{"artifacts":{"doi:10.1007/bf02646133/p1/text-01":{"artifact":"text_passage","label":"page 1, passage 1","page":1},"doi:10.1007/bf02646133/p1/text-06":{"artifact":"text_passage","label":"page 1, passage 6","page":1},"doi:10.1007/bf02646133/p4/text-07":{"artifact":"text_passage","label":"page 4, passage 7","page":4},"doi:10.1007/bf02646133/p5/text-01":{"artifact":"text_passage","label":"page 5, passage 1","page":5},"doi:10.1007/bf02646133/p7/text-73":{"artifact":"text_passage","label":"page 7, passage 73","page":7},"doi:10.1007/s11669-012-0073-5/p10/text-73":{"artifact":"text_passage","label":"page 10, passage 73","page":10},"doi:10.1007/s11669-012-0073-5/p5/text-36":{"artifact":"text_passage","label":"page 5, passage 36","page":5},"doi:10.1007/s11669-012-0073-5/p8/tab-4":{"artifact":"table","caption":"Comparison of the calculated solubility of N in molten Al with literature data","label":"4","page":8},"sha256:26ebd8cbe2163f4b/p18/tab-ai":{"artifact":"table","caption":"Experimental, estimated, and optimized thermodynamic data for III-V nitride phases.","label":"AI","page":18}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["AL","N"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/bf02646133":{"authors":["Mats Hillert","Stefan Jonsson"],"citation":"Mats Hillert, Stefan Jonsson, An Assessment of the Al- Fe- N System, Metall Trans A 23, 3141-3149 (1992).","container":"Metall Trans A","doi":"10.1007/bf02646133","doi_url":"https://doi.org/10.1007/bf02646133","id":"doi:10.1007/bf02646133","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"df38cd552889f650","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"An Assessment of the Al- Fe- N System","year":1992},"doi:10.1007/s11669-012-0073-5":{"authors":["D. Pavlyuchkov","O. Fabrichnaya","M. Herrmann","H. J. Seifert"],"citation":"D. Pavlyuchkov, O. Fabrichnaya, M. Herrmann, H. J. Seifert, Thermodynamic Assessments of the Al2O3-Al4C3-AlN and Al4C3-AlN-SiC Systems, J. Phase Equilib. Diffus. 33, 357-368 (2012).","container":"J. Phase Equilib. Diffus.","doi":"10.1007/s11669-012-0073-5","doi_url":"https://doi.org/10.1007/s11669-012-0073-5","id":"doi:10.1007/s11669-012-0073-5","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"6c0ea812f48bd35d","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic Assessments of the Al2O3-Al4C3-AlN and Al4C3-AlN-SiC Systems","year":2012},"doi:10.1557/jmr.2002.0445":{"authors":["B. Onderka","J. Unland","R. Schmid-Fetzer"],"citation":"B. Onderka, J. Unland, R. Schmid-Fetzer, Thermodynamics and phase stability in the In–N system, J. Mater. Res. 17, 3065-3083 (2002).","container":"J. Mater. Res.","doi":"10.1557/jmr.2002.0445","doi_url":"https://doi.org/10.1557/jmr.2002.0445","id":"doi:10.1557/jmr.2002.0445","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"26ebd8cbe2163f4b","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamics and phase stability in the In–N system","year":2002}},"part":1,"parts":1,"records":[{"chemical_system":"AL-N","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-012-0073-5"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":2,"id":"ORC-3FSJU2W3H5","locator":{"ref":"doi:10.1007/s11669-012-0073-5/p8/tab-4","row":1},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-012-0073-5","own_work_of_paper":true},"paper":"doi:10.1007/s11669-012-0073-5","paper_id":"doi:10.1007/s11669-012-0073-5","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":1.0,"N":0.0},"composition_source":"printed","phase":"molten Al"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":1.0,"N":0.0},"composition_source":"printed","phase":"liquid Al"}],"phases":[{"label":"molten Al"},{"label":"liquid Al"}],"pid":"doi:10.1007/s11669-012-0073-5/p8/tab-4/r01#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-N","system":"AL-N","temperature_K":923.15,"temperature_basis":"printed","temperature_printed":"650","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AL-N","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-012-0073-5"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":2,"id":"ORC-T3H62NK6L4","locator":{"ref":"doi:10.1007/s11669-012-0073-5/p8/tab-4","row":2},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-012-0073-5","own_work_of_paper":true},"paper":"doi:10.1007/s11669-012-0073-5","paper_id":"doi:10.1007/s11669-012-0073-5","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.56,"N":0.44},"composition_source":"printed","phase":"molten Al"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.56,"N":0.44},"composition_source":"printed","phase":"liquid Al"}],"phases":[{"label":"molten Al"},{"label":"liquid Al"}],"pid":"doi:10.1007/s11669-012-0073-5/p8/tab-4/r02#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-N","system":"AL-N","temperature_K":1173.15,"temperature_basis":"printed","temperature_printed":"900","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AL-N","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-012-0073-5"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":2,"id":"ORC-6UYJKZKJNF","locator":{"ref":"doi:10.1007/s11669-012-0073-5/p8/tab-4","row":3},"merged_ids":["ORC-UMAXJUAGYA"],"merged_pids":["doi:10.1007/s11669-012-0073-5/p8/tab-4/r14#phase_region_vertex_set"],"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-012-0073-5","own_work_of_paper":true},"paper":"doi:10.1007/s11669-012-0073-5","paper_id":"doi:10.1007/s11669-012-0073-5","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.3,"N":0.7},"composition_source":"printed","phase":"molten Al"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.3,"N":0.7},"composition_source":"printed","phase":"liquid Al"}],"phases":[{"label":"molten Al"},{"label":"liquid Al"}],"pid":"doi:10.1007/s11669-012-0073-5/p8/tab-4/r03#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-N","system":"AL-N","temperature_K":1473.15,"temperature_basis":"printed","temperature_printed":"1200","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AL-N","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-012-0073-5"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":2,"id":"ORC-463AUQ3OAS","locator":{"ref":"doi:10.1007/s11669-012-0073-5/p8/tab-4","row":4},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-012-0073-5","own_work_of_paper":true},"paper":"doi:10.1007/s11669-012-0073-5","paper_id":"doi:10.1007/s11669-012-0073-5","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.04,"N":0.96},"composition_source":"printed","phase":"molten Al"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.04,"N":0.96},"composition_source":"printed","phase":"liquid Al"}],"phases":[{"label":"molten Al"},{"label":"liquid Al"}],"pid":"doi:10.1007/s11669-012-0073-5/p8/tab-4/r04#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-N","system":"AL-N","temperature_K":1773.15,"temperature_basis":"printed","temperature_printed":"1500","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AL-N","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-012-0073-5"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":2,"id":"ORC-ZVET4JTZ4J","locator":{"ref":"doi:10.1007/s11669-012-0073-5/p8/tab-4","row":5},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-012-0073-5","own_work_of_paper":true},"paper":"doi:10.1007/s11669-012-0073-5","paper_id":"doi:10.1007/s11669-012-0073-5","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.73,"N":0.27},"composition_source":"printed","phase":"molten Al"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.73,"N":0.27},"composition_source":"printed","phase":"liquid Al"}],"phases":[{"label":"molten Al"},{"label":"liquid Al"}],"pid":"doi:10.1007/s11669-012-0073-5/p8/tab-4/r05#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-N","system":"AL-N","temperature_K":963.15,"temperature_basis":"printed","temperature_printed":"690","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AL-N","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-012-0073-5"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":2,"id":"ORC-UH2ZDDWHD2","locator":{"ref":"doi:10.1007/s11669-012-0073-5/p8/tab-4","row":6},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-012-0073-5","own_work_of_paper":true},"paper":"doi:10.1007/s11669-012-0073-5","paper_id":"doi:10.1007/s11669-012-0073-5","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.68,"N":0.32},"composition_source":"printed","phase":"molten Al"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.68,"N":0.32},"composition_source":"printed","phase":"liquid Al"}],"phases":[{"label":"molten Al"},{"label":"liquid Al"}],"pid":"doi:10.1007/s11669-012-0073-5/p8/tab-4/r06#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-N","system":"AL-N","temperature_K":1033.15,"temperature_basis":"printed","temperature_printed":"760","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AL-N","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-012-0073-5"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":2,"id":"ORC-UY62PLEW2D","locator":{"ref":"doi:10.1007/s11669-012-0073-5/p8/tab-4","row":8},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-012-0073-5","own_work_of_paper":true},"paper":"doi:10.1007/s11669-012-0073-5","paper_id":"doi:10.1007/s11669-012-0073-5","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.53,"N":0.47},"composition_source":"printed","phase":"molten