{"artifacts":{"doi:10.1007/s11664-005-0082-9/p10/tab-v":{"artifact":"table","caption":"Calculated Invariant Reactions of the Sn-Au-Ni System","label":"V","page":10},"doi:10.1007/s11664-005-0082-9/p4/text-03":{"artifact":"text_passage","label":"page 4, passage 3","page":4},"doi:10.1007/s11664-005-0082-9/p7/text-12":{"artifact":"text_passage","label":"page 7, passage 12","page":7},"doi:10.1016/j.calphad.2013.10.001/p10/tab-3":{"artifact":"table","caption":"Calculated ternary invariant reactions in Au–Ni–Sn ternary system.","label":"3","page":10},"sha256:90491ef3ea9a4a15/p7/tab-2":{"artifact":"table","caption":"Comparison of the ternary solubility of binary phase between previously reported data and the calculated results in this work.","label":"2","page":7},"sha256:e626e9af186c9d36/p5/tab-ii":{"artifact":"table","caption":"Phase Equilibrium Compositions of the Sn-Au-Ni System Determined By the Present Work","label":"II","page":5},"sha256:e626e9af186c9d36/p7/tab-iii":{"artifact":"table","caption":"Transformation Temperatures Determined by Differential Scanning Calorimetry","label":"III","page":7}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{"doi:10.1007/s11664-005-0082-9":{"context_id":"context:source-doi-10-1007-s11664-005-0082-9","items":[{"applies_to":"multiphase specimens","calibration":"standard calibration method","extraction_accepted":true,"id":"ORC-HWF6HVX6CC","method":"electron-probe microanalyzer (EPMA)","page":2,"quote":"Equilibrium phase compositions in multiphase specimens were determined by a electron-probe microanalyzer (EPMA) using the standard calibration method.","second_reader_agrees":true,"type":"measurement"},{"applies_to":"Sn-35Au15Ni (at.%) and Sn-30Au-20Ni","extraction_accepted":false,"id":"ORC-RJ2RJUU7T3","method":"Xray diffraction","page":2,"quote":"Xray diffraction was carried out using Cu Kα radiation to identify the crystal structure for the Sn-35Au15Ni (at.%) and Sn-30Au-20Ni equilibrated at 300°C and 400°C for 40 days, respectively, in order to verify","second_reader_agrees":false,"type":"measurement"},{"atmosphere":"flowing argon atmosphere","extraction_accepted":true,"heating_or_cooling_rate":"3-10°C/min","id":"ORC-XIJWMA4Q42","method":"differential scanning calorimetry (DSC)","page":2,"quote":"Transformation temperatures were determined by differential scanning calorimetry (DSC) using the heating curve. The experiments were carried out in a flowing argon atmosphere at rates of 3-10°C/min, using sintered Al2O3 as the reference specimen.","second_reader_agrees":true,"type":"measurement"},{"extraction_accepted":true,"id":"ORC-K7TOR6W4YW","label":"Sn-Au-Ni ternary alloys","page":2,"purity":"pure Sn (99.9%), Au (99.99%), and Ni(99.9%)","quote":"EXPERIMENTAL PROCEDURE Sn-Au-Ni ternary alloys were prepared using pure Sn (99.9%), Au (99.99%), and Ni(99.9%) in evacuated transparent quartz capsules at about 1200°C for 4 h.","second_reader_agrees":true,"starting_materials":"pure Sn (99.9%), Au (99.99%), and Ni(99.9%)","synthesis":"prepared using pure Sn (99.9%), Au (99.99%), and Ni(99.9%) in evacuated transparent quartz capsules at about 1200°C for 4 h","type":"sample"},{"composition_basis":"at.%","extraction_accepted":false,"id":"ORC-R2IVPL3XEW","label":"Sn-35Au15Ni","nominal_composition":"Sn-35Au15Ni (at.%)","page":2,"quote":"Xray diffraction was carried out using Cu Kα radiation to identify the crystal structure for the Sn-35Au15Ni (at.%) and Sn-30Au-20Ni equilibrated at 300°C and 400°C for 40 days, respectively, in order to verify","second_reader_agrees":false,"type":"sample"},{"composition_basis":"at.%","extraction_accepted":false,"id":"ORC-R2IVPL3XEW","label":"Sn-30Au-20Ni","nominal_composition":"Sn-30Au-20Ni","page":2,"quote":"Xray diffraction was carried out using Cu Kα radiation to identify the crystal structure for the Sn-35Au15Ni (at.%) and Sn-30Au-20Ni equilibrated at 300°C and 400°C for 40 days, respectively, in order to verify","second_reader_agrees":false,"type":"sample"},{"applies_to":"Sn-35Au15Ni (at.%) and Sn-30Au-20Ni","duration":"40 days","duration_parsed":{"hours":960.0,"printed":"40 days"},"extraction_accepted":false,"id":"ORC-6IH7OULXOK","page":2,"purpose":"equilibrated","quote":"Xray diffraction was carried out using Cu Kα radiation to identify the crystal structure for the Sn-35Au15Ni (at.%) and Sn-30Au-20Ni equilibrated at 300°C and 400°C for 40 days, respectively, in order to verify","second_reader_agrees":false,"temperature":{"T_K":573.15,"converted_in_code":true,"printed":"300°C and 400°C","unit_basis":"printed_with_value","unit_printed":"°C","value_printed":300.0},"temperature_printed":"300°C and 400°C","temperature_status":"parsed_from_printed","type":"treatment"},{"applies_to":"Sn-Au-Ni ternary alloys","atmosphere_or_container":"evacuated transparent quartz capsules","duration":"4 h","duration_parsed":{"hours":4.0,"printed":"4 h"},"extraction_accepted":true,"has_dropped_fields":true,"id":"ORC-ZED5G6W5TU","page":2,"quote":"EXPERIMENTAL PROCEDURE Sn-Au-Ni ternary alloys were prepared using pure Sn (99.9%), Au (99.99%), and Ni(99.9%) in evacuated transparent quartz capsules at about 1200°C for 4 h.","second_reader_agrees":true,"temperature":{"T_K":1473.15,"converted_in_code":true,"printed":"about 1200°C","unit_basis":"printed_with_value","unit_printed":"°C","value_printed":1200.0},"temperature_printed":"about 1200°C","temperature_status":"parsed_from_printed","type":"treatment"},{"applies_to":"specimens","cooling":"quenched in ice water","duration":"20-720 h","duration_parsed":{"hours":720.0,"printed":"720 h"},"extraction_accepted":false,"id":"ORC-ZX446B7CPI","page":2,"purpose":"equilibrated","quote":"After homogenization treatment, the specimens were equilibrated at 200°C, 250°C, 300°C, 400°C, 500°C, and 600°C for 20-720 h and then quenched in ice water.","second_reader_agrees":false,"temperature":{"T_K":473.15,"converted_in_code":true,"printed":"200°C, 250°C, 300°C, 400°C, 500°C, and 600°C","unit_basis":"printed_with_value","unit_printed":"°C","value_printed":200.0},"temperature_printed":"200°C, 250°C, 300°C, 400°C, 500°C, and 600°C","temperature_status":"parsed_from_printed","type":"treatment"}],"paper":"doi:10.1007/s11664-005-0082-9","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash / exp-context-v2.1-quote","claude-opus-5.5 / exp-context-v2.1-quote (claude broker)"],"section_basis":"methods_heading"},"doi:10.1016/j.calphad.2013.10.001":{"context_id":"context:source-doi-10-1016-j-calphad-2013-10-001","items":[{"extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-BGTX6ZUDSQ","instrument":"JEOL 6335 F FE-SEM","page":2,"quote":"The cross-sections of the samples were prepared with the standard metallographic methods, and they were analyzed with a field emission scanning electron microscope (JEOL 6335 F FE-SEM) equipped with an energy dispersive spectrometer (EDS, Oxford ISIS).","second_reader_agrees":false,"type":"measurement"},{"extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-BGTX6ZUDSQ","instrument":"Oxford ISIS","page":2,"quote":"The cross-sections of the samples were prepared with the standard metallographic methods, and they were analyzed with a field emission scanning electron microscope (JEOL 6335 F FE-SEM) equipped with an energy dispersive spectrometer (EDS, Oxford ISIS).","second_reader_agrees":false,"type":"measurement"},{"extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-SJHBAXKZMF","label":"reaction couples","nominal_composition":"Au80/Sn20 (wt%) [Au70.7/Sn29.3 (at%)]","page":2,"purity":"99,99þ","quote":"The reaction couples were manufactured by placing a 100 mm thick near eutectic Au80/Sn20 (wt%) [Au70.7/Sn29.3 (at%)] alloy foil between etched (1 min in dilute HCl þmethanol solution) 0.5 mm thick Ni foils (99,99þ , Goodfellow Ltd.).","second_reader_agrees":false,"synthesis":"manufactured by placing a 100 mm thick near eutectic Au80/Sn20 (wt%) [Au70.7/Sn29.3 (at%)] alloy foil between etched (1 min in dilute HCl þmethanol solution) 0.5 mm thick Ni foils (99,99þ , Goodfellow Ltd.)","type":"sample"},{"applies_to":"sandwich structure","atmosphere_or_container":"air furnace","duration":"from 100 s up to 10,000 s","duration_parsed":{"hours":0.0278,"printed":"100 s"},"extraction_accepted":true,"id":"ORC-4VYHXESPEO","page":2,"purpose":"soldered","quote":"The sandwich structure was then soldered at 320 1C for from 100 s up to 10,000 s at air furnace by utilizing Rosin Mildly Activated (RMA) flux.","second_reader_agrees":true,"temperature":{"converted_in_code":false,"printed":"320 1C"},"temperature_printed":"320 1C","temperature_status":"unparsed","type":"treatment"},{"applies_to":"a few samples","atmosphere_or_container":"forced convection oven (Heraeus Instruments UT6)","duration":"different periods of time up to 2500 h","duration_parsed":{"hours":2500.0,"printed":"2500 h"},"extraction_accepted":true,"id":"ORC-UZFA2DHIQ5","page":2,"purpose":"annealed","quote":"After the soldering a few samples were annealed in a forced convection oven (Heraeus Instruments UT6) for different periods of time up to 2500 h at 150 1C.","second_reader_agrees":true,"temperature":{"converted_in_code":false,"printed":"150 1C"},"temperature_printed":"150 1C","temperature_status":"unparsed","type":"treatment"}],"paper":"doi:10.1016/j.calphad.2013.10.001","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash / exp-context-v2.1-quote","claude-opus-5.5 / exp-context-v2.1-quote (claude broker)"],"section_basis":"methods_heading"}},"elements":["AU","NI","SN"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1006/jssc.1996.0169":{"authors":["Alexandra Neumann","A. Kjekshus","E. Røst"],"citation":"Alexandra Neumann, A. Kjekshus, E. Røst, The Ternary System Au–Ni–Sn, Journal of Solid State Chemistry 123, 203-207 (1996).","container":"Journal of Solid State Chemistry","doi":"10.1006/jssc.1996.0169","doi_url":"https://doi.org/10.1006/jssc.1996.0169","id":"doi:10.1006/jssc.1996.0169","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The Ternary System Au–Ni–Sn","year":1996},"doi:10.1007/s11664-005-0082-9":{"authors":["X. J. Liu","M. Kinaka","Y. Takaku","I. Ohnuma","R. Kainuma","K. Ishida"],"citation":"X. J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, Experimental investigation and thermodynamic calculation of phase equilibria in the Sn-Au-Ni system, J. Electron. Mater. 