{"artifacts":{"doi:10.1088/2053-1591/ab19fa/p10/tab-5":{"artifact":"table","caption":"Calculated invariant reaction of the Ni–Al–Pr ternary system.","label":"5","page":10},"doi:10.1088/2053-1591/ab19fa/p7/text-10":{"artifact":"text_passage","label":"page 7, passage 10","page":7},"sha256:c05204da44ec79d3/p6/tab-4":{"artifact":"table","caption":"Calculated enthalpies of formation of ternary intermetallic compounds .","label":"4","page":6}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["AL","NI","PR"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1088/2053-1591/ab19fa":{"authors":["Jinfa Liao","Yuehui Liao","Hang Wang","Ligang Zhang","Yue Ma"],"citation":"Jinfa Liao, Yuehui Liao, Hang Wang, Ligang Zhang, Yue Ma, Thermodynamic optimization of the Ni–Al–Pr ternary system, Mater. Res. Express 6, 086512 (2019).","container":"Mater. Res. Express","doi":"10.1088/2053-1591/ab19fa","doi_url":"https://doi.org/10.1088/2053-1591/ab19fa","id":"doi:10.1088/2053-1591/ab19fa","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"c05204da44ec79d3","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic optimization of the Ni–Al–Pr ternary system","year":2019}},"part":1,"parts":1,"records":[{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-O6ORJJTW46.507807","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":1},"merged_ids":["ORC-O6ORJJTW46.5e1fe4"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"overall_composition":{"NI":0.2,"PR":0.1},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Ni2Al7Pr","label_variants":["Ni₂Al₇Pr"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.0305},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-40.61,"value_printed":-40.61,"value_stored":-40610.0},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-UULYRIUEJS.02f3de","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":2},"merged_ids":["ORC-UULYRIUEJS.cf01c2"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"overall_composition":{"NI":0.2,"PR":0.1},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Ni₂Al₇Pr","label_variants":["Ni2Al7Pr"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.0455},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-40.91,"value_printed":-40.91,"value_stored":-40910.0},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-DVYF2XWRDN.04eb9c","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":3},"merged_ids":["ORC-DVYF2XWRDN.615e69"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"overall_composition":{"NI":0.25,"PR":0.125},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Ni2Al5Pr","label_variants":["Ni₂Al₅Pr"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.478},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-49.56,"value_printed":-49.56,"value_stored":-49560.0},{"chemical_system":"AL-NI-PR","cited_sources":[{"first_author":"Kirklin","kind":"unknown","label":"52","reference":"Kirklin S et al 2015 Npj Comp. Mater. 1 15010","status":"resolved","year":"2015"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-3ZE4GWV3ZV.2977cb","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":4},"merged_ids":["ORC-3ZE4GWV3ZV.c9b178"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"NI":0.25,"PR":0.125},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Ni2Al5Pr","label_variants":["Ni₂Al₅Pr"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"},"PR":{"phase":"DHCP"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.851},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-57.02,"value_printed":-57.02,"value_stored":-57020.0},{"chemical_system":"AL-NI-PR","cited_sources":[{"first_author":"Jain","kind":"unknown","label":"53","reference":"Jain A et al 2013 APL Mater. 1 011002","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-2MBUDOK3LY.a5c8d0","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":5},"merged_ids":["ORC-2MBUDOK3LY.c0a30e"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"NI":0.25,"PR":0.125},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Ni₂Al₅Pr","label_variants":["Ni2Al5Pr"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.822},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-56.44,"value_printed":-56.44,"value_stored":-56440.0},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-BV43LPFLC5.8aae42","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":6},"merged_ids":["ORC-BV43LPFLC5.c7c06d"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"overall_composition":{"NI":0.25,"PR":0.125},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Ni2Al5Pr","label_variants":["Ni₂Al₅Pr"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.625},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-52.5,"value_printed":-52.5,"value_stored":-52500.0},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-GY6HFTN5B5.c054a4","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":7},"merged_ids":["ORC-GY6HFTN5B5.d4cf64"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"overall_composition":{"NI":0.166667,"PR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"NiAl4Pr","label_variants":["NiAl₄Pr"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.4855},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-49.71,"value_printed":-49.71,"value_stored":-49710.0},{"chemical_system":"AL-NI-PR","cited_sources":[{"first_author":"Kirklin","kind":"unknown","label":"52","reference":"Kirklin S et al 2015 Npj Comp. Mater. 1 15010","status":"resolved","year":"2015"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-UMU3U3GRSX.5ce736","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":8},"merged_ids":["ORC-UMU3U3GRSX.a8f6fa"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"NI":0.166667,"PR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"NiAl₄Pr","label_variants":["NiAl4Pr"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"},"PR":{"phase":"DHCP"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.601},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-52.02,"value_printed":-52.02,"value_stored":-52020.0},{"chemical_system":"AL-NI-PR","cited_sources":[{"first_author":"Jain","kind":"unknown","label":"53","reference":"Jain A et al 2013 APL Mater. 