Al"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.53,"N":0.47},"composition_source":"printed","phase":"liquid Al"}],"phases":[{"label":"molten Al"},{"label":"liquid Al"}],"pid":"doi:10.1007/s11669-012-0073-5/p8/tab-4/r08#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-N","system":"AL-N","temperature_K":1203.15,"temperature_basis":"printed","temperature_printed":"930","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AL-N","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-012-0073-5"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":2,"id":"ORC-2YKHUHSMHQ","locator":{"ref":"doi:10.1007/s11669-012-0073-5/p8/tab-4","row":9},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-012-0073-5","own_work_of_paper":true},"paper":"doi:10.1007/s11669-012-0073-5","paper_id":"doi:10.1007/s11669-012-0073-5","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.55,"N":0.45},"composition_source":"printed","phase":"molten Al"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.55,"N":0.45},"composition_source":"printed","phase":"liquid Al"}],"phases":[{"label":"molten Al"},{"label":"liquid Al"}],"pid":"doi:10.1007/s11669-012-0073-5/p8/tab-4/r09#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-N","system":"AL-N","temperature_K":660.0,"temperature_basis":"printed_bound","temperature_bound":{"op":">","value_K":660.0},"tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AL-N","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-012-0073-5"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":2,"id":"ORC-JHSN2KNOM3","locator":{"ref":"doi:10.1007/s11669-012-0073-5/p8/tab-4","row":10},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-012-0073-5","own_work_of_paper":true},"paper":"doi:10.1007/s11669-012-0073-5","paper_id":"doi:10.1007/s11669-012-0073-5","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.73,"N":0.27},"composition_source":"printed","phase":"molten Al"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.73,"N":0.27},"composition_source":"printed","phase":"liquid Al"}],"phases":[{"label":"molten Al"},{"label":"liquid Al"}],"pid":"doi:10.1007/s11669-012-0073-5/p8/tab-4/r10#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-N","system":"AL-N","temperature_K":973.15,"temperature_basis":"printed","temperature_printed":"700","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AL-N","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-012-0073-5"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":2,"id":"ORC-36FLNF4JVS","locator":{"ref":"doi:10.1007/s11669-012-0073-5/p8/tab-4","row":11},"merged_ids":["ORC-7CNFAIWOBA"],"merged_pids":["doi:10.1007/s11669-012-0073-5/p8/tab-4/r07#phase_region_vertex_set"],"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-012-0073-5","own_work_of_paper":true},"paper":"doi:10.1007/s11669-012-0073-5","paper_id":"doi:10.1007/s11669-012-0073-5","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.61,"N":0.39},"composition_source":"printed","phase":"molten Al"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.61,"N":0.39},"composition_source":"printed","phase":"liquid Al"}],"phases":[{"label":"molten Al"},{"label":"liquid Al"}],"pid":"doi:10.1007/s11669-012-0073-5/p8/tab-4/r11#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-N","system":"AL-N","temperature_K":1123.15,"temperature_basis":"printed","temperature_printed":"850","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AL-N","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-012-0073-5"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":2,"id":"ORC-62RTZ4D3JK","locator":{"ref":"doi:10.1007/s11669-012-0073-5/p8/tab-4","row":12},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-012-0073-5","own_work_of_paper":true},"paper":"doi:10.1007/s11669-012-0073-5","paper_id":"doi:10.1007/s11669-012-0073-5","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.52,"N":0.48},"composition_source":"printed","phase":"molten Al"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.52,"N":0.48},"composition_source":"printed","phase":"liquid Al"}],"phases":[{"label":"molten Al"},{"label":"liquid Al"}],"pid":"doi:10.1007/s11669-012-0073-5/p8/tab-4/r12#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-N","system":"AL-N","temperature_K":1213.15,"temperature_basis":"printed","temperature_printed":"940","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AL-N","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-012-0073-5"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":2,"id":"ORC-MQPR3QGJJT","locator":{"ref":"doi:10.1007/s11669-012-0073-5/p8/tab-4","row":13},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-012-0073-5","own_work_of_paper":true},"paper":"doi:10.1007/s11669-012-0073-5","paper_id":"doi:10.1007/s11669-012-0073-5","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.51,"N":0.49},"composition_source":"printed","phase":"molten Al"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.51,"N":0.49},"composition_source":"printed","phase":"liquid Al"}],"phases":[{"label":"molten Al"},{"label":"liquid Al"}],"pid":"doi:10.1007/s11669-012-0073-5/p8/tab-4/r13#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-N","system":"AL-N","temperature_K":1223.15,"temperature_basis":"printed","temperature_printed":"950","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AL-N","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-012-0073-5"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":2,"id":"ORC-ZMEFMBGHFY","locator":{"ref":"doi:10.1007/s11669-012-0073-5/p8/tab-4","row":15},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-012-0073-5","own_work_of_paper":true},"paper":"doi:10.1007/s11669-012-0073-5","paper_id":"doi:10.1007/s11669-012-0073-5","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.998,"N":0.002},"composition_source":"printed","phase":"molten Al"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.998,"N":0.002},"composition_source":"printed","phase":"liquid Al"}],"phases":[{"label":"molten Al"},{"label":"liquid Al"}],"pid":"doi:10.1007/s11669-012-0073-5/p8/tab-4/r15#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-N","system":"AL-N","temperature_K":1473.15,"temperature_basis":"printed","temperature_printed":"1200","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AL-N","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-012-0073-5"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":2,"id":"ORC-ZBARUE47EY","locator":{"ref":"doi:10.1007/s11669-012-0073-5/p8/tab-4","row":16},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11669-012-0073-5","own_work_of_paper":true},"paper":"doi:10.1007/s11669-012-0073-5","paper_id":"doi:10.1007/s11669-012-0073-5","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.12,"N":0.88},"composition_source":"printed","phase":"molten Al"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AL":0.12,"N":0.88},"composition_source":"printed","phase":"liquid Al"}],"phases":[{"label":"molten Al"},{"label":"liquid Al"}],"pid":"doi:10.1007/s11669-012-0073-5/p8/tab-4/r16#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-N","system":"AL-N","temperature_K":1673.15,"temperature_basis":"printed","temperature_printed":"1400","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AL-N","cited_sources":[{"first_author":"Van","kind":"unknown","label":"39","reference":"J.A. Van Vechten, Phys. Rev. B 7, 1479 (1973).","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"AlN","label_source":"printed_source_page"}],"before":[{"label":"unspecified"}],"evidence":{"batch":"table_context_batch_03","doi":"10.1557/jmr.2002.0445","pdf_page":18,"pdf_sha256":"26ebd8cbe2163f4bcc224e4492e52ad1bbf59e57d04b46e071422775520a8211","printed":"Phase column prints 'AlN' on the first row of the block; other rows of the block blank in the Phase column","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[3,5,6,7,8,9],"table":"AI","table_key":"t052"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"11bd07eeb06186f2a9b71e669bf52d9c761fc31c259c38336c6a7bd0901d08c7","page":18,"pdf_sha256_prefix":"26ebd8cbe2163f4b","seen":"AlN block: Tm 3073/~3300/3487/3025; dmS 69.5/66.9/63.6; Cp 30.04/30.25/34.60; S298 20.1/19.69; ends before GaN","verdict":"confirmed"}},{"after":"AL-N","before":"AL-AS-GA-IN-N","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["AlN"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-MMEMZ4U37H","locator":{"ref":"sha256:26ebd8cbe2163f4b/p18/tab-ai","row":3},"observation_type":"equilibrium_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1557/jmr.2002.0445","paper_id":"doi:10.1557/jmr.2002.0445","phases":[{"label":"AlN","label_source":"printed_source_page"}],"pid":"sha256:26ebd8cbe2163f4b/p18/tab-ai/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"ENTROPY","property_group":"heat capacity / entropy / enthalpy","property_printed":"ΔmS","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-AS-GA-IN-N","system":"AL-N","temperature_K":3487.0,"tool_release":"tools-release-v2.1.13","uncertainty":{"basis":"stated_default","note":"5% default","value":3.475},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.285111,1.174159],"class":"unknown","entry":"value_types/S_ABS/classes/unknown","floor":0.7,"floor_unit":"J/K/mol","n_pairs":77,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol-formula K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-formula K","unit_printed":"J/mol-formula K","value":69.5,"value_printed":69.5},{"chemical_system":"AL-N","cited_sources":[{"first_author":"Jones","kind":"assessment","label":"37","reference":"R.D. Jones and K. Rose, CALPHAD 8, 343 (1984).","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"AlN","label_source":"printed_source_page"}],"before":[{"label":"unspecified"}],"evidence":{"batch":"table_context_batch_03","doi":"10.1557/jmr.2002.0445","pdf_page":18,"pdf_sha256":"26ebd8cbe2163f4bcc224e4492e52ad1bbf59e57d04b46e071422775520a8211","printed":"Phase column prints 'AlN' on the first row of the block; other rows of the block blank in the Phase column","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[3,5,6,7,8,9],"table":"AI","table_key":"t052"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"11bd07eeb06186f2a9b71e669bf52d9c761fc31c259c38336c6a7bd0901d08c7","page":18,"pdf_sha256_prefix":"26ebd8cbe2163f4b","seen":"AlN block: Tm 3073/~3300/3487/3025; dmS 69.5/66.9/63.6; Cp 30.04/30.25/34.60; S298 20.1/19.69; ends before GaN","verdict":"confirmed"}},{"after":"AL-N","before":"AL-AS-GA-IN-N","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["AlN"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-5ZUETBL665","locator":{"ref":"sha256:26ebd8cbe2163f4b/p18/tab-ai","row":5},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1557/jmr.2002.0445","paper_id":"doi:10.1557/jmr.2002.0445","phases":[{"label":"AlN","label_source":"printed_source_page"}],"pid":"sha256:26ebd8cbe2163f4b/p18/tab-ai/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"ENTROPY","property_group":"heat capacity / entropy / enthalpy","property_printed":"ΔmS","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-AS-GA-IN-N","system":"AL-N","temperature_K":298.15,"tool_release":"tools-release-v2.1.13","uncertainty":{"basis":"stated_default","note":"5% default","value":3.345},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/S_ABS","floor":1.0,"floor_unit":"J/K/mol","n_pairs":260,"value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol-formula K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-formula K","unit_printed":"J/mol-formula K","value":66.9,"value_printed":66.9},{"chemical_system":"AL-N","cited_sources":[{"first_author":"Jones","kind":"assessment","label":"37","reference":"R.D. Jones and K. Rose, CALPHAD 8, 343 (1984).","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"AlN","label_source":"printed_source_page"}],"before":[{"label":"unspecified"}],"evidence":{"batch":"table_context_batch_03","doi":"10.1557/jmr.2002.0445","pdf_page":18,"pdf_sha256":"26ebd8cbe2163f4bcc224e4492e52ad1bbf59e57d04b46e071422775520a8211","printed":"Phase column prints 'AlN' on the first row of the block; other rows of the block blank in the Phase column","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[3,5,6,7,8,9],"table":"AI","table_key":"t052"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"11bd07eeb06186f2a9b71e669bf52d9c761fc31c259c38336c6a7bd0901d08c7","page":18,"pdf_sha256_prefix":"26ebd8cbe2163f4b","seen":"AlN block: Tm 3073/~3300/3487/3025; dmS 69.5/66.9/63.6; Cp 30.04/30.25/34.60; S298 20.1/19.69; ends before GaN","verdict":"confirmed"}},{"after":"AL-N","before":"AL-AS-GA-IN-N","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["AlN"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-4SUFGCWB5N","locator":{"ref":"sha256:26ebd8cbe2163f4b/p18/tab-ai","row":6},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1557/jmr.2002.0445","paper_id":"doi:10.1557/jmr.2002.0445","phases":[{"label":"AlN","label_source":"printed_source_page"}],"pid":"sha256:26ebd8cbe2163f4b/p18/tab-ai/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"ENTROPY","property_group":"heat capacity / entropy / enthalpy","property_printed":"ΔmS","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-AS-GA-IN-N","system":"AL-N","temperature_K":298.15,"tool_release":"tools-release-v2.1.13","uncertainty":{"basis":"stated_default","note":"5% default","value":3.18},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/S_ABS","floor":1.0,"floor_unit":"J/K/mol","n_pairs":260,"value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol-formula K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-formula K","unit_printed":"J/mol-formula K","value":63.6,"value_printed":63.6},{"chemical_system":"AL-N","cited_sources":[{"first_author":"Mah","kind":"unknown","label":"49","reference":"A.D. Mah, E.G. King, W.W. Weller, and A.U. Christensen, RI 5716, U.S. Bureau of Mines, Berkeley, CA (1961).","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"AlN","label_source":"printed_source_page"}],"before":[{"label":"unspecified"}],"evidence":{"doi":"10.1557/jmr.2002.0445","locator":{"artifact":"table","asset":"sha256:26ebd8cbe2163f4b/p18/tab-ai","caption":"Experimental, estimated, and optimized thermodynamic data for III-V nitride phases.","label":"AI","page":18,"row":7},"pdf_page":18,"pdf_sha256":"26ebd8cbe2163f4bcc224e4492e52ad1bbf59e57d04b46e071422775520a8211","printed_phase_text":"AlN","rationale":"Table AI merged phase labels independently read within bounded compound groups. No neighbouring compound carried across a boundary; row numbers checked against formation-enthalpy values.","rendered_page_sha256":"cc44b88ea4884a83beb45446ecbe6674a1f9f0947e9b56fe215ee52f7f442626","report_id":"ORCHID-PR-20261027-v1","review_group":31,"table":"AI"},"field":"phases","gate":"PR20261027","rule":"source_adjudicated_placeholder_recovery","visual_check":{"checked":"2026-10-27; Codex rendered-page inspection","image_sha256":"cc44b88ea4884a83beb45446ecbe6674a1f9f0947e9b56fe215ee52f7f442626","method":"Explicit printed row or bounded table group; no composition or diagram inference","page":18,"pdf_sha256_prefix":"26ebd8cbe2163f4b","seen":"AlN","verdict":"confirmed"}},{"after":"AL-N","before":"AL-AS-GA-IN-N","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["AlN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":null,"before":"state_phases_missing","evidence":{"basis":"phases recovered on the printed page","evidence_id":"ORCHID-PR-20261027-v1"},"field":"gate_failures","gate":"PR20261027","rule":"placeholder_recovery_lifts_state_phases_missing"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"magnitude_suspect":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","placeholder_recovery_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Phase labels only. Preserve all original scientific and state qualifications; downstream gates and ESPEI revalidation required. Table AI merged phase labels independently read within bounded compound groups. No neighbouring compound carried across a boundary; row numbers checked against formation-enthalpy values.","effect":"not_espei_ready","gate":"PR20261027"}],"id":"ORC-RV7HORYS2S.364abc","locator":{"ref":"sha256:26ebd8cbe2163f4b/p18/tab-ai","row":7},"observation_type":"equilibrium_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1557/jmr.2002.0445","paper_id":"doi:10.1557/jmr.2002.0445","phases":[{"label":"AlN","label_source":"printed_source_page"}],"pid":"sha256:26ebd8cbe2163f4b/p18/tab-ai/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"AS":{"phase":"printed:none"},"GA":{"phase":"printed:none"},"IN":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"source_system":"AL-AS-GA-IN-N","system":"AL-N","temperature_K":298.15,"tool_release":"tools-release-v2.1.13","uncertainty":{"basis":"stated_default","note":"5% default","value":15.92},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.0,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"scaled_for_unstated_basis":2,"value":7.