{"artifacts":{"sha256:ff4f6d4b8815e3bb/p10/tab-4":{"artifact":"table","caption":"The partial enthalpy of dissolution of the pure metals and the single ␥-alloy Ti 25.3 Nb 19.0 Al 55.7 in pure Ni at inﬁnite dilution at the temperature 1773 ± 5 K","label":"4","page":10}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{"doi:10.1016/j.jallcom.2008.05.008":{"context_id":"context:source-doi-10-1016-j-jallcom-2008-05-008","items":[{"extraction_accepted":true,"id":"ORC-CXEYXDAMD4","instrument":"JEOL Superprobe 733","method":"Scanning electron microscopy (SEM)","page":4,"quote":"Scanning electron microscopy (SEM) was carried out in a JEOL Superprobe 733.","second_reader_agrees":true,"type":"measurement"},{"extraction_accepted":true,"id":"ORC-HLPKFGBJA7","instrument":"DRON-3 diffractometer","method":"XRD","page":4,"quote":"XRD was carried out in a DRON-3 diffractometer on metallographic sections for ductile samples and on powders for brittle samples, respectively.","second_reader_agrees":true,"type":"measurement"},{"extraction_accepted":false,"id":"ORC-OBVPZDNBG4","instrument":"Gemini 1550 scanning electron microscope equipped with an INCA analysis system","method":"EDS","page":4,"quote":"The integral chemical composition of the samples was measured by EDS in a Gemini 1550 scanning electron microscope equipped with an INCA analysis system.","second_reader_agrees":false,"type":"measurement"},{"applies_to":"samples nos. 2, 3, 7 and 11","extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-3HQOBZGDKK","page":6,"quote":"The solidus temperature for the samples nos. 2, 3, 7 and 11 (incipient melting) were also determined using the method devised by Pirani and Alterthum [31].","second_reader_agrees":false,"type":"measurement"},{"extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-QP7S7LFHUG","page":6,"quote":"Its maximum instrumental errors amount to ±2.8 K for the temperature region 1200-1700 K and ±4 K for 1700-2300 K.","second_reader_agrees":false,"stated_uncertainty":"±2.8 K for the temperature region 1200-1700 K and ±4 K for 1700-2300 K","type":"measurement"},{"atmosphere":"high purity He","extraction_accepted":true,"heating_or_cooling_rate":"20 or 40 K min-1","id":"ORC-RHQM6A5X7O","method":"DTA","page":6,"quote":"The DTA measurements were performed under high purity He with heating and cooling rates of 20 or 40 K min-1 .","second_reader_agrees":true,"type":"measurement"},{"calibration":"W/W-20Re string thermocouples designed by Kocherzhinsky et al. [29,30]","crucible":"Sc2 O3 crucibles","extraction_accepted":true,"id":"ORC-TWG2IZ2BQ2","method":"DTA","page":6,"quote":"Temperatures of solid-state and solid-liquid phase transformations were determined by DTA using Sc2 O3 crucibles and W/W-20Re string thermocouples designed by Kocherzhinsky et al. [29,30].","second_reader_agrees":true,"type":"measurement"},{"extraction_accepted":false,"id":"ORC-C7LJUQHVM3","method":"drop isoperibolic calorimetry","page":7,"quote":"The method is well described in Refs. [33,34] and involves the determination of the enthalpy of dissolution of pure solid Al, Nb, Ti as well as that of the alloy in liquid Ni at 1773 ± 5 K by drop isoperibolic calorimetry.","second_reader_agrees":false,"type":"measurement"},{"extraction_accepted":false,"id":"ORC-Q3FDSQQIV5","label":"26 different samples","page":4,"quote":"In order to verify phase equilibria in the Al-Nb and Al-Nb-Ti systems a number of 26 different samples, with a mass of 15 or 20 g each, were prepared (Table 2) by arc melting with a non-consumable tungsten electrode on a water-cooled copper hearth under purified Ar (cooling rates of about 100 K s-1 ).","second_reader_agrees":false,"synthesis":"arc melting with a non-consumable tungsten electrode on a water-cooled copper hearth under purified Ar (cooling rates of about 100 K s-1 )","type":"sample"},{"extraction_accepted":true,"id":"ORC-GO545ICUJR","label":"samples nos. 2, 3, 7 and 11","page":6,"quote":"The solidus temperature for the samples nos. 2, 3, 7 and 11 (incipient melting) were also determined using the method devised by Pirani and Alterthum [31].","second_reader_agrees":true,"type":"sample"},{"extraction_accepted":true,"id":"ORC-BS4JKAW5BM","label":"no. 18 in Table 2","measured_composition":"Ti25.3 Nb19.0 Al55.7","page":7,"quote":"Within the frame of the present work the standard enthalpy of formation at 298 K was experimentally determined for the ␥ single-phase sample Ti25.3 Nb19.0 Al55.7 (no. 18 in Table 2) annealed for 8 h at 1673 K.","second_reader_agrees":true,"type":"sample"},{"extraction_accepted":false,"id":"ORC-QEDDB2A5TZ","nominal_composition":"nominal Nb content of 8 at.% and Al contents of 45, 46, 47 and 48 at.%, respectively","page":7,"quote":"Fig. 6 depicts selected heating curves obtained by DTA for a series of samples with the nominal Nb content of 8 at.% and Al contents of 45, 46, 47 and 48 at.