3̄m","strukturbericht":"hR15"},"system":"AL-LI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03137,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03137},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":14.259,"value_stored":14.259},{"chemical_system":"AL-LI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.6,"ZR":0.0},"phases":["Al2Li3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-QE24O4MH7Z.f2bc2f","locator":{"ref":"sha256:8ee5c169b908262e/p2/tab-1","row":15},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.6},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.6,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al2Li3"}],"pid":"sha256:8ee5c169b908262e/p2/tab-1/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-LI-ZR","structure":{"prototype":"Bi2Te3","space_group":"R 3̄m","strukturbericht":"hR15"},"system":"AL-LI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009918,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009918},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.508,"value_stored":4.508},{"chemical_system":"AL-LI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.692308,"ZR":0.0},"phases":["Al4Li9"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-64PSUZZFIS.7ab5a3","locator":{"ref":"sha256:8ee5c169b908262e/p2/tab-1","row":16},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.692308},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.692308,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al4Li9"}],"pid":"sha256:8ee5c169b908262e/p2/tab-1/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-LI-ZR","structure":{"prototype":"Al4Li9","space_group":"C2/m","strukturbericht":"mC26"},"system":"AL-LI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009898,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009898},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.499,"value_stored":4.499},{"chemical_system":"AL-LI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.692308,"ZR":0.0},"phases":["Al4Li9"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-64PSUZZFIS.b2ae5b","locator":{"ref":"sha256:8ee5c169b908262e/p2/tab-1","row":16},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.692308},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.692308,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al4Li9"}],"pid":"sha256:8ee5c169b908262e/p2/tab-1/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-LI-ZR","structure":{"prototype":"Al4Li9","space_group":"C2/m","strukturbericht":"mC26"},"system":"AL-LI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04213,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.04213},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":19.151,"value_stored":19.151},{"chemical_system":"AL-LI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.692308,"ZR":0.0},"phases":["Al4Li9"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-64PSUZZFIS.cd2d64","locator":{"ref":"sha256:8ee5c169b908262e/p2/tab-1","row":16},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.692308},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.692308,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al4Li9"}],"pid":"sha256:8ee5c169b908262e/p2/tab-1/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-LI-ZR","structure":{"prototype":"Al4Li9","space_group":"C2/m","strukturbericht":"mC26"},"system":"AL-LI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01194,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01194},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":5.429,"value_stored":5.429},{"chemical_system":"AL-LI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.666667,"ZR":0.0},"phases":["AlLi2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-CU4EZKYILG.1f3c2c","locator":{"ref":"sha256:8ee5c169b908262e/p2/tab-1","row":17},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.666667,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi2"}],"pid":"sha256:8ee5c169b908262e/p2/tab-1/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-LI-ZR","structure":{"prototype":"GaLi2","space_group":"Cmcm"},"system":"AL-LI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01025,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01025},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.658,"value_stored":4.658},{"chemical_system":"AL-LI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.666667,"ZR":0.0},"phases":["AlLi2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-CU4EZKYILG.285bb2","locator":{"ref":"sha256:8ee5c169b908262e/p2/tab-1","row":17},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.666667,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi2"}],"pid":"sha256:8ee5c169b908262e/p2/tab-1/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-LI-ZR","structure":{"prototype":"GaLi2","space_group":"Cmcm"},"system":"AL-LI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009878,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009878},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":4.49,"value_stored":4.49},{"chemical_system":"AL-LI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.666667,"ZR":0.0},"phases":["AlLi2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-CU4EZKYILG.5fa8f8","locator":{"ref":"sha256:8ee5c169b908262e/p2/tab-1","row":17},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.666667,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi2"}],"pid":"sha256:8ee5c169b908262e/p2/tab-1/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-LI-ZR","structure":{"prototype":"GaLi2","space_group":"Cmcm"},"system":"AL-LI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02149,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02149},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"Å","value":9.767,"value_stored":9.767},{"chemical_system":"AL-LI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi (B32)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-TVPAVRDRI7.474546","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":125},"merged_ids":["ORC-TVPAVRDRI7.055889"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi (B32)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r125#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-20.0,"value_printed":-20.0,"value_stored":-20000.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1149/1.2408242","first_author":"Yao","kind":"unknown","label":"63","paper":"doi:10.1149/1.2408242","reference":"N.P. Yao, L.A. Herédy, and R.C. Saunders, Emf Measurements of Electrochemically Prepared Lithium-Aluminum Alloy, J. Electrochem. Soc., 1971, 118, p 1039-1042. https://doi.org/10. 1149/1.2408242","status":"resolved","year":"1971"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi (B32)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-EXFDUPW5V4.808d8e","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":126},"merged_ids":["ORC-EXFDUPW5V4.fb756a"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi (B32)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r126#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.09},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-21.8,"value_printed":-21.8,"value_stored":-21800.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.32.207","first_author":"Christensen","kind":"unknown","label":"59","paper":"doi:10.1103/physrevb.32.207","reference":"N.E. Christensen, Structural Phase Stability of B2 and B32 Intermetallic Compounds, Phys. Rev. B, 1985, 32, p 207-228. https://doi.org/10.1103/PhysRevB.32.207","status":"resolved","year":"1985"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi (B32)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-2VDV3OES3L.73426f","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":127},"merged_ids":["ORC-2VDV3OES3L.f41b2c"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi (B32)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r127#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.015},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-20.3,"value_printed":-20.3,"value_stored":-20300.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.42.10912","first_author":"Guo","kind":"unknown","label":"60","paper":"doi:10.1103/physrevb.42.10912","reference":"X.Q. Guo and R. Podloucky, Phase Stability and Bonding Characteristics of Li-rich Al-Li Intermetallic Compounds: Al2Li3 and Al4Li9, Phys. Rev. B, 1990, 42, p 10912-10923. https://doi. org/10.1103/PhysRevB.42.10912","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi (B32)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-RTFTIK56P4.4ce17d","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":128},"merged_ids":["ORC-RTFTIK56P4.275b82"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi (B32)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r128#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.095},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-21.9,"value_printed":-21.9,"value_stored":-21900.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1088/0953-8984/6/18/015","first_author":"Arya","kind":"unknown","label":"61","paper":"doi:10.1088/0953-8984/6/18/015","reference":"A. Arya, G.P. Das, H.G. Salunke, and S. Banerjee, Cohesive and Electronic Properties of Ordered Li-Al Intermetallic Compounds, 641 J. Phys. Condens. Matter, 1994, 6, p 3389-3402. https://doi.org/ 10.1088/0953-8984/6/18/015","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi (B32)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-HBLKHWAMBH.c95cc7","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":129},"merged_ids":["ORC-HBLKHWAMBH.e813f9"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi (B32)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r129#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.19},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-23.8,"value_printed":-23.8,"value_stored":-23800.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.53.6137","first_author":"Sluiter","kind":"unknown","label":"62","paper":"doi:10.1103/physrevb.53.6137","reference":"M.H.F. Sluiter, Y. Watanabe, D. de Fontaine, and Y. Kawazoe, First-Principles Calculation of the Pressure Dependence of Phase Equilibria in the Al-Li System, Phys. Rev. B, 1996, 53, p 61376150. https://doi.org/10.1103/PhysRevB.53.6137","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi (B32)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-X22E4KDUDC.80ee67","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":130},"merged_ids":["ORC-X22E4KDUDC.4c6f31"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi (B32)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r130#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.035},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-20.7,"value_printed":-20.7,"value_stored":-20700.0},{"chemical_system":"AL-LI","cited_sources":[{"first_author":"Ga","kind":"unknown","label":"64","reference":"W. Ga˛sior, A. De˛bski, A. Góral, and R. Major, Enthalpy of Formation of Intermetallic Phases from Al-Li System by Solution and Direct Reaction Calorimetric Method, J. Alloys Compd., 2014, 586, p 703-708. https://doi.org/10.1016/j.jallcom.2013.10. 143","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi (B32)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-YQCPH2UMXQ.eaa1b2","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":131},"merged_ids":["ORC-YQCPH2UMXQ.797e59"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi (B32)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r131#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.035},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-20.7,"value_printed":-20.7,"value_stored":-20700.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.3139/146.101553","first_author":"Hallstedt","kind":"assessment","label":"17","paper":"doi:10.3139/146.101553","reference":"B. Hallstedt and O. Kim, Thermodynamic Assessment of the AlLi system, Z. Metall., 2007, 98, p 961-969. https://doi.org/10. 3139/146.101553","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi (B32)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-LTISH4VV3X.e898af","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":132},"merged_ids":["ORC-LTISH4VV3X.c0ce04"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.3139/146.101553","own_work_of_paper":false},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi (B32)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r132#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-20.0,"value_printed":-20.0,"value_stored":-20000.0},{"chemical_system":"AL-LI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi (B2)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-PBOIMMCRW4.d579c1","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":133},"merged_ids":["ORC-PBOIMMCRW4.b5d565"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi (B2)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r133#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.7},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-14.0,"value_printed":-14.0,"value_stored":-14000.