{"artifacts":{"doi:10.1016/j.commatsci.2018.03.008/p6/text-04":{"artifact":"text_passage","label":"page 6, passage 4","page":6},"sha256:85fd53a1a176b694/p112/tab-i":{"artifact":"table","caption":"- Invariant Reactions.","label":"I","page":112},"sha256:b1356970bfc99c23/p4/tab-1":{"artifact":"table","caption":"Enthalpy of formation and physical properties (cell parameters a and magnetic moments μ) of Fe 3 Al and V 3 Al in the structures D0 3 , A15 and A2. The most stable phase is in bold face.","label":"1","page":4},"sha256:c5892ceee404a9fd/p5/tab-3":{"artifact":"table","caption":"Calculated enthalpies of formation of Al–Si–V compounds.","label":"3","page":5}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["AL","V"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/j.commatsci.2018.03.008":{"authors":["Alexandre Berche","Philippe Jund"],"citation":"Alexandre Berche, Philippe Jund, Ab initio description of the different phases in the Al-Fe-V system: Structure, magnetism and thermodynamics, Computational Materials Science 149, 28-36 (2018).","container":"Computational Materials Science","doi":"10.1016/j.commatsci.2018.03.008","doi_url":"https://doi.org/10.1016/j.commatsci.2018.03.008","id":"doi:10.1016/j.commatsci.2018.03.008","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"b1356970bfc99c23","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Ab initio description of the different phases in the Al-Fe-V system: Structure, magnetism and thermodynamics","year":2018},"doi:10.1016/j.jmst.2018.01.004":{"authors":["Qun Luo","Kang Li","Qian Li"],"citation":"Qun Luo, Kang Li, Qian Li, Thermodynamic investigation of phase equilibria in Al–Si–V system, Journal of Materials Science & Technology 34, 1592-1601 (2018).","container":"Journal of Materials Science & Technology","doi":"10.1016/j.jmst.2018.01.004","doi_url":"https://doi.org/10.1016/j.jmst.2018.01.004","id":"doi:10.1016/j.jmst.2018.01.004","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"c5892ceee404a9fd","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic investigation of phase equilibria in Al–Si–V system","year":2018},"doi:10.3139/146.018057":{"authors":["Weiping Gong","Yong Du","Baiyun Huang","Rainer Schmid-Fetzer","Chuanfu Zhang","Honghui Xu"],"citation":"Weiping Gong, Yong Du, Baiyun Huang, Rainer Schmid-Fetzer, Chuanfu Zhang, Honghui Xu, Thermodynamic reassessment of the Al – V system, MEKU 95, 978-986 (2004).","container":"MEKU","doi":"10.3139/146.018057","doi_url":"https://doi.org/10.3139/146.018057","id":"doi:10.3139/146.018057","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Thermodynamic reassessment of the Al – V system","year":2004},"sha256:85fd53a1a176b694":{"authors":["I. Ansara (ed.)","A. T. Dinsdale (ed.)","M. H. Rand (ed.)"],"citation":"I. Ansara, A. T. Dinsdale, M. H. Rand (eds.), COST 507: Thermochemical database for light metal alloys, Volume 2, EUR 18499 EN, Office for Official Publications of the European Communities, Luxembourg (1998), ISBN 92-828-3902-8.","container":"EUR 18499 EN","doi_not_used":"10.1016/s0364-5916(98)00037-6","id":"sha256:85fd53a1a176b694","kind":"corpus_paper","metadata_source":"pdf_title_page","pdf_sha256_prefix":"85fd53a1a176b694","roles":["cited_source","reporting_paper"],"source_kinds":["journal_article"],"title":"COST 507: Thermochemical database for light metal alloys, Volume 2","year":1998}},"part":1,"parts":1,"records":[{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-FE-V","evidence":{"basis":"phase_formula","overall_composition":{"FE":0.0,"V":0.75},"phases":["V3Al A15"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-R7ON4U6EA6.eeb1b4","locator":{"ref":"sha256:b1356970bfc99c23/p4/tab-1","row":5},"merged_ids":["ORC-R7ON4U6EA6.91c21a"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.commatsci.2018.03.008","own_work_of_paper":true},"overall_composition":{"V":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"FE":0.0,"V":0.75},"paper":"doi:10.1016/j.commatsci.2018.03.008","paper_id":"doi:10.1016/j.commatsci.2018.03.008","phases":[{"label":"V3Al A15","label_variants":["A15"]}],"pid":"sha256:b1356970bfc99c23/p4/tab-1/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"FE":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"source_system":"AL-FE-V","system":"AL-V","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.6515},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":33.58,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"scaled_for_unstated_basis":4,"stratum":"literature/metal","value":33.58},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_printed":"kJ/mol","unit_stored":"J/mol (basis unstated)","value":-13.03,"value_printed":-13.03,"value_stored":-13030.0},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-FE-V","evidence":{"basis":"phase_formula","overall_composition":{"FE":0.0,"V":0.75},"phases":["V3Al A15"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":{"phase":"V3Al A15","strukturbericht":"A15"},"before":null,"evidence":{"batch":"table_context_batch_10","doi":"10.1016/j.commatsci.2018.03.008","pdf_page":4,"pdf_sha256":"b1356970bfc99c23dbe12110b9cbec15d1fa6b27012e253e5cfe0f41c2ddaabb","printed":"V3Al | A15 | Ferro | 4.8086 | -13.03","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[5],"table":"1","table_key":"t197"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 10","image_sha256":"b2c7a97c7470ef1412aa66cd4a3e447da19c1dc987e15ccd7090185603b515b2","page":4,"pdf_sha256_prefix":"b1356970bfc99c23","seen":"own row","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-XL2JV6KW3Y.db975e","locator":{"ref":"sha256:b1356970bfc99c23/p4/tab-1","row":5},"merged_ids":["ORC-XL2JV6KW3Y.4c15fd"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.commatsci.2018.03.008","own_work_of_paper":true},"overall_composition":{"V":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"FE":0.0,"V":0.75},"paper":"doi:10.1016/j.commatsci.2018.03.008","paper_id":"doi:10.1016/j.commatsci.2018.03.008","phases":[{"label":"V3Al A15","label_variants":["A15"]}],"pid":"sha256:b1356970bfc99c23/p4/tab-1/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-FE-V","structure":{"phase":"V3Al A15","strukturbericht":"A15"},"system":"AL-V","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.24043},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04809,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04809},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":4.8086,"value_printed":4.8086,"value_stored":4.8086},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-FE-V","evidence":{"basis":"phase_formula","overall_composition":{"FE":0.0,"V":0.75},"phases":["V3Al