%, respectively.","second_reader_agrees":false,"type":"sample"},{"applies_to":"Ti25.3 Nb19.0 Al55.7 (no. 18 in Table 2)","duration":"8 h","duration_parsed":{"hours":8.0,"printed":"8 h"},"extraction_accepted":true,"id":"ORC-T3AE2O3YMS","page":7,"quote":"Within the frame of the present work the standard enthalpy of formation at 298 K was experimentally determined for the ␥ single-phase sample Ti25.3 Nb19.0 Al55.7 (no. 18 in Table 2) annealed for 8 h at 1673 K.","second_reader_agrees":true,"temperature":{"T_K":1673.0,"converted_in_code":false,"printed":"1673 K","unit_basis":"printed_with_value","unit_printed":"K","value_printed":1673.0},"temperature_printed":"1673 K","temperature_status":"parsed_from_printed","type":"treatment"}],"paper":"doi:10.1016/j.jallcom.2008.05.008","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash / exp-context-v2.1-quote","claude-opus-5.5 / exp-context-v2.1-quote (claude broker)"],"section_basis":"own_work_method_cues"}},"elements":["AL","NB","NI","TI"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/j.jallcom.2008.05.008":{"authors":["V.T. Witusiewicz","A.A. Bondar","U. Hecht","T.Ya. Velikanova"],"citation":"V.T. Witusiewicz, A.A. Bondar, U. Hecht, T.Ya. Velikanova, The Al–B–Nb–Ti system, Journal of Alloys and Compounds 472, 133-161 (2009).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2008.05.008","doi_url":"https://doi.org/10.1016/j.jallcom.2008.05.008","id":"doi:10.1016/j.jallcom.2008.05.008","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"ff4f6d4b8815e3bb","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"The Al–B–Nb–Ti system","year":2009}},"part":1,"parts":1,"records":[{"chemical_system":"AL-NB-NI-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2008.05.008"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-ORTDT2CYNV.86be06","locator":{"ref":"sha256:ff4f6d4b8815e3bb/p10/tab-4","row":1},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2008.05.008","own_work_of_paper":true},"overall_composition":{"NB":1.0,"NI":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2008.05.008","paper_id":"doi:10.1016/j.jallcom.2008.05.008","phases":[{"label":"UNKNOWN"}],"pid":"sha256:ff4f6d4b8815e3bb/p10/tab-4/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔdissH̄i°","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-NB-NI-TI","system":"AL-NB-NI-TI","temperature_K":1773.0,"temperature_basis":"printed","temperature_uncertainty":{"basis":"printed","value":5.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.7},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.7,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.7},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"column_header","unit_printed":"kJ mol−1","unit_stored":"kJ mol−1","value":-81.3,"value_printed":-81.3,"value_stored":-81.3},{"chemical_system":"AL-NB-NI-TI","component":"NB","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2008.05.008"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-ORTDT2CYNV.f62ea2","locator":{"ref":"sha256:ff4f6d4b8815e3bb/p10/tab-4","row":1},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2008.05.008","own_work_of_paper":true},"overall_composition":{"NB":1.0,"NI":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2008.05.008","paper_id":"doi:10.1016/j.jallcom.2008.05.008","phases":[{"label":"liquid Ni"}],"pid":"sha256:ff4f6d4b8815e3bb/p10/tab-4/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔdissH°i (infinite dilution in Ni)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"LIQUID"},"NB":{"phase":"LIQUID"},"NI":{"phase":"LIQUID"},"TI":{"phase":"LIQUID"}},"source_system":"AL-NB-NI-TI","system":"AL-NB-NI-TI","temperature_K":1773.0,"temperature_basis":"printed","temperature_uncertainty":{"basis":"printed","value":5.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.7},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.7,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.7},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"column_header","unit_printed":"kJ mol−1","unit_stored":"kJ mol−1","value":-81.3,"value_printed":-81.3,"value_stored":-81.3},{"chemical_system":"AL-NB-NI-TI","component":"TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2008.05.008"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-LNFBAUXRHZ.4f9607","locator":{"ref":"sha256:ff4f6d4b8815e3bb/p10/tab-4","row":2},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2008.05.008","own_work_of_paper":true},"overall_composition":{"NB":0.0,"NI":0.0,"TI":1.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2008.05.008","paper_id":"doi:10.1016/j.jallcom.2008.05.008","phases":[{"label":"liquid Ni"}],"pid":"sha256:ff4f6d4b8815e3bb/p10/tab-4/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔdissH°i (infinite dilution in Ni)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"LIQUID"},"NB":{"phase":"LIQUID"},"NI":{"phase":"LIQUID"},"TI":{"phase":"LIQUID"}},"source_system":"AL-NB-NI-TI","system":"AL-NB-NI-TI","temperature_K":1773.0,"temperature_basis":"printed","temperature_uncertainty":{"basis":"printed","value":5.