{"artifacts":{"doi:10.1016/j.actamat.2014.02.042/p14/text-02":{"artifact":"text_passage","label":"page 14, passage 2","page":14},"doi:10.1016/j.actamat.2014.02.042/p15/text-06":{"artifact":"text_passage","label":"page 15, passage 6","page":15},"doi:10.1016/j.actamat.2014.02.042/p5/text-74":{"artifact":"text_passage","label":"page 5, passage 74","page":5},"doi:10.1016/j.actamat.2014.02.042/p8/text-43":{"artifact":"text_passage","label":"page 8, passage 43","page":8}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["AL","P","SI"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/j.actamat.2014.02.042":{"authors":["Song-Mao Liang","Rainer Schmid-Fetzer"],"citation":"Song-Mao Liang, Rainer Schmid-Fetzer, Phosphorus in Al–Si cast alloys: Thermodynamic prediction of the AlP and eutectic (Si) solidification sequence validated by microstructure and nucleation undercooling data, Acta Materialia 72, 41-56 (2014).","container":"Acta Materialia","doi":"10.1016/j.actamat.2014.02.042","doi_url":"https://doi.org/10.1016/j.actamat.2014.02.042","id":"doi:10.1016/j.actamat.2014.02.042","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"263ea1333af518a1","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Phosphorus in Al–Si cast alloys: Thermodynamic prediction of the AlP and eutectic (Si) solidification sequence validated by microstructure and nucleation undercooling data","year":2014}},"part":1,"parts":1,"records":[{"chemical_system":"AL-P-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:1)","effect":"not_accepted","gate":"R3"}],"id":"ORC-5KVSHEFEQ7","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.actamat.2014.02.042/p14/text-02"},"method":"Scheil simulation","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.actamat.2014.02.042","own_work_of_paper":true},"paper":"doi:10.1016/j.actamat.2014.02.042","paper_id":"doi:10.1016/j.actamat.2014.02.042","pid":"doi:10.1016/j.actamat.2014.02.042/p14/text-02/s08#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"In the normal simulation all phases are allowed to form, and thus the formation of eutectic (Si) occurs at 577 °C in the L ! (Al) + (Si) reaction with f(Si) = 0.018.","quote_page":14,"reaction":{"printed":"L -> (Al) + (Si)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-P-SI","system":"AL-P-SI","temperature_K":850.15,"temperature_printed":"577","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":850.15},{"chemical_system":"AL-P-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-CYFWBNDDKQ","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.actamat.2014.02.042/p14/text-02"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.actamat.2014.02.042","own_work_of_paper":true},"paper":"doi:10.1016/j.actamat.2014.02.042","paper_id":"doi:10.1016/j.actamat.2014.02.042","phases":[{"label":"(Al)"},{"label":"AlP"},{"label":"liquid"}],"pid":"doi:10.1016/j.actamat.2014.02.042/p14/text-02/s17#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"This ends at 516 °C, where the extended solidification path hits the metastable extension of the AlP crystallization surface. At this point the calculated residual liquid composition is 19.9 wt.% Si and 2.2 ppm P, which may be compared with Fig. 6.","quote_page":14,"reaction":{"printed":"L -> (Al) + AlP"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-P-SI","system":"AL-P-SI","temperature_K":789.15,"temperature_printed":"516","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":789.15},{"chemical_system":"AL-P-SI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-P-SI","before":"AL-SI","evidence":{"caption_systems":["AL-P-SI"],"cement_notation":null,"foreign_elements":["P"]},"field":"system","gate":"G4","rule":"system_from_phase_formulas_and_caption","visual_check":{"checked":"2026-10-23","image_sha256":"a824436ba5be86b9be27fac3b202e69af993d30c17bb2c12ea6868d6fe3dcd29","page":15,"pdf_sha256_prefix":"263ea1333af518a1","seen":"Conclusion: self-consistent description of Al-Si-P ternary; calculated Al-Si-P diagram incl. ternary eutectic L -> (Al)+(Si)+AlP at 577 °C.