A2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-P23NAL7KHR.fe1340","locator":{"ref":"sha256:b1356970bfc99c23/p4/tab-1","row":6},"merged_ids":["ORC-P23NAL7KHR.e4fc56"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.commatsci.2018.03.008","own_work_of_paper":true},"overall_composition":{"V":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"FE":0.0,"V":0.75},"paper":"doi:10.1016/j.commatsci.2018.03.008","paper_id":"doi:10.1016/j.commatsci.2018.03.008","phases":[{"label":"V3Al A2","label_variants":["A2"]}],"pid":"sha256:b1356970bfc99c23/p4/tab-1/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"FE":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"source_system":"AL-FE-V","system":"AL-V","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.4985},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":33.58,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"scaled_for_unstated_basis":4,"stratum":"literature/metal","value":33.58},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_printed":"kJ/mol","unit_stored":"J/mol (basis unstated)","value":-9.97,"value_printed":-9.97,"value_stored":-9970.0},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-FE-V","evidence":{"basis":"phase_formula","overall_composition":{"FE":0.0,"V":0.75},"phases":["V3Al A2"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":{"phase":"V3Al A2","strukturbericht":"A2"},"before":null,"evidence":{"batch":"table_context_batch_10","doi":"10.1016/j.commatsci.2018.03.008","pdf_page":4,"pdf_sha256":"b1356970bfc99c23dbe12110b9cbec15d1fa6b27012e253e5cfe0f41c2ddaabb","printed":"V3Al block | A2 | Non-mag. | 3.0336 | -9.97","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[6],"table":"1","table_key":"t197"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 10","image_sha256":"b2c7a97c7470ef1412aa66cd4a3e447da19c1dc987e15ccd7090185603b515b2","page":4,"pdf_sha256_prefix":"b1356970bfc99c23","seen":"own row","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-VSLA5NPIVU.e6dc59","locator":{"ref":"sha256:b1356970bfc99c23/p4/tab-1","row":6},"merged_ids":["ORC-VSLA5NPIVU.aea9d9"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.commatsci.2018.03.008","own_work_of_paper":true},"overall_composition":{"V":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"FE":0.0,"V":0.75},"paper":"doi:10.1016/j.commatsci.2018.03.008","paper_id":"doi:10.1016/j.commatsci.2018.03.008","phases":[{"label":"V3Al A2","label_variants":["A2"]}],"pid":"sha256:b1356970bfc99c23/p4/tab-1/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-FE-V","structure":{"phase":"V3Al A2","strukturbericht":"A2"},"system":"AL-V","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.15168},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03034,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.03034},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":3.0336,"value_printed":3.0336,"value_stored":3.0336},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-FE-V","evidence":{"basis":"phase_formula","overall_composition":{"FE":0.0,"V":0.75},"phases":["V3Al D03"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-3DVK63XIC4.b65938","locator":{"ref":"sha256:b1356970bfc99c23/p4/tab-1","row":7},"merged_ids":["ORC-3DVK63XIC4.36cca5"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.commatsci.2018.03.008","own_work_of_paper":true},"overall_composition":{"V":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"FE":0.0,"V":0.75},"paper":"doi:10.1016/j.commatsci.2018.03.008","paper_id":"doi:10.1016/j.commatsci.2018.03.008","phases":[{"label":"V3Al D03","label_variants":["D03"]}],"pid":"sha256:b1356970bfc99c23/p4/tab-1/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"FE":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"source_system":"AL-FE-V","system":"AL-V","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.4565},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":33.58,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"scaled_for_unstated_basis":4,"stratum":"literature/metal","value":33.58},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_printed":"kJ/mol","unit_stored":"J/mol (basis unstated)","value":-9.13,"value_printed":-9.13,"value_stored":-9130.0},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-FE-V","evidence":{"basis":"phase_formula","overall_composition":{"FE":0.0,"V":0.75},"phases":["V3Al D03"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":{"phase":"V3Al D03","strukturbericht":"D03"},"before":null,"evidence":{"batch":"table_context_batch_10","doi":"10.1016/j.commatsci.2018.03.008","pdf_page":4,"pdf_sha256":"b1356970bfc99c23dbe12110b9cbec15d1fa6b27012e253e5cfe0f41c2ddaabb","printed":"V3Al block | D0_3 | Non-mag. | 6.0539 | -9.13","rationale":"Printed table context for this group supplies strukturbericht; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[7],"table":"1","table_key":"t197"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 10","image_sha256":"b2c7a97c7470ef1412aa66cd4a3e447da19c1dc987e15ccd7090185603b515b2","page":4,"pdf_sha256_prefix":"b1356970bfc99c23","seen":"own row","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-IGTBOAP5IK.fae699","locator":{"ref":"sha256:b1356970bfc99c23/p4/tab-1","row":7},"merged_ids":["ORC-IGTBOAP5IK.324c9f"],"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.commatsci.2018.03.008","own_work_of_paper":true},"overall_composition":{"V":0.75},"overall_composition_basis":"from_formula","overall_composition_stored":{"FE":0.0,"V":0.75},"paper":"doi:10.1016/j.commatsci.2018.03.008","paper_id":"doi:10.1016/j.commatsci.2018.03.008","phases":[{"label":"V3Al D03","label_variants":["D03"]}],"pid":"sha256:b1356970bfc99c23/p4/tab-1/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-FE-V","structure":{"phase":"V3Al