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.32.207","first_author":"Christensen","kind":"unknown","label":"59","paper":"doi:10.1103/physrevb.32.207","reference":"N.E. Christensen, Structural Phase Stability of B2 and B32 Intermetallic Compounds, Phys. Rev. B, 1985, 32, p 207-228. https://doi.org/10.1103/PhysRevB.32.207","status":"resolved","year":"1985"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi (B2)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-5CCJXCXDVG.4cfeb2","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":134},"merged_ids":["ORC-5CCJXCXDVG.919398"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi (B2)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r134#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.305},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":6.1,"value_printed":6.1,"value_stored":6100.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.42.10912","first_author":"Guo","kind":"unknown","label":"60","paper":"doi:10.1103/physrevb.42.10912","reference":"X.Q. Guo and R. Podloucky, Phase Stability and Bonding Characteristics of Li-rich Al-Li Intermetallic Compounds: Al2Li3 and Al4Li9, Phys. Rev. B, 1990, 42, p 10912-10923. https://doi. org/10.1103/PhysRevB.42.10912","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi (B2)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-BVIPM22DTA.f12f07","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":135},"merged_ids":["ORC-BVIPM22DTA.398d03","ORC-HAFPGASCAW.6f56a2"],"merged_pids":["sha256:8ee5c169b908262e/p7/tab-4/r139#equilibrium_property"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi (B2)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r135#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.685},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-13.7,"value_printed":-13.7,"value_stored":-13700.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.53.6137","first_author":"Sluiter","kind":"unknown","label":"62","paper":"doi:10.1103/physrevb.53.6137","reference":"M.H.F. Sluiter, Y. Watanabe, D. de Fontaine, and Y. Kawazoe, First-Principles Calculation of the Pressure Dependence of Phase Equilibria in the Al-Li System, Phys. Rev. B, 1996, 53, p 61376150. https://doi.org/10.1103/PhysRevB.53.6137","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi (B2)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-Y25LT7RFCH.e6e4f0","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":136},"merged_ids":["ORC-Y25LT7RFCH.ca203f"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi (B2)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r136#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.69},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-13.8,"value_printed":-13.8,"value_stored":-13800.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.3139/146.101553","first_author":"Hallstedt","kind":"assessment","label":"17","paper":"doi:10.3139/146.101553","reference":"B. Hallstedt and O. Kim, Thermodynamic Assessment of the AlLi system, Z. Metall., 2007, 98, p 961-969. https://doi.org/10. 3139/146.101553","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi (B2)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-CU34JPNHL4.e41ca2","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":137},"merged_ids":["ORC-CU34JPNHL4.13cedc"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.3139/146.101553","own_work_of_paper":false},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi (B2)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r137#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.7},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-14.0,"value_printed":-14.0,"value_stored":-14000.0},{"chemical_system":"AL-LI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi(L10)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-2UCYLD3PRV.f15774","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":138},"merged_ids":["ORC-2UCYLD3PRV.63057b"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi(L10)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r138#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.655},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-13.1,"value_printed":-13.1,"value_stored":-13100.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.42.10912","first_author":"Guo","kind":"unknown","label":"60","paper":"doi:10.1103/physrevb.42.10912","reference":"X.Q. Guo and R. Podloucky, Phase Stability and Bonding Characteristics of Li-rich Al-Li Intermetallic Compounds: Al2Li3 and Al4Li9, Phys. Rev. B, 1990, 42, p 10912-10923. https://doi. org/10.1103/PhysRevB.42.10912","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi(L10)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-HAFPGASCAW.f7c8b7","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":139},"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi(L10)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r139#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.685},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-13.7,"value_printed":-13.7,"value_stored":-13700.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1088/0953-8984/6/18/015","first_author":"Arya","kind":"unknown","label":"61","paper":"doi:10.1088/0953-8984/6/18/015","reference":"A. Arya, G.P. Das, H.G. Salunke, and S. Banerjee, Cohesive and Electronic Properties of Ordered Li-Al Intermetallic Compounds, 641 J. Phys. Condens. Matter, 1994, 6, p 3389-3402. https://doi.org/ 10.1088/0953-8984/6/18/015","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi(L10)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-SKUTHOCACS.5ea5a7","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":140},"merged_ids":["ORC-SKUTHOCACS.33e6ed"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi(L10)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r140#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.595},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-11.9,"value_printed":-11.9,"value_stored":-11900.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.53.6137","first_author":"Sluiter","kind":"unknown","label":"62","paper":"doi:10.1103/physrevb.53.6137","reference":"M.H.F. Sluiter, Y. Watanabe, D. de Fontaine, and Y. Kawazoe, First-Principles Calculation of the Pressure Dependence of Phase Equilibria in the Al-Li System, Phys. Rev. B, 1996, 53, p 61376150. https://doi.org/10.1103/PhysRevB.53.6137","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi(L10)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-KPI2O4T3PW.726ee6","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":141},"merged_ids":["ORC-KPI2O4T3PW.259aa9"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi(L10)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r141#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.475},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-9.5,"value_printed":-9.5,"value_stored":-9500.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.3139/146.101553","first_author":"Hallstedt","kind":"assessment","label":"17","paper":"doi:10.3139/146.101553","reference":"B. Hallstedt and O. Kim, Thermodynamic Assessment of the AlLi system, Z. Metall., 2007, 98, p 961-969. https://doi.org/10. 3139/146.101553","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.5,"ZR":0.0},"phases":["AlLi(L10)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-PTXRD7ZUNW.3161eb","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":142},"merged_ids":["ORC-PTXRD7ZUNW.d76aa0"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.3139/146.101553","own_work_of_paper":false},"overall_composition":{"LI":0.5},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.5,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi(L10)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r142#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.655},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-13.1,"value_printed":-13.1,"value_stored":-13100.0},{"chemical_system":"AL-LI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.6,"ZR":0.0},"phases":["Al2Li3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-IKJSPHN5ZV.0e34f1","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":143},"merged_ids":["ORC-IKJSPHN5ZV.25a498"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.6},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.6,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al2Li3"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r143#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.94},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-18.8,"value_printed":-18.8,"value_stored":-18800.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.42.10912","first_author":"Guo","kind":"unknown","label":"60","paper":"doi:10.1103/physrevb.42.10912","reference":"X.Q. Guo and R. Podloucky, Phase Stability and Bonding Characteristics of Li-rich Al-Li Intermetallic Compounds: Al2Li3 and Al4Li9, Phys. Rev. B, 1990, 42, p 10912-10923. https://doi. org/10.1103/PhysRevB.42.10912","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.6,"ZR":0.0},"phases":["Al2Li3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-WGEKYGWHWE.0c2bd4","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":144},"merged_ids":["ORC-WGEKYGWHWE.9bbe42"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.6},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.6,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al2Li3"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r144#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.95},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-19.0,"value_printed":-19.0,"value_stored":-19000.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.53.6137","first_author":"Sluiter","kind":"unknown","label":"62","paper":"doi:10.1103/physrevb.53.6137","reference":"M.H.F. Sluiter, Y. Watanabe, D. de Fontaine, and Y. Kawazoe, First-Principles Calculation of the Pressure Dependence of Phase Equilibria in the Al-Li System, Phys. Rev. B, 1996, 53, p 61376150. https://doi.org/10.1103/PhysRevB.53.6137","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.6,"ZR":0.0},"phases":["Al2Li3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-WV7L2XRBME.03f062","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":145},"merged_ids":["ORC-WV7L2XRBME.136397"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.6},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.6,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al2Li3"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r145#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.055},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-21.1,"value_printed":-21.1,"value_stored":-21100.0},{"chemical_system":"AL-LI","cited_sources":[{"first_author":"Ga","kind":"unknown","label":"64","reference":"W. Ga˛sior, A. De˛bski, A. Góral, and R. Major, Enthalpy of Formation of Intermetallic Phases from Al-Li System by Solution and Direct Reaction Calorimetric Method, J. Alloys Compd., 2014, 586, p 703-708. https://doi.org/10.1016/j.jallcom.2013.10. 143","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.6,"ZR":0.0},"phases":["Al2Li3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-EMYKU7Q3MI.71dbb1","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":146},"merged_ids":["ORC-EMYKU7Q3MI.018e43"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"LI":0.6},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.6,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al2Li3"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r146#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.955},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-19.1,"value_printed":-19.1,"value_stored":-19100.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.3139/146.101553","first_author":"Hallstedt","kind":"assessment","label":"17","paper":"doi:10.3139/146.101553","reference":"B. Hallstedt and O. Kim, Thermodynamic Assessment of the AlLi system, Z. Metall., 2007, 98, p 961-969. https://doi.org/10. 