34, 670-679 (2005).","container":"J. Electron. Mater.","doi":"10.1007/s11664-005-0082-9","doi_url":"https://doi.org/10.1007/s11664-005-0082-9","id":"doi:10.1007/s11664-005-0082-9","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"e626e9af186c9d36","roles":["cited_source","reporting_paper"],"source_kinds":["journal_article"],"title":"Experimental investigation and thermodynamic calculation of phase equilibria in the Sn-Au-Ni system","year":2005},"doi:10.1016/0022-4596(95)80021-g":{"authors":["Alexandra Neumann","A. Kjekshus","C. Rømming","E. Røst"],"citation":"Alexandra Neumann, A. Kjekshus, C. Rømming, E. Røst, The crystal structure of AuNi2Sn4, Journal of Solid State Chemistry 119, 142-146 (1995).","container":"Journal of Solid State Chemistry","doi":"10.1016/0022-4596(95)80021-g","doi_url":"https://doi.org/10.1016/0022-4596(95)80021-g","id":"doi:10.1016/0022-4596(95)80021-g","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The crystal structure of AuNi2Sn4","year":1995},"doi:10.1016/j.calphad.2013.10.001":{"authors":["H.Q. Dong","V. Vuorinen","T. Laurila","M. Paulasto-Kröckel"],"citation":"H.Q. Dong, V. Vuorinen, T. Laurila, M. Paulasto-Kröckel, Thermodynamic reassessment of Au–Ni–Sn ternary system, Calphad 43, 61-70 (2013).","container":"Calphad","doi":"10.1016/j.calphad.2013.10.001","doi_url":"https://doi.org/10.1016/j.calphad.2013.10.001","id":"doi:10.1016/j.calphad.2013.10.001","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"90491ef3ea9a4a15","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic reassessment of Au–Ni–Sn ternary system","year":2013}},"part":1,"parts":1,"records":[{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.calphad.2013.10.001"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-3D5O3C5YMJ","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":1},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.32},"composition_source":"printed","phase":"Ni3Sn2"}],"phases":[{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r01#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":423.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-CYCBT4PMZQ","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":2},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.315},"composition_source":"printed","phase":"Ni3Sn2"}],"phases":[{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r02#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":423.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-KXQI2L73ME","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":3},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.018},"composition_source":"printed","phase":"Ni3Sn_LT"}],"phases":[{"label":"Ni3Sn_LT"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r03#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":423.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.calphad.2013.10.001"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-NTJ3KVXYPP","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":4},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.035},"composition_source":"printed","phase":"AuSn"}],"phases":[{"label":"AuSn"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r04#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":423.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-ZMPCYGONSJ","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":5},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.028},"composition_source":"printed","phase":"AuSn"}],"phases":[{"label":"AuSn"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r05#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":423.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.calphad.2013.10.001"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-FKMX2CNU2V","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":6},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.03},"composition_source":"printed","phase":"Au5Sn"}],"phases":[{"label":"Au5Sn"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r06#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":423.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-FUVFBGE6ZY","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":7},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.03},"composition_source":"printed","phase":"Au5Sn"}],"phases":[{"label":"Au5Sn"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r07#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":423.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-OONEDUR3I7","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":8},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.104},"composition_source":"printed","phase":"AuSn4"}],"phases":[{"label":"AuSn4"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r08#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":423.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-EGP53O4LM3","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":9},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.291},"composition_source":"printed","phase":"Ni3Sn2"}],"phases":[{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r09#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-TNJFSST42B","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":10},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.264},"composition_source":"printed","phase":"Ni3Sn2"}],"phases":[{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r10#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-G3FMLVWMPR","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":11},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.311},"composition_source":"printed","phase":"Ni3Sn2"}],"phases":[{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r11#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-DFUXI62ZS2","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":12},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.019},"composition_source":"printed","phase":"Ni3Sn_LT"}],"phases":[{"label":"Ni3Sn_LT"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r12#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-6S3UUDCV4O","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":13},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.045},"composition_source":"printed","phase":"AuSn"}],"phases":[{"label":"AuSn"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r13#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-WHHVHKQPN7","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":14},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.04},"composition_source":"printed","phase":"AuSn"}],"phases":[{"label":"AuSn"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r14#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-Y2KANDYJAW","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":15},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.041},"composition_source":"printed","phase":"AuSn"}],"phases":[{"label":"AuSn"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r15#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-NQ56HLHV3Q","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":16},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.002},"composition_source":"printed","phase":"Hcp"}],"phases":[{"label":"Hcp"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r16#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-K4NE3AHBPS","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":17},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.0006},"composition_source":"printed","phase":"Hcp"}],"phases":[{"label":"Hcp"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r17#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-KHNPUM5PIC","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":18},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.0016},"composition_source":"printed","phase":"Hcp"}],"phases":[{"label":"Hcp"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r18#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-Q6ZRMBORM4","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":19},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.105},"composition_source":"printed","phase":"AuSn4"}],"phases":[{"label":"AuSn4"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r19#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-WYHEPVCREX","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":20},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.08},"composition_source":"printed","phase":"AuSn4"}],"phases":[{"label":"AuSn4"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r20#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-GPVHUCAWC4","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":21},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.101},"composition_source":"printed","phase":"AuSn4"}],"phases":[{"label":"AuSn4"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r21#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-WICTAUL533","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":22},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.292},"composition_source":"printed","phase":"Ni3Sn2"}],"phases":[{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r22#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-6ZXRKOF7R5","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":23},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.287},"composition_source":"printed","phase":"Ni3Sn2"}],"phases":[{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r23#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-FOYFDHKNGQ","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":24},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.304},"composition_source":"printed","phase":"Ni3Sn2"}],"phases":[{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r24#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-CHM3BBZKEW","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":25},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.025},"composition_source":"printed","phase":"Ni3Sn_LT"}],"phases":[{"label":"Ni3Sn_LT"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r25#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-CIX6WKGKBC","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":26},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.109},"composition_source":"printed","phase":"AuSn"}],"phases":[{"label":"AuSn"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r26#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-AB7BSVQV6J","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":27},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.081},"composition_source":"printed","phase":"AuSn"}],"phases":[{"label":"AuSn"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r27#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-OZXB3MJSSR","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":28},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.075},"composition_source":"printed","phase":"AuSn"}],"phases":[{"label":"AuSn"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r28#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-UGD4RAOVGG","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":29},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.006},"composition_source":"printed","phase":"Hcp"}],"phases":[{"label":"Hcp"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r29#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-RBX52DQUYW","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":30},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.006},"composition_source":"printed","phase":"Hcp"}],"phases":[{"label":"Hcp"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r30#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-HUINL45IOF","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":31},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.006},"composition_source":"printed","phase":"Hcp"}],"phases":[{"label":"Hcp"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r31#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-DPNBYR3FAQ","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":32},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.005},"composition_source":"printed","phase":"Au10Sn"}],"phases":[{"label":"Au10Sn"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r32#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1006/jssc.1996.0169","first_author":"Neumann","kind":"unknown","label":"20","paper":"doi:10.1006/jssc.1996.0169","reference":"A. Neumann, A. Kjekshus, E. Røst, J. Solid State Chem. 123 (1996) 203.