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_printed":"kJ/mol","unit_stored":"J/mol (basis unstated)","value":-318.4,"value_printed":-318.4,"value_stored":-318400.0},{"chemical_system":"AL-N","cited_sources":[{"first_author":"Mah","kind":"unknown","label":"49","reference":"A.D. Mah, E.G. King, W.W. Weller, and A.U. Christensen, RI 5716, U.S. Bureau of Mines, Berkeley, CA (1961).","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"AlN","label_source":"printed_source_page"}],"before":[{"label":"unspecified"}],"evidence":{"batch":"table_context_batch_03","doi":"10.1557/jmr.2002.0445","pdf_page":18,"pdf_sha256":"26ebd8cbe2163f4bcc224e4492e52ad1bbf59e57d04b46e071422775520a8211","printed":"Phase column prints 'AlN' on the first row of the block; other rows of the block blank in the Phase column","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[3,5,6,7,8,9],"table":"AI","table_key":"t052"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"11bd07eeb06186f2a9b71e669bf52d9c761fc31c259c38336c6a7bd0901d08c7","page":18,"pdf_sha256_prefix":"26ebd8cbe2163f4b","seen":"AlN block: Tm 3073/~3300/3487/3025; dmS 69.5/66.9/63.6; Cp 30.04/30.25/34.60; S298 20.1/19.69; ends before GaN","verdict":"confirmed"}},{"after":"AL-N","before":"AL-AS-GA-IN-N","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["AlN"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-RV7HORYS2S.78a9c1","locator":{"ref":"sha256:26ebd8cbe2163f4b/p18/tab-ai","row":7},"observation_type":"equilibrium_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1557/jmr.2002.0445","paper_id":"doi:10.1557/jmr.2002.0445","phases":[{"label":"AlN","label_source":"printed_source_page"}],"pid":"sha256:26ebd8cbe2163f4b/p18/tab-ai/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp,298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"AS":{"phase":"printed:none"},"GA":{"phase":"printed:none"},"IN":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"source_system":"AL-AS-GA-IN-N","system":"AL-N","temperature_K":298.15,"tool_release":"tools-release-v2.1.13","uncertainty":{"basis":"stated_default","note":"5% default","value":1.502},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"unstated","unit_printed":"J/mol-formula K","value":30.04,"value_printed":30.04},{"chemical_system":"AL-N","cited_sources":[{"first_author":"Mah","kind":"unknown","label":"49","reference":"A.D. Mah, E.G. King, W.W. Weller, and A.U. Christensen, RI 5716, U.S. Bureau of Mines, Berkeley, CA (1961).","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"AlN","label_source":"printed_source_page"}],"before":[{"label":"unspecified"}],"evidence":{"batch":"table_context_batch_03","doi":"10.1557/jmr.2002.0445","pdf_page":18,"pdf_sha256":"26ebd8cbe2163f4bcc224e4492e52ad1bbf59e57d04b46e071422775520a8211","printed":"Phase column prints 'AlN' on the first row of the block; other rows of the block blank in the Phase column","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[3,5,6,7,8,9],"table":"AI","table_key":"t052"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"11bd07eeb06186f2a9b71e669bf52d9c761fc31c259c38336c6a7bd0901d08c7","page":18,"pdf_sha256_prefix":"26ebd8cbe2163f4b","seen":"AlN block: Tm 3073/~3300/3487/3025; dmS 69.5/66.9/63.6; Cp 30.04/30.25/34.60; S298 20.1/19.69; ends before GaN","verdict":"confirmed"}},{"after":"AL-N","before":"AL-AS-GA-IN-N","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["AlN"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-RV7HORYS2S.c7e276","locator":{"ref":"sha256:26ebd8cbe2163f4b/p18/tab-ai","row":7},"observation_type":"equilibrium_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1557/jmr.2002.0445","paper_id":"doi:10.1557/jmr.2002.0445","phases":[{"label":"AlN","label_source":"printed_source_page"}],"pid":"sha256:26ebd8cbe2163f4b/p18/tab-ai/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"ENTROPY","property_group":"heat capacity / entropy / enthalpy","property_printed":"S°298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-AS-GA-IN-N","system":"AL-N","temperature_K":298.15,"tool_release":"tools-release-v2.1.13","uncertainty":{"basis":"stated_default","note":"5% default","value":1.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.285111,1.174159],"class":"unknown","entry":"value_types/S_ABS/classes/unknown","floor":0.7,"floor_unit":"J/K/mol","n_pairs":77,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol-formula K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-formula K","unit_printed":"J/mol-formula K","value":20.1,"value_printed":20.1},{"chemical_system":"AL-N","cited_sources":[{"first_author":"Koshchenko","kind":"unknown","label":"50","reference":"V.I. Koshchenko, Ya.Kh. Grinberg, and A.F. Demidenko, Neorg. Mater. 20, 1787 (1984, in Russian).","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"AlN","label_source":"printed_source_page"}],"before":[{"label":"unspecified"}],"evidence":{"batch":"table_context_batch_03","doi":"10.1557/jmr.2002.0445","pdf_page":18,"pdf_sha256":"26ebd8cbe2163f4bcc224e4492e52ad1bbf59e57d04b46e071422775520a8211","printed":"Phase column prints 'AlN' on the first row of the block; other rows of the block blank in the Phase column","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[3,5,6,7,8,9],"table":"AI","table_key":"t052"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"11bd07eeb06186f2a9b71e669bf52d9c761fc31c259c38336c6a7bd0901d08c7","page":18,"pdf_sha256_prefix":"26ebd8cbe2163f4b","seen":"AlN block: Tm 3073/~3300/3487/3025; dmS 69.5/66.9/63.6; Cp 30.04/30.25/34.60; S298 20.1/19.69; ends before GaN","verdict":"confirmed"}},{"after":"AL-N","before":"AL-AS-GA-IN-N","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["AlN"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-TYSHPITKQL.0c1b29","locator":{"ref":"sha256:26ebd8cbe2163f4b/p18/tab-ai","row":8},"observation_type":"equilibrium_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1557/jmr.2002.0445","paper_id":"doi:10.1557/jmr.2002.0445","phases":[{"label":"AlN","label_source":"printed_source_page"}],"pid":"sha256:26ebd8cbe2163f4b/p18/tab-ai/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"ENTROPY","property_group":"heat capacity / entropy / enthalpy","property_printed":"S°298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-AS-GA-IN-N","system":"AL-N","temperature_K":298.15,"tool_release":"tools-release-v2.1.13","uncertainty":{"basis":"stated_default","note":"5% default","value":0.9845},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.7,"sigma_method":{"basis":"calibrated","ci95":[0.285111,1.174159],"class":"unknown","entry":"value_types/S_ABS/classes/unknown","floor":0.7,"floor_unit":"J/K/mol","n_pairs":77,"value":0.7},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol-formula K","value_type":"S_ABS"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-formula K","unit_printed":"J/mol-formula K","value":19.69,"value_printed":19.69},{"chemical_system":"AL-N","cited_sources":[{"first_author":"Koshchenko","kind":"unknown","label":"50","reference":"V.I. Koshchenko, Ya.Kh. Grinberg, and A.F. Demidenko, Neorg. Mater. 20, 1787 (1984, in Russian).","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"AlN","label_source":"printed_source_page"}],"before":[{"label":"unspecified"}],"evidence":{"batch":"table_context_batch_03","doi":"10.1557/jmr.2002.0445","pdf_page":18,"pdf_sha256":"26ebd8cbe2163f4bcc224e4492e52ad1bbf59e57d04b46e071422775520a8211","printed":"Phase column prints 'AlN' on the first row of the block; other rows of the block blank in the Phase column","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[3,5,6,7,8,9],"table":"AI","table_key":"t052"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"11bd07eeb06186f2a9b71e669bf52d9c761fc31c259c38336c6a7bd0901d08c7","page":18,"pdf_sha256_prefix":"26ebd8cbe2163f4b","seen":"AlN block: Tm 3073/~3300/3487/3025; dmS 69.5/66.9/63.6; Cp 30.04/30.25/34.60; S298 20.1/19.69; ends before GaN","verdict":"confirmed"}},{"after":"AL-N","before":"AL-AS-GA-IN-N","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["AlN"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-TYSHPITKQL.1204bc","locator":{"ref":"sha256:26ebd8cbe2163f4b/p18/tab-ai","row":8},"observation_type":"equilibrium_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1557/jmr.2002.0445","paper_id":"doi:10.1557/jmr.2002.0445","phases":[{"label":"AlN","label_source":"printed_source_page"}],"pid":"sha256:26ebd8cbe2163f4b/p18/tab-ai/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp,298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"AS":{"phase":"printed:none"},"GA":{"phase":"printed:none"},"IN":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"source_system":"AL-AS-GA-IN-N","system":"AL-N","temperature_K":298.15,"tool_release":"tools-release-v2.1.13","uncertainty":{"basis":"stated_default","note":"5% default","value":1.5125},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"unstated","unit_printed":"J/mol-formula K","value":30.25,"value_printed":30.25},{"chemical_system":"AL-N","cited_sources":[{"first_author":"Strelchenko","kind":"unknown","label":"51","reference":"S.S. Strel’chenko and V.V. Lebedev, III-V Compounds Handbook (Metallurgia Moscow, USSR, 1984).","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"AlN","label_source":"printed_source_page"}],"before":[{"label":"unspecified"}],"evidence":{"batch":"table_context_batch_03","doi":"10.1557/jmr.2002.0445","pdf_page":18,"pdf_sha256":"26ebd8cbe2163f4bcc224e4492e52ad1bbf59e57d04b46e071422775520a8211","printed":"Phase column prints 'AlN' on the first row of the block; other rows of the block blank in the Phase column","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[3,5,6,7,8,9],"table":"AI","table_key":"t052"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 03","image_sha256":"11bd07eeb06186f2a9b71e669bf52d9c761fc31c259c38336c6a7bd0901d08c7","page":18,"pdf_sha256_prefix":"26ebd8cbe2163f4b","seen":"AlN block: Tm 3073/~3300/3487/3025; dmS 69.5/66.9/63.6; Cp 30.04/30.25/34.60; S298 20.1/19.69; ends before GaN","verdict":"confirmed"}},{"after":"AL-N","before":"AL-AS-GA-IN-N","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["AlN"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-3J2PIHG6TF","locator":{"ref":"sha256:26ebd8cbe2163f4b/p18/tab-ai","row":9},"observation_type":"equilibrium_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1557/jmr.2002.0445","paper_id":"doi:10.1557/jmr.2002.0445","phases":[{"label":"AlN","label_source":"printed_source_page"}],"pid":"sha256:26ebd8cbe2163f4b/p18/tab-ai/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"CPM","property_group":"heat capacity / entropy / enthalpy","property_printed":"Cp,298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"AS":{"phase":"printed:none"},"GA":{"phase":"printed:none"},"IN":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"source_system":"AL-AS-GA-IN-N","system":"AL-N","temperature_K":298.15,"tool_release":"tools-release-v2.1.13","uncertainty":{"basis":"stated_default","note":"5% default","value":1.73},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.6,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.256323,1.118072],"class":"unknown","entry":"value_types/CPM/classes/unknown","floor":0.6,"floor_unit":"J/K/mol","n_pairs":6,"prior_source":"kubaschewski","value":0.