3139/146.101553","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.6,"ZR":0.0},"phases":["Al2Li3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-JDDH6NIMNW.560966","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":147},"merged_ids":["ORC-JDDH6NIMNW.171c44"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.3139/146.101553","own_work_of_paper":false},"overall_composition":{"LI":0.6},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.6,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al2Li3"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r147#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.94},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-18.8,"value_printed":-18.8,"value_stored":-18800.0},{"chemical_system":"AL-LI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.666667,"ZR":0.0},"phases":["AlLi2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-L4IAMI7OLB.f7db48","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":148},"merged_ids":["ORC-L4IAMI7OLB.9ae474"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.666667,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi2"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r148#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.86},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-17.2,"value_printed":-17.2,"value_stored":-17200.0},{"chemical_system":"AL-LI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.692308,"ZR":0.0},"phases":["Al4Li9"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-BDWPCDCWCQ.422f71","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":149},"merged_ids":["ORC-BDWPCDCWCQ.f76d1d"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.692308},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.692308,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al4Li9"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r149#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.755},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-15.1,"value_printed":-15.1,"value_stored":-15100.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.42.10912","first_author":"Guo","kind":"unknown","label":"60","paper":"doi:10.1103/physrevb.42.10912","reference":"X.Q. Guo and R. Podloucky, Phase Stability and Bonding Characteristics of Li-rich Al-Li Intermetallic Compounds: Al2Li3 and Al4Li9, Phys. Rev. B, 1990, 42, p 10912-10923. https://doi. org/10.1103/PhysRevB.42.10912","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.692308,"ZR":0.0},"phases":["Al4Li9"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-UJNWOK6PNN.9ec994","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":150},"merged_ids":["ORC-UJNWOK6PNN.fdfd3b"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.692308},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.692308,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al4Li9"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r150#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.745},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-14.9,"value_printed":-14.9,"value_stored":-14900.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.53.6137","first_author":"Sluiter","kind":"unknown","label":"62","paper":"doi:10.1103/physrevb.53.6137","reference":"M.H.F. Sluiter, Y. Watanabe, D. de Fontaine, and Y. Kawazoe, First-Principles Calculation of the Pressure Dependence of Phase Equilibria in the Al-Li System, Phys. Rev. B, 1996, 53, p 61376150. https://doi.org/10.1103/PhysRevB.53.6137","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.692308,"ZR":0.0},"phases":["Al4Li9"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-DLZOZS4YTD.3deae1","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":151},"merged_ids":["ORC-DLZOZS4YTD.2e6e5d"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.692308},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.692308,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al4Li9"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r151#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.84},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-16.8,"value_printed":-16.8,"value_stored":-16800.0},{"chemical_system":"AL-LI","cited_sources":[{"first_author":"Ga","kind":"unknown","label":"64","reference":"W. Ga˛sior, A. De˛bski, A. Góral, and R. Major, Enthalpy of Formation of Intermetallic Phases from Al-Li System by Solution and Direct Reaction Calorimetric Method, J. Alloys Compd., 2014, 586, p 703-708. https://doi.org/10.1016/j.jallcom.2013.10. 143","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.692308,"ZR":0.0},"phases":["Al4Li9"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-OZJIYXWG3C.b8074a","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":152},"merged_ids":["ORC-OZJIYXWG3C.4dcd71"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"LI":0.692308},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.692308,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al4Li9"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r152#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.755},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-15.1,"value_printed":-15.1,"value_stored":-15100.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.3139/146.101553","first_author":"Hallstedt","kind":"assessment","label":"17","paper":"doi:10.3139/146.101553","reference":"B. Hallstedt and O. Kim, Thermodynamic Assessment of the AlLi system, Z. Metall., 2007, 98, p 961-969. https://doi.org/10. 3139/146.101553","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.692308,"ZR":0.0},"phases":["Al4Li9"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-XBOXNWGXLL.54004d","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":153},"merged_ids":["ORC-XBOXNWGXLL.9850b4"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.3139/146.101553","own_work_of_paper":false},"overall_composition":{"LI":0.692308},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.692308,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al4Li9"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r153#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.745},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-14.9,"value_printed":-14.9,"value_stored":-14900.0},{"chemical_system":"AL-LI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.25,"ZR":0.0},"phases":["Al3Li(L12)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-ECT3WOEE5J.f50fda","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":154},"merged_ids":["ORC-ECT3WOEE5J.5c4b25"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.25,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al3Li(L12)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r154#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.405},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-8.1,"value_printed":-8.1,"value_stored":-8100.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.42.10912","first_author":"Guo","kind":"unknown","label":"60","paper":"doi:10.1103/physrevb.42.10912","reference":"X.Q. Guo and R. Podloucky, Phase Stability and Bonding Characteristics of Li-rich Al-Li Intermetallic Compounds: Al2Li3 and Al4Li9, Phys. Rev. B, 1990, 42, p 10912-10923. https://doi. org/10.1103/PhysRevB.42.10912","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.25,"ZR":0.0},"phases":["Al3Li(L12)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-YJ2JJHVBTF.f187cd","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":155},"merged_ids":["ORC-YJ2JJHVBTF.11d0b2"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.25,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al3Li(L12)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r155#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.555},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-11.1,"value_printed":-11.1,"value_stored":-11100.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1088/0953-8984/6/18/015","first_author":"Arya","kind":"unknown","label":"61","paper":"doi:10.1088/0953-8984/6/18/015","reference":"A. Arya, G.P. Das, H.G. Salunke, and S. Banerjee, Cohesive and Electronic Properties of Ordered Li-Al Intermetallic Compounds, 641 J. Phys. Condens. Matter, 1994, 6, p 3389-3402. https://doi.org/ 10.1088/0953-8984/6/18/015","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.25,"ZR":0.0},"phases":["Al3Li(L12)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-FCQXJFOIGF.58e44a","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":156},"merged_ids":["ORC-FCQXJFOIGF.9eb663"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.25,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al3Li(L12)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r156#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.505},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-10.1,"value_printed":-10.1,"value_stored":-10100.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.53.6137","first_author":"Sluiter","kind":"unknown","label":"62","paper":"doi:10.1103/physrevb.53.6137","reference":"M.H.F. Sluiter, Y. Watanabe, D. de Fontaine, and Y. Kawazoe, First-Principles Calculation of the Pressure Dependence of Phase Equilibria in the Al-Li System, Phys. Rev. B, 1996, 53, p 61376150. https://doi.org/10.1103/PhysRevB.53.6137","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.25,"ZR":0.0},"phases":["Al3Li(L12)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-R5N5JMVBWF.399b02","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":157},"merged_ids":["ORC-R5N5JMVBWF.7be6bd"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.25,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al3Li(L12)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r157#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.375},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-7.5,"value_printed":-7.5,"value_stored":-7500.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.3139/146.101553","first_author":"Hallstedt","kind":"assessment","label":"17","paper":"doi:10.3139/146.101553","reference":"B. Hallstedt and O. Kim, Thermodynamic Assessment of the AlLi system, Z. Metall., 2007, 98, p 961-969. https://doi.org/10. 3139/146.101553","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.25,"ZR":0.0},"phases":["Al3Li(L12)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-2ZGXQO6JL6.eba9bf","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":158},"merged_ids":["ORC-2ZGXQO6JL6.326651"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.3139/146.101553","own_work_of_paper":false},"overall_composition":{"LI":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.25,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al3Li(L12)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r158#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.405},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-8.1,"value_printed":-8.1,"value_stored":-8100.0},{"chemical_system":"AL-LI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.25,"ZR":0.0},"phases":["Al3Li(D03)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-O5JSQF2ZNS.f6ccad","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":159},"merged_ids":["ORC-O5JSQF2ZNS.b89909"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.25,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al3Li(D03)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r159#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.25},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-5.0,"value_printed":-5.0,"value_stored":-5000.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.42.10912","first_author":"Guo","kind":"unknown","label":"60","paper":"doi:10.1103/physrevb.42.10912","reference":"X.Q. Guo and R. Podloucky, Phase Stability and Bonding Characteristics of Li-rich Al-Li Intermetallic Compounds: Al2Li3 and Al4Li9, Phys. Rev. B, 1990, 42, p 10912-10923. https://doi. org/10.1103/PhysRevB.42.10912","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.25,"ZR":0.0},"phases":["Al3Li(D03)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-NCROKQZ52N.ea618c","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":160},"merged_ids":["ORC-NCROKQZ52N.fa9df7"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.25,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al3Li(D03)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r160#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.095},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":1.9,"value_printed":1.9,"value_stored":1900.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.53.6137","first_author":"Sluiter","kind":"unknown","label":"62","paper":"doi:10.1103/physrevb.53.6137","reference":"M.H.F. Sluiter, Y. Watanabe, D. de Fontaine, and Y. Kawazoe, First-Principles Calculation of the Pressure Dependence of Phase Equilibria in the Al-Li System, Phys. Rev. B, 1996, 53, p 61376150. https://doi.org/10.1103/PhysRevB.53.6137","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.25,"ZR":0.0},"phases":["Al3Li(D03)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-4ICN4HYMND.56650a","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":161},"merged_ids":["ORC-4ICN4HYMND.5e70ae"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.25,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al3Li(D03)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r161#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.195},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-3.9,"value_printed":-3.9,"value_stored":-3900.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.3139/146.101553","first_author":"Hallstedt","kind":"assessment","label":"17","paper":"doi:10.3139/146.101553","reference":"B. Hallstedt and O. Kim, Thermodynamic Assessment of the AlLi system, Z. Metall., 2007, 98, p 961-969. https://doi.org/10. 