D03","strukturbericht":"D03"},"system":"AL-V","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.302695},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.06054,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.06054},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":6.0539,"value_printed":6.0539,"value_stored":6.0539},{"chemical_system":"AL-V","cited_sources":[{"kind":"unknown","label":"21","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.134615},"phases":["Al45V7"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-S2AO4ARLVV","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":1},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"V":0.134615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.134615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al45V7"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"SI":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.697},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":-13.94,"value_printed":-13.94,"value_stored":-13940.0},{"chemical_system":"AL-V","cited_sources":[{"kind":"unknown","label":"21","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.134615},"phases":["Al45V7"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:computation_context","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-EMDGS3IMSD.15aa26","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":1},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"V":0.134615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.134615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al45V7"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","property_printed":"c","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.5542},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1108,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1108},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":11.084,"value_printed":11.084,"value_stored":11.084},{"chemical_system":"AL-V","cited_sources":[{"kind":"unknown","label":"21","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.134615},"phases":["Al45V7"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:computation_context","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-EMDGS3IMSD.5822be","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":1},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"V":0.134615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.134615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al45V7"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.55525},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1111,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1111},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":11.105,"value_printed":11.105,"value_stored":11.105},{"chemical_system":"AL-V","cited_sources":[{"kind":"unknown","label":"21","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.134615},"phases":["Al45V7"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:computation_context","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-EMDGS3IMSD.72886e","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":1},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"V":0.134615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.134615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al45V7"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","property_printed":"b","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.38055},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07611,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.07611},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":7.611,"value_printed":7.611,"value_stored":7.611},{"chemical_system":"AL-V","cited_sources":[{"doi":"10.3139/146.018057","first_author":"Gong","kind":"assessment","label":"26","paper":"doi:10.3139/146.018057","reference":"W. Gong, Y. Du, B. Huang, R. Schmid-Fetzer, C. Zhuang, H. Xu, Z. Metallkd. 95 (2004) 978–986.","status":"resolved","year":"2004"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.134615},"phases":["Al45V7"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-SOMR4662IA","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":2},"method":"Calphad","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"overall_composition":{"V":0.134615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.134615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al45V7"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"SI":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.645},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":-12.9,"value_printed":-12.9,"value_stored":-12900.0},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.134615},"phases":["Al45V7"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","dft_outlier_unexplained":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-DMIDUOBAKE","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":3},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.jmst.2018.01.004","own_work_of_paper":true},"overall_composition":{"V":0.134615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.134615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al45V7"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"SI":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.17136},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":3.4272,"value_printed":3.4272,"value_stored":3427.2},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.134615},"phases":["Al45V7"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-LGFPL43TZG.1e0482","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":3},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.jmst.2018.01.004","own_work_of_paper":true},"overall_composition":{"V":0.134615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.134615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al45V7"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.51325},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07904,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.07904},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":10.265,"value_printed":10.265,"value_stored":10.265},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.134615},"phases":["Al45V7"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-LGFPL43TZG.da236a","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":3},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.jmst.2018.01.004","own_work_of_paper":true},"overall_composition":{"V":0.134615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.134615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al45V7"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","property_printed":"c","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.5655},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.08709,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.08709},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":11.31,"value_printed":11.31,"value_stored":11.31},{"chemical_system":"AL-V","cited_sources":[{"kind":"unknown","label":"21","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.384615},"phases":["Al8V5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-ZG3J7RSXT2","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":4},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"V":0.384615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.384615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al8V5"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"SI":