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-VBERN6CE6T","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":33},"observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"NI":0.6,"SN":0.4},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phases":[{"label":"Ni3Sn2"},{"label":"AuSn"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r33#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-JQEHXZURS4","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":34},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.268},"composition_source":"printed","phase":"Ni3Sn2"}],"phases":[{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r34#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-3I4VXXGRFG","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":35},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.26},"composition_source":"printed","phase":"Ni3Sn2"}],"phases":[{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r35#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-OKT5JC7VXF","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":36},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.277},"composition_source":"printed","phase":"Ni3Sn2"}],"phases":[{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r36#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1006/jssc.1996.0169","first_author":"Neumann","kind":"unknown","label":"20","paper":"doi:10.1006/jssc.1996.0169","reference":"A. Neumann, A. Kjekshus, E. Røst, J. Solid State Chem. 123 (1996) 203.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-GGJD2XT7I4","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":37},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.044},"composition_source":"printed","phase":"Ni3Sn_LT"}],"phases":[{"label":"Ni3Sn_LT"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r37#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-VIKWBTVQLP","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":38},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.031},"composition_source":"printed","phase":"Ni3Sn_LT"}],"phases":[{"label":"Ni3Sn_LT"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r38#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1006/jssc.1996.0169","first_author":"Neumann","kind":"unknown","label":"20","paper":"doi:10.1006/jssc.1996.0169","reference":"A. Neumann, A. Kjekshus, E. Røst, J. Solid State Chem. 123 (1996) 203.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-2BIBHJ5ATJ","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":39},"observation_type":"phase_assemblage_node","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"NI":0.0,"SN":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phases":[{"label":"AuSn"},{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r39#phase_assemblage_node","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_ASSEMBLAGE","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-6KVLQIUWNN","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":40},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.119},"composition_source":"printed","phase":"AuSn"}],"phases":[{"label":"AuSn"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r40#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-OTXNWJVM3V","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":41},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.099},"composition_source":"printed","phase":"AuSn"}],"phases":[{"label":"AuSn"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r41#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-3XYV2KY5SH","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":42},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.108},"composition_source":"printed","phase":"AuSn"}],"phases":[{"label":"AuSn"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r42#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1006/jssc.1996.0169","first_author":"Neumann","kind":"unknown","label":"20","paper":"doi:10.1006/jssc.1996.0169","reference":"A. Neumann, A. Kjekshus, E. Røst, J. Solid State Chem. 123 (1996) 203.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-DCAJ7XNHXH","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":43},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.01},"composition_source":"printed","phase":"Hcp"}],"phases":[{"label":"Hcp"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r43#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-4HMLCHNKOE","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":44},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.017},"composition_source":"printed","phase":"Hcp"}],"phases":[{"label":"Hcp"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r44#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-76NVR5APXE","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":45},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.017},"composition_source":"printed","phase":"Hcp"}],"phases":[{"label":"Hcp"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r45#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-DPAYCOBR3N","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":46},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.014},"composition_source":"printed","phase":"Hcp"}],"phases":[{"label":"Hcp"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r46#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1006/jssc.1996.0169","first_author":"Neumann","kind":"unknown","label":"20","paper":"doi:10.1006/jssc.1996.0169","reference":"A. Neumann, A. Kjekshus, E. Røst, J. Solid State Chem. 123 (1996) 203.","status":"resolved","year":"1996"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-ZQHYQWDWCV","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":47},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.01},"composition_source":"printed","phase":"Au10Sn"}],"phases":[{"label":"Au10Sn"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r47#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-W2ETKTMZJG","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":48},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"NI":0.007},"composition_source":"printed","phase":"Au10Sn"}],"phases":[{"label":"Au10Sn"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r48#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-6NJRJYGKUM","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":49},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.235},"composition_source":"printed","phase":"Ni3Sn2"}],"phases":[{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r49#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":773.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-KQ52JPNSRO","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":50},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.226},"composition_source":"printed","phase":"Ni3Sn2"}],"phases":[{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r50#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":773.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-5YTD6TVUUI","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":51},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.224},"composition_source":"printed","phase":"Ni3Sn2"}],"phases":[{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r51#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":773.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-YN3PB5NL47","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":52},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.139},"composition_source":"printed","phase":"Ni3Sn2"}],"phases":[{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r52#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":873.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","cited_sources":[{"doi":"10.1007/s11664-005-0082-9","first_author":"Liu","kind":"unknown","label":"22","paper":"doi:10.1007/s11664-005-0082-9","reference":"X.J. Liu, M. Kinaka, Y. Takaku, I. Ohnuma, R. Kainuma, K. Ishida, J. Electron. Mater. 34 (2005) 670.","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-A7CVZQARTZ","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":53},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.135},"composition_source":"printed","phase":"Ni3Sn2"}],"phases":[{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r53#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":873.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-VMNGNUPSRQ","locator":{"ref":"sha256:90491ef3ea9a4a15/p7/tab-2","row":54},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"phase_region_vertex_set","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.168},"composition_source":"printed","phase":"Ni3Sn2"}],"phases":[{"label":"Ni3Sn2"}],"pid":"sha256:90491ef3ea9a4a15/p7/tab-2/r54#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":873.