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","second_reader":"done","system_reassigned":true,"value_in_quote":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-5E2CCCWSR4","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.actamat.2014.02.042/p15/text-06"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.actamat.2014.02.042","own_work_of_paper":true},"paper":"doi:10.1016/j.actamat.2014.02.042","paper_id":"doi:10.1016/j.actamat.2014.02.042","phases":[{"label":"L"},{"label":"(Al)"},{"label":"(Si)"},{"label":"AlP"}],"pid":"doi:10.1016/j.actamat.2014.02.042/p15/text-06/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Based on this, the first consistent and experimentally supported Al-Si-P phase diagram was calculated, including details of the most important ternary eutectic, L ! (Al) + (Si) + AlP, at 577 °C.","quote_page":15,"reaction":{"printed":"L ! (Al) + (Si) + AlP","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-P-SI","system":"AL-P-SI","system_stored":"AL-SI","temperature_K":850.15,"temperature_printed":"577","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":850.15},{"chemical_system":"AL-P-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:1)","effect":"not_accepted","gate":"R3"}],"id":"ORC-7LVX4ISW3W","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.actamat.2014.02.042/p5/text-74"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.actamat.2014.02.042","own_work_of_paper":true},"paper":"doi:10.1016/j.actamat.2014.02.042","paper_id":"doi:10.1016/j.actamat.2014.02.042","pid":"doi:10.1016/j.actamat.2014.02.042/p5/text-74/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Very close to the Si-P binary eutectic L ! (Si) + SiP the ternary eutectic L ! (Si) + SiP + AlP at 1130.5 °C is calculated, where [P](Si) = 1.21 wt.% P is still relatively large.","quote_page":5,"reaction":{"printed":"L ! (Si) + SiP + AlP","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-P-SI","system":"AL-P-SI","temperature_K":1403.65,"temperature_printed":"1130.5 C","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1403.65},{"chemical_system":"AL-P-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:4)","effect":"not_accepted","gate":"R3"}],"id":"ORC-AO7B2JRIMZ","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.actamat.2014.02.042/p5/text-74"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.actamat.2014.02.042","own_work_of_paper":true},"paper":"doi:10.1016/j.actamat.2014.02.042","paper_id":"doi:10.1016/j.actamat.2014.02.042","pid":"doi:10.1016/j.actamat.2014.02.042/p5/text-74/s10#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The calculated composition of all solid phases at the ternary eutectic, L ! (Al) + (Si) + AlP, at 577 °C is as follows: [Si](Al) = 1.55 wt.% Si, [P](Al) = 0.009 ppm P, [Al](Si) = 0.0014 wt.% Al, [P](Si) = 0.005 ppm P and stoichiometric AlP.","quote_page":5,"reaction":{"printed":"L ! (Al) + (Si) + AlP","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-P-SI","system":"AL-P-SI","temperature_K":850.15,"temperature_printed":"577 C","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":850.15},{"chemical_system":"AL-P-SI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-P-SI","before":"AL-SI","evidence":{"caption_systems":[],"cement_notation":null,"foreign_elements":["P"]},"field":"system","gate":"G4","rule":"system_from_phase_formulas_and_caption","visual_check":{"checked":"2026-10-23","image_sha256":"1cb65dd27ecdc82cbc33185b6681ee4f5ad483112486983a628a14178a0b7787","page":8,"pdf_sha256_prefix":"263ea1333af518a1","seen":"Sec 3.4 Al-Si-P vertical section (Fig. 10a, 3.7 ppm P): horizontal line at 577 °C is cut through ternary eutectic L -> (Al)+(Si)+AlP four-phase equilibrium. Ternary Al-P-Si, calculated.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","second_reader":"done","system_reassigned":true,"value_in_quote":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-3MHB2PKEZY","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.actamat.2014.02.042/p8/text-43"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.actamat.2014.02.042","own_work_of_paper":true},"paper":"doi:10.1016/j.actamat.2014.02.042","paper_id":"doi:10.1016/j.actamat.2014.02.042","phases":[{"label":"L"},{"label":"(Al)"},{"label":"(Si)"},{"label":"AlP"}],"pid":"doi:10.1016/j.actamat.2014.02.042/p8/text-43/s10#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"However, an extra ZPF line of the AlP phase appears, shown as the red dashed line between the liquidus and solidus line of (Al) and continuing exactly along the horizontal line at 577 °C above 7 wt.% Si. This entire horizontal line in Fig. 10a represents the cut through the ternary eutectic L ! (Al) + (Si) + AlP four-phase equilibrium.","quote_page":8,"reaction":{"printed":"L -> (Al) + (Si) + AlP","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-P-SI","system":"AL-P-SI","system_stored":"AL-SI","temperature_K":850.15,"temperature_printed":"577 °C","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":850.15}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"AL-P-SI"}