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.6325},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":-12.65,"value_printed":-12.65,"value_stored":-12650.0},{"chemical_system":"AL-V","cited_sources":[{"kind":"unknown","label":"21","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.384615},"phases":["Al8V5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:computation_context","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-4ZJGEXF4WH","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":4},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"V":0.384615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.384615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al8V5"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.46715},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.09343,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.09343},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":9.343,"value_printed":9.343,"value_stored":9.343},{"chemical_system":"AL-V","cited_sources":[{"kind":"unknown","label":"21","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.384615},"phases":["Al8V5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-4YOQWHMSI6","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":5},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"V":0.384615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.384615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al8V5"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"SI":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.9695},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":-19.39,"value_printed":-19.39,"value_stored":-19390.0},{"chemical_system":"AL-V","cited_sources":[{"kind":"unknown","label":"21","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.384615},"phases":["Al8V5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:computation_context","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-CCXNMDG7S2","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":5},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"V":0.384615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.384615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al8V5"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.46475},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.09295,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.09295},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":9.295,"value_printed":9.295,"value_stored":9.295},{"chemical_system":"AL-V","cited_sources":[{"kind":"unknown","label":"21","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.384615},"phases":["Al8V5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-7FC26Y65SS","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":6},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"V":0.384615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.384615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al8V5"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"SI":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.9095},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":-18.19,"value_printed":-18.19,"value_stored":-18190.0},{"chemical_system":"AL-V","cited_sources":[{"kind":"unknown","label":"21","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.384615},"phases":["Al8V5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:computation_context","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-XC27PMVX3M","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":6},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"V":0.384615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.384615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al8V5"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.45825},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.09165,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.09165},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":9.165,"value_printed":9.165,"value_stored":9.165},{"chemical_system":"AL-V","cited_sources":[{"first_author":"Meschel","kind":"assessment","label":"27","reference":"S.V. Meschel, O.J. Kleppa, The standard enthalpies of formation of some 3d transition metal aluminides by high-temperature direct synthesis calorimetry, in: J.S. Faulkner, R.G. Jordan (Eds.), Metallic Alloys: Experimental and Theoretical Perspectives, Springer, Dordrecht, 1994.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.384615},"phases":["Al8V5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-32J4O2DDG6","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":7},"method":"Exp","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"V":0.384615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.384615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al8V5"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"SI":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"source_system":"AL-SI-V","system":"AL-V","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.7},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":-34.0,"value_printed":-34.0,"value_stored":-34000.0},{"chemical_system":"AL-V","cited_sources":[{"kind":"unknown","label":"21","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.384615},"phases":["Al8V5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-XANB3HVNAZ","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":8},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"V":0.384615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.384615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al8V5"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"SI":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.909},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":-18.18,"value_printed":-18.18,"value_stored":-18180.0},{"chemical_system":"AL-V","cited_sources":[{"kind":"unknown","label":"21","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.384615},"phases":["Al8V5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:computation_context","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-NS3ANXUOXJ","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":8},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"V":0.384615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.384615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al8V5"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.45685},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.09137,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.09137},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":9.137,"value_printed":9.137,"value_stored":9.137