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_CONDITION","floor":5.0,"floor_unit":"K","n_pairs":0,"value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-P7QAU5TR3P","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":1},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.116,"NI":0.453,"SN":0.431},"composition_source":"printed","phase":"Sn2Ni3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.564,"NI":0.029,"SN":0.407},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Sn2Ni3"},{"label":"liquid"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r01#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":873.15,"temperature_basis":"printed","temperature_printed":"600","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase SnNi3 printed composition {'AU': 0.0018, 'NI': 0.45, 'SN': 0.5482} deviates 0.30 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-CJ6OOJPQTK","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":2},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.0018,"NI":0.45,"SN":0.5482},"composition_source":"printed","phase":"SnNi3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.177,"NI":0.027,"SN":0.796},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"SnNi3"},{"label":"liquid"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r02#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":873.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase Sn2Ni3 printed composition {'AU': 0.16, 'NI': 0.399, 'SN': 0.441} deviates 0.20 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-MOBUOZRA5K","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":3},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.16,"NI":0.399,"SN":0.441},"composition_source":"printed","phase":"Sn2Ni3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.624,"NI":0.007,"SN":0.369},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Sn2Ni3"},{"label":"liquid"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r03#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":773.15,"temperature_basis":"printed","temperature_printed":"500","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase SnNi3 printed composition {'AU': 0.004, 'NI': 0.433, 'SN': 0.563} deviates 0.32 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-DJS4ZCOMF2","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":4},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.004,"NI":0.433,"SN":0.563},"composition_source":"printed","phase":"SnNi3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.193,"NI":0.01,"SN":0.797},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"SnNi3"},{"label":"liquid"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r04#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":773.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase Sn2Ni3 printed composition {'AU': 0.005, 'NI': 0.436, 'SN': 0.559} deviates 0.16 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-TIUMNUZ2K6","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":5},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.005,"NI":0.436,"SN":0.559},"composition_source":"printed","phase":"Sn2Ni3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.119,"NI":0.406,"SN":0.475},"composition_source":"printed","phase":"SnNi3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.25,"NI":0.009,"SN":0.741},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Sn2Ni3"},{"label":"SnNi3"},{"label":"liquid"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r05#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":773.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase Sn2Ni3 printed composition {'AU': 0.239, 'NI': 0.3, 'SN': 0.461} deviates 0.30 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-SO3E4FNC7O","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":6},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.239,"NI":0.3,"SN":0.461},"composition_source":"printed","phase":"Sn2Ni3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.555,"NI":0.006,"SN":0.439},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Sn2Ni3"},{"label":"liquid"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r06#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","temperature_printed":"400","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase SnNi3 printed composition {'AU': 0.009, 'NI': 0.42, 'SN': 0.571} deviates 0.33 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-WQ2ZOPHYX7","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":7},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.009,"NI":0.42,"SN":0.571},"composition_source":"printed","phase":"SnNi3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.201,"NI":0.007,"SN":0.792},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"SnNi3"},{"label":"liquid"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r07#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-F5JIVDOF7M","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":8},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.136,"NI":0.289,"SN":0.575},"composition_source":"printed","phase":"Sn4AuNi2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.211,"NI":0.007,"SN":0.782},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Sn4AuNi2"},{"label":"liquid"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r08#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase Sn2Ni3 printed composition {'AU': 0.148, 'NI': 0.371, 'SN': 0.481} deviates 0.23 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-J34EVIPVJD","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":9},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.148,"NI":0.371,"SN":0.481},"composition_source":"printed","phase":"Sn2Ni3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.005,"NI":0.431,"SN":0.564},"composition_source":"printed","phase":"SnNi3"}],"phases":[{"label":"Sn2Ni3"},{"label":"SnNi3"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r09#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-OBJRNEMBWT","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":10},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.113,"NI":0.468,"SN":0.419},"composition_source":"printed","phase":"Sn2Ni3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.863,"NI":0.017,"SN":0.12},"composition_source":"printed","phase":"hcp"}],"phases":[{"label":"Sn2Ni3"},{"label":"hcp"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r10#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase SnAu printed composition {'AU': 0.319, 'NI': 0.18, 'SN': 0.501} deviates 0.18 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-54S67R3LYE","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":11},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.319,"NI":0.18,"SN":0.501},"composition_source":"printed","phase":"SnAu"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.268,"NI":0.226,"SN":0.506},"composition_source":"printed","phase":"Sn2Ni3"}],"phases":[{"label":"SnAu"},{"label":"Sn2Ni3"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r11#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":673.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-SZC5ZPCO46","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":12},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.135,"NI":0.284,"SN":0.581},"composition_source":"printed","phase":"Sn4AuNi2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.104,"NI":0.004,"SN":0.892},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Sn4AuNi2"},{"label":"liquid"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r12#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","temperature_printed":"300","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase Sn2Ni3 printed composition {'AU': 0.098, 'NI': 0.444, 'SN': 0.458} deviates 0.16 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-OETZWSYCWP","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":13},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.098,"NI":0.444,"SN":0.458},"composition_source":"printed","phase":"Sn2Ni3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.008,"NI":0.44,"SN":0.552},"composition_source":"printed","phase":"SnNi3"}],"phases":[{"label":"Sn2Ni3"},{"label":"SnNi3"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r13#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-FBPJZBUV3L","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":14},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.098,"NI":0.492,"SN":0.41},"composition_source":"printed","phase":"Sn2Ni3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.02,"NI":0.843,"SN":0.137},"composition_source":"printed","phase":"hcp"}],"phases":[{"label":"Sn2Ni3"},{"label":"hcp"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r14#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase SnAu printed composition {'AU': 0.322, 'NI': 0.177, 'SN': 0.501} deviates 0.18 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-45JKLR3NB6","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":15},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.322,"NI":0.177,"SN":0.501},"composition_source":"printed","phase":"SnAu"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.261,"NI":0.235,"SN":0.504},"composition_source":"printed","phase":"Sn2Ni3"}],"phases":[{"label":"SnAu"},{"label":"Sn2Ni3"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r15#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase SnNi3 printed composition {'AU': 0.255, 'NI': 0.207, 'SN': 0.538} deviates 0.54 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-Z356PE3DXA","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":16},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.136,"NI":0.283,"SN":0.581},"composition_source":"printed","phase":"Sn4AuNi2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.255,"NI":0.207,"SN":0.538},"composition_source":"printed","phase":"SnNi3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.208,"NI":0.002,"SN":0.79},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Sn4AuNi2"},{"label":"SnNi3"},{"label":"liquid"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r16#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase SnAu printed composition {'AU': 0.007, 'NI': 0.417, 'SN': 0.576} deviates 0.49 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-5BCZAHUEC4","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":17},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.135,"NI":0.286,"SN":0.579},"composition_source":"printed","phase":"Sn4AuNi2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.007,"NI":0.417,"SN":0.576},"composition_source":"printed","phase":"SnAu"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.09,"NI":0.008,"SN":0.902},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Sn4AuNi2"},{"label":"SnAu"},{"label":"liquid"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r17#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase Sn3Ni2 printed composition {'AU': 0.292, 'NI': 0.229, 'SN': 0.479} deviates 0.29 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-7CP4ZVYXZF","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":18},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.292,"NI":0.229,"SN":0.479},"composition_source":"printed","phase":"Sn3Ni2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.831,"NI":0.001,"SN":0.168},"composition_source":"printed","phase":"hcp"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.697,"NI":0.002,"SN":0.301},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Sn3Ni2"},{"label":"hcp"},{"label":"liquid"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r18#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase Sn2Ni3 printed composition {'AU': 0.278, 'NI': 0.177, 'SN': 0.545} deviates 0.42 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-P3LVF6UYJT","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":19},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.278,"NI":0.177,"SN":0.545},"composition_source":"printed","phase":"Sn2Ni3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.353,"NI":0.109,"SN":0.538},"composition_source":"printed","phase":"SnAu"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.319,"NI":0.006,"SN":0.675},"composition_source":"printed","phase":"hcp"}],"phases":[{"label":"Sn2Ni3"},{"label":"SnAu"},{"label":"hcp"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r19#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-VXCJHBKNMB","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":20},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.135,"NI":0.289,"SN":0.576},"composition_source":"printed","phase":"Sn4AuNi2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.113,"NI":0.006,"SN":0.881},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Sn4AuNi2"},{"label":"liquid"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r20#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":523.15,"temperature_basis":"printed","temperature_printed":"250","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase SnNi3 printed composition {'AU': 0.003, 'NI': 0.427, 'SN': 0.57} deviates 0.32 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-7OKNAIJ4V6","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":21},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.003,"NI":0.427,"SN":0.57},"composition_source":"printed","phase":"SnNi3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.048,"NI":0.005,"SN":0.947},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"SnNi3"},{"label":"liquid"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r21#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":523.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-YFT24YUH2P","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":22},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.136,"NI":0.289,"SN":0.575},"composition_source":"printed","phase":"Sn4AuNi2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.317,"NI":0.005,"SN":0.678},"composition_source":"printed","phase":"Sn2Au"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.168,"NI":0.024,"SN":0.808},"composition_source":"printed","phase":"liquid"}],"phases":[{"label":"Sn4AuNi2"},{"label":"Sn2Au"},{"label":"liquid"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r22#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":523.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-HTYTLHJOGU","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":23},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.136,"NI":0.281,"SN":0.583},"composition_source":"printed","phase":"Sn4AuNi2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.116,"NI":0.076,"SN":0.808},"composition_source":"printed","phase":"Sn4Au"}],"phases":[{"label":"Sn4AuNi2"},{"label":"Sn4Au"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r23#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","temperature_printed":"200","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-A5IUSZBNX5","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":24},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.093,"NI":0.1,"SN":0.807},"composition_source":"printed","phase":"Sn4Au"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.001,"NI":0.0,"SN":0.999},"composition_source":"printed","phase":"βSn"}],"phases":[{"label":"Sn4Au"},{"label":"βSn"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r24#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase SnNi3 printed composition {'AU': 0.006, 'NI': 0.44, 'SN': 0.554} deviates 0.31 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-ZGTJBI4IGG","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":25},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.006,"NI":0.44,"SN":0.554},"composition_source":"printed","phase":"SnNi3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.137,"NI":0.394,"SN":0.469},"composition_source":"printed","phase":"Sn2Ni3"}],"phases":[{"label":"SnNi3"},{"label":"Sn2Ni3"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r25#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-HHBHVIFBZE","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":26},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.091,"NI":0.495,"SN":0.414},"composition_source":"printed","phase":"Sn2Ni3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.837,"NI":0.025,"SN":0.138},"composition_source":"printed","phase":"hcp"}],"phases":[{"label":"Sn2Ni3"},{"label":"hcp"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r26#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase SnNi3 printed composition {'AU': 0.003, 'NI': 0.414, 'SN': 0.583} deviates 0.34 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-TMRDEXF4Z4","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":27},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.133,"NI":0.282,"SN":0.585},"composition_source":"printed","phase":"Sn4AuNi2"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.082,"NI":0.115,"SN":0.803},"composition_source":"printed","phase":"Sn4Au"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.003,"NI":0.414,"SN":0.583},"composition_source":"printed","phase":"SnNi3"}],"phases":[{"label":"Sn4AuNi2"},{"label":"Sn4Au"},{"label":"SnNi3"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r27#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase SnNi3 printed composition {'AU': 0.262, 'NI': 0.206, 'SN': 0.532} deviates 0.54 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-XQBV6YSLNB","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":28},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.262,"NI":0.206,"SN":0.532},"composition_source":"printed","phase":"SnNi3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.321,"NI":0.002,"SN":0.677},"composition_source":"printed","phase":"Sn2Au"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.444,"NI":0.045,"SN":0.511},"composition_source":"printed","phase":"SnAu"}],"phases":[{"label":"SnNi3"},{"label":"Sn2Au"},{"label":"SnAu"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r28#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["composition_label_mismatch"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"composition_label_mismatch","detail":"phase Sn2Ni3 printed composition {'AU': 0.291, 'NI': 0.227, 'SN': 0.482} deviates 0.37 from its formula","effect":"flag_only","gate":"G9"}],"id":"ORC-3HL574N5DT","locator":{"ref":"sha256:e626e9af186c9d36/p5/tab-ii","row":29},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.291,"NI":0.227,"SN":0.482},"composition_source":"printed","phase":"Sn2Ni3"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.845,"NI":0.002,"SN":0.153},"composition_source":"printed","phase":"hcp"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.482,"NI":0.008,"SN":0.51},"composition_source":"printed","phase":"SnAu"}],"phases":[{"label":"Sn2Ni3"},{"label":"hcp"},{"label":"SnAu"}],"pid":"sha256:e626e9af186c9d36/p5/tab-ii/r29#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":473.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-3ZNLSN3F33","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":1},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.25,"NI":0.25,"SN":0.5},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"liquidus"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r01#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":1290.15,"temperature_basis":"printed","temperature_printed":"1017","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1290.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-KAIYHG3R7O","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":2},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.175,"NI":0.175,"SN":0.65},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"liquidus"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":1153.15,"temperature_basis":"printed","temperature_printed":"880","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1153.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-SUFXDNSBPX","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":3},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.125,"NI":0.125,"SN":0.75},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"liquidus"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":1048.15,"temperature_basis":"printed","temperature_printed":"775","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1048.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":4,"id":"ORC-NBLI2LP7O5","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":4},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"liquidus"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":878.15,"temperature_basis":"printed","temperature_printed":"605","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":878.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-KMY5BIATTR","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":5},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.1,"NI":0.4,"SN":0.5},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"liquidus"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":1441.15,"temperature_basis":"printed","temperature_printed":"1168","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1441.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-VDPVUF2IRM","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":6},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.4,"NI":0.1,"SN":0.5},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"liquidus"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":1138.15,"temperature_basis":"printed","temperature_printed":"865","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1138.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-QSDSYD5LKV","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":7},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.15,"NI":0.45,"SN":0.4},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"liquidus"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r07#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":1423.15,"temperature_basis":"printed","temperature_printed":"1150","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1423.