{"artifacts":{"doi:10.1007/s11661-005-0001-y/p1/text-01":{"artifact":"text_passage","label":"page 1, passage 1","page":1},"doi:10.1007/s11661-005-0001-y/p3/text-01":{"artifact":"text_passage","label":"page 3, passage 1","page":3},"doi:10.1007/s11661-005-0001-y/p3/text-02":{"artifact":"text_passage","label":"page 3, passage 2","page":3},"doi:10.1007/s11661-005-0001-y/p7/text-10":{"artifact":"text_passage","label":"page 7, passage 10","page":7},"doi:10.1007/s11661-005-0001-y/p9/text-20":{"artifact":"text_passage","label":"page 9, passage 20","page":9},"doi:10.1016/s0364-5916(96)00020-x/p1/text-35":{"artifact":"text_passage","label":"page 1, passage 35","page":1},"sha256:85fd53a1a176b694/p93/tab-i":{"artifact":"table","caption":"­ Invariant Reactions.","label":"I","page":93}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{"doi:10.1007/s11661-005-0001-y":{"context_id":"context:source-doi-10-1007-s11661-005-0001-y","items":[{"calibration":"7 standards, including Sn, Bi, Zn, Al, Ag, Au, and Ni","extraction_accepted":false,"id":"ORC-SVMJFUNHSX","instrument":"Netzsch DTA carrier","method":"DTA","page":2,"quote":"The Netzsch DTA carrier was calibrated with 7 standards, including Sn, Bi, Zn, Al, Ag, Au, and Ni, to ensure that the measurement would be accurate over a wide temperature range of 100 °C to 1600 °C. The overall accuracy of the DTA measurement is  3 °C.","second_reader_agrees":false,"stated_uncertainty":" 3 °C","type":"measurement"},{"applies_to":"alloy Al75Ce25","extraction_accepted":false,"heating_or_cooling_rate":"10 K/min","id":"ORC-6FRHMWXLNF","instrument":"Perkin-Elmer DTA 7","method":"DTA","page":3,"quote":"Figure 4(c) shows the DTA plot of alloy Al75Ce25, obtained with a Perkin-Elmer DTA 7, with a heating/cooling rate of 10 K/min.","second_reader_agrees":false,"type":"measurement"},{"applies_to":"alloy Al11Nd3","extraction_accepted":false,"heating_or_cooling_rate":"20 K/min","id":"ORC-BS7ZOPMNOH","method":"DSC","page":3,"quote":"Figure 4(a) shows the DSC plot for alloy Al11Nd3 at a heating rate of 20 K/min.","second_reader_agrees":false,"type":"measurement"},{"applies_to":"alloy Al76Nd24","extraction_accepted":false,"heating_or_cooling_rate":"10 K/min","id":"ORC-JAD24LR35M","instrument":"Perkin-Elmer DTA7","method":"DTA","page":3,"quote":"Figure 4(b) shows the DTA plot of alloy Al76Nd24 at a rate of 10 K/min, using a Perkin-Elmer DTA7.","second_reader_agrees":false,"type":"measurement"},{"extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-W24OPKK5C4","instrument":"JEOL* 6700","page":3,"quote":"Following heat treatment, the samples are ground with a series of SiC papers and polished using diamond paste, and finally examined in a JEOL* 6700 scan*JEOL is a trademark of Japan Electron Optics Ltd., Tokyo. ning electron microscope (SEM) for microstructure analysis.","second_reader_agrees":false,"type":"measurement"},{"calibration":"pure-element samples as external standards","extraction_accepted":true,"id":"ORC-WZD5LBQIT6","method":"Electron probe microanalysis (EPMA)","page":3,"quote":"Electron probe microanalysis (EPMA), using pure-element samples as external standards, is employed to perform all the chemical analysis. The accuracy of the EPMA measurements in this study is about 1 at. pct.","second_reader_agrees":true,"stated_uncertainty":"about 1 at. pct.","type":"measurement"},{"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-V6MAAHGGVF","label":"Al97.4Ce2.6","nominal_composition":"Al97.4Ce2.6","page":2,"quote":"A typical DTA plot is shown in Figure 2, for alloys Al97.4Ce2.6 and Al82.5Ce17.5.","second_reader_agrees":true,"type":"sample"},{"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-V6MAAHGGVF","label":"Al82.5Ce17.5","nominal_composition":"Al82.5Ce17.5","page":2,"quote":"A typical DTA plot is shown in Figure 2, for alloys Al97.4Ce2.6 and Al82.5Ce17.5.","second_reader_agrees":true,"type":"sample"},{"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-HNV32OQAQU","label":"Al11Nd3","nominal_composition":"Al11Nd3","page":3,"quote":"Figure 4(a) shows the DSC plot for alloy Al11Nd3 at a heating rate of 20 K/min.","second_reader_agrees":true,"type":"sample"},{"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-MUP5LENSZU","label":"Al77Ce23","nominal_composition":"Al77Ce23","page":3,"quote":"This kind of thermal event is also observed in alloys Al77Ce23 and Al77Ce30 on their DTA scan.","second_reader_agrees":true,"type":"sample"},{"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-MUP5LENSZU","label":"Al77Ce30","nominal_composition":"Al77Ce30","page":3,"quote":"This kind of thermal event is also observed in alloys Al77Ce23 and Al77Ce30 on their DTA scan.","second_reader_agrees":true,"type":"sample"},{"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-P3YSXIA2RZ","label":"Al75Ce25","nominal_composition":"Al75Ce25","page":3,"quote":"Figure 4(c) shows the DTA plot of alloy Al75Ce25, obtained with a Perkin-Elmer DTA 7, with a heating/cooling