3139/146.101553","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.25,"ZR":0.0},"phases":["Al3Li(D03)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-CAMTNXCQZ2.207856","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":162},"merged_ids":["ORC-CAMTNXCQZ2.97695a"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.3139/146.101553","own_work_of_paper":false},"overall_composition":{"LI":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.25,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"Al3Li(D03)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r162#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.25},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-5.0,"value_printed":-5.0,"value_stored":-5000.0},{"chemical_system":"AL-LI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.75,"ZR":0.0},"phases":["AlLi3(L12)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-FJ2HAIFXHU.b2ce18","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":163},"merged_ids":["ORC-FJ2HAIFXHU.fe9e46"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.75,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi3(L12)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r163#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.25},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-5.0,"value_printed":-5.0,"value_stored":-5000.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.42.10912","first_author":"Guo","kind":"unknown","label":"60","paper":"doi:10.1103/physrevb.42.10912","reference":"X.Q. Guo and R. Podloucky, Phase Stability and Bonding Characteristics of Li-rich Al-Li Intermetallic Compounds: Al2Li3 and Al4Li9, Phys. Rev. B, 1990, 42, p 10912-10923. https://doi. org/10.1103/PhysRevB.42.10912","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.75,"ZR":0.0},"phases":["AlLi3(L12)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-N62ATWI4NE.1ff2fb","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":164},"merged_ids":["ORC-N62ATWI4NE.0d5e74"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.75,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi3(L12)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r164#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.325},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-6.5,"value_printed":-6.5,"value_stored":-6500.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1088/0953-8984/6/18/015","first_author":"Arya","kind":"unknown","label":"61","paper":"doi:10.1088/0953-8984/6/18/015","reference":"A. Arya, G.P. Das, H.G. Salunke, and S. Banerjee, Cohesive and Electronic Properties of Ordered Li-Al Intermetallic Compounds, 641 J. Phys. Condens. Matter, 1994, 6, p 3389-3402. https://doi.org/ 10.1088/0953-8984/6/18/015","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.75,"ZR":0.0},"phases":["AlLi3(L12)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-UC6DXOOHZW.23c988","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":165},"merged_ids":["ORC-UC6DXOOHZW.22dffa"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.75,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi3(L12)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r165#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.25},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-5.0,"value_printed":-5.0,"value_stored":-5000.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.53.6137","first_author":"Sluiter","kind":"unknown","label":"62","paper":"doi:10.1103/physrevb.53.6137","reference":"M.H.F. Sluiter, Y. Watanabe, D. de Fontaine, and Y. Kawazoe, First-Principles Calculation of the Pressure Dependence of Phase Equilibria in the Al-Li System, Phys. Rev. B, 1996, 53, p 61376150. https://doi.org/10.1103/PhysRevB.53.6137","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.75,"ZR":0.0},"phases":["AlLi3(L12)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-73YU4NVCO3.6b4117","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":166},"merged_ids":["ORC-73YU4NVCO3.52d57d"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.75,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi3(L12)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r166#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.115},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-2.3,"value_printed":-2.3,"value_stored":-2300.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.3139/146.101553","first_author":"Hallstedt","kind":"assessment","label":"17","paper":"doi:10.3139/146.101553","reference":"B. Hallstedt and O. Kim, Thermodynamic Assessment of the AlLi system, Z. Metall., 2007, 98, p 961-969. https://doi.org/10. 3139/146.101553","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.75,"ZR":0.0},"phases":["AlLi3(L12)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-CAMTE2JJTT.e5208b","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":167},"merged_ids":["ORC-CAMTE2JJTT.444f6e"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.3139/146.101553","own_work_of_paper":false},"overall_composition":{"LI":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.75,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi3(L12)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r167#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.25},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-5.0,"value_printed":-5.0,"value_stored":-5000.0},{"chemical_system":"AL-LI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.75,"ZR":0.0},"phases":["AlLi3(D03)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-LDJLE4M2UK.c134d4","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":168},"merged_ids":["ORC-LDJLE4M2UK.00dffa"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-020-00827-z","own_work_of_paper":true},"overall_composition":{"LI":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.75,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi3(D03)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r168#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.525},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-10.5,"value_printed":-10.5,"value_stored":-10500.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.42.10912","first_author":"Guo","kind":"unknown","label":"60","paper":"doi:10.1103/physrevb.42.10912","reference":"X.Q. Guo and R. Podloucky, Phase Stability and Bonding Characteristics of Li-rich Al-Li Intermetallic Compounds: Al2Li3 and Al4Li9, Phys. Rev. B, 1990, 42, p 10912-10923. https://doi. org/10.1103/PhysRevB.42.10912","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.75,"ZR":0.0},"phases":["AlLi3(D03)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-NMYMDA337N.f4e697","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":169},"merged_ids":["ORC-NMYMDA337N.ce05fd"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.75,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi3(D03)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r169#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.545},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-10.9,"value_printed":-10.9,"value_stored":-10900.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1103/physrevb.53.6137","first_author":"Sluiter","kind":"unknown","label":"62","paper":"doi:10.1103/physrevb.53.6137","reference":"M.H.F. Sluiter, Y. Watanabe, D. de Fontaine, and Y. Kawazoe, First-Principles Calculation of the Pressure Dependence of Phase Equilibria in the Al-Li System, Phys. Rev. B, 1996, 53, p 61376150. https://doi.org/10.1103/PhysRevB.53.6137","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.75,"ZR":0.0},"phases":["AlLi3(D03)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-7MFUNDJ7HW.01b7f0","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":170},"merged_ids":["ORC-7MFUNDJ7HW.ed542b"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"LI":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.75,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi3(D03)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r170#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.51},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-10.2,"value_printed":-10.2,"value_stored":-10200.0},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.3139/146.101553","first_author":"Hallstedt","kind":"assessment","label":"17","paper":"doi:10.3139/146.101553","reference":"B. Hallstedt and O. Kim, Thermodynamic Assessment of the AlLi system, Z. Metall., 2007, 98, p 961-969. https://doi.org/10. 3139/146.101553","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-LI","before":"AL-LI-ZR","evidence":{"basis":"phase_formula","overall_composition":{"LI":0.75,"ZR":0.0},"phases":["AlLi3(D03)"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-S4TDZMCDYP.b3800e","locator":{"ref":"sha256:8ee5c169b908262e/p7/tab-4","row":171},"merged_ids":["ORC-S4TDZMCDYP.62d6f1"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.3139/146.101553","own_work_of_paper":false},"overall_composition":{"LI":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"LI":0.75,"ZR":0.0},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phases":[{"label":"AlLi3(D03)"}],"pid":"sha256:8ee5c169b908262e/p7/tab-4/r171#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"LI":{"phase":"printed:none"},"ZR":{"phase":"printed:none"}},"source_system":"AL-LI-ZR","system":"AL-LI","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.525},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"reviewer","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-10.5,"value_printed":-10.5,"value_stored":-10500.0},{"chemical_system":"AL-LI","cited_sources":[{"first_author":"Myles","kind":"unknown","label":"50","reference":"K.M. Myles, F.C. Mrazek, J.A. Smaga and J.L. Settle, in Advanced Battery Research and Design, U.S. ERDA Report ANL76-8, Proceedings of Symposium and Workshop, Argonne National Laboratory, B50 (cited from [7]), 1976 J. Phase Equilib. Diffus. (2020) 41:623–641","status":"resolved","year":"2020"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-6NRJUYGPET","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":1},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"phase_transition","origin":{"basis":"cited_work_title_modelling","class":"model_value","measured_in":"ref:c9e6d1b0a02f9ff9","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.5},"composition_source":"congruent_same_composition","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.5},"composition_source":"formula_nominal","phase":"AlLi"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"AlLi","mapping_confidence":"confirmed","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r01#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L ↔ AlLi"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":965,"temperature_printed":"965","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":965},{"chemical_system":"AL-LI","cited_sources":[{"first_author":"Schurmann","kind":"experimental","label":"51","reference":"E. Schürmann and H.J. Voss, Investigation of the Melting Equilibria of Mg-Li-Al Alloys, Giessereiforschung, 1981, 33, p 33","status":"resolved","year":"1981"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-7D74SQUJ54","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":2},"observation_type":"phase_transition","origin":{"basis":"cited_work_is_experimental","class":"experimental","measured_in":"ref:c1884defdae4ec20","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.49},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.49},"composition_source":"printed","phase":"AlLi"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"AlLi","mapping_confidence":"confirmed","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r02#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L ↔ AlLi"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":970,"temperature_printed":"970","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":970},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.3139/146.101553","first_author":"Hallstedt","kind":"assessment","label":"17","paper":"doi:10.3139/146.101553","reference":"B. Hallstedt and O. Kim, Thermodynamic Assessment of the AlLi system, Z. Metall., 2007, 98, p 961-969. https://doi.org/10. 3139/146.101553","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","source_disputed":true,"state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-XQOS2WNDJA","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":3},"model_unlinked_reason":"cited calculation matches several corpus TDBs (AlLi-07Hal-condensed.tdb, AlLi-07Hal.tdb)","observation_type":"phase_transition","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.3139/146.101553","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.497},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.497},"composition_source":"printed","phase":"AlLi"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"AlLi","mapping_confidence":"confirmed","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r03#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"L ↔ AlLi"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":975,"temperature_printed":"975","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":975},{"chemical_system":"AL-LI","cited_sources":[{"first_author":"Muller","kind":"experimental","label":"47","reference":"A. Müller, The Al-Li Phase Diagram, Z. Metallkd., 1926, 18, p 231","status":"resolved","year":"1926"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-13.069,"dx":{"L":-0.0036,"fcc(Al)":-0.0073},"model":"AlLi-20Lon.