1 011002","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-KWB4IDIMAR.161f4d","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":9},"merged_ids":["ORC-KWB4IDIMAR.ed723a"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"NI":0.166667,"PR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"NiAl4Pr","label_variants":["NiAl₄Pr"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.5915},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-51.83,"value_printed":-51.83,"value_stored":-51830.0},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-TCQASYORN5.5fc827","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":10},"merged_ids":["ORC-TCQASYORN5.b1afb3"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"overall_composition":{"NI":0.166667,"PR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"NiAl4Pr","label_variants":["NiAl₄Pr"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.4955},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-49.91,"value_printed":-49.91,"value_stored":-49910.0},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-EML7MXJBZG.53809d","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":11},"merged_ids":["ORC-EML7MXJBZG.72a4de"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"overall_composition":{"NI":0.333333,"PR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Ni2Al3Pr","label_variants":["Ni₂Al₃Pr"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.067},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-61.34,"value_printed":-61.34,"value_stored":-61340.0},{"chemical_system":"AL-NI-PR","cited_sources":[{"first_author":"Kirklin","kind":"unknown","label":"52","reference":"Kirklin S et al 2015 Npj Comp. Mater. 1 15010","status":"resolved","year":"2015"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-IIFS7E73AH.2c3284","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":12},"merged_ids":["ORC-IIFS7E73AH.5b69b4"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"NI":0.333333,"PR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Ni2Al3Pr","label_variants":["Ni₂Al₃Pr"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r12#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"},"PR":{"phase":"DHCP"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.9085},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-58.17,"value_printed":-58.17,"value_stored":-58170.0},{"chemical_system":"AL-NI-PR","cited_sources":[{"first_author":"Jain","kind":"unknown","label":"53","reference":"Jain A et al 2013 APL Mater. 1 011002","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-V4FGAD4FTA.13e3ef","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":13},"merged_ids":["ORC-V4FGAD4FTA.693c79"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"NI":0.333333,"PR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Ni2Al3Pr","label_variants":["Ni₂Al₃Pr"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r13#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.8605},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-57.21,"value_printed":-57.21,"value_stored":-57210.0},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-47CJFTHNYF.1c3818","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":14},"merged_ids":["ORC-47CJFTHNYF.9bc593"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"overall_composition":{"NI":0.333333,"PR":0.166667},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Ni₂Al₃Pr","label_variants":["Ni2Al3Pr"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r14#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.1205},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-62.41,"value_printed":-62.41,"value_stored":-62410.0},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-IMD4244FIX.48561a","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":15},"merged_ids":["ORC-IMD4244FIX.6253fa"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"overall_composition":{"NI":0.25,"PR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"NiAl₂Pr","label_variants":["NiAl2Pr"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r15#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.316},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-66.32,"value_printed":-66.32,"value_stored":-66320.0},{"chemical_system":"AL-NI-PR","cited_sources":[{"first_author":"Jain","kind":"unknown","label":"53","reference":"Jain A et al 2013 APL Mater. 1 011002","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-DRINF3WXUW.9dd593","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":16},"merged_ids":["ORC-DRINF3WXUW.b94d35"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"NI":0.25,"PR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"NiAl2Pr","label_variants":["NiAl₂Pr"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r16#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.751},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-55.02,"value_printed":-55.02,"value_stored":-55020.0},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-QWEDHM3DYN.90522e","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":17},"merged_ids":["ORC-QWEDHM3DYN.ef8d31"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"overall_composition":{"NI":0.25,"PR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"NiAl₂Pr","label_variants":["NiAl2Pr"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.3105},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-66.21,"value_printed":-66.21,"value_stored":-66210.0},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-GW4TTRFD5N.dcfdf8","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":18},"merged_ids":["ORC-GW4TTRFD5N.eeca98"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"overall_composition":{"NI":0.666667,"PR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Ni₈AlPr₃","label_variants":["Ni8AlPr3"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.859},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-37.18,"value_printed":-37.18,"value_stored":-37180.0},{"chemical_system":"AL-NI-PR","cited_sources":[{"first_author":"Jain","kind":"unknown","label":"53","reference":"Jain A et al 2013 APL Mater. 