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.9},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.9,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.9},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"column_header","unit_printed":"kJ mol−1","unit_stored":"kJ mol−1","value":-88.8,"value_printed":-88.8,"value_stored":-88.8},{"chemical_system":"AL-NB-NI-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2008.05.008"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-LNFBAUXRHZ.c0166e","locator":{"ref":"sha256:ff4f6d4b8815e3bb/p10/tab-4","row":2},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2008.05.008","own_work_of_paper":true},"overall_composition":{"NB":0.0,"NI":0.0,"TI":1.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2008.05.008","paper_id":"doi:10.1016/j.jallcom.2008.05.008","phases":[{"label":"UNKNOWN"}],"pid":"sha256:ff4f6d4b8815e3bb/p10/tab-4/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔdissH̄i°","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-NB-NI-TI","system":"AL-NB-NI-TI","temperature_K":1773.0,"temperature_basis":"printed","temperature_uncertainty":{"basis":"printed","value":5.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.9},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.9,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.9},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"column_header","unit_printed":"kJ mol−1","unit_stored":"kJ mol−1","value":-88.8,"value_printed":-88.8,"value_stored":-88.8},{"chemical_system":"AL-NB-NI-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2008.05.008"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-GGYWGKOJNO.414c88","locator":{"ref":"sha256:ff4f6d4b8815e3bb/p10/tab-4","row":3},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2008.05.008","own_work_of_paper":true},"overall_composition":{"NB":0.0,"NI":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2008.05.008","paper_id":"doi:10.1016/j.jallcom.2008.05.008","phases":[{"label":"UNKNOWN"}],"pid":"sha256:ff4f6d4b8815e3bb/p10/tab-4/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔdissH̄i°","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-NB-NI-TI","system":"AL-NB-NI-TI","temperature_K":1773.0,"temperature_basis":"printed","temperature_uncertainty":{"basis":"printed","value":5.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.9},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.9,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.9},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"column_header","unit_printed":"kJ mol−1","unit_stored":"kJ mol−1","value":-98.3,"value_printed":-98.3,"value_stored":-98.3},{"chemical_system":"AL-NB-NI-TI","component":"AL","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2008.05.008"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":4,"fold_lso":3,"id":"ORC-GGYWGKOJNO.a3fecf","locator":{"ref":"sha256:ff4f6d4b8815e3bb/p10/tab-4","row":3},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2008.05.008","own_work_of_paper":true},"overall_composition":{"NB":0.0,"NI":0.0,"TI":0.0},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2008.05.008","paper_id":"doi:10.1016/j.jallcom.2008.05.008","phases":[{"label":"liquid Ni"}],"pid":"sha256:ff4f6d4b8815e3bb/p10/tab-4/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔdissH°i (infinite dilution in Ni)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"LIQUID"},"NB":{"phase":"LIQUID"},"NI":{"phase":"LIQUID"},"TI":{"phase":"LIQUID"}},"source_system":"AL-NB-NI-TI","system":"AL-NB-NI-TI","temperature_K":1773.0,"temperature_basis":"printed","temperature_uncertainty":{"basis":"printed","value":5.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.9},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.9,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.9},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"column_header","unit_printed":"kJ mol−1","unit_stored":"kJ mol−1","value":-98.3,"value_printed":-98.3,"value_stored":-98.3},{"chemical_system":"AL-NB-NI-TI","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.jallcom.2008.05.008"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":4,"fold_lso":3,"id":"ORC-CQPSZSTOHT","locator":{"ref":"sha256:ff4f6d4b8815e3bb/p10/tab-4","row":4},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2008.05.008","own_work_of_paper":true},"overall_composition":{"NB":0.19,"NI":0.0,"TI":0.253},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.jallcom.2008.05.008","paper_id":"doi:10.1016/j.jallcom.2008.05.008","phases":[{"label":"UNKNOWN"}],"pid":"sha256:ff4f6d4b8815e3bb/p10/tab-4/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔdissH̄i°","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-NB-NI-TI","system":"AL-NB-NI-TI","temperature_K":1773.0,"temperature_basis":"printed","temperature_uncertainty":{"basis":"printed","value":5.0},"tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":1.8},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.8,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":1.8},"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"column_header","unit_printed":"kJ mol−1","unit_stored":"kJ mol−1","value":-55.9,"value_printed":-55.9,"value_stored":-55.9}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"AL-NB-NI-TI"}