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-NOKGAXYWXY","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":4},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:1fa019436d752c75","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.234},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.124},"composition_source":"printed","phase":"fcc(Al)"},{"basis":"mole_fraction","composition":{"LI":0.5},"composition_source":"formula_nominal","phase":"AlLi"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"fcc(Al)","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"AlLi","mapping_confidence":"confirmed","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r04#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ fcc(Al) + AlLi"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":863,"temperature_printed":"863","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":863},{"chemical_system":"AL-LI","cited_sources":[{"first_author":"Grube","kind":"experimental","label":"48","reference":"A. Grube, L. Mohr, and W. Breuning, Elektrische Leitfähigkeit und Zustandsdiagramm bei binären Legierungen. 17. Mitteilung. Das System Lithium–Aluminium, Z. Elektrochem., 1935, 41, p 880-883. https://doi.org/10.1002/bbpc.19350411213","status":"resolved","year":"1935"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-3.069,"dx":{"L":0.0624,"fcc(Al)":0.0487},"fail_reason":"composition_pure_element_label","model":"AlLi-20Lon.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-74FUJ7XHGF","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":5},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:232ba85e4082a28c","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.3},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.18},"composition_source":"printed","phase":"fcc(Al)"},{"basis":"mole_fraction","composition":{"LI":0.5},"composition_source":"formula_nominal","phase":"AlLi"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"fcc(Al)","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"AlLi","mapping_confidence":"confirmed","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r05#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ fcc(Al) + AlLi"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":873,"temperature_printed":"873","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":873},{"chemical_system":"AL-LI","cited_sources":[{"first_author":"Shamray","kind":"unknown","label":"49","reference":"F.I. Shamray and P.Ya. Saldau, Equilibrium Diagram of the System Al-Li, Izv. Akad. Nauk SSSR, Otd. Khim., 1937, 3, p 631640","status":"resolved","year":"1937"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-5.069,"dx":{"L":0.0224},"model":"AlLi-20Lon.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-SLGJ6TEXEO","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":6},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:639878ea89f3392b","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.26},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.5},"composition_source":"formula_nominal","phase":"AlLi"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"fcc(Al)","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"AlLi","mapping_confidence":"confirmed","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r06#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ fcc(Al) + AlLi"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":871,"temperature_printed":"871","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":871},{"chemical_system":"AL-LI","cited_sources":[{"first_author":"Myles","kind":"unknown","label":"50","reference":"K.M. Myles, F.C. Mrazek, J.A. Smaga and J.L. Settle, in Advanced Battery Research and Design, U.S. ERDA Report ANL76-8, Proceedings of Symposium and Workshop, Argonne National Laboratory, B50 (cited from [7]), 1976 J. Phase Equilib. Diffus. (2020) 41:623–641","status":"resolved","year":"2020"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-3.069,"dx":{},"model":"AlLi-20Lon.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-2HA7QWOFNY","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":7},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_modelling","class":"model_value","measured_in":"ref:c9e6d1b0a02f9ff9","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.5},"composition_source":"formula_nominal","phase":"AlLi"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"fcc(Al)","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"AlLi","mapping_confidence":"confirmed","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r07#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ fcc(Al) + AlLi"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":873,"temperature_printed":"873","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":873},{"chemical_system":"AL-LI","cited_sources":[{"first_author":"Schurmann","kind":"experimental","label":"51","reference":"E. Schürmann and H.J. Voss, Investigation of the Melting Equilibria of Mg-Li-Al Alloys, Giessereiforschung, 1981, 33, p 33","status":"resolved","year":"1981"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-1.069,"dx":{"AlLi":0.0187,"L":0.0144,"fcc(Al)":0.0067},"model":"AlLi-20Lon.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-5QBASPWCER","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":8},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_is_experimental","class":"experimental","measured_in":"ref:c1884defdae4ec20","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.252},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.138},"composition_source":"printed","phase":"fcc(Al)"},{"basis":"mole_fraction","composition":{"LI":0.475},"composition_source":"printed","phase":"AlLi"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"fcc(Al)","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"AlLi","mapping_confidence":"confirmed","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r08#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ fcc(Al) + AlLi"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":875,"temperature_printed":"875","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":875},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.3139/146.101553","first_author":"Hallstedt","kind":"assessment","label":"17","paper":"doi:10.3139/146.101553","reference":"B. Hallstedt and O. Kim, Thermodynamic Assessment of the AlLi system, Z. Metall., 2007, 98, p 961-969. https://doi.org/10. 3139/146.101553","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.069,"dx":{"AlLi":-0.0003,"L":0.0004,"fcc(Al)":-0.0003},"model":"AlLi-20Lon.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","source_disputed":true,"state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-W53IOYC56J","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":9},"model_unlinked_reason":"cited calculation matches several corpus TDBs (AlLi-07Hal-condensed.tdb, AlLi-07Hal.tdb)","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.3139/146.101553","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.238},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.131},"composition_source":"printed","phase":"fcc(Al)"},{"basis":"mole_fraction","composition":{"LI":0.456},"composition_source":"printed","phase":"AlLi"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"fcc(Al)","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"AlLi","mapping_confidence":"confirmed","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r09#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ fcc(Al) + AlLi"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":876,"temperature_printed":"876","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":876},{"chemical_system":"AL-LI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.069,"dx":{"AlLi":-0.0003,"L":0.0004,"fcc(Al)":-0.0003},"model":"AlLi-20Lon.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-MBIA43UNOF","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":10},"model":"Mb4ef1200","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-020-00827-z","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.238},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.131},"composition_source":"printed","phase":"fcc(Al)"},{"basis":"mole_fraction","composition":{"LI":0.456},"composition_source":"printed","phase":"AlLi"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"fcc(Al)","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"AlLi","mapping_confidence":"confirmed","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r10#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L ↔ fcc(Al) + AlLi"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":876,"temperature_printed":"876","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":876},{"chemical_system":"AL-LI","cited_sources":[{"first_author":"Grube","kind":"experimental","label":"48","reference":"A. Grube, L. Mohr, and W. Breuning, Elektrische Leitfähigkeit und Zustandsdiagramm bei binären Legierungen. 17. Mitteilung. Das System Lithium–Aluminium, Z. Elektrochem., 1935, 41, p 880-883. https://doi.org/10.1002/bbpc.19350411213","status":"resolved","year":"1935"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":1.047,"dx":{"Al2Li3":0.067,"AlLi":-0.0074,"L":0.0353},"fail_reason":"composition","model":"AlLi-20Lon.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-RA66IPE7HX","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":11},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:232ba85e4082a28c","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.56},"composition_source":"printed","phase":"AlLi"},{"basis":"mole_fraction","composition":{"LI":0.78},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.667},"composition_source":"printed","phase":"Al2Li3"}],"phases":[{"label":"AlLi","mapping_confidence":"confirmed","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"},{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Al2Li3","mapping_confidence":"confirmed","model_phase":"AL2LI3","pearson_symbol":"hR5","prototype":"Al2Li3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r11#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"AlLi + L ↔ Al2Li3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":794,"temperature_printed":"794","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":794},{"chemical_system":"AL-LI","cited_sources":[{"first_author":"Shamray","kind":"unknown","label":"49","reference":"F.I. Shamray and P.Ya. Saldau, Equilibrium Diagram of the System Al-Li, Izv. Akad. Nauk SSSR, Otd. Khim., 1937, 3, p 631640","status":"resolved","year":"1937"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["label_conflicts_composition"],"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.047,"dx":{"AlLi":0.1326},"fail_reason":"composition","model":"AlLi-20Lon.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"gate_failures":[{"code":"label_conflicts_composition","detail":"AlLi printed x(LI)=0.7, formula 0.5","effect":"not_espei_ready","gate":"A1"}],"id":"ORC-J67MWTVMN5","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":12},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:639878ea89f3392b","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.7},"composition_source":"printed","phase":"AlLi"},{"basis":"mole_fraction","composition":{"LI":0.6},"composition_source":"stoichiometry","phase":"Al2Li3"}],"phases":[{"label":"AlLi","mapping_confidence":"confirmed","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"},{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Al2Li3","mapping_confidence":"confirmed","model_phase":"AL2LI3","pearson_symbol":"hR5","prototype":"Al2Li3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r12#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"AlLi + L ↔ Al2Li3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":793,"temperature_printed":"793","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":793},{"chemical_system":"AL-LI","cited_sources":[{"first_author":"Myles","kind":"unknown","label":"50","reference":"K.M. Myles, F.C. Mrazek, J.A. Smaga and J.L. Settle, in Advanced Battery Research and Design, U.S. ERDA Report ANL76-8, Proceedings of Symposium and Workshop, Argonne National Laboratory, B50 (cited from [7]), 1976 J. Phase Equilib. Diffus. (2020) 41:623–641","status":"resolved","year":"2020"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.047,"dx":{"Al2Li3":-0.0},"model":"AlLi-20Lon.