},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.384615},"phases":["Al8V5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-FUZUXKJXM6","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":9},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.jmst.2018.01.004","own_work_of_paper":true},"overall_composition":{"V":0.384615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.384615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al8V5"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"SI":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.9515},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":-19.03,"value_printed":-19.03,"value_stored":-19030.0},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.384615},"phases":["Al8V5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-SKAUAUEBM6","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":9},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.jmst.2018.01.004","own_work_of_paper":true},"overall_composition":{"V":0.384615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.384615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al8V5"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.45725},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.07042,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.07042},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":9.145,"value_printed":9.145,"value_stored":9.145},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.384615},"phases":["Al8V5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-7Q525HXRWT","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":10},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.jmst.2018.01.004","own_work_of_paper":true},"overall_composition":{"V":0.384615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.384615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al8V5"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"SI":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.12785},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":-22.557,"value_printed":-22.557,"value_stored":-22557.0},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.384615},"phases":["Al8V5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-ZDFUMLQT5Y","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":10},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.jmst.2018.01.004","own_work_of_paper":true},"overall_composition":{"V":0.384615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.384615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al8V5"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.4451},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.06855,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.06855},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":8.902,"value_printed":8.902,"value_stored":8.902},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.384615},"phases":["Al8V5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-MX6HXD236P","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":11},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.jmst.2018.01.004","own_work_of_paper":true},"overall_composition":{"V":0.384615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.384615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al8V5"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"SI":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.01345},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":-20.269,"value_printed":-20.269,"value_stored":-20269.0},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.384615},"phases":["Al8V5"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-3J4GCY3ST2","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":11},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.jmst.2018.01.004","own_work_of_paper":true},"overall_composition":{"V":0.384615},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.384615},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al8V5"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.4417},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.06802,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.06802},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":8.834,"value_printed":8.834,"value_stored":8.834},{"chemical_system":"AL-V","cited_sources":[{"kind":"unknown","label":"21","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.25},"phases":["Al3V"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:computation_context","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-XMO2TGI4S3","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":12},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"V":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.25},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al3V"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r12#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"SI":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.3455},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":-26.91,"value_printed":-26.91,"value_stored":-26910.0},{"chemical_system":"AL-V","cited_sources":[{"kind":"unknown","label":"21","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.25},"phases":["Al3V"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:computation_context","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-VOKBEACMRK.0c8c73","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":12},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"V":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.25},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al3V"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.18845},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03769,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.03769},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":3.769,"value_printed":3.769,"value_stored":3.769},{"chemical_system":"AL-V","cited_sources":[{"kind":"unknown","label":"21","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.25},"phases":["Al3V"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","state:computation_context","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-VOKBEACMRK.e1ceed","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":12},"method":"DFT","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"printed_source_other_calculation","class":"computed","own_work_of_paper":false},"overall_composition":{"V":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.25},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al3V"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","property_printed":"c","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.41565},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.08313,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.08313},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":8.313,"value_printed":8.313,"value_stored":8.313},{"chemical_system":"AL-V","cited_sources":[{"first_author":"Meschel","kind":"assessment","label":"27","reference":"S.V. Meschel, O.J. Kleppa, The standard enthalpies of formation of some 3d transition metal aluminides by high-temperature direct synthesis calorimetry, in: J.S. Faulkner, R.G. Jordan (Eds.), Metallic Alloys: Experimental and Theoretical Perspectives, Springer, Dordrecht, 1994.