rate of 10 K/min.","second_reader_agrees":true,"type":"sample"},{"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-SXO5C46NA5","label":"Al40Ce60","nominal_composition":"Al40Ce60","page":3,"quote":"Figure 3 shows the DTA plot for four alloys, namely, (a) Al40Ce60, (b) Al30Ce70, (c) Al20Ce80, and (d) Al25Ce75, during the heating segment.","second_reader_agrees":true,"type":"sample"},{"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-SXO5C46NA5","label":"Al30Ce70","nominal_composition":"Al30Ce70","page":3,"quote":"Figure 3 shows the DTA plot for four alloys, namely, (a) Al40Ce60, (b) Al30Ce70, (c) Al20Ce80, and (d) Al25Ce75, during the heating segment.","second_reader_agrees":true,"type":"sample"},{"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-SXO5C46NA5","label":"Al20Ce80","nominal_composition":"Al20Ce80","page":3,"quote":"Figure 3 shows the DTA plot for four alloys, namely, (a) Al40Ce60, (b) Al30Ce70, (c) Al20Ce80, and (d) Al25Ce75, during the heating segment.","second_reader_agrees":true,"type":"sample"},{"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-SXO5C46NA5","label":"Al25Ce75","nominal_composition":"Al25Ce75","page":3,"quote":"Figure 3 shows the DTA plot for four alloys, namely, (a) Al40Ce60, (b) Al30Ce70, (c) Al20Ce80, and (d) Al25Ce75, during the heating segment.","second_reader_agrees":true,"type":"sample"},{"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-WECODP2VV3","label":"Al76Nd24","nominal_composition":"Al76Nd24","page":3,"quote":"Figure 4(b) shows the DTA plot of alloy Al76Nd24 at a rate of 10 K/min, using a Perkin-Elmer DTA7.","second_reader_agrees":true,"type":"sample"},{"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-XZXSCG6Z6A","label":"Al45Ce55","nominal_composition":"Al45Ce55","page":3,"quote":"Alloy Al45Ce55 exhibits a DTA plot similar to that of Al40Ce60, with three main peaks that occur at temperatures almost identical to Al40Ce60, plus a final melting peak.","second_reader_agrees":true,"type":"sample"},{"applies_to":"Al45Ce55 and Al40Ce60","atmosphere_or_container":"encapsulated and sealed inside silica tubes under a partial pressure of argon","cooling":"cold-water quenching","duration":"10 days","duration_parsed":{"hours":240.0,"printed":"10 days"},"extraction_accepted":true,"id":"ORC-27IWNJK4W2","page":3,"purpose":"To verify the existence and crystal structure of AlCe2 and the polymorphous transformation of AlCe3 at 250 °C","quote":"To verify the existence and crystal structure of AlCe2 and the polymorphous transformation of AlCe3 at 250 °C,[5] two samples are chosen, i.e., Al45Ce55 and Al40Ce60, for heat treatment at 700 °C, 500 °C, and 200 °C for 10 days each, followed by cold-water quenching. These samples are encapsulated and sealed inside silica tubes under a partial pressure of argon.","second_reader_agrees":true,"temperature":{"T_K":973.15,"converted_in_code":true,"printed":"700 °C","unit_basis":"printed_with_value","unit_printed":"°C","value_printed":700.0},"temperature_printed":"700 °C","temperature_status":"parsed_from_printed","type":"treatment"},{"applies_to":"Al45Ce55 and Al40Ce60","atmosphere_or_container":"encapsulated and sealed inside silica tubes under a partial pressure of argon","cooling":"cold-water quenching","duration":"10 days","duration_parsed":{"hours":240.0,"printed":"10 days"},"extraction_accepted":true,"id":"ORC-27IWNJK4W2","page":3,"purpose":"To verify the existence and crystal structure of AlCe2 and the polymorphous transformation of AlCe3 at 250 °C","quote":"To verify the existence and crystal structure of AlCe2 and the polymorphous transformation of AlCe3 at 250 °C,[5] two samples are chosen, i.e., Al45Ce55 and Al40Ce60, for heat treatment at 700 °C, 500 °C, and 200 °C for 10 days each, followed by cold-water quenching. 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Ferro, Thermodynamic modeling of some aluminium-rare earth binary systems: Al-La, Al-Ce and Al-Nd, Calphad 25, 583-597 (2001).","container":"Calphad","doi":"10.1016/s0364-5916(02)00009-3","doi_url":"https://doi.org/10.1016/s0364-5916(02)00009-3","id":"doi:10.1016/s0364-5916(02)00009-3","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"526a7155c46b6932","roles":["cited_source","reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic modeling of some aluminium-rare earth binary systems: Al-La, Al-Ce and Al-Nd","year":2001},"doi:10.1016/s0364-5916(96)00020-x":{"authors":["Wang Jixin"],"citation":"Wang Jixin, Thermodynamic evaluation of Al-Nd system, Calphad 20, 135-138 (1996).","container":"Calphad","doi":"10.1016/s0364-5916(96)00020-x","doi_url":"https://doi.org/10.1016/s0364-5916(96)00020-x","id":"doi:10.1016/s0364-5916(96)00020-x","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"47d61f3ee95b6b32","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic evaluation of Al-Nd system","year":1996},"sha256:85fd53a1a176b694":{"authors":["I. 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