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-YW22OZPLMY","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":13},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_modelling","class":"model_value","measured_in":"ref:c9e6d1b0a02f9ff9","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.5},"composition_source":"formula_nominal","phase":"AlLi"},{"basis":"mole_fraction","composition":{"LI":0.6},"composition_source":"printed","phase":"Al2Li3"}],"phases":[{"label":"AlLi","mapping_confidence":"confirmed","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"},{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Al2Li3","mapping_confidence":"confirmed","model_phase":"AL2LI3","pearson_symbol":"hR5","prototype":"Al2Li3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r13#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"AlLi + L ↔ Al2Li3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":793,"temperature_printed":"793","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":793},{"chemical_system":"AL-LI","cited_sources":[{"first_author":"Schurmann","kind":"experimental","label":"51","reference":"E. Schürmann and H.J. Voss, Investigation of the Melting Equilibria of Mg-Li-Al Alloys, Giessereiforschung, 1981, 33, p 33","status":"resolved","year":"1981"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.953,"dx":{"Al2Li3":0.067,"AlLi":0.0126,"L":0.0113},"fail_reason":"composition","model":"AlLi-20Lon.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-LGMLDVXRU4","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":14},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_is_experimental","class":"experimental","measured_in":"ref:c1884defdae4ec20","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.58},"composition_source":"printed","phase":"AlLi"},{"basis":"mole_fraction","composition":{"LI":0.756},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.667},"composition_source":"printed","phase":"Al2Li3"}],"phases":[{"label":"AlLi","mapping_confidence":"confirmed","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"},{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Al2Li3","mapping_confidence":"confirmed","model_phase":"AL2LI3","pearson_symbol":"hR5","prototype":"Al2Li3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r14#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"AlLi + L ↔ Al2Li3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":792,"temperature_printed":"792","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":792},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.3139/146.101553","first_author":"Hallstedt","kind":"assessment","label":"17","paper":"doi:10.3139/146.101553","reference":"B. Hallstedt and O. Kim, Thermodynamic Assessment of the AlLi system, Z. Metall., 2007, 98, p 961-969. https://doi.org/10. 3139/146.101553","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.047,"dx":{"Al2Li3":-0.0,"AlLi":-0.0004,"L":0.0003},"model":"AlLi-20Lon.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","source_disputed":true,"state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-ST6E2YUNY5","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":15},"model_unlinked_reason":"cited calculation matches several corpus TDBs (AlLi-07Hal-condensed.tdb, AlLi-07Hal.tdb)","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.3139/146.101553","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.567},"composition_source":"printed","phase":"AlLi"},{"basis":"mole_fraction","composition":{"LI":0.745},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.6},"composition_source":"printed","phase":"Al2Li3"}],"phases":[{"label":"AlLi","mapping_confidence":"confirmed","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"},{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Al2Li3","mapping_confidence":"confirmed","model_phase":"AL2LI3","pearson_symbol":"hR5","prototype":"Al2Li3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r15#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"AlLi + L ↔ Al2Li3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":793,"temperature_printed":"793","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":793},{"chemical_system":"AL-LI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.047,"dx":{"Al2Li3":-0.0,"AlLi":-0.0004,"L":0.0003},"model":"AlLi-20Lon.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-DKKIOJCGVH","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":16},"model":"Mb4ef1200","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-020-00827-z","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.567},"composition_source":"printed","phase":"AlLi"},{"basis":"mole_fraction","composition":{"LI":0.745},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.6},"composition_source":"printed","phase":"Al2Li3"}],"phases":[{"label":"AlLi","mapping_confidence":"confirmed","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"},{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Al2Li3","mapping_confidence":"confirmed","model_phase":"AL2LI3","pearson_symbol":"hR5","prototype":"Al2Li3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r16#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"AlLi + L ↔ Al2Li3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":793,"temperature_printed":"793","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":793},{"chemical_system":"AL-LI","cited_sources":[{"first_author":"Myles","kind":"unknown","label":"50","reference":"K.M. Myles, F.C. Mrazek, J.A. Smaga and J.L. Settle, in Advanced Battery Research and Design, U.S. ERDA Report ANL76-8, Proceedings of Symposium and Workshop, Argonne National Laboratory, B50 (cited from [7]), 1976 J. Phase Equilib. Diffus. (2020) 41:623–641","status":"resolved","year":"2020"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-562NYVNFGR","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":17},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_modelling","class":"model_value","measured_in":"ref:c9e6d1b0a02f9ff9","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.6},"composition_source":"printed","phase":"Al2Li3"},{"basis":"mole_fraction","composition":{"LI":0.692},"composition_source":"printed","phase":"Al4Li9"}],"phases":[{"label":"Al2Li3","mapping_confidence":"confirmed","model_phase":"AL2LI3","pearson_symbol":"hR5","prototype":"Al2Li3","structure_basis":"mapped_model_phase"},{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Al4Li9","mapping_confidence":"confirmed","model_phase":"AL4LI9","pearson_symbol":"mC26","prototype":"Al4Li9","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r17#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Al2Li3 + L ↔ Al4Li9"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":608,"temperature_printed":"608","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":608},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1007/bf02647619","first_author":"Pulham","kind":"experimental","label":"52","paper":"doi:10.1007/bf02647619","reference":"R.J. Pulham, P. Hubberstey, and P. Hemptenmacher, Solutions of Aluminum in Liquid Lithium: Contribution to the Li-Al Phase Diagram, JPE, 1994, 15, p 587-590. https://doi.org/10.1007/ BF02647619","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["composition_outside_unit_interval"],"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"gate_failures":[{"code":"composition_outside_unit_interval","detail":"stored as a mole fraction outside [0, 1]: L LI=9.208 (raw percentage or mass-to-mole conversion error)","effect":"not_accepted","gate":"A1"}],"id":"ORC-FCQZCMLZ6M","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":18},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_is_experimental","class":"experimental","measured_in":"doi:10.1007/bf02647619","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.6},"composition_source":"printed","phase":"Al2Li3"},{"basis":"unresolved","composition":{"LI":9.208},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.692},"composition_source":"printed","phase":"Al4Li9"}],"phases":[{"label":"Al2Li3","mapping_confidence":"confirmed","model_phase":"AL2LI3","pearson_symbol":"hR5","prototype":"Al2Li3","structure_basis":"mapped_model_phase"},{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Al4Li9","mapping_confidence":"confirmed","model_phase":"AL4LI9","pearson_symbol":"mC26","prototype":"Al4Li9","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r18#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Al2Li3 + L ↔ Al4Li9"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":620,"temperature_printed":"620","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":620},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.3139/146.101553","first_author":"Hallstedt","kind":"assessment","label":"17","paper":"doi:10.3139/146.101553","reference":"B. Hallstedt and O. Kim, Thermodynamic Assessment of the AlLi system, Z. Metall., 2007, 98, p 961-969. https://doi.org/10. 3139/146.101553","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","source_disputed":true,"state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-J46PEAUI3T","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":19},"model_unlinked_reason":"cited calculation matches several corpus TDBs (AlLi-07Hal-condensed.tdb, AlLi-07Hal.tdb)","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.3139/146.101553","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.6},"composition_source":"printed","phase":"Al2Li3"},{"basis":"mole_fraction","composition":{"LI":0.916},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.6923076923},"composition_source":"stoichiometry","phase":"Al4Li9"}],"phases":[{"label":"Al2Li3","mapping_confidence":"confirmed","model_phase":"AL2LI3","pearson_symbol":"hR5","prototype":"Al2Li3","structure_basis":"mapped_model_phase"},{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Al4Li9","mapping_confidence":"confirmed","model_phase":"AL4LI9","pearson_symbol":"mC26","prototype":"Al4Li9","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r19#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Al2Li3 + L ↔ Al4Li9"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":610,"temperature_printed":"610","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":610},{"chemical_system":"AL-LI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-4X5SS3X5PG","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":20},"model":"Mca4c82bc","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-020-00827-z","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.6},"composition_source":"printed","phase":"Al2Li3"},{"basis":"mole_fraction","composition":{"LI":0.916},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.6923076923},"composition_source":"stoichiometry","phase":"Al4Li9"}],"phases":[{"label":"Al2Li3","mapping_confidence":"confirmed","model_phase":"AL2LI3","pearson_symbol":"hR5","prototype":"Al2Li3","structure_basis":"mapped_model_phase"},{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Al4Li9","mapping_confidence":"confirmed","model_phase":"AL4LI9","pearson_symbol":"mC26","prototype":"Al4Li9","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r20#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Al2Li3 + L ↔ Al4Li9"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":610,"temperature_printed":"610","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":610},{"chemical_system":"AL-LI","cited_sources":[{"first_author":"Myles","kind":"unknown","label":"50","reference":"K.M. Myles, F.C. Mrazek, J.A. Smaga and J.L. Settle, in Advanced Battery Research and Design, U.S. ERDA Report ANL76-8, Proceedings of Symposium and Workshop, Argonne National Laboratory, B50 (cited from [7]), 1976 J. Phase Equilib. Diffus. (2020) 41:623–641","status":"resolved","year":"2020"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.722,"dx":{"Al4Li9":-0.0003},"model":"AlLi-20Lon.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-AEJRAOFBIN","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":21},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_modelling","class":"model_value","measured_in":"ref:c9e6d1b0a02f9ff9","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.692},"composition_source":"printed","phase":"Al4Li9"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Al4Li9","mapping_confidence":"confirmed","model_phase":"AL4LI9","pearson_symbol":"mC26","prototype":"Al4Li9","structure_basis":"mapped_model_phase"},{"label":"bcc(Li)","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r21#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Al4Li9 ↔ bcc(Li)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":453,"temperature_printed":"453","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":453},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1007/bf02647619","first_author":"Pulham","kind":"experimental","label":"52","paper":"doi:10.1007/bf02647619","reference":"R.J. Pulham, P. Hubberstey, and P. Hemptenmacher, Solutions of Aluminum in Liquid Lithium: Contribution to the Li-Al Phase Diagram, JPE, 1994, 15, p 587-590. https://doi.org/10.1007/ BF02647619","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":1.322,"dx":{"Al4Li9":-0.0003,"bcc(Li)":-0.0017},"model":"AlLi-20Lon.