1 011002","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-RNIZE2T3B5.91e015","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":19},"merged_ids":["ORC-RNIZE2T3B5.96da1f"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"NI":0.666667,"PR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Ni8AlPr3","label_variants":["Ni₈AlPr₃"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r19#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.548},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-30.96,"value_printed":-30.96,"value_stored":-30960.0},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-ZN2SD64CUS.21f1de","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":20},"merged_ids":["ORC-ZN2SD64CUS.88ed13"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"overall_composition":{"NI":0.666667,"PR":0.25},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Ni₈AlPr₃","label_variants":["Ni8AlPr3"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r20#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.9295},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-38.59,"value_printed":-38.59,"value_stored":-38590.0},{"chemical_system":"AL-NI-PR","cited_sources":[{"first_author":"Borzone","kind":"unknown","label":"38","reference":"Borzone G, Raggio R and Delsante S 2003 Intermetallics 11 1217–22","status":"resolved","year":"2003"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-6FDZV64ILN.5080eb","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":21},"merged_ids":["ORC-6FDZV64ILN.bf3086"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"NI":0.333333,"PR":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"NiAlPr"}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r21#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":300.0,"temperature_basis":"printed","temperature_printed":"300 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"printed","value":3.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":{"kind":"plus_minus_coverage_not_stated","taken_as":"1 sigma","value":3.0},"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol−1","unit_stored":"J/mol-atom","value":-56.0,"value_printed":-56,"value_stored":-56000.0},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-LX55FPX3UB","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":22},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"overall_composition":{"NI":0.333333,"PR":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"NiAlPr"}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r22#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.3485},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-66.97,"value_printed":-66.97,"value_stored":-66970.0},{"chemical_system":"AL-NI-PR","cited_sources":[{"first_author":"Kirklin","kind":"unknown","label":"52","reference":"Kirklin S et al 2015 Npj Comp. Mater. 1 15010","status":"resolved","year":"2015"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-O26DKNIH2Y","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":23},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"NI":0.333333,"PR":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"NiAlPr"}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r23#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"},"PR":{"phase":"DHCP"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.38},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-47.6,"value_printed":-47.6,"value_stored":-47600.0},{"chemical_system":"AL-NI-PR","cited_sources":[{"first_author":"Jain","kind":"unknown","label":"53","reference":"Jain A et al 2013 APL Mater. 1 011002","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-ZKV4HLBZE6","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":24},"observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"NI":0.333333,"PR":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"NiAlPr"}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r24#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.327},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-46.54,"value_printed":-46.54,"value_stored":-46540.0},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-TJIGRAE3UR","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":25},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"overall_composition":{"NI":0.333333,"PR":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"NiAlPr"}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r25#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.1035},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-62.07,"value_printed":-62.07,"value_stored":-62070.0},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-REJY3TRGYM.07d430","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":26},"merged_ids":["ORC-REJY3TRGYM.ac510e"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"overall_composition":{"NI":0.4,"PR":0.4},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Ni2AlPr2","label_variants":["Ni₂AlPr₂"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r26#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.7095},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-54.19,"value_printed":-54.19,"value_stored":-54190.0},{"chemical_system":"AL-NI-PR","cited_sources":[{"first_author":"Kirklin","kind":"unknown","label":"52","reference":"Kirklin S et al 2015 Npj Comp. Mater. 1 15010","status":"resolved","year":"2015"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","state:computation_context","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-SSF3O7Z5E5.081357","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":27},"merged_ids":["ORC-SSF3O7Z5E5.197429"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"NI":0.4,"PR":0.4},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Ni2AlPr2","label_variants":["Ni₂AlPr₂"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r27#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"FCC_A1"},"NI":{"phase":"FCC_A1"},"PR":{"phase":"DHCP"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.024},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-40.48,"value_printed":-40.48,"value_stored":-40480.0},{"chemical_system":"AL-NI-PR","cited_sources":[{"first_author":"Jain","kind":"unknown","label":"53","reference":"Jain A et al 2013 APL Mater. 