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.25},"phases":["Al3V"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-SRULXM6ONT","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":13},"method":"Exp","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"V":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.25},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al3V"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r13#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"SI":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"source_system":"AL-SI-V","system":"AL-V","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.39},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.1,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[1.991877,9.330373],"class":"experimental_unspecified","entry":"value_types/HM_FORM/classes/experimental_unspecified","floor":4.1,"floor_unit":"kJ/mol-atom","n_pairs":29,"prior_source":"kubaschewski","value":4.1},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":-27.8,"value_printed":-27.8,"value_stored":-27800.0},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.25},"phases":["Al3V"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","dft_outlier_unexplained":true,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-IBVD2A4HP4","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":14},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.jmst.2018.01.004","own_work_of_paper":true},"overall_composition":{"V":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.25},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al3V"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r14#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"AL":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"SI":{"phase":"printed:none"},"V":{"phase":"printed:none"}},"source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.0597},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"kJ/mol atom","unit_stored":"J/mol-atom","value":1.194,"value_printed":1.194,"value_stored":1194.0},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.25},"phases":["Al3V"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-FIXGX2BSS6.2bc2de","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":14},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.jmst.2018.01.004","own_work_of_paper":true},"overall_composition":{"V":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.25},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al3V"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","property_printed":"a","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.18205},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02804,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.02804},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":3.641,"value_printed":3.641,"value_stored":3.641},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"AL-V","before":"AL-SI-V","evidence":{"basis":"phase_formula","overall_composition":{"SI":0.0,"V":0.25},"phases":["Al3V"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":4,"fold_lso":0,"id":"ORC-FIXGX2BSS6.6081c1","locator":{"ref":"sha256:c5892ceee404a9fd/p5/tab-3","row":14},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"structural_property","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.jmst.2018.01.004","own_work_of_paper":true},"overall_composition":{"V":0.25},"overall_composition_basis":"from_formula","overall_composition_stored":{"SI":0.0,"V":0.25},"paper":"doi:10.1016/j.jmst.2018.01.004","paper_id":"doi:10.1016/j.jmst.2018.01.004","phases":[{"label":"Al3V"}],"pid":"sha256:c5892ceee404a9fd/p5/tab-3/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","property_printed":"c","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AL-SI-V","system":"AL-V","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.39605},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.06099,"sigma_method":{"basis":"calibrated","ci95":[0.005826,0.012707],"class":"model_calculated","entry":"model/LATTICE_LENGTH","floor":0.0077,"floor_unit":"relative (fraction of the value)","n_pairs":175,"value":0.06099},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_printed":"Å","unit_stored":"Å","value":7.921,"value_printed":7.921,"value_stored":7.921},{"chemical_system":"AL-V","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"model","before":"unspecified","evidence":{"source":"I. Ansara, A. T. Dinsdale, M. H. Rand (eds.), COST 507: Thermochemical database for light metal alloys, Volume 2, EUR 18","why":"the book is the documentation of the COST 507 assessed light-alloy database; its invariant tables list the reactions calculated from the assessed descriptions (Cu-Zr Table I p210 page-checked: no measured / calculated column, values of the assessment); values whose class the readers left unspecified are model"},"field":"evidence_class","gate":"R3","rule":"assessed_database_values","visual_check":{"checked":"2026-10-24","image_sha256":"3ff5715e8c11f6a96cefdf5a6d7080f9698fcbc8fdb7381d535c8549984d9634","page":210,"pdf_sha256_prefix":"85fd53a1a176b694","seen":"COST 507 vol. 2 (assessed light-alloy database): Cu-Zr Table I p210 lists the invariant reactions of the assessment (no measured column); Al-Nb Table I p89 likewise.","verdict":"rule_confirmed"}}],"evidence_class":"model","evidence_class_before_gates":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-ZVUWTSOIGH","locator":{"ref":"sha256:85fd53a1a176b694/p112/tab-i","row":1},"observation_type":"invariant_reaction","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","class_gate":"model","measured_in":"sha256:85fd53a1a176b694","own_work_of_paper":true},"paper":"sha256:85fd53a1a176b694","paper_id":"sha256:85fd53a1a176b694","phase_compositions":[{"basis":"mole_fraction","composition":{"V":0.25},"composition_source":"printed","phase":"AlM-D0*22"},{"basis":"mole_fraction","composition":{"V":0.148},"composition_source":"printed","phase":"Al23V4"},{"basis":"mole_fraction","composition":{"V":0.003},"composition_source":"printed","phase":"Liquid"}],"phases":[{"label":"AlM-D0*22","model_phase":"AL3M_D022","pearson_symbol":"tI8","prototype":"Al3Ti","structure_basis":"mapped_model_phase"},{"label":"Al23V4","model_phase":"AL23V4","pearson_symbol":"hP54","prototype":"Al23V4","structure_basis":"mapped_model_phase"},{"label":"Liquid","model_phase":"LIQUID"}],"pid":"sha256:85fd53a1a176b694/p112/tab-i/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + AlM-D0*22 -> Al23V4","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-V","system":"AL-V","temperature_K":1007.3,"temperature_printed":"1007.3","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1007.3},{"chemical_system":"AL-V","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"model","before":"unspecified","evidence":{"source":"I. Ansara, A. T. Dinsdale, M. H. Rand (eds.), COST 507: Thermochemical database for light metal alloys, Volume 2, EUR 18","why":"the book is the documentation of the COST 507 assessed light-alloy database; its invariant tables list the reactions calculated from the assessed descriptions (Cu-Zr Table I p210 page-checked: no measured / calculated column, values of the assessment); values whose class the readers left unspecified are model"},"field":"evidence_class","gate":"R3","rule":"assessed_database_values","visual_check":{"checked":"2026-10-24","image_sha256":"3ff5715e8c11f6a96cefdf5a6d7080f9698fcbc8fdb7381d535c8549984d9634","page":210,"pdf_sha256_prefix":"85fd53a1a176b694","seen":"COST 507 vol. 2 (assessed light-alloy database): Cu-Zr Table I p210 lists the invariant reactions of the assessment (no measured column); Al-Nb Table I p89 likewise.","verdict":"rule_confirmed"}}],"evidence_class":"model","evidence_class_before_gates":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-TV2ECWDGTT","locator":{"ref":"sha256:85fd53a1a176b694/p112/tab-i","row":2},"observation_type":"invariant_reaction","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","class_gate":"model","measured_in":"sha256:85fd53a1a176b694","own_work_of_paper":true},"paper":"sha256:85fd53a1a176b694","paper_id":"sha256:85fd53a1a176b694","phase_compositions":[{"basis":"mole_fraction","composition":{"V":0.148},"composition_source":"printed","phase":"Al23V4"},{"basis":"mole_fraction","composition":{"V":0.125},"composition_source":"printed","phase":"Al7V"},{"basis":"mole_fraction","composition":{"V":0.002},"composition_source":"printed","phase":"Liquid"}],"phases":[{"label":"Al23V4","model_phase":"AL23V4","pearson_symbol":"hP54","prototype":"Al23V4","structure_basis":"mapped_model_phase"},{"label":"Al7V","model_phase":"AL45V7","pearson_symbol":"mC104","prototype":"Al45V7","structure_basis":"mapped_model_phase"},{"label":"Liquid","model_phase":"LIQUID"}],"pid":"sha256:85fd53a1a176b694/p112/tab-i/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + Al23V4 -> Al7V","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-V","system":"AL-V","temperature_K":969.0,"temperature_printed":"969.0","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":969.0},{"chemical_system":"AL-V","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"model","before":"unspecified","evidence":{"source":"I. Ansara, A. T. Dinsdale, M. H. Rand (eds.), COST 507: Thermochemical database for light metal alloys, Volume 2, EUR 18","why":"the book is the documentation of the COST 507 assessed light-alloy database; its invariant tables list the reactions calculated from the assessed descriptions (Cu-Zr Table I p210 page-checked: no measured / calculated column, values of the assessment); values whose class the readers left unspecified are model"},"field":"evidence_class","gate":"R3","rule":"assessed_database_values","visual_check":{"checked":"2026-10-24","image_sha256":"3ff5715e8c11f6a96cefdf5a6d7080f9698fcbc8fdb7381d535c8549984d9634","page":210,"pdf_sha256_prefix":"85fd53a1a176b694","seen":"COST 507 vol. 2 (assessed light-alloy database): Cu-Zr Table I p210 lists the invariant reactions of the assessment (no measured column); Al-Nb Table I p89 likewise.","verdict":"rule_confirmed"}}],"evidence_class":"model","evidence_class_before_gates":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-OFXA2PC3VC","locator":{"ref":"sha256:85fd53a1a176b694/p112/tab-i","row":3},"observation_type":"invariant_reaction","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","class_gate":"model","measured_in":"sha256:85fd53a1a176b694","own_work_of_paper":true},"paper":"sha256:85fd53a1a176b694","paper_id":"sha256:85fd53a1a176b694","phase_compositions":[{"basis":"mole_fraction","composition":{"V":0.125},"composition_source":"printed","phase":"Al7V"},{"basis":"mole_fraction","composition":{"V":0.091},"composition_source":"printed","phase":"Al10V"},{"basis":"mole_fraction","composition":{"V":0.001},"composition_source":"printed","phase":"Liquid"}],"phases":[{"label":"Al7V","model_phase":"AL45V7","pearson_symbol":"mC104","prototype":"Al45V7","structure_basis":"mapped_model_phase"},{"label":"Al10V"},{"label":"Liquid","model_phase":"LIQUID"}],"pid":"sha256:85fd53a1a176b694/p112/tab-i/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + Al7V -> Al10V","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-V","system":"AL-V","temperature_K":945.2,"temperature_printed":"945.2","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":945.2},{"chemical_system":"AL-V","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"model","before":"unspecified","evidence":{"source":"I. Ansara, A. T. Dinsdale, M. H. Rand (eds.), COST 507: Thermochemical database for light metal alloys, Volume 2, EUR 18","why":"the book is the documentation of the COST 507 assessed light-alloy database; its invariant tables list the reactions calculated from the assessed descriptions (Cu-Zr Table I p210 page-checked: no measured / calculated column, values of the assessment); values whose class the readers left unspecified are model"},"field":"evidence_class","gate":"R3","rule":"assessed_database_values","visual_check":{"checked":"2026-10-24","image_sha256":"3ff5715e8c11f6a96cefdf5a6d7080f9698fcbc8fdb7381d535c8549984d9634","page":210,"pdf_sha256_prefix":"85fd53a1a176b694","seen":"COST 507 vol. 2 (assessed light-alloy database): Cu-Zr Table I p210 lists the invariant reactions of the assessment (no measured column); Al-Nb Table I p89 