{"artifacts":{"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1":{"artifact":"table","caption":"Invariant reactions in the Au–Sb–Si ternary system.","label":"1","page":2},"doi:10.1016/j.jallcom.2010.11.199/p3/text-17":{"artifact":"text_passage","label":"page 3, passage 17","page":3}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["AU","SB","SI"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1002/zaac.19060500116":{"authors":["Rudolf Vogel"],"citation":"Rudolf Vogel, Metallographische Mitteilungen aus dem Institut für anorganische Chemie der Universität Göttingen. XXXIII. Über die Legierungen des Goldes mit Wismut und Antimon, Z. Anorg. Chem. 50, 145-157 (1906).","container":"Z. Anorg. Chem.","doi":"10.1002/zaac.19060500116","doi_url":"https://doi.org/10.1002/zaac.19060500116","id":"doi:10.1002/zaac.19060500116","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Metallographische Mitteilungen aus dem Institut für anorganische Chemie der Universität Göttingen. XXXIII. Über die Legierungen des Goldes mit Wismut und Antimon","year":1906},"doi:10.1002/zaac.19322090312":{"authors":["A. T. Grigorjew"],"citation":"A. T. Grigorjew, Über die Legierungen des Goldes mit Antimon, Z. Anorg. Allg. Chem. 209, 289-294 (1932).","container":"Z. Anorg. Allg. Chem.","doi":"10.1002/zaac.19322090312","doi_url":"https://doi.org/10.1002/zaac.19322090312","id":"doi:10.1002/zaac.19322090312","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Über die Legierungen des Goldes mit Antimon","year":1932},"doi:10.1007/bf02667876":{"citation":"Redetermination of the eutectic point in the Au-Sb-Si system, JPE 14, 659-660 (1993).","container":"JPE","doi":"10.1007/bf02667876","doi_url":"https://doi.org/10.1007/bf02667876","id":"doi:10.1007/bf02667876","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Redetermination of the eutectic point in the Au-Sb-Si system","year":1993},"doi:10.1007/bf02868954":{"citation":"H. Okamoto, T.B. Massalski, Bull. Alloy Phase Diagrams 5 (1984) 166.","doi":"10.1007/bf02868954","doi_url":"https://doi.org/10.1007/bf02868954","id":"doi:10.1007/bf02868954","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"]},"doi:10.1007/s11664-002-0125-4":{"authors":["Jong Hoon Kim","Sang Won Jeong","Hyuck Mo Lee"],"citation":"Jong Hoon Kim, Sang Won Jeong, Hyuck Mo Lee, A thermodynamic study of phase equilibria in the Au-Sb-Sn solder system, Journal of Elec Materi 31, 557-563 (2002).","container":"Journal of Elec Materi","doi":"10.1007/s11664-002-0125-4","doi_url":"https://doi.org/10.1007/s11664-002-0125-4","id":"doi:10.1007/s11664-002-0125-4","kind":"corpus_paper","metadata_source":"crossref","roles":["cited_source","reporting_paper"],"source_kinds":["cited_work","journal_article"],"title":"A thermodynamic study of phase equilibria in the Au-Sb-Sn solder system","year":2002},"doi:10.1007/s11664-003-0240-x":{"authors":["H. S. Liu","C. L. Liu","C. Wang","Z. P. Jin","K. Ishida"],"citation":"H. S. Liu, C. L. Liu, C. Wang, Z. P. Jin, K. Ishida, Thermodynamic modeling of the Au-In-Sb ternary system, Journal of Elec Materi 32, 81-88 (2003).","container":"Journal of Elec Materi","doi":"10.1007/s11664-003-0240-x","doi_url":"https://doi.org/10.1007/s11664-003-0240-x","id":"doi:10.1007/s11664-003-0240-x","kind":"corpus_paper","metadata_source":"crossref","roles":["cited_source","reporting_paper"],"source_kinds":["cited_work","journal_article"],"title":"Thermodynamic modeling of the Au-In-Sb ternary system","year":2003},"doi:10.1016/0040-6031(81)80143-8":{"authors":["Peter C. Wallbrecht","Roger Blachnik","Kennth C. Mills"],"citation":"Peter C. Wallbrecht, Roger Blachnik, Kennth C. Mills, The heat capacity and enthalpy of some Hume—Rothery phases formed by copper, silver and gold. Part I. Cu + Sb, Ag + Sb, Au + Sb, Au + Bi systems, Thermochimica Acta 45, 189-198 (1981).","container":"Thermochimica Acta","doi":"10.1016/0040-6031(81)80143-8","doi_url":"https://doi.org/10.1016/0040-6031(81)80143-8","id":"doi:10.1016/0040-6031(81)80143-8","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The heat capacity and enthalpy of some Hume—Rothery phases formed by copper, silver and gold. Part I. Cu + Sb, Ag + Sb, Au + Sb, Au + Bi systems","year":1981},"doi:10.1016/0040-6031(89)87147-3":{"authors":["Pierre-Yves Chevalier"],"citation":"Pierre-Yves Chevalier, A thermodynamic evaluation of the Au-Sb and Au-Tl systems, Thermochimica Acta 155, 211-225 (1989).","container":"Thermochimica Acta","doi":"10.1016/0040-6031(89)87147-3","doi_url":"https://doi.org/10.1016/0040-6031(89)87147-3","id":"doi:10.1016/0040-6031(89)87147-3","kind":"corpus_paper","metadata_source":"crossref","roles":["cited_source","reporting_paper"],"source_kinds":["cited_work","journal_article"],"title":"A thermodynamic evaluation of the Au-Sb and Au-Tl systems","year":1989},"doi:10.1016/j.jallcom.2006.04.018":{"authors":["E. Zoro","C. Servant","B. Legendre"],"citation":"E. Zoro, C. Servant, B. Legendre, Experimental study of the phase diagram of the Ag–Au–Sb ternary system, Journal of Alloys and Compounds 426, 193-199 (2006).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2006.04.018","doi_url":"https://doi.org/10.1016/j.jallcom.2006.04.018","id":"doi:10.1016/j.jallcom.2006.04.018","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Experimental study of the phase diagram of the Ag–Au–Sb ternary system","year":2006},"doi:10.1016/j.jallcom.2006.05.066":{"authors":["F.G. Meng","H.S. Liu","L.B. Liu","Z.P. Jin"],"citation":"F.G. Meng, H.S. Liu, L.B. Liu, Z.P. Jin, Thermodynamic description of the Au–Si–Sn system, Journal of Alloys and Compounds 431, 292-297 (2007).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2006.05.066","doi_url":"https://doi.org/10.1016/j.jallcom.2006.05.066","id":"doi:10.1016/j.jallcom.2006.05.066","kind":"corpus_paper","metadata_source":"crossref","roles":["cited_source","reporting_paper"],"source_kinds":["cited_work","journal_article"],"title":"Thermodynamic description of the Au–Si–Sn system","year":2007},"doi:10.1016/j.jallcom.2010.11.199":{"authors":["J. Wang","Y.J. Liu","L.B. Liu","H.Y. Zhou","Z.P. Jin"],"citation":"J. Wang, Y.J. Liu, L.B. Liu, H.Y. Zhou, Z.P. Jin, Thermodynamic modeling of the Au–Sb–Si ternary system, Journal of Alloys and Compounds 509, 3057-3064 (2011).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2010.11.199","doi_url":"https://doi.org/10.1016/j.jallcom.2010.11.199","id":"doi:10.1016/j.jallcom.2010.11.199","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"2b684eb0a6901355","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic modeling of the Au–Sb–Si ternary system","year":2011}},"part":1,"parts":1,"records":[{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1016/j.jallcom.2006.05.066","first_author":"Meng","kind":"assessment","label":"25","paper":"doi:10.1016/j.jallcom.2006.05.066","reference":"F.G. Meng, H.S. Liu, L.B. Liu, Z.P. Jin, J. Alloys Compd. 