1 011002","status":"resolved","year":"2013"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-NCAQTNBNAI.19136e","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":28},"merged_ids":["ORC-NCAQTNBNAI.50423d"],"observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"NI":0.4,"PR":0.4},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Ni₂AlPr₂","label_variants":["Ni2AlPr2"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r28#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.9185},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.929,"sigma_method":{"basis":"calibrated","ci95":[2.742,4.87],"class":"dft","entry":"dft/literature/strata/magnetic_3d","floor":3.929,"floor_unit":"kJ/mol-atom","n_pairs":105,"stratum":"literature/magnetic_3d","value":3.929},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-38.37,"value_printed":-38.37,"value_stored":-38370.0},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":0,"id":"ORC-FIVLT3ATCL.757a28","locator":{"ref":"sha256:c05204da44ec79d3/p6/tab-4","row":29},"merged_ids":["ORC-FIVLT3ATCL.f34a2c"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"overall_composition":{"NI":0.4,"PR":0.4},"overall_composition_basis":"from_formula","paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Ni2AlPr2","label_variants":["Ni₂AlPr₂"]}],"pid":"sha256:c05204da44ec79d3/p6/tab-4/r29#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"Enthalpy of formation","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"NI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.8005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ mol⁻¹","unit_stored":"J/mol-atom","value":-56.01,"value_printed":-56.01,"value_stored":-56010.0},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-NZ4NZJX34C","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":1},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ7"},{"label":"τ4"},{"label":"τ5"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + τ7 -> τ4 + τ5","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1644.15,"temperature_printed":"1371","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1644.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-ISI57EBPDZ","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":2},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ2"},{"label":"τ5"},{"label":"τ4"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> τ2 + τ5 + τ4","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1613.15,"temperature_printed":"1340","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1613.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-RZR6IQ4FRN","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":3},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ2"},{"label":"NiAl"},{"label":"τ4"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> τ2 + NiAl + τ4","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1545.15,"temperature_printed":"1272","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1545.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-V26AXFOR2W","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":4},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ6"},{"label":"Ni5Pr","model_phase":"NI5PR_D2D","pearson_symbol":"hP6","prototype":"CaCu5","structure_basis":"mapped_model_phase"},{"label":"fcc","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> τ6 + Ni5Pr + fcc","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1530.15,"temperature_printed":"1257","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1530.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-4MZINYLB5Y","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":5},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"NiAl"},{"label":"τ4"},{"label":"τ7"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> NiAl + τ4 + τ7","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1511.15,"temperature_printed":"1238","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1511.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-MJZ45NNCSP","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":6},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ2"},{"label":"τ3"},{"label":"τ5"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + τ2 -> τ3 + τ5","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1491.15,"temperature_printed":"1218","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1491.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-BMABMXY5UZ","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":7},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"Ni5Pr","model_phase":"NI5PR_D2D","pearson_symbol":"hP6","prototype":"CaCu5","structure_basis":"mapped_model_phase"},{"label":"τ6"},{"label":"Ni17Pr2"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + Ni5Pr -> τ6 + Ni17Pr2","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1490.15,"temperature_printed":"1217","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1490.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-7DFWYNAMSE","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":8},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ6"},{"label":"fcc","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Ni5Pr","model_phase":"NI5PR_D2D","pearson_symbol":"hP6","prototype":"CaCu5","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + τ6 + fcc -> Ni5Pr","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1454.15,"temperature_printed":"1181","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1454.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-RXBQE3JWLD","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":9},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ7"},{"label":"τ6"},{"label":"τ8"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r09#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> τ7 + τ6 + τ8","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1419.15,"temperature_printed":"1146","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1419.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-KIR4Z5FCPI","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":10},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ5"},{"label":"PrAl2"},{"label":"τ3"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> τ5 + PrAl2 + τ3","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1414.15,"temperature_printed":"1141","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1414.