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"CPM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"unstated","unit_printed":"J/mol-formula K","value":34.6,"value_printed":34.6},{"chemical_system":"AL-N","cited_sources":[{"first_author":"Sato","kind":"unknown","label":"52","reference":"S. Sato, Sci. Papers Inst. Phys. Chem. Research (Tokyo) 29, 19 (1932).","status":"resolved","year":"1932"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"AlN","label_source":"printed_source_page"}],"before":[{"label":"unspecified"}],"evidence":{"doi":"10.1557/jmr.2002.0445","locator":{"artifact":"table","asset":"sha256:26ebd8cbe2163f4b/p18/tab-ai","caption":"Experimental, estimated, and optimized thermodynamic data for III-V nitride phases.","label":"AI","page":18,"row":10},"pdf_page":18,"pdf_sha256":"26ebd8cbe2163f4bcc224e4492e52ad1bbf59e57d04b46e071422775520a8211","printed_phase_text":"AlN","rationale":"Table AI merged phase labels independently read within bounded compound groups. No neighbouring compound carried across a boundary; row numbers checked against formation-enthalpy values.","rendered_page_sha256":"cc44b88ea4884a83beb45446ecbe6674a1f9f0947e9b56fe215ee52f7f442626","report_id":"ORCHID-PR-20261027-v1","review_group":31,"table":"AI"},"field":"phases","gate":"PR20261027","rule":"source_adjudicated_placeholder_recovery","visual_check":{"checked":"2026-10-27; Codex rendered-page inspection","image_sha256":"cc44b88ea4884a83beb45446ecbe6674a1f9f0947e9b56fe215ee52f7f442626","method":"Explicit printed row or bounded table group; no composition or diagram inference","page":18,"pdf_sha256_prefix":"26ebd8cbe2163f4b","seen":"AlN","verdict":"confirmed"}},{"after":"AL-N","before":"AL-AS-GA-IN-N","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["AlN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":null,"before":"state_phases_missing","evidence":{"basis":"phases recovered on the printed page","evidence_id":"ORCHID-PR-20261027-v1"},"field":"gate_failures","gate":"PR20261027","rule":"placeholder_recovery_lifts_state_phases_missing"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"magnitude_suspect":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","placeholder_recovery_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Phase labels only. Preserve all original scientific and state qualifications; downstream gates and ESPEI revalidation required. Table AI merged phase labels independently read within bounded compound groups. No neighbouring compound carried across a boundary; row numbers checked against formation-enthalpy values.","effect":"not_espei_ready","gate":"PR20261027"}],"id":"ORC-CGJSSMUS7E","locator":{"ref":"sha256:26ebd8cbe2163f4b/p18/tab-ai","row":10},"observation_type":"equilibrium_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1557/jmr.2002.0445","paper_id":"doi:10.1557/jmr.2002.0445","phases":[{"label":"AlN","label_source":"printed_source_page"}],"pid":"sha256:26ebd8cbe2163f4b/p18/tab-ai/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"AS":{"phase":"printed:none"},"GA":{"phase":"printed:none"},"IN":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"source_system":"AL-AS-GA-IN-N","system":"AL-N","temperature_K":298.15,"tool_release":"tools-release-v2.1.13","uncertainty":{"basis":"stated_default","note":"5% default","value":15.625},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.0,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"scaled_for_unstated_basis":2,"value":7.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_printed":"kJ/mol","unit_stored":"J/mol (basis unstated)","value":-312.5,"value_printed":-312.5,"value_stored":-312500.0},{"chemical_system":"AL-N","cited_sources":[{"first_author":"Neugebauer","kind":"unknown","label":"53","reference":"C.A. Neugebauer and J.L. Margrave, Z. Anorg. Allgem. Chem. 290, 82 (1957).","status":"resolved","year":"1957"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"AlN","label_source":"printed_source_page"}],"before":[{"label":"unspecified"}],"evidence":{"doi":"10.1557/jmr.2002.0445","locator":{"artifact":"table","asset":"sha256:26ebd8cbe2163f4b/p18/tab-ai","caption":"Experimental, estimated, and optimized thermodynamic data for III-V nitride phases.","label":"AI","page":18,"row":11},"pdf_page":18,"pdf_sha256":"26ebd8cbe2163f4bcc224e4492e52ad1bbf59e57d04b46e071422775520a8211","printed_phase_text":"AlN","rationale":"Table AI merged phase labels independently read within bounded compound groups. No neighbouring compound carried across a boundary; row numbers checked against formation-enthalpy values.","rendered_page_sha256":"cc44b88ea4884a83beb45446ecbe6674a1f9f0947e9b56fe215ee52f7f442626","report_id":"ORCHID-PR-20261027-v1","review_group":31,"table":"AI"},"field":"phases","gate":"PR20261027","rule":"source_adjudicated_placeholder_recovery","visual_check":{"checked":"2026-10-27; Codex rendered-page inspection","image_sha256":"cc44b88ea4884a83beb45446ecbe6674a1f9f0947e9b56fe215ee52f7f442626","method":"Explicit printed row or bounded table group; no composition or diagram inference","page":18,"pdf_sha256_prefix":"26ebd8cbe2163f4b","seen":"AlN","verdict":"confirmed"}},{"after":"AL-N","before":"AL-AS-GA-IN-N","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["AlN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":null,"before":"state_phases_missing","evidence":{"basis":"phases recovered on the printed page","evidence_id":"ORCHID-PR-20261027-v1"},"field":"gate_failures","gate":"PR20261027","rule":"placeholder_recovery_lifts_state_phases_missing"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"magnitude_suspect":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","placeholder_recovery_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Phase labels only. Preserve all original scientific and state qualifications; downstream gates and ESPEI revalidation required. Table AI merged phase labels independently read within bounded compound groups. No neighbouring compound carried across a boundary; row numbers checked against formation-enthalpy values.","effect":"not_espei_ready","gate":"PR20261027"}],"id":"ORC-H3GAN2DCZE","locator":{"ref":"sha256:26ebd8cbe2163f4b/p18/tab-ai","row":11},"observation_type":"equilibrium_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1557/jmr.2002.0445","paper_id":"doi:10.1557/jmr.2002.0445","phases":[{"label":"AlN","label_source":"printed_source_page"}],"pid":"sha256:26ebd8cbe2163f4b/p18/tab-ai/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"AS":{"phase":"printed:none"},"GA":{"phase":"printed:none"},"IN":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"source_system":"AL-AS-GA-IN-N","system":"AL-N","temperature_K":298.15,"tool_release":"tools-release-v2.1.13","uncertainty":{"basis":"stated_default","note":"5% default","value":15.65},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.0,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"scaled_for_unstated_basis":2,"value":7.