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-JY3ZN7WAT6","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":22},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_is_experimental","class":"experimental","measured_in":"doi:10.1007/bf02647619","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.692},"composition_source":"printed","phase":"Al4Li9"},{"basis":"mole_fraction","composition":{"LI":0.994},"composition_source":"printed","phase":"bcc(Li)"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Al4Li9","mapping_confidence":"confirmed","model_phase":"AL4LI9","pearson_symbol":"mC26","prototype":"Al4Li9","structure_basis":"mapped_model_phase"},{"label":"bcc(Li)","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r22#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Al4Li9 ↔ bcc(Li)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":453.6,"temperature_printed":"453.6","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":453.6},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.3139/146.101553","first_author":"Hallstedt","kind":"assessment","label":"17","paper":"doi:10.3139/146.101553","reference":"B. Hallstedt and O. Kim, Thermodynamic Assessment of the AlLi system, Z. Metall., 2007, 98, p 961-969. https://doi.org/10. 3139/146.101553","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.022,"dx":{"Al4Li9":-0.0003,"L":0.0026,"bcc(Li)":-0.0025},"model":"AlLi-20Lon.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","source_disputed":true,"state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-K4N7FI3P47","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":23},"model_unlinked_reason":"cited calculation matches several corpus TDBs (AlLi-07Hal-condensed.tdb, AlLi-07Hal.tdb)","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.3139/146.101553","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.9957},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.692},"composition_source":"printed","phase":"Al4Li9"},{"basis":"mole_fraction","composition":{"LI":0.9932},"composition_source":"printed","phase":"bcc(Li)"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Al4Li9","mapping_confidence":"confirmed","model_phase":"AL4LI9","pearson_symbol":"mC26","prototype":"Al4Li9","structure_basis":"mapped_model_phase"},{"label":"bcc(Li)","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r23#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Al4Li9 ↔ bcc(Li)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":452.3,"temperature_printed":"452.3","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":452.3},{"chemical_system":"AL-LI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.022,"dx":{"Al4Li9":-0.0003,"L":0.0026,"bcc(Li)":-0.0025},"model":"AlLi-20Lon.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-45EKEUSETE","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":24},"model":"Mb4ef1200","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-020-00827-z","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.9957},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.692},"composition_source":"printed","phase":"Al4Li9"},{"basis":"mole_fraction","composition":{"LI":0.9932},"composition_source":"printed","phase":"bcc(Li)"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Al4Li9","mapping_confidence":"confirmed","model_phase":"AL4LI9","pearson_symbol":"mC26","prototype":"Al4Li9","structure_basis":"mapped_model_phase"},{"label":"bcc(Li)","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r24#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Al4Li9 ↔ bcc(Li)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":452.3,"temperature_printed":"452.3","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":452.3},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1016/j.jssc.2010.08.029","first_author":"Puhakainen","kind":"experimental","label":"9","paper":"doi:10.1016/j.jssc.2010.08.029","reference":"K. Puhakainen, M. Boström, T.L. Groy, and U. Häussermann, A New Phase in the System Lithium–Aluminum: Characterization of Orthorhombic Li2Al, J. Solid State Chem., 2010, 183, p 25282533. https://doi.org/10.1016/j.jssc.2010.08.029","status":"resolved","year":"2010"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-1.049,"dx":{"Al2Li3":-0.0,"AlLi2":-0.0098,"L":-0.0212},"model":"AlLi-20Lon.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-MUEFNSQVSU","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":25},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","measured_in":"doi:10.1016/j.jssc.2010.08.029","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.6},"composition_source":"printed","phase":"Al2Li3"},{"basis":"mole_fraction","composition":{"LI":0.895},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.642},"composition_source":"printed","phase":"AlLi2"}],"phases":[{"label":"Al2Li3","mapping_confidence":"confirmed","model_phase":"AL2LI3","pearson_symbol":"hR5","prototype":"Al2Li3","structure_basis":"mapped_model_phase"},{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"AlLi2","mapping_confidence":"confirmed","model_phase":"ALLI2","pearson_symbol":"oC12","prototype":"GaLi2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r25#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Al2Li3 + L ↔ AlLi2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":608,"temperature_printed":"608","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":608},{"chemical_system":"AL-LI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-1.049,"dx":{"Al2Li3":-0.0,"AlLi2":-0.0008,"L":-0.0032},"model":"AlLi-20Lon.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-B5PSSHNXKB","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":26},"model":"Mb4ef1200","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-020-00827-z","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.6},"composition_source":"printed","phase":"Al2Li3"},{"basis":"mole_fraction","composition":{"LI":0.913},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.651},"composition_source":"printed","phase":"AlLi2"}],"phases":[{"label":"Al2Li3","mapping_confidence":"confirmed","model_phase":"AL2LI3","pearson_symbol":"hR5","prototype":"Al2Li3","structure_basis":"mapped_model_phase"},{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"AlLi2","mapping_confidence":"confirmed","model_phase":"ALLI2","pearson_symbol":"oC12","prototype":"GaLi2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r26#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Al2Li3 + L ↔ AlLi2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":608,"temperature_printed":"608","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":608},{"chemical_system":"AL-LI","cited_sources":[{"doi":"10.1016/j.jssc.2010.08.029","first_author":"Puhakainen","kind":"experimental","label":"9","paper":"doi:10.1016/j.jssc.2010.08.029","reference":"K. Puhakainen, M. Boström, T.L. Groy, and U. Häussermann, A New Phase in the System Lithium–Aluminum: Characterization of Orthorhombic Li2Al, J. Solid State Chem., 2010, 183, p 25282533. https://doi.org/10.1016/j.jssc.2010.08.029","status":"resolved","year":"2010"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-2.863,"dx":{"Al4Li9":-0.0003,"AlLi2":0.0051,"L":-0.0162},"model":"AlLi-20Lon.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-3XB46JIMSK","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":27},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","measured_in":"doi:10.1016/j.jssc.2010.08.029","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.95},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.663},"composition_source":"printed","phase":"AlLi2"},{"basis":"mole_fraction","composition":{"LI":0.692},"composition_source":"printed","phase":"Al4Li9"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"AlLi2","mapping_confidence":"confirmed","model_phase":"ALLI2","pearson_symbol":"oC12","prototype":"GaLi2","structure_basis":"mapped_model_phase"},{"label":"Al4Li9","mapping_confidence":"confirmed","model_phase":"AL4LI9","pearson_symbol":"mC26","prototype":"Al4Li9","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r27#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + AlLi2 ↔ Al4Li9"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":543,"temperature_printed":"543","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":543},{"chemical_system":"AL-LI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.863,"dx":{"Al4Li9":-0.0003,"AlLi2":0.0001,"L":-0.0032},"model":"AlLi-20Lon.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":2,"id":"ORC-NJLBBTSRV3","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p5/tab-3","row":28},"model":"Mb4ef1200","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-020-00827-z","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.963},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"LI":0.658},"composition_source":"printed","phase":"AlLi2"},{"basis":"mole_fraction","composition":{"LI":0.692},"composition_source":"printed","phase":"Al4Li9"}],"phases":[{"label":"L","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"AlLi2","mapping_confidence":"confirmed","model_phase":"ALLI2","pearson_symbol":"oC12","prototype":"GaLi2","structure_basis":"mapped_model_phase"},{"label":"Al4Li9","mapping_confidence":"confirmed","model_phase":"AL4LI9","pearson_symbol":"mC26","prototype":"Al4Li9","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-020-00827-z/p5/tab-3/r28#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + AlLi2 ↔ Al4Li9"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":545,"temperature_printed":"545","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":545},{"chemical_system":"AL-LI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"model","before":"unspecified","evidence":{"source":"I. Ansara, A. T. Dinsdale, M. H. Rand (eds.), COST 507: Thermochemical database for light metal alloys, Volume 2, EUR 18","why":"the book is the documentation of the COST 507 assessed light-alloy database; its invariant tables list the reactions calculated from the assessed descriptions (Cu-Zr Table I p210 page-checked: no measured / calculated column, values of the assessment); values whose class the readers left unspecified are model"},"field":"evidence_class","gate":"R3","rule":"assessed_database_values","visual_check":{"checked":"2026-10-24","image_sha256":"3ff5715e8c11f6a96cefdf5a6d7080f9698fcbc8fdb7381d535c8549984d9634","page":210,"pdf_sha256_prefix":"85fd53a1a176b694","seen":"COST 507 vol. 2 (assessed light-alloy database): Cu-Zr Table I p210 lists the invariant reactions of the assessment (no measured column); Al-Nb Table I p89 likewise.","verdict":"rule_confirmed"}},{"after":["Liquid","AlLi","fcc-A1"],"before":["Liquid","fcc-Al","AlLi","fcc-A1"],"evidence":{"dropped":{"fcc-Al":"misread duplicate of 'fcc-A1' (Strukturbericht A1 italic); page prints Liquid ⇌ fcc-A1 + AlLi"}},"field":"phases","gate":"G6","rule":"non_phase_labels_dropped_on_page","visual_check":{"checked":"2026-10-24","image_sha256":"52bb172718f5322e58c5bb987d49ad7bea3558c0781d938f06e6ee3149179c76","page":58,"pdf_sha256_prefix":"85fd53a1a176b694","seen":"COST507 Table I Invariant Reactions (Al-Li): Liquid ⇌ fcc-A1 + AlLi Eutectic, x_Li .256 .155 .462, 868.8 K","verdict":"checked"}}],"evidence_class":"model","evidence_class_before_gates":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":2,"fold_lso":2,"id":"ORC-3JQQVIZKIJ","locator":{"ref":"sha256:85fd53a1a176b694/p58/tab-i","row":1},"observation_type":"invariant_reaction","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","class_gate":"model","measured_in":"sha256:85fd53a1a176b694","own_work_of_paper":true},"paper":"sha256:85fd53a1a176b694","paper_id":"sha256:85fd53a1a176b694","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.256},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"LI":0.462},"composition_source":"printed","phase":"AlLi"},{"basis":"mole_fraction","composition":{"LI":0.155},"composition_source":"printed","phase":"fcc-A1"}],"phase_compositions_dropped":[{"basis":"mole_fraction","composition":{"LI":0.155},"composition_source":"printed","phase":"fcc-Al"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"AlLi","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"},{"label":"fcc-A1","model_phase":"A1_FCC"}],"phases_dropped":[{"label":"fcc-Al","reason":"not a phase of the row on the page: misread duplicate of 'fcc-A1' (Strukturbericht A1 italic); page prints Liquid ⇌ fcc-A1 + AlLi"}],"phases_stored":["Liquid","fcc-Al","AlLi","fcc-A1"],"pid":"sha256:85fd53a1a176b694/p58/tab-i/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid -> fcc-Al + AlLi","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":868.8,"temperature_printed":"868.8","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":868.8},{"chemical_system":"AL-LI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"model","before":"unspecified","evidence":{"source":"I. Ansara, A. T. Dinsdale, M. H. Rand (eds.), COST 507: Thermochemical database for light metal alloys, Volume 2, EUR 18","why":"the book is the documentation of the COST 507 assessed light-alloy database; its invariant tables list the reactions calculated from the assessed descriptions (Cu-Zr Table I p210 page-checked: no measured / calculated column, values of the assessment); values whose class the readers left unspecified are model"},"field":"evidence_class","gate":"R3","rule":"assessed_database_values","visual_check":{"checked":"2026-10-24","image_sha256":"3ff5715e8c11f6a96cefdf5a6d7080f9698fcbc8fdb7381d535c8549984d9634","page":210,"pdf_sha256_prefix":"85fd53a1a176b694","seen":"COST 507 vol. 2 (assessed light-alloy database): Cu-Zr Table I p210 lists the invariant reactions of the assessment (no measured column); Al-Nb Table I p89 likewise.","verdict":"rule_confirmed"}}],"evidence_class":"model","evidence_class_before_gates":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-E2X7E5M3OR","locator":{"ref":"sha256:85fd53a1a176b694/p58/tab-i","row":2},"observation_type":"invariant_reaction","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","class_gate":"model","measured_in":"sha256:85fd53a1a176b694","own_work_of_paper":true},"paper":"sha256:85fd53a1a176b694","paper_id":"sha256:85fd53a1a176b694","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.775},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"LI":0.555},"composition_source":"printed","phase":"AlLi"},{"basis":"mole_fraction","composition":{"LI":0.6},"composition_source":"printed","phase":"Al2Li3"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"AlLi","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"},{"label":"Al2Li3","model_phase":"AL2LI3","pearson_symbol":"hR5","prototype":"Al2Li3","structure_basis":"mapped_model_phase"}],"pid":"sha256:85fd53a1a176b694/p58/tab-i/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + AlLi -> Al2Li3","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":793.6,"temperature_printed":"793.6","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":793.6},{"chemical_system":"AL-LI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"model","before":"unspecified","evidence":{"source":"I. Ansara, A. T. Dinsdale, M. H. Rand (eds.), COST 507: Thermochemical database for light metal alloys, Volume 2, EUR 18","why":"the book is the documentation of the COST 507 assessed light-alloy database; its invariant tables list the reactions calculated from the assessed descriptions (Cu-Zr Table I p210 page-checked: no measured / calculated column, values of the assessment); values whose class the readers left unspecified are model"},"field":"evidence_class","gate":"R3","rule":"assessed_database_values","visual_check":{"checked":"2026-10-24","image_sha256":"3ff5715e8c11f6a96cefdf5a6d7080f9698fcbc8fdb7381d535c8549984d9634","page":210,"pdf_sha256_prefix":"85fd53a1a176b694","seen":"COST 507 vol. 2 (assessed light-alloy database): Cu-Zr Table I p210 lists the invariant reactions of the assessment (no measured column); Al-Nb Table I p89 likewise.","verdict":"rule_confirmed"}}],"evidence_class":"model","evidence_class_before_gates":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-LOXXLCR6XR","locator":{"ref":"sha256:85fd53a1a176b694/p58/tab-i","row":3},"observation_type":"invariant_reaction","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","class_gate":"model","measured_in":"sha256:85fd53a1a176b694","own_work_of_paper":true},"paper":"sha256:85fd53a1a176b694","paper_id":"sha256:85fd53a1a176b694","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.912},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"LI":0.6},"composition_source":"printed","phase":"Al2Li3"},{"basis":"mole_fraction","composition":{"LI":0.692},"composition_source":"printed","phase":"Al4Li9"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Al2Li3","model_phase":"AL2LI3","pearson_symbol":"hR5","prototype":"Al2Li3","structure_basis":"mapped_model_phase"},{"label":"Al4Li9","model_phase":"AL4LI9","pearson_symbol":"mC26","prototype":"Al4Li9","structure_basis":"mapped_model_phase"}],"pid":"sha256:85fd53a1a176b694/p58/tab-i/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + Al2Li3 -> Al4Li9","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":607.6,"temperature_printed":"607.6","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":607.6},{"chemical_system":"AL-LI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"model","before":"unspecified","evidence":{"source":"I. Ansara, A. T. Dinsdale, M. H. Rand (eds.), COST 507: Thermochemical database for light metal alloys, Volume 2, EUR 18","why":"the book is the documentation of the COST 507 assessed light-alloy database; its invariant tables list the reactions calculated from the assessed descriptions (Cu-Zr Table I p210 page-checked: no measured / calculated column, values of the assessment); values whose class the readers left unspecified are model"},"field":"evidence_class","gate":"R3","rule":"assessed_database_values","visual_check":{"checked":"2026-10-24","image_sha256":"3ff5715e8c11f6a96cefdf5a6d7080f9698fcbc8fdb7381d535c8549984d9634","page":210,"pdf_sha256_prefix":"85fd53a1a176b694","seen":"COST 507 vol. 2 (assessed light-alloy database): Cu-Zr Table I p210 lists the invariant reactions of the assessment (no measured column); Al-Nb Table I p89 likewise.","verdict":"rule_confirmed"}}],"evidence_class":"model","evidence_class_before_gates":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-KVKU5EYDIZ","locator":{"ref":"sha256:85fd53a1a176b694/p58/tab-i","row":4},"observation_type":"invariant_reaction","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","class_gate":"model","measured_in":"sha256:85fd53a1a176b694","own_work_of_paper":true},"paper":"sha256:85fd53a1a176b694","paper_id":"sha256:85fd53a1a176b694","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.989},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"LI":0.692},"composition_source":"printed","phase":"Al4Li9"},{"basis":"mole_fraction","composition":{"LI":0.999},"composition_source":"printed","phase":"bcc-A2"}],"phases":[{"label":"Liquid","model_phase":"LIQUID"},{"label":"Al4Li9","model_phase":"AL4LI9","pearson_symbol":"mC26","prototype":"Al4Li9","structure_basis":"mapped_model_phase"},{"label":"bcc-A2","model_phase":"A2_BCC"}],"pid":"sha256:85fd53a1a176b694/p58/tab-i/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid -> Al4Li9 + bcc-A2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":447.8,"temperature_printed":"447.8","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":447.8},{"chemical_system":"AL-LI","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"model","before":"unspecified","evidence":{"source":"I. Ansara, A. T. Dinsdale, M. H. Rand (eds.), COST 507: Thermochemical database for light metal alloys, Volume 2, EUR 18","why":"the book is the documentation of the COST 507 assessed light-alloy database; its invariant tables list the reactions calculated from the assessed descriptions (Cu-Zr Table I p210 page-checked: no measured / calculated column, values of the assessment); values whose class the readers left unspecified are model"},"field":"evidence_class","gate":"R3","rule":"assessed_database_values","visual_check":{"checked":"2026-10-24","image_sha256":"3ff5715e8c11f6a96cefdf5a6d7080f9698fcbc8fdb7381d535c8549984d9634","page":210,"pdf_sha256_prefix":"85fd53a1a176b694","seen":"COST 507 vol. 2 (assessed light-alloy database): Cu-Zr Table I p210 lists the invariant reactions of the assessment (no measured column); Al-Nb Table I p89 likewise.","verdict":"rule_confirmed"}}],"evidence_class":"model","evidence_class_before_gates":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-Y26UWOHZTX","locator":{"ref":"sha256:85fd53a1a176b694/p58/tab-i","row":5},"observation_type":"invariant_reaction","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","class_gate":"model","measured_in":"sha256:85fd53a1a176b694","own_work_of_paper":true},"paper":"sha256:85fd53a1a176b694","paper_id":"sha256:85fd53a1a176b694","phase_compositions":[{"basis":"mole_fraction","composition":{"LI":0.5},"composition_source":"printed","phase":"AlLi"},{"basis":"mole_fraction","composition":{"LI":0.5},"composition_source":"printed","phase":"Liquid"}],"phases":[{"label":"AlLi","model_phase":"BCC_4SL","pearson_symbol":"cF16","prototype":"NaTl","structure_basis":"mapped_model_phase"},{"label":"Liquid","model_phase":"LIQUID"}],"pid":"sha256:85fd53a1a176b694/p58/tab-i/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"AlLi -> Liquid","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-LI","system":"AL-LI","temperature_K":978.0,"temperature_printed":"978.0","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":978.0},{"chemical_system":"AL-LI","citations_printed":["9"],"cited_sources":[{"doi":"10.1016/j.jssc.2010.08.029","first_author":"Puhakainen","kind":"unknown","label":"9","paper":"doi:10.1016/j.jssc.2010.08.029","reference":"K. Puhakainen, M. Boström, T.L. Groy, and U. Häussermann, A New Phase in the System Lithium–Aluminum: Characterization of Orthorhombic Li2Al, J. Solid State Chem., 2010, 183, p 25282533. https://doi.org/10.1016/j.jssc.2010.08.029","status":"resolved","year":"2010"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-YS3DFAYWO7","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-020-00827-z/p4/text-02"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1016/j.jssc.2010.08.029","own_work_of_paper":false},"paper":"doi:10.1007/s11669-020-00827-z","paper_id":"doi:10.1007/s11669-020-00827-z","pid":"doi:10.1007/s11669-020-00827-z/p4/text-02/s05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"AlLi2 is formed by a peritectic reaction of Al2Li3 with liquid at about 608 K.","quote_page":4,"reaction":{"printed":"Al2Li3 + liquid -> AlLi2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-LI","system":"AL-LI","temperature_K":608.0,"temperature_printed":"608 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":608.0},{"chemical_system":"AL-LI","citations_printed":["13"],"cited_sources":[{"first_author":"Badaeva","kind":"unknown","label":"13","reference":"T.A. Badaeva, P.Ya. Saldau, Zh. Obshch. Khim. 12 (1943) 643.","status":"resolved","year":"1943"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-KKXM3ILVUW","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2010.11.006/p10/text-27"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2010.11.006","paper_id":"doi:10.1016/j.calphad.2010.11.006","pid":"doi:10.1016/j.calphad.2010.11.006/p10/text-27/s08#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"If the composition of Zn in AlLi is changed from 0.01 at.% (the present result) to 2 at.% at 470 K, the homogeneity range of Zn in AlLi and τ2 will become worse in comparison with the reviewed results [23] and the reaction temperature of liq. + AlLi → τ 1 decreases to 820 K, which was 853 K reported by Badaeva and Saldau [13].","quote_page":10,"reaction":{"printed":"liq. + AlLi → τ 1"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-LI","system":"AL-LI","temperature_K":853.0,"temperature_printed":"853 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":853.0},{"chemical_system":"AL-LI","citations_printed":["17"],"cited_sources":[{"first_author":"Ghosh","kind":"assessment","label":"17","reference":"G. Ghosh, in: Landolt–Bornstein, Group IV, Physical Chemistry, Berlin Heidelberg, 2005.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-UUPVRVRFUO.266251","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2011.09.003/p7/text-08"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2011.09.003","paper_id":"doi:10.1016/j.calphad.2011.09.003","pid":"doi:10.1016/j.calphad.2011.09.003/p7/text-08/s21#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"In the Li-rich corner without experimental data, the present calculation shows that Al4 Li9 is formed by a transition reaction L + Al2 Li3 = Al4 Li9 + (Li) at 195 °C, which is much lower than the assessed temperature 350 °C by Ghosh [17].","quote_page":7,"reaction":{"printed":"L + Al2 Li3 = Al4 Li9 + (Li)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-LI","system":"AL-LI","temperature_K":623.15,"temperature_printed":"350","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":623.15},{"chemical_system":"AL-LI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-UUPVRVRFUO.b35520","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2011.09.003/p7/text-08"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.calphad.2011.09.003","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2011.09.003","paper_id":"doi:10.1016/j.calphad.2011.09.003","pid":"doi:10.1016/j.calphad.2011.09.003/p7/text-08/s21#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"In the Li-rich corner without experimental data, the present calculation shows that Al4 Li9 is formed by a transition reaction L + Al2 Li3 = Al4 Li9 + (Li) at 195 °C, which is much lower than the assessed temperature 350 °C by Ghosh [17].","quote_page":7,"reaction":{"printed":"L + Al2 Li3 = Al4 Li9 + (Li)"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-LI","system":"AL-LI","temperature_K":468.15,"temperature_printed":"195","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":468.15}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"AL-LI"}