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-CZLOU2SFYT","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":8},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.3,"NI":0.3,"SN":0.4},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"liquidus"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r08#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":1303.15,"temperature_basis":"printed","temperature_printed":"1030","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1303.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"id":"ORC-KF64AGP5SU","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":9},"method":"DSC","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"printed_source_this_work_experimental","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.45,"NI":0.15,"SN":0.4},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"liquidus"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r09#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"other"},"reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":1148.15,"temperature_basis":"printed","temperature_printed":"875","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"liquidus","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1148.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-AAG4O3B7X4","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":10},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.25,"NI":0.25,"SN":0.5},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r10#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni25 Au25 (at.%)","type":"other"},"reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":584.15,"temperature_basis":"printed","temperature_printed":"311","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":584.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-25OVYB32AO","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":11},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.25,"NI":0.25,"SN":0.5},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r11#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni25 Au25 (at.%)","type":"other"},"reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":791.15,"temperature_basis":"printed","temperature_printed":"518","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":791.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-3OLC6EZATI","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":12},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.175,"NI":0.175,"SN":0.65},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r12#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni17.5 Au17.5 (at.%)","type":"other"},"reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":533.15,"temperature_basis":"printed","temperature_printed":"260","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":533.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-E4KIZLWU6P","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":13},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.175,"NI":0.175,"SN":0.65},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r13#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni17.5 Au17.5 (at.%)","type":"other"},"reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":681.15,"temperature_basis":"printed","temperature_printed":"408","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":681.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-OY3U6HIOGF","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":14},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.125,"NI":0.125,"SN":0.75},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r14#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni12.5 Au12.5 (at.%)","type":"other"},"reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":484.15,"temperature_basis":"printed","temperature_printed":"211","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":484.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-C3E4BSJ7DN","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":15},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.125,"NI":0.125,"SN":0.75},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r15#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni12.5 Au12.5 (at.%)","type":"other"},"reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":513.15,"temperature_basis":"printed","temperature_printed":"240","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":513.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-MZ674I3CQN","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":16},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.125,"NI":0.125,"SN":0.75},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r16#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni12.5 Au12.5 (at.%)","type":"other"},"reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":589.15,"temperature_basis":"printed","temperature_printed":"316","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":589.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-IFWA3SLFHV","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":17},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.125,"NI":0.125,"SN":0.75},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r17#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni12.5 Au12.5 (at.%)","type":"other"},"reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":984.15,"temperature_basis":"printed","temperature_printed":"711","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":984.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-NUUIHYGI74","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":18},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r18#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni5 Au5 (at.%)","type":"other"},"reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":489.15,"temperature_basis":"printed","temperature_printed":"216","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":489.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-AZA4EMY7JR","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":19},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r19#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni5 Au5 (at.%)","type":"other"},"reader_agreement":"single_reader","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":514.15,"temperature_basis":"printed","temperature_printed":"241","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":514.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-JLCNFMT3TP","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":20},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.1,"NI":0.4,"SN":0.5},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r20#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni40 Au10 (at.%)","type":"other"},"reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":786.15,"temperature_basis":"printed","temperature_printed":"513","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":786.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-DWBSC3QB32","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":21},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.1,"NI":0.4,"SN":0.5},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r21#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni40 Au10 (at.%)","type":"other"},"reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":757.15,"temperature_basis":"printed","temperature_printed":"484","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":757.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-NQ5HZQ3CT4","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":22},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.4,"NI":0.1,"SN":0.5},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r22#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni10 Au40 (at.%)","type":"other"},"reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":588.15,"temperature_basis":"printed","temperature_printed":"315","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":588.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-SA5VQLHCQ6","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":23},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.4,"NI":0.1,"SN":0.5},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r23#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni10 Au40 (at.%)","type":"other"},"reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":718.15,"temperature_basis":"printed","temperature_printed":"445","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":718.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-G3VX7UQO7K","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":24},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.15,"NI":0.45,"SN":0.4},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r24#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni45 Au15 (at.%)","type":"other"},"reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":675.15,"temperature_basis":"printed","temperature_printed":"402","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":675.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-XHX2PRJJ76","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":25},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.3,"NI":0.3,"SN":0.4},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r25#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni30 Au30 (at.%)","type":"other"},"reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":557.15,"temperature_basis":"printed","temperature_printed":"284","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":557.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-FVLZB2B3QK","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":26},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.3,"NI":0.3,"SN":0.4},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r26#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni30 Au30 (at.%)","type":"other"},"reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":577.15,"temperature_basis":"printed","temperature_printed":"304","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":577.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-AJOCX676KY","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":27},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.45,"NI":0.15,"SN":0.4},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r27#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni15 Au45 (at.%)","type":"other"},"reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":553.15,"temperature_basis":"printed","temperature_printed":"280","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":553.