431 (2007) 292.","status":"resolved","year":"2007"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-4KHWHDNT42","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":5},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_modelling","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.05.066","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SI":0.207},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Au)"},{"label":"(Si)"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L <-> (Au) + (Si)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":637.0,"temperature_printed":"637","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"e","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":637.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1002/zaac.19060500116","first_author":"Vogel","kind":"unknown","label":"35","paper":"doi:10.1002/zaac.19060500116","reference":"R. Vogel, Z. Anorg. Chem. 50 (1906) 145.","status":"resolved","year":"1906"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-SMJNBJH4OG","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":6},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.66},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Sb)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + (Sb) <-> AuSb2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":723.0,"temperature_max_K":733.0,"temperature_printed":"723–733","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":723.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1002/zaac.19322090312","first_author":"Grigorjew","kind":"unknown","label":"36","paper":"doi:10.1002/zaac.19322090312","reference":"A.T. Grigorjew, Z. Anorg. Chem. 209 (1932) 289.","status":"resolved","year":"1932"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-Y344ODKFPC","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":7},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.66},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Sb)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + (Sb) <-> AuSb2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":725.0,"temperature_max_K":736.0,"temperature_printed":"725–736","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":725.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"first_author":"Evans","kind":"assessment","label":"37","reference":"D.S. Evans, A. Prince, CALPHAD XIII, Villard de Lans, France, 1984.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-REVOOGS5TD","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":8},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Sb)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + (Sb) <-> AuSb2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":733.0,"temperature_printed":"733","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":733.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"first_author":"Gaither","kind":"unknown","label":"38","reference":"B. Gaither, R. Blachnik, Z. Metallkd. 67 (1976) 395.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-65PW5VUQ3U","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":9},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Sb)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r09#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + (Sb) <-> AuSb2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":733.0,"temperature_printed":"733","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":733.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1016/0040-6031(81)80143-8","first_author":"Wallbrecht","kind":"unknown","label":"39","paper":"doi:10.1016/0040-6031(81)80143-8","reference":"P.C. Wallbrecht, R. Blachnik, K.C. Mills, Thermochim. Acta 45 (1981) 189.","status":"resolved","year":"1981"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-MAGF5RQUWN","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":10},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Sb)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + (Sb) <-> AuSb2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":740.0,"temperature_printed":"740","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":740.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1016/j.jallcom.2006.04.018","first_author":"Zoro","kind":"unknown","label":"40","paper":"doi:10.1016/j.jallcom.2006.04.018","reference":"E. Zoro, C. Servant, B. Legendre, J. Alloys Compd. 426 (2006) 193.","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-J4DBI2CEPP","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":11},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.67},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Sb)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r11#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + (Sb) <-> AuSb2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":732.0,"temperature_printed":"732","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":732.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1007/bf02868954","first_author":"Okamoto","kind":"assessment","label":"30","paper":"doi:10.1007/bf02868954","reference":"H. Okamoto, T.B. Massalski, Bull. Alloy Phase Diagrams 5 (1984) 166.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-W3C4WH2NY7","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":12},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.666},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Sb)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + (Sb) <-> AuSb2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":733.0,"temperature_printed":"733","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":733.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1016/0040-6031(89)87147-3","first_author":"Chevalier","kind":"assessment","label":"31","paper":"doi:10.1016/0040-6031(89)87147-3","reference":"P.Y. Chevalier, Thermochim. Acta 155 (1989) 211.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-O4EJFQ4F3A","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":13},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1016/0040-6031(89)87147-3","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.663},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Sb)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r13#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + (Sb) <-> AuSb2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":734.0,"temperature_printed":"734","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":734.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1007/s11664-002-0125-4","first_author":"Kim","kind":"unknown","label":"32","paper":"doi:10.1007/s11664-002-0125-4","reference":"J.H. Kim, S.W. Jeong, H.M. Lee, J. Electron. Mater. 31 (2002) 557.