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_printed":"kJ/mol","unit_stored":"J/mol (basis unstated)","value":-313.0,"value_printed":-313.0,"value_stored":-313000.0},{"chemical_system":"AL-N","cited_sources":[{"first_author":"Hildebrand","kind":"unknown","label":"54","reference":"D.L. Hildebrand and W.F. Hall, J. Phys. Chem. 67, 888 (1963). J. Mater. Res., Vol. 17, No. 12, Dec 2002 3081 B. Onderka et al.: Thermodynamics and phase stability in the In–N system","status":"resolved","year":1963,"year_basis":"printed_parenthesised_year","year_read":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"AlN","label_source":"printed_source_page"}],"before":[{"label":"unspecified"}],"evidence":{"doi":"10.1557/jmr.2002.0445","locator":{"artifact":"table","asset":"sha256:26ebd8cbe2163f4b/p18/tab-ai","caption":"Experimental, estimated, and optimized thermodynamic data for III-V nitride phases.","label":"AI","page":18,"row":12},"pdf_page":18,"pdf_sha256":"26ebd8cbe2163f4bcc224e4492e52ad1bbf59e57d04b46e071422775520a8211","printed_phase_text":"AlN","rationale":"Table AI merged phase labels independently read within bounded compound groups. No neighbouring compound carried across a boundary; row numbers checked against formation-enthalpy values.","rendered_page_sha256":"cc44b88ea4884a83beb45446ecbe6674a1f9f0947e9b56fe215ee52f7f442626","report_id":"ORCHID-PR-20261027-v1","review_group":31,"table":"AI"},"field":"phases","gate":"PR20261027","rule":"source_adjudicated_placeholder_recovery","visual_check":{"checked":"2026-10-27; Codex rendered-page inspection","image_sha256":"cc44b88ea4884a83beb45446ecbe6674a1f9f0947e9b56fe215ee52f7f442626","method":"Explicit printed row or bounded table group; no composition or diagram inference","page":18,"pdf_sha256_prefix":"26ebd8cbe2163f4b","seen":"AlN","verdict":"confirmed"}},{"after":"AL-N","before":"AL-AS-GA-IN-N","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["AlN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":null,"before":"state_phases_missing","evidence":{"basis":"phases recovered on the printed page","evidence_id":"ORCHID-PR-20261027-v1"},"field":"gate_failures","gate":"PR20261027","rule":"placeholder_recovery_lifts_state_phases_missing"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"magnitude_suspect":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","placeholder_recovery_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Phase labels only. Preserve all original scientific and state qualifications; downstream gates and ESPEI revalidation required. Table AI merged phase labels independently read within bounded compound groups. No neighbouring compound carried across a boundary; row numbers checked against formation-enthalpy values.","effect":"not_espei_ready","gate":"PR20261027"}],"id":"ORC-4D3CFBSIUE","locator":{"ref":"sha256:26ebd8cbe2163f4b/p18/tab-ai","row":12},"observation_type":"equilibrium_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1557/jmr.2002.0445","paper_id":"doi:10.1557/jmr.2002.0445","phases":[{"label":"AlN","label_source":"printed_source_page"}],"pid":"sha256:26ebd8cbe2163f4b/p18/tab-ai/r12#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"AS":{"phase":"printed:none"},"GA":{"phase":"printed:none"},"IN":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"source_system":"AL-AS-GA-IN-N","system":"AL-N","temperature_K":298.15,"tool_release":"tools-release-v2.1.13","uncertainty":{"basis":"stated_default","note":"5% default","value":15.815},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.0,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"scaled_for_unstated_basis":2,"value":7.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_printed":"kJ/mol","unit_stored":"J/mol (basis unstated)","value":-316.3,"value_printed":-316.3,"value_stored":-316300.0},{"chemical_system":"AL-N","cited_sources":[{"first_author":"Era","kind":"unknown","label":"55","reference":"K. Era, Muki Zaishitsu Kenky-usho kenky-u h-okokusho 4, 59 (1973, in Japanese); Chem. Abstr. 87, 192133m (1977).","status":"resolved","year":"1977"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"AlN","label_source":"printed_source_page"}],"before":[{"label":"unspecified"}],"evidence":{"doi":"10.1557/jmr.2002.0445","locator":{"artifact":"table","asset":"sha256:26ebd8cbe2163f4b/p18/tab-ai","caption":"Experimental, estimated, and optimized thermodynamic data for III-V nitride phases.","label":"AI","page":18,"row":13},"pdf_page":18,"pdf_sha256":"26ebd8cbe2163f4bcc224e4492e52ad1bbf59e57d04b46e071422775520a8211","printed_phase_text":"AlN","rationale":"Table AI merged phase labels independently read within bounded compound groups. No neighbouring compound carried across a boundary; row numbers checked against formation-enthalpy values.","rendered_page_sha256":"cc44b88ea4884a83beb45446ecbe6674a1f9f0947e9b56fe215ee52f7f442626","report_id":"ORCHID-PR-20261027-v1","review_group":31,"table":"AI"},"field":"phases","gate":"PR20261027","rule":"source_adjudicated_placeholder_recovery","visual_check":{"checked":"2026-10-27; Codex rendered-page inspection","image_sha256":"cc44b88ea4884a83beb45446ecbe6674a1f9f0947e9b56fe215ee52f7f442626","method":"Explicit printed row or bounded table group; no composition or diagram inference","page":18,"pdf_sha256_prefix":"26ebd8cbe2163f4b","seen":"AlN","verdict":"confirmed"}},{"after":"AL-N","before":"AL-AS-GA-IN-N","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["AlN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":null,"before":"state_phases_missing","evidence":{"basis":"phases recovered on the printed page","evidence_id":"ORCHID-PR-20261027-v1"},"field":"gate_failures","gate":"PR20261027","rule":"placeholder_recovery_lifts_state_phases_missing"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"magnitude_suspect":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","placeholder_recovery_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Phase labels only. Preserve all original scientific and state qualifications; downstream gates and ESPEI revalidation required. Table AI merged phase labels independently read within bounded compound groups. No neighbouring compound carried across a boundary; row numbers checked against formation-enthalpy values.","effect":"not_espei_ready","gate":"PR20261027"}],"id":"ORC-SCJ6PTKNQD","locator":{"ref":"sha256:26ebd8cbe2163f4b/p18/tab-ai","row":13},"observation_type":"equilibrium_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1557/jmr.2002.0445","paper_id":"doi:10.1557/jmr.2002.0445","phases":[{"label":"AlN","label_source":"printed_source_page"}],"pid":"sha256:26ebd8cbe2163f4b/p18/tab-ai/r13#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"AS":{"phase":"printed:none"},"GA":{"phase":"printed:none"},"IN":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"source_system":"AL-AS-GA-IN-N","system":"AL-N","temperature_K":298.15,"tool_release":"tools-release-v2.1.13","uncertainty":{"basis":"stated_default","note":"5% default","value":15.895},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.0,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"scaled_for_unstated_basis":2,"value":7.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_printed":"kJ/mol","unit_stored":"J/mol (basis unstated)","value":-317.9,"value_printed":-317.9,"value_stored":-317900.0},{"chemical_system":"AL-N","cited_sources":[{"first_author":"McHale","kind":"unknown","label":"56","reference":"J.M. McHale, A. Navrotsky, and F.J. DiSalvo, Chem. Mater. 11, 1148 (1999).","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"AlN","label_source":"printed_source_page"}],"before":[{"label":"unspecified"}],"evidence":{"doi":"10.1557/jmr.2002.0445","locator":{"artifact":"table","asset":"sha256:26ebd8cbe2163f4b/p18/tab-ai","caption":"Experimental, estimated, and optimized thermodynamic data for III-V nitride phases.","label":"AI","page":18,"row":14},"pdf_page":18,"pdf_sha256":"26ebd8cbe2163f4bcc224e4492e52ad1bbf59e57d04b46e071422775520a8211","printed_phase_text":"AlN","rationale":"Table AI merged phase labels independently read within bounded compound groups. No neighbouring compound carried across a boundary; row numbers checked against formation-enthalpy values.","rendered_page_sha256":"cc44b88ea4884a83beb45446ecbe6674a1f9f0947e9b56fe215ee52f7f442626","report_id":"ORCHID-PR-20261027-v1","review_group":31,"table":"AI"},"field":"phases","gate":"PR20261027","rule":"source_adjudicated_placeholder_recovery","visual_check":{"checked":"2026-10-27; Codex rendered-page inspection","image_sha256":"cc44b88ea4884a83beb45446ecbe6674a1f9f0947e9b56fe215ee52f7f442626","method":"Explicit printed row or bounded table group; no composition or diagram inference","page":18,"pdf_sha256_prefix":"26ebd8cbe2163f4b","seen":"AlN","verdict":"confirmed"}},{"after":"AL-N","before":"AL-AS-GA-IN-N","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["AlN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":null,"before":"state_phases_missing","evidence":{"basis":"phases recovered on the printed page","evidence_id":"ORCHID-PR-20261027-v1"},"field":"gate_failures","gate":"PR20261027","rule":"placeholder_recovery_lifts_state_phases_missing"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"magnitude_suspect":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","placeholder_recovery_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Phase labels only. Preserve all original scientific and state qualifications; downstream gates and ESPEI revalidation required. Table AI merged phase labels independently read within bounded compound groups. No neighbouring compound carried across a boundary; row numbers checked against formation-enthalpy values.","effect":"not_espei_ready","gate":"PR20261027"}],"id":"ORC-LZU5HZK74A","locator":{"ref":"sha256:26ebd8cbe2163f4b/p18/tab-ai","row":14},"observation_type":"equilibrium_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1557/jmr.2002.0445","paper_id":"doi:10.1557/jmr.2002.0445","phases":[{"label":"AlN","label_source":"printed_source_page"}],"pid":"sha256:26ebd8cbe2163f4b/p18/tab-ai/r14#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH°298","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"AS":{"phase":"printed:none"},"GA":{"phase":"printed:none"},"IN":{"phase":"printed:none"},"N":{"phase":"printed:none"}},"source_system":"AL-AS-GA-IN-N","system":"AL-N","temperature_K":298.15,"tool_release":"tools-release-v2.1.13","uncertainty":{"basis":"stated_default","note":"5% default","value":15.555},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.0,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"scaled_for_unstated_basis":2,"value":7.