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-LY5WHT3UPU","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":11},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"fcc","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Ni5Pr","model_phase":"NI5PR_D2D","pearson_symbol":"hP6","prototype":"CaCu5","structure_basis":"mapped_model_phase"},{"label":"Ni3Al"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r11#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + fcc -> Ni5Pr + Ni3Al","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1403.15,"temperature_printed":"1130","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1403.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":null,"before":"BCC_A2","evidence":{"label":"β_Pr3Al11","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"greek_or_compound_label_mapped_to_element_structure"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-3AVAVZFKX7","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":12},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"PrAl2"},{"label":"τ3"},{"label":"β_Pr3Al11","model_phase_rejected":{"model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","reason":"greek_or_compound_label_mapped_to_element_structure"}}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> PrAl2 + τ3 + β_Pr3Al11","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1396.15,"temperature_printed":"1123","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1396.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-5TDM75OSZ6","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":13},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"NiAl"},{"label":"Al3Ni2"},{"label":"τ2"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r13#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + NiAl -> Al3Ni2 + τ2","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1375.15,"temperature_printed":"1102","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1375.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-PXPGVPN2DT","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":14},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"Ni5Pr","model_phase":"NI5PR_D2D","pearson_symbol":"hP6","prototype":"CaCu5","structure_basis":"mapped_model_phase"},{"label":"Ni3Al"},{"label":"NiAl"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r14#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> Ni5Pr + Ni3Al + NiAl","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1362.15,"temperature_printed":"1089","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1362.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-KCJW3JNRTR","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":15},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"Ni5Pr","model_phase":"NI5PR_D2D","pearson_symbol":"hP6","prototype":"CaCu5","structure_basis":"mapped_model_phase"},{"label":"τ7"},{"label":"τ6"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r15#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> Ni5Pr + τ7 + τ6","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1359.15,"temperature_printed":"1086","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1359.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-AAFCX4VUD4","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":16},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"Ni5Pr","model_phase":"NI5PR_D2D","pearson_symbol":"hP6","prototype":"CaCu5","structure_basis":"mapped_model_phase"},{"label":"NiAl"},{"label":"τ7"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r16#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> Ni5Pr + NiAl + τ7","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1338.15,"temperature_printed":"1065","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1338.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-264TCNCGTR","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":17},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"Ni17Pr2"},{"label":"τ6"},{"label":"Ni3Pr","model_phase":"NI3PR","pearson_symbol":"hR12","prototype":"Ni3Pu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r17#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + Ni17Pr2 -> τ6 + Ni3Pr","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1268.15,"temperature_printed":"995","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1268.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-WRPZF4SPFS","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":18},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ6"},{"label":"Ni3Pr","model_phase":"NI3PR","pearson_symbol":"hR12","prototype":"Ni3Pu","structure_basis":"mapped_model_phase"},{"label":"Ni2Pr","model_phase":"NI2PR_C15","pearson_symbol":"cF24","prototype":"Cu2Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r18#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + τ6 + Ni3Pr -> Ni2Pr","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1240.15,"temperature_printed":"967","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1240.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":null,"before":"BCC_A2","evidence":{"label":"β_Pr3Al11","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"greek_or_compound_label_mapped_to_element_structure"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-U7KOI2WRZY","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":19},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"β_Pr3Al11","model_phase_rejected":{"model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","reason":"greek_or_compound_label_mapped_to_element_structure"}},{"label":"τ3"},{"label":"α_Pr3Al11","model_phase":"AL11PR3_ALPHA"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r19#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + β_Pr3Al11 -> τ3 + α_Pr3Al11","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1238.15,"temperature_printed":"965","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1238.