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-HFQGQWTC2Q","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":14},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-002-0125-4","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.655},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Sb)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r14#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + (Sb) <-> AuSb2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":733.0,"temperature_printed":"733","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":733.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1007/s11664-003-0240-x","first_author":"Liu","kind":"assessment","label":"20","paper":"doi:10.1007/s11664-003-0240-x","reference":"H.S. Liu, C.L. Liu, C. Wang, Z.P. Jin, K. Ishida, J. Electron. Mater. 32 (2003) 81.","status":"resolved","year":"2003"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-K2QAQXKEBY","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":15},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-003-0240-x","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.655},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Sb)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r15#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + (Sb) <-> AuSb2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":740.0,"temperature_printed":"740","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":740.0},{"chemical_system":"AU-SB-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-IMT36QEC7M","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":16},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2010.11.199","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.653},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Sb)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r16#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + (Sb) <-> AuSb2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":732.0,"temperature_printed":"732","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"p","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":732.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1002/zaac.19060500116","first_author":"Vogel","kind":"unknown","label":"35","paper":"doi:10.1002/zaac.19060500116","reference":"R. Vogel, Z. Anorg. Chem. 50 (1906) 145.","status":"resolved","year":"1906"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-UW2JY2Q2RA","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":17},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Au)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r17#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L <-> (Au) + AuSb2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":630.0,"temperature_max_K":634.0,"temperature_printed":"630–634","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"e","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":630.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1002/zaac.19322090312","first_author":"Grigorjew","kind":"unknown","label":"36","paper":"doi:10.1002/zaac.19322090312","reference":"A.T. Grigorjew, Z. Anorg. Chem. 209 (1932) 289.","status":"resolved","year":"1932"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-KZQZ6HED6T","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":18},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Au)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r18#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L <-> (Au) + AuSb2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":624.0,"temperature_max_K":631.0,"temperature_printed":"624–631","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"e","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":624.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"first_author":"Gaither","kind":"unknown","label":"38","reference":"B. Gaither, R. Blachnik, Z. Metallkd. 67 (1976) 395.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-7BULRFP7BL","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":19},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Au)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r19#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L <-> (Au) + AuSb2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":633.0,"temperature_printed":"633","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"e","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":633.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1016/0040-6031(81)80143-8","first_author":"Wallbrecht","kind":"unknown","label":"39","paper":"doi:10.1016/0040-6031(81)80143-8","reference":"P.C. Wallbrecht, R. Blachnik, K.C. Mills, Thermochim. Acta 45 (1981) 189.","status":"resolved","year":"1981"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-U6WCYG3XF5","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":20},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Au)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r20#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L <-> (Au) + AuSb2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":634.0,"temperature_printed":"634","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"e","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":634.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"first_author":"Hayer","kind":"unknown","label":"41","reference":"E. Hayer, R. Castanet, Z. Metallkd. 86 (1995) 8.","status":"resolved","year":"1995"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-ULZWJU4UB7","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":21},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Au)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r21#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L <-> (Au) + AuSb2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":630.0,"temperature_printed":"630","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"e","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":630.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1016/j.jallcom.2006.04.018","first_author":"Zoro","kind":"unknown","label":"40","paper":"doi:10.1016/j.jallcom.2006.04.018","reference":"E. Zoro, C. Servant, B. Legendre, J. Alloys Compd. 426 (2006) 193.","status":"resolved","year":"2006"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-3VVFWDCLAU","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":22},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.36},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Au)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r22#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L <-> (Au) + AuSb2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":631.0,"temperature_printed":"631","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"e","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":631.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1007/bf02868954","first_author":"Okamoto","kind":"assessment","label":"30","paper":"doi:10.1007/bf02868954","reference":"H. Okamoto, T.B. Massalski, Bull. Alloy Phase Diagrams 5 (1984) 166.