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_printed":"kJ/mol","unit_stored":"J/mol (basis unstated)","value":-311.1,"value_printed":-311.1,"value_stored":-311100.0},{"chemical_system":"AL-N","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":4,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-T2O46GCLCX","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/bf02646133/p1/text-01"},"observation_type":"equilibrium_property","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/bf02646133","own_work_of_paper":true},"paper":"doi:10.1007/bf02646133","paper_id":"doi:10.1007/bf02646133","pid":"doi:10.1007/bf02646133/p1/text-01/s03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"VAPOR_PRESSURE","property_group":"activity / EMF / Gibbs energy","property_printed":"p","quote":"The melting point of A1N is taken as 3068 K, and a required gas pressure of 9.75 bar is predicted.","quote_page":1,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-N","system":"AL-N","temperature_K":3068.0,"temperature_printed":"3068 K","tool_release":"release v2 + tools dev copy record build","uncertainty":{"basis":"stated_default","note":"10% placeholder; none printed","value":0.975},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property VAPOR_PRESSURE","sigma_method":{"reason":"no method floor defined for property VAPOR_PRESSURE","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"bar","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"bar","value":9.75},{"chemical_system":"AL-N","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-CBLMSE2PMT","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/bf02646133/p1/text-01"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/bf02646133","own_work_of_paper":true},"paper":"doi:10.1007/bf02646133","paper_id":"doi:10.1007/bf02646133","pid":"doi:10.1007/bf02646133/p1/text-01/s04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"A sublimation point of 2690 K at 1 bar is also predicted.","quote_page":1,"reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-N","system":"AL-N","temperature_K":2690.0,"temperature_printed":"2690 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2690.0},{"chemical_system":"AL-N","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02646133"},"corrections":[{"after":298.15,"before":298.0,"evidence":{"printed":"298 K"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"proposed","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"HM_FORM without the phases of its state (compounds_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-XK7OCJDP3E.bb11af","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/bf02646133/p1/text-06"},"method":"combustion calorimeter","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"equilibrium_property","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/bf02646133","own_work_of_paper":true},"paper":"doi:10.1007/bf02646133","paper_id":"doi:10.1007/bf02646133","pid":"doi:10.1007/bf02646133/p1/text-06/s04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_FORM","property_group":"formation","property_printed":"A~","quote":"If their results are recalculated using a recent value of A~ = --1676 kJ/mol at 298 K from JANAF, I31 one obtains A~ = --299.3 --+ 7 kJ/mol from the former authors and A~ = --316.4 -- 1.7 kJ/mol from the latter ones.","quote_page":1,"reader_agreement":"single_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash"],"record_kind":"running_text","reference_state":{},"reference_state_stored":{"printed":"pure solid elements"},"source_system":"AL-N","system":"AL-N","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_printed":"298 K","tool_release":"release v2 + tools dev copy record build","uncertainty":{"basis":"printed","value":7.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":7.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.088062,5.330144],"class":"combustion_calorimetry","entry":"value_types/HM_FORM/classes/combustion_calorimetry","floor":1.0,"floor_unit":"kJ/mol-atom","n_pairs":15,"prior_source":"kubaschewski","reason":"unit 'unspecified' not convertible to kJ/mol-atom","value":null},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":7.0},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"unspecified","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"unspecified","value":-299.3},{"chemical_system":"AL-N","citations_printed":["rll"],"conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/bf02646133"},"corrections":[{"after":298.15,"before":298.0,"evidence":{"printed":"298 K"},"field":"temperature_K","gate":"G1","rule":"standard_reference_temperature"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"proposed","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"HM_FORM without the phases of its state (compounds_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-XK7OCJDP3E.c31585","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/bf02646133/p1/text-06"},"method":"combustion calorimeter","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"equilibrium_property","origin":{"class":"experimental","measured_in":"doi:10.1007/bf02646133","own_work_of_paper":true},"paper":"doi:10.1007/bf02646133","paper_id":"doi:10.1007/bf02646133","pid":"doi:10.1007/bf02646133/p1/text-06/s04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_FORM","property_group":"formation","property_printed":"A~","quote":"If their results are recalculated using a recent value of A~ = --1676 kJ/mol at 298 K from JANAF, I31 one obtains A~ = --299.3 --+ 7 kJ/mol from the former authors and A~ = --316.4 -- 1.7 kJ/mol from the latter ones.","quote_page":1,"reader_agreement":"single_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash"],"record_kind":"running_text","reference_state":{},"reference_state_stored":{"printed":"pure solid elements"},"source_system":"AL-N","system":"AL-N","temperature_K":298.15,"temperature_K_stored":298.0,"temperature_printed":"298 K","tool_release":"release v2 + tools dev copy record build","uncertainty":{"basis":"printed","value":1.7},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.7,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[0.088062,5.330144],"class":"combustion_calorimetry","entry":"value_types/HM_FORM/classes/combustion_calorimetry","floor":1.0,"floor_unit":"kJ/mol-atom","n_pairs":15,"prior_source":"kubaschewski","reason":"unit 'unspecified' not convertible to kJ/mol-atom","value":null},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.7},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"unspecified","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"unspecified","value":-316.4},{"chemical_system":"AL-N","citations_printed":["~6]"],"cited_sources":[{"first_author":"Class","kind":"assessment","label":"6","reference":"W. Class: NASA Contract Rep. 1968, NASA-CR-1171.","status":"resolved","year":"1968"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"experimental","before":"model","evidence":{"quote_keywords":["determined"]},"field":"evidence_class","gate":"G8","rule":"quote_wording_experimental_cited","visual_check":{"checked":"2026-10-23","image_sha256":"9284fa4746312b13e4321238bb520df3da5434d8fe90bcf7cb93d765cb23a6e5","page":1,"pdf_sha256_prefix":"df38cd552889f650","seen":"Sec. II: melting point of AlN has been determined to 2800 °C ± 50 °C by Class [6] using a high-pressure technique; cited experimental (assessment later takes 3068 K).","verdict":"confirmed"}}],"evidence_class":"experimental","evidence_class_before_gates":"model","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["evidence_class_reclassified","state_phases_missing"],"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"evidence_class_reclassified","detail":"model -> experimental by quote wording","effect":"not_espei_ready","gate":"G8","visual_check":{"checked":"2026-10-23","image_sha256":"9284fa4746312b13e4321238bb520df3da5434d8fe90bcf7cb93d765cb23a6e5","page":1,"pdf_sha256_prefix":"df38cd552889f650","seen":"Sec. II: melting point of AlN has been determined to 2800 °C ± 50 °C by Class [6] using a high-pressure technique; cited experimental (assessment later takes 3068 K).","verdict":"confirmed"}},{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-LLXONX7RQF","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/bf02646133/p1/text-06"},"method":"high-pressure technique","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"phase_transition","origin":{"basis_gate":"quote_wording_experimental_cited","class":"model_value","class_gate":"experimental (cited)","own_work_of_paper":false},"paper":"doi:10.1007/bf02646133","paper_id":"doi:10.1007/bf02646133","pid":"doi:10.1007/bf02646133/p1/text-06/s11#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The melting point has been determined to 2800 ~ - 50 ~ by Class ~6]using a high-pressure technique.","quote_page":1,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-N","system":"AL-N","temperature_K":3073.15,"temperature_printed":"2800 ~ - 50 ~","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"experimental_unspecified","entry":"value_types/T_TRANSITION/classes/experimental_unspecified","floor":10.