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"paper_context","paper":"doi:10.1007/s11664-005-0082-9"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted"},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (placeholder phases only (other))","effect":"not_accepted","gate":"R3"}],"id":"ORC-O6MCCFYHJQ","locator":{"ref":"sha256:e626e9af186c9d36/p7/tab-iii","row":28},"method":"Differential Scanning Calorimetry","method_basis":"printed in the table row/column","observation_type":"phase_transition","origin":{"basis":"method_names_experiment_only","class":"experimental","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"overall_composition":{"AU":0.45,"NI":0.15,"SN":0.4},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"other"}],"pid":"sha256:e626e9af186c9d36/p7/tab-iii/r28#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Ni15 Au45 (at.%)","type":"other"},"reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":608.15,"temperature_basis":"printed","temperature_printed":"335","tool_release":"tools-release-v2.1.18","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":608.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-IFIQ62UVFP","locator":{"ref":"doi:10.1007/s11664-005-0082-9/p10/tab-v","row":1},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.0023,"NI":0.0033},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Sn4Ni3"},{"label":"Sn4Au"},{"label":"βSn","model_phase":"BCT_A5","pearson_symbol":"tI4","prototype":"beta-Sn","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11664-005-0082-9/p10/tab-v/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L <=> Sn4Ni3 + Sn4Au + βSn (E)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":503.35,"temperature_printed":"230.2","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":503.35},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-X46JQEDQZV","locator":{"ref":"doi:10.1007/s11664-005-0082-9/p10/tab-v","row":2},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.697,"NI":2e-05},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Sn2Ni3"},{"label":"SnAu"},{"label":"hcp","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11664-005-0082-9/p10/tab-v/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Sn2Ni3 <=> SnAu + hcp (P1)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":557.55,"temperature_printed":"284.4","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":557.55},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-HAKTCUWTS2","locator":{"ref":"doi:10.1007/s11664-005-0082-9/p10/tab-v","row":3},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.103,"NI":0.0031},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Sn4AuNi2"},{"label":"Sn4Ni3"},{"label":"Sn4Au"}],"pid":"doi:10.1007/s11664-005-0082-9/p10/tab-v/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Sn4AuNi2 <=> Sn4Ni3 + Sn4Au (P2)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":568.35,"temperature_printed":"295.2","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":568.35},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-7DXBZLBLT2","locator":{"ref":"doi:10.1007/s11664-005-0082-9/p10/tab-v","row":4},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.214,"NI":0.0008},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Sn4AuNi2"},{"label":"Sn4Au"},{"label":"Sn2Au"}],"pid":"doi:10.1007/s11664-005-0082-9/p10/tab-v/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Sn4AuNi2 <=> Sn4Au + Sn2Au (P3)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":569.65,"temperature_printed":"296.5","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":569.65},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-L2NPJ5UTG2","locator":{"ref":"doi:10.1007/s11664-005-0082-9/p10/tab-v","row":5},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.226,"NI":0.0008},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Sn2Ni3"},{"label":"Sn4AuNi2"},{"label":"Sn2Au"}],"pid":"doi:10.1007/s11664-005-0082-9/p10/tab-v/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Sn2Ni3 <=> Sn4AuNi2 + Sn2Au (P4)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":573.05,"temperature_printed":"299.9","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":573.05},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-NLQC2EHMVE","locator":{"ref":"doi:10.1007/s11664-005-0082-9/p10/tab-v","row":6},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.246,"NI":0.0006},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"SnAu"},{"label":"Sn2Au"},{"label":"Sn2Ni3"}],"pid":"doi:10.1007/s11664-005-0082-9/p10/tab-v/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + SnAu <=> Sn2Au + Sn2Ni3 (P5)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":578.05,"temperature_printed":"304.9","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":578.05},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-SXQYMM57E4","locator":{"ref":"doi:10.1007/s11664-005-0082-9/p10/tab-v","row":7},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.242,"NI":0.0054},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Sn2Ni3"},{"label":"Sn4Ni3"},{"label":"Sn4AuNi2"}],"pid":"doi:10.1007/s11664-005-0082-9/p10/tab-v/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Sn2Ni3 + Sn4Ni3 <=> Sn4AuNi2 (P6)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":694.85,"temperature_printed":"421.7","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":694.85},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-CRCNPQBSXF","locator":{"ref":"doi:10.1007/s11664-005-0082-9/p10/tab-v","row":8},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.257,"NI":0.0064},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Sn2Ni3"},{"label":"Sn4Ni3"},{"label":"SnAu"}],"pid":"doi:10.1007/s11664-005-0082-9/p10/tab-v/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Sn2Ni3 <=> Sn4Ni3 + SnAu (P7)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":718.45,"temperature_printed":"445.3","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":718.45},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-I3AFNKVEBC","locator":{"ref":"doi:10.1007/s11664-005-0082-9/p10/tab-v","row":9},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.793,"NI":0.0005},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"fcc","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"hcp","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"},{"label":"SnAu10"}],"pid":"doi:10.1007/s11664-005-0082-9/p10/tab-v/r09#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + fcc <=> hcp + SnAu10 (P8)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":802.55,"temperature_printed":"529.4","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":802.55},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-HXPPUK342R","locator":{"ref":"doi:10.1007/s11664-005-0082-9/p10/tab-v","row":10},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.793,"NI":0.013},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Sn2Ni3"},{"label":"fcc","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"hcp","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11664-005-0082-9/p10/tab-v/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Sn2Ni3 + fcc <=> hcp (P9)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":843.35,"temperature_printed":"570.2","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":843.35},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-NO64KIV675","locator":{"ref":"doi:10.1007/s11664-005-0082-9/p10/tab-v","row":11},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.794,"NI":0.017},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"SnNi3-LT"},{"label":"Sn2Ni3"},{"label":"fcc","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11664-005-0082-9/p10/tab-v/r11#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + SnNi3-LT <=> Sn2Ni3 + fcc (P10)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":860.25,"temperature_printed":"587.1","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":860.25},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-EZNMIWOZED","locator":{"ref":"doi:10.1007/s11664-005-0082-9/p10/tab-v","row":12},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.511,"NI":0.255},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"SnNi3-HT"},{"label":"SnNi3-LT"},{"label":"Sn2Ni3"}],"pid":"doi:10.1007/s11664-005-0082-9/p10/tab-v/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + SnNi3-HT <=> SnNi3-LT + Sn2Ni3 (P11)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":1155.35,"temperature_printed":"882.2","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1155.35},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-BDUKVKKNIJ","locator":{"ref":"doi:10.1007/s11664-005-0082-9/p10/tab-v","row":13},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.279,"NI":0.59},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni3Sn-HT"},{"label":"Ni3Sn-LT","model_phase":"NI3SN_D019","pearson_symbol":"hP8","prototype":"CdMg3","structure_basis":"mapped_model_phase"},{"label":"fcc","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11664-005-0082-9/p10/tab-v/r13#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni3Sn-HT <=> Ni3Sn-LT + fcc (P12)","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":1210.15,"temperature_printed":"937.0","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1210.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-TM5FXIME7H","locator":{"ref":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3","row":1},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.3205,"NI":0.4936},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Bcc","model_phase":"BCC_A2","pearson_symbol":"cF16","prototype":"BiF3","structure_basis":"mapped_model_phase"},{"label":"Ni3Sn_LT","model_phase":"NI3SN_D019","pearson_symbol":"hP8","prototype":"CdMg3","structure_basis":"mapped_model_phase"},{"label":"Ni3Sn2"}],"pid":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Bcc -> Ni3Sn_LT + Ni3Sn2","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":1229.62,"temperature_printed":"1229.62","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1229.62},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-EYBLCTEPEB","locator":{"ref":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3","row":2},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.2441,"NI":0.62},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Bcc","model_phase":"BCC_A2","pearson_symbol":"cF16","prototype":"BiF3","structure_basis":"mapped_model_phase"},{"label":"Ni3Sn_LT","model_phase":"NI3SN_D019","pearson_symbol":"hP8","prototype":"CdMg3","structure_basis":"mapped_model_phase"},{"label":"Fcc","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Bcc -> Ni3Sn_LT + Fcc","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":1220.95,"temperature_printed":"1220.95","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1220.95},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-JPIOAIQHJT","locator":{"ref":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3","row":3},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.7873,"NI":0.0198},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni3Sn_LT","model_phase":"NI3SN_D019","pearson_symbol":"hP8","prototype":"CdMg3","structure_basis":"mapped_model_phase"},{"label":"Ni3Sn2"},{"label":"Fcc","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni3Sn_LT -> Ni3Sn2 + Fcc","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":844.34,"temperature_printed":"844.34","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":844.34},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-HEOKJDZRR6","locator":{"ref":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3","row":4},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.7921,"NI":0.001},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Fcc","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Au10Sn"},{"label":"Hcp","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Fcc -> Au10Sn + Hcp","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":802.15,"temperature_printed":"802.15","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":802.