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-JM5FKK43YA","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":20},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ2"},{"label":"τ3"},{"label":"τ1"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r20#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + τ2 -> τ3 + τ1","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1221.15,"temperature_printed":"948","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1221.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-T5TRICLVBR","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":21},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ2"},{"label":"τ1"},{"label":"Al3Ni2"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r21#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + τ2 -> τ1 + Al3Ni2","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1158.15,"temperature_printed":"885","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1158.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-LRFJLSGFMJ","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":22},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"Al3Ni2"},{"label":"Al3Ni","model_phase":"AL3NI_D011","pearson_symbol":"oP16","prototype":"Fe3C","structure_basis":"mapped_model_phase"},{"label":"τ1"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r22#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + Al3Ni2 -> Al3Ni + τ1","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1110.15,"temperature_printed":"837","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1110.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-A5TX4LTOXR","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":23},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ3"},{"label":"α_Pr3Al11","model_phase":"AL11PR3_ALPHA"},{"label":"τ1"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r23#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + τ3 -> α_Pr3Al11 + τ1","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1100.15,"temperature_printed":"827","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1100.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-6CFDZB2QW5","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":24},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ5"},{"label":"τ7"},{"label":"PrAl2"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r24#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + τ5 -> τ7 + PrAl2","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1074.15,"temperature_printed":"801","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1074.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-GK46FY3M4Q","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":25},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ6"},{"label":"τ8"},{"label":"Ni2Pr","model_phase":"NI2PR_C15","pearson_symbol":"cF24","prototype":"Cu2Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r25#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + τ6 -> τ8 + Ni2Pr","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1073.15,"temperature_printed":"800","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1073.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-C3WSKJKD37","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":26},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"Ni2Pr","model_phase":"NI2PR_C15","pearson_symbol":"cF24","prototype":"Cu2Mg","structure_basis":"mapped_model_phase"},{"label":"τ8"},{"label":"NiPr","model_phase":"NIPR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r26#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + Ni2Pr -> τ8 + NiPr","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":934.15,"temperature_printed":"661","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":934.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-IGQ3XY2X2O","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":27},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ1"},{"label":"α_Pr3Al11","model_phase":"AL11PR3_ALPHA"},{"label":"Al3Ni","model_phase":"AL3NI_D011","pearson_symbol":"oP16","prototype":"Fe3C","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r27#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + τ1 -> α_Pr3Al11 + Al3Ni","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":909.15,"temperature_printed":"636","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":909.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-V77U2YT66D","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":28},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"α_Pr3Al11","model_phase":"AL11PR3_ALPHA"},{"label":"fcc","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"τ1"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r28#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> α_Pr3Al11 + fcc + τ1","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":894.15,"temperature_printed":"621","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":894.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-UGHMOJWHLY","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":29},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"bcc","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"Liq","model_phase":"LIQUID"},{"label":"dhcp"},{"label":"Pr3Al"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r29#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"bcc -> Liq + dhcp + Pr3Al","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":895.15,"temperature_printed":"622","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":895.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-TUTOYLIYVB","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":30},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ7"},{"label":"dhcp"},{"label":"τ8"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r30#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> τ7 + dhcp + τ8","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":815.15,"temperature_printed":"542","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":815.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-E3HHW5MING","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":31},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"PrAl2"},{"label":"τ7"},{"label":"PrAl"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r31#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + PrAl2 -> τ7 + PrAl","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":784.15,"temperature_printed":"511","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":784.