likewise.","verdict":"rule_confirmed"}}],"evidence_class":"model","evidence_class_before_gates":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-STKOBJPAXW","locator":{"ref":"sha256:85fd53a1a176b694/p112/tab-i","row":4},"observation_type":"invariant_reaction","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","class_gate":"model","measured_in":"sha256:85fd53a1a176b694","own_work_of_paper":true},"paper":"sha256:85fd53a1a176b694","paper_id":"sha256:85fd53a1a176b694","phase_compositions":[{"basis":"mole_fraction","composition":{"V":0.091},"composition_source":"printed","phase":"Al10V"},{"basis":"mole_fraction","composition":{"V":0.001},"composition_source":"printed","phase":"fcc-Al"},{"basis":"mole_fraction","composition":{"V":0.0},"composition_source":"printed","phase":"Liquid"}],"phases":[{"label":"Al10V"},{"label":"fcc-Al","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Liquid","model_phase":"LIQUID"}],"pid":"sha256:85fd53a1a176b694/p112/tab-i/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + Al10V -> fcc-Al","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-V","system":"AL-V","temperature_K":935.3,"temperature_printed":"935.3","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":935.3},{"chemical_system":"AL-V","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"model","before":"unspecified","evidence":{"source":"I. Ansara, A. T. Dinsdale, M. H. Rand (eds.), COST 507: Thermochemical database for light metal alloys, Volume 2, EUR 18","why":"the book is the documentation of the COST 507 assessed light-alloy database; its invariant tables list the reactions calculated from the assessed descriptions (Cu-Zr Table I p210 page-checked: no measured / calculated column, values of the assessment); values whose class the readers left unspecified are model"},"field":"evidence_class","gate":"R3","rule":"assessed_database_values","visual_check":{"checked":"2026-10-24","image_sha256":"3ff5715e8c11f6a96cefdf5a6d7080f9698fcbc8fdb7381d535c8549984d9634","page":210,"pdf_sha256_prefix":"85fd53a1a176b694","seen":"COST 507 vol. 2 (assessed light-alloy database): Cu-Zr Table I p210 lists the invariant reactions of the assessment (no measured column); Al-Nb Table I p89 likewise.","verdict":"rule_confirmed"}}],"evidence_class":"model","evidence_class_before_gates":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-C2NWLRIUQG","locator":{"ref":"sha256:85fd53a1a176b694/p112/tab-i","row":5},"observation_type":"invariant_reaction","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","class_gate":"model","measured_in":"sha256:85fd53a1a176b694","own_work_of_paper":true},"paper":"sha256:85fd53a1a176b694","paper_id":"sha256:85fd53a1a176b694","phase_compositions":[{"basis":"mole_fraction","composition":{"V":0.384},"composition_source":"printed","phase":"Al8V5"},{"basis":"mole_fraction","composition":{"V":0.25},"composition_source":"printed","phase":"AlM-D0*22"},{"basis":"mole_fraction","composition":{"V":0.167},"composition_source":"printed","phase":"Liquid"}],"phases":[{"label":"Al8V5","model_phase":"AL8V5_D82","pearson_symbol":"cI52","prototype":"Cu5Zn8","structure_basis":"mapped_model_phase"},{"label":"AlM-D0*22","model_phase":"AL3M_D022","pearson_symbol":"tI8","prototype":"Al3Ti","structure_basis":"mapped_model_phase"},{"label":"Liquid","model_phase":"LIQUID"}],"pid":"sha256:85fd53a1a176b694/p112/tab-i/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + Al8V5 -> AlM-D0*22","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-V","system":"AL-V","temperature_K":1640.1,"temperature_printed":"1640.1","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1640.1},{"chemical_system":"AL-V","conditions":{"kind":"own_work_origin_unspecified"},"corrections":[{"after":"model","before":"unspecified","evidence":{"source":"I. Ansara, A. T. Dinsdale, M. H. Rand (eds.), COST 507: Thermochemical database for light metal alloys, Volume 2, EUR 18","why":"the book is the documentation of the COST 507 assessed light-alloy database; its invariant tables list the reactions calculated from the assessed descriptions (Cu-Zr Table I p210 page-checked: no measured / calculated column, values of the assessment); values whose class the readers left unspecified are model"},"field":"evidence_class","gate":"R3","rule":"assessed_database_values","visual_check":{"checked":"2026-10-24","image_sha256":"3ff5715e8c11f6a96cefdf5a6d7080f9698fcbc8fdb7381d535c8549984d9634","page":210,"pdf_sha256_prefix":"85fd53a1a176b694","seen":"COST 507 vol. 2 (assessed light-alloy database): Cu-Zr Table I p210 lists the invariant reactions of the assessment (no measured column); Al-Nb Table I p89 likewise.","verdict":"rule_confirmed"}}],"evidence_class":"model","evidence_class_before_gates":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-MV7TR6QIPZ","locator":{"ref":"sha256:85fd53a1a176b694/p112/tab-i","row":6},"observation_type":"invariant_reaction","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","class_gate":"model","measured_in":"sha256:85fd53a1a176b694","own_work_of_paper":true},"paper":"sha256:85fd53a1a176b694","paper_id":"sha256:85fd53a1a176b694","phase_compositions":[{"basis":"mole_fraction","composition":{"V":0.471},"composition_source":"printed","phase":"bcc-A2"},{"basis":"mole_fraction","composition":{"V":0.384},"composition_source":"printed","phase":"Al8V5"},{"basis":"mole_fraction","composition":{"V":0.376},"composition_source":"printed","phase":"Liquid"}],"phases":[{"label":"bcc-A2","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"Al8V5","model_phase":"AL8V5_D82","pearson_symbol":"cI52","prototype":"Cu5Zn8","structure_basis":"mapped_model_phase"},{"label":"Liquid","model_phase":"LIQUID"}],"pid":"sha256:85fd53a1a176b694/p112/tab-i/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + bcc-A2 -> Al8V5","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AL-V","system":"AL-V","temperature_K":1932.7,"temperature_printed":"1932.7","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1932.7},{"chemical_system":"AL-V","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":2,"fold_lso":0,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-ONUVWK7XD3","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.commatsci.2018.03.008/p6/text-04"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.commatsci.2018.03.008","own_work_of_paper":true},"paper":"doi:10.1016/j.commatsci.2018.03.008","paper_id":"doi:10.1016/j.commatsci.2018.03.008","pid":"doi:10.1016/j.commatsci.2018.03.008/p6/text-04/s14#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"The A15 phase is transformed congruently into the A2 phase at 910 K and at 77.6 at.% of V.","quote_page":6,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AL-V","system":"AL-V","temperature_K":910.0,"temperature_printed":"910 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":910.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"AL-V"}