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":3073.15},{"chemical_system":"AL-N","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-SSKNZX3ULV","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/bf02646133/p4/text-07"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/bf02646133","own_work_of_paper":true},"paper":"doi:10.1007/bf02646133","paper_id":"doi:10.1007/bf02646133","pid":"doi:10.1007/bf02646133/p4/text-07/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"It is evident that the solubility of A1N decreases rapidly at decreasing temperature, reaching the value of 10 -16 at the eutectic temperature of 933 K.","quote_page":4,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-N","system":"AL-N","temperature_K":933.0,"temperature_printed":"933 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":933.0},{"chemical_system":"AL-N","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-D2YCJMYKFO.4e42b8","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/bf02646133/p5/text-01"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/bf02646133","own_work_of_paper":true},"paper":"doi:10.1007/bf02646133","paper_id":"doi:10.1007/bf02646133","pid":"doi:10.1007/bf02646133/p5/text-01/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"It shows a liquid miscibility gap with a maximum at about 4220 K and the compositions XN = 0.0070 and xN = 0.4984 at the monotectic temperature of 3064.5 K.","quote_page":5,"reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-N","system":"AL-N","temperature_K":4220.0,"temperature_printed":"4220 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":4220.0},{"chemical_system":"AL-N","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-D2YCJMYKFO.e612da","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/bf02646133/p5/text-01"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/bf02646133","own_work_of_paper":true},"paper":"doi:10.1007/bf02646133","paper_id":"doi:10.1007/bf02646133","pid":"doi:10.1007/bf02646133/p5/text-01/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"It shows a liquid miscibility gap with a maximum at about 4220 K and the compositions XN = 0.0070 and xN = 0.4984 at the monotectic temperature of 3064.5 K.","quote_page":5,"reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-N","system":"AL-N","temperature_K":3064.5,"temperature_printed":"3064.5 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":3064.5},{"chemical_system":"AL-N","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-6ZFW6EL627","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/bf02646133/p5/text-01"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/bf02646133","own_work_of_paper":true},"paper":"doi:10.1007/bf02646133","paper_id":"doi:10.1007/bf02646133","pid":"doi:10.1007/bf02646133/p5/text-01/s05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Figure 5 gives a magnification of the region around the melting point of A1N, which is here given as 3067.7 K.","quote_page":5,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-N","system":"AL-N","temperature_K":3067.7,"temperature_printed":"3067.7 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":3067.7},{"chemical_system":"AL-N","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-EQFVFVVBYM","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/bf02646133/p5/text-01"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/bf02646133","own_work_of_paper":true},"paper":"doi:10.1007/bf02646133","paper_id":"doi:10.1007/bf02646133","pid":"doi:10.1007/bf02646133/p5/text-01/s14#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The sublimation point at 1 bar is obtained at T = 2690 K, in agreement with Figure 7.","quote_page":5,"reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-N","system":"AL-N","temperature_K":2690.0,"temperature_printed":"2690 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2690.0},{"chemical_system":"AL-N","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":4,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-KRCDKG5FIO","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/bf02646133/p5/text-01"},"observation_type":"equilibrium_property","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/bf02646133","own_work_of_paper":true},"paper":"doi:10.1007/bf02646133","paper_id":"doi:10.1007/bf02646133","pid":"doi:10.1007/bf02646133/p5/text-01/s15#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"VAPOR_PRESSURE","property_group":"activity / EMF / Gibbs energy","property_printed":"p","quote":"The triple point is found at 9.75 bar and 3067.7 K.","quote_page":5,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-N","system":"AL-N","temperature_K":3067.7,"temperature_printed":"3067.7 K","tool_release":"release v2 + tools dev copy record build","uncertainty":{"basis":"stated_default","note":"10% placeholder; none printed","value":0.975},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property VAPOR_PRESSURE","sigma_method":{"reason":"no method floor defined for property VAPOR_PRESSURE","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"bar","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"bar","value":9.75},{"chemical_system":"AL-N","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-H6KM4RHK3B","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/bf02646133/p7/text-73"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/bf02646133","own_work_of_paper":true},"paper":"doi:10.1007/bf02646133","paper_id":"doi:10.1007/bf02646133","pid":"doi:10.1007/bf02646133/p7/text-73/s05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The following values were obtained by neglecting the N content in A15Fe4: L + solid A1N + fcc + e: T = 1644.4K","quote_page":7,"reaction":{"printed":"L + solid A1N + fcc + e"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-N","system":"AL-N","temperature_K":1644.4,"temperature_printed":"1644.4 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1644.4},{"chemical_system":"AL-N","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-012-0073-5"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-IUPP7UBIJF","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-012-0073-5/p10/text-73"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11669-012-0073-5","own_work_of_paper":true},"paper":"doi:10.1007/s11669-012-0073-5","paper_id":"doi:10.1007/s11669-012-0073-5","pid":"doi:10.1007/s11669-012-0073-5/p10/text-73/s04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The average value of temperature between the above mentioned 2300 °C (2573 K) and 2100 °C (2373 K), i.e. 2473 K was taken as experimental point determining a maximum of the miscibility gap.","quote_page":10,"reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-N","system":"AL-N","temperature_K":2473.0,"temperature_printed":"2473 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2473.0},{"chemical_system":"AL-N","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-5J35GNAPM4","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-012-0073-5/p10/text-73"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/s11669-012-0073-5","own_work_of_paper":true},"paper":"doi:10.1007/s11669-012-0073-5","paper_id":"doi:10.1007/s11669-012-0073-5","pid":"doi:10.1007/s11669-012-0073-5/p10/text-73/s06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"According to our calculation the separation of the 2H solid solution starts at 2420 K.","quote_page":10,"reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-N","system":"AL-N","temperature_K":2420.0,"temperature_printed":"2420 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2420.0},{"chemical_system":"AL-N","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-HEQ5QSECHM","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-012-0073-5/p5/text-36"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/s11669-012-0073-5","own_work_of_paper":true},"paper":"doi:10.1007/s11669-012-0073-5","paper_id":"doi:10.1007/s11669-012-0073-5","pid":"doi:10.1007/s11669-012-0073-5/p5/text-36/s01#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The a coefficient was obtained by optimization to be equal to  16925.7 in order to reproduce the eutectoid decomposition of the 2H-phase at 1715 K.","quote_page":5,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-N","system":"AL-N","temperature_K":1715.0,"temperature_printed":"1715 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1715.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"AL-N"}