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-TNF3MIPNIH","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":32},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ8"},{"label":"NiPr3","model_phase":"NIPR3_D011","pearson_symbol":"oP16","prototype":"Fe3C","structure_basis":"mapped_model_phase"},{"label":"Ni3Pr7","model_phase":"NI3PR7_D102","pearson_symbol":"hP20","prototype":"Fe3Th7","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r32#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> τ8 + NiPr3 + Ni3Pr7","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":780.15,"temperature_printed":"507","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":780.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-HYEPCWFULH","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":33},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"dhcp"},{"label":"τ8"},{"label":"NiPr3","model_phase":"NIPR3_D011","pearson_symbol":"oP16","prototype":"Fe3C","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r33#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> dhcp + τ8 + NiPr3","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":772.15,"temperature_printed":"499","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":772.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-RIV5BJEEFY","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":34},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ8"},{"label":"Ni3Pr7","model_phase":"NI3PR7_D102","pearson_symbol":"hP20","prototype":"Fe3Th7","structure_basis":"mapped_model_phase"},{"label":"NiPr","model_phase":"NIPR_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r34#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> τ8 + Ni3Pr7 + NiPr","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":771.15,"temperature_printed":"498","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":771.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-M4PDANGH6R","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":35},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"PrAl"},{"label":"τ7"},{"label":"Pr2Al"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r35#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + PrAl -> τ7 + Pr2Al","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":720.15,"temperature_printed":"447","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":720.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-MUZMBWZL3C","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":36},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"Pr2Al"},{"label":"τ7"},{"label":"Pr3Al"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r36#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + Pr2Al -> τ7 + Pr3Al","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":650.15,"temperature_printed":"377","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":650.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":0,"id":"ORC-IOBALHZFQA","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p10/tab-5","row":37},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","phases":[{"label":"Liq","model_phase":"LIQUID"},{"label":"τ7"},{"label":"Pr3Al"},{"label":"dhcp"}],"pid":"doi:10.1088/2053-1591/ab19fa/p10/tab-5/r37#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> τ7 + Pr3Al + dhcp","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":626.15,"temperature_printed":"353","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":626.15},{"chemical_system":"AL-NI-PR","citations_printed":["19"],"conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-IWNSZJAHA4","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p7/text-10"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","pid":"doi:10.1088/2053-1591/ab19fa/p7/text-10/s07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"For the Al11Pr3 phase, the allotropic transformation was included, and the transformation temperature between the α-Al11Pr3 and β-Al11Pr3 phases is 965 °C, which is the same as that in the literature [19].","quote_page":7,"reaction":{"type":"polymorphic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1238.15,"temperature_printed":"965.0 C","tool_release":"release v2 + tools dev copy record build","transition_kind":"polymorphic","transition_kind_printed":"polymorphic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1238.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-OV76BX4NT5.53c9cb","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p7/text-10"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","pid":"doi:10.1088/2053-1591/ab19fa/p7/text-10/s08#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The temperatures of the related invariant reactions, Liq+Al2Pr→β-Al11Pr3 and β-Al11Pr3+Al2Pr→Al3Pr were 1246 °C and 1075 °C, respectively, which is consistent with the experimental data.","quote_page":7,"reaction":{"printed":"β-Al11Pr3 + Al2Pr -> Al3Pr"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1348.15,"temperature_printed":"1075.0 C","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1348.15},{"chemical_system":"AL-NI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-OV76BX4NT5.883e47","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1088/2053-1591/ab19fa/p7/text-10"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1088/2053-1591/ab19fa","own_work_of_paper":true},"paper":"doi:10.1088/2053-1591/ab19fa","paper_id":"doi:10.1088/2053-1591/ab19fa","pid":"doi:10.1088/2053-1591/ab19fa/p7/text-10/s08#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The temperatures of the related invariant reactions, Liq+Al2Pr→β-Al11Pr3 and β-Al11Pr3+Al2Pr→Al3Pr were 1246 °C and 1075 °C, respectively, which is consistent with the experimental data.","quote_page":7,"reaction":{"printed":"Liq + Al2Pr -> β-Al11Pr3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-NI-PR","system":"AL-NI-PR","temperature_K":1519.15,"temperature_printed":"1246.0 C","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1519.15}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"AL-NI-PR"}