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-BLT6H6BRZL","locator":{"ref":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3","row":5},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.2416,"NI":0.00036},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"AuSn","model_phase":"AUSN_B81","pearson_symbol":"hP4","prototype":"NiAs","structure_basis":"mapped_model_phase"},{"label":"Ni3Sn2"},{"label":"AuSn2","model_phase":"AUSN2","pearson_symbol":"oP24","prototype":"AuSn2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + AuSn -> Ni3Sn2 + AuSn2","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":577.88,"temperature_printed":"577.88","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-06},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":577.88},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-HKGHPUNPV7","locator":{"ref":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3","row":6},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.2404,"NI":0.00037},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni3Sn2"},{"label":"AuSn2","model_phase":"AUSN2","pearson_symbol":"oP24","prototype":"AuSn2","structure_basis":"mapped_model_phase"},{"label":"τ"}],"pid":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni3Sn2 -> AuSn2 + τ","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":577.57,"temperature_printed":"577.57","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-06},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":577.57},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-VEWHTKGUU2","locator":{"ref":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3","row":7},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.1999,"NI":0.0004},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"τ"},{"label":"AuSn4","model_phase":"AUSN4_D1C","pearson_symbol":"oC20","prototype":"PtSn4","structure_basis":"mapped_model_phase"},{"label":"AuSn2","model_phase":"AUSN2","pearson_symbol":"oP24","prototype":"AuSn2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + τ -> AuSn4 + AuSn2","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":563.33,"temperature_printed":"563.33","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":563.33},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-FXYUH3O3CN","locator":{"ref":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3","row":8},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.6983,"NI":6.1e-05},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni3Sn2"},{"label":"AuSn","model_phase":"AUSN_B81","pearson_symbol":"hP4","prototype":"NiAs","structure_basis":"mapped_model_phase"},{"label":"Hcp","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni3Sn2 -> AuSn + Hcp","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":561.05,"temperature_printed":"561.05","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":561.05},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-Z2KJI5VWVT","locator":{"ref":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3","row":9},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.0095,"NI":0.0008},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni3Sn4","model_phase":"NI3SN4","pearson_symbol":"mC14","prototype":"Ni3Sn4","structure_basis":"mapped_model_phase"},{"label":"AuSn4","model_phase":"AUSN4_D1C","pearson_symbol":"oC20","prototype":"PtSn4","structure_basis":"mapped_model_phase"},{"label":"Bct"}],"pid":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3/r09#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni3Sn4 -> AuSn4 + Bct","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":489.9,"temperature_printed":"489.9","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":489.9},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-YMUO4FSVQY","locator":{"ref":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3","row":10},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.7867,"NI":0.0176},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni3Sn2"},{"label":"Fcc","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Hcp","model_phase":"HCP_A3","pearson_symbol":"hP2","prototype":"Mg","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni3Sn2 + Fcc -> Hcp","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":835.91,"temperature_printed":"835.91","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":835.91},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-55CWEBSTF2","locator":{"ref":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3","row":11},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.2379,"NI":0.0027},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ni3Sn4","model_phase":"NI3SN4","pearson_symbol":"mC14","prototype":"Ni3Sn4","structure_basis":"mapped_model_phase"},{"label":"Ni3Sn2"},{"label":"τ"}],"pid":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3/r11#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ni3Sn4 + Ni3Sn2 -> τ","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":693.39,"temperature_printed":"693.39","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":693.39},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-JNTJWCBGR6","locator":{"ref":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3","row":12},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1016/j.calphad.2013.10.001","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2013.10.001","paper_id":"doi:10.1016/j.calphad.2013.10.001","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"AU":0.1255,"NI":0.001},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"τ"},{"label":"Ni3Sn4","model_phase":"NI3SN4","pearson_symbol":"mC14","prototype":"Ni3Sn4","structure_basis":"mapped_model_phase"},{"label":"AuSn4","model_phase":"AUSN4_D1C","pearson_symbol":"oC20","prototype":"PtSn4","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2013.10.001/p10/tab-3/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + τ + Ni3Sn4 -> AuSn4","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":572.82,"temperature_printed":"572.82","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"P","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":572.82},{"chemical_system":"AU-NI-SN","citations_printed":["19"],"cited_sources":[{"doi":"10.1016/0022-4596(95)80021-g","first_author":"Neumann","kind":"unknown","label":"19","paper":"doi:10.1016/0022-4596(95)80021-g","reference":"A. Neumann, A. Kjekshus, C. Romming, and E. Rost, J. Solid State Chem. 119, 142 (1995).","status":"resolved","year":"1995"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-HNPJPW4PR6.51a22f","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-005-0082-9/p4/text-03"},"method":"DSC","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","pid":"doi:10.1007/s11664-005-0082-9/p4/text-03/s06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The present DSC results show that this peritectic reaction occurs at 422°C, which is in good agreement with the data reported by Neumann et al.19","quote_page":4,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":695.15,"temperature_printed":"422°C","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"thermal_analysis","entry":"value_types/T_INVARIANT/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":695.15},{"chemical_system":"AU-NI-SN","citations_printed":["19"],"cited_sources":[{"doi":"10.1016/0022-4596(95)80021-g","first_author":"Neumann","kind":"unknown","label":"19","paper":"doi:10.1016/0022-4596(95)80021-g","reference":"A. Neumann, A. Kjekshus, C. Romming, and E. Rost, J. Solid State Chem. 119, 142 (1995).","status":"resolved","year":"1995"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_rule_count_mismatch"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"phase_rule_count_mismatch","detail":"peritectic with 2 phases in a 3-component system ('L  Sn4Ni3  Sn2Ni3 ↔ Sn4AuNi2')","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-HNPJPW4PR6.d1f64d","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-005-0082-9/p4/text-03"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","phases":[{"label":"L"},{"label":"Sn4Ni3"},{"label":"Sn2Ni3"},{"label":"Sn4AuNi2"}],"pid":"doi:10.1007/s11664-005-0082-9/p4/text-03/s06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Neumann et al. studied the crystal structure of the Sn4AuNi2 compound, and reported that it is stable up to 420°C, at which temperature it undergoes the peritectic reaction (L  Sn4Ni3  Sn2Ni3 ↔ Sn4AuNi2).19","quote_page":4,"reaction":{"printed":"L  Sn4Ni3  Sn2Ni3 ↔ Sn4AuNi2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":693.15,"temperature_printed":"420°C","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":693.15},{"chemical_system":"AU-NI-SN","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-KS3NUWMQVK","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11664-005-0082-9/p7/text-12"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1007/s11664-005-0082-9","own_work_of_paper":true},"paper":"doi:10.1007/s11664-005-0082-9","paper_id":"doi:10.1007/s11664-005-0082-9","pid":"doi:10.1007/s11664-005-0082-9/p7/text-12/s05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Figure 6d shows the calculated vertical section including the Sn4AuNi2 ternary compound. It is seen that the ternary compound is stable until 422°C, at which a peritectic reaction occurs.","quote_page":7,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AU-NI-SN","system":"AU-NI-SN","temperature_K":695.15,"temperature_printed":"422","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":695.15}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"AU-NI-SN"}