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-S6MTFYAT5C","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":23},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.355},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Au)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r23#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L <-> (Au) + AuSb2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":633.0,"temperature_printed":"633","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"e","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":633.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1016/0040-6031(89)87147-3","first_author":"Chevalier","kind":"assessment","label":"31","paper":"doi:10.1016/0040-6031(89)87147-3","reference":"P.Y. Chevalier, Thermochim. Acta 155 (1989) 211.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-BHIFFD5FN5","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":24},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1016/0040-6031(89)87147-3","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.349},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Au)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r24#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L <-> (Au) + AuSb2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":630.0,"temperature_printed":"630","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"e","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":630.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1007/s11664-002-0125-4","first_author":"Kim","kind":"unknown","label":"32","paper":"doi:10.1007/s11664-002-0125-4","reference":"J.H. Kim, S.W. Jeong, H.M. Lee, J. Electron. Mater. 31 (2002) 557.","status":"resolved","year":"2002"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-BPHKMQPHMA","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":25},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-002-0125-4","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.362},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Au)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r25#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L <-> (Au) + AuSb2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":633.0,"temperature_printed":"633","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"e","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":633.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1007/s11664-003-0240-x","first_author":"Liu","kind":"assessment","label":"20","paper":"doi:10.1007/s11664-003-0240-x","reference":"H.S. Liu, C.L. Liu, C. Wang, Z.P. Jin, K. Ishida, J. Electron. Mater. 32 (2003) 81.","status":"resolved","year":"2003"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-R6TQJHDMT4","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":26},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","measured_in":"doi:10.1007/s11664-003-0240-x","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.366},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Au)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r26#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L <-> (Au) + AuSb2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":626.0,"temperature_printed":"626","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"e","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":626.0},{"chemical_system":"AU-SB-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-C2Z4MCR3CT","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":27},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2010.11.199","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.369},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Au)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r27#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L <-> (Au) + AuSb2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":630.0,"temperature_printed":"630","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"e","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":630.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"first_author":"Legendre","kind":"unknown","label":"60","reference":"B. Legendre, C. Hancheng, Bull. Soc. Chim. France 2 (1986) 138.","status":"resolved","year":"1986"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-HPT2ELYFTR","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":28},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Sb)"},{"label":"(Si)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r28#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + (Sb) <-> (Si) + AuSb2","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":730.0,"temperature_printed":"730","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":730.0},{"chemical_system":"AU-SB-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-JMWSSBOZM4","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":29},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2010.11.199","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.649,"SI":0.002},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Sb)"},{"label":"(Si)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r29#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + (Sb) <-> (Si) + AuSb2","type":"quasi-peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":732.0,"temperature_printed":"732","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"quasi-peritectic","transition_kind_printed":"U","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":732.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"first_author":"Legendre","kind":"unknown","label":"60","reference":"B. Legendre, C. Hancheng, Bull. Soc. Chim. France 2 (1986) 138.","status":"resolved","year":"1986"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-TPGWDW3C52","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":30},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.2,"SI":0.1},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Au)"},{"label":"(Si)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r30#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L <-> (Au) + (Si) + AuSb2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":605.0,"temperature_printed":"605","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":605.0},{"chemical_system":"AU-SB-SI","cited_sources":[{"doi":"10.1007/bf02667876","first_author":"Humpston","kind":"unknown","label":"62","paper":"doi:10.1007/bf02667876","reference":"G. Humpston, S.P.S. Sangha, J. Phase Equilibira 14 (1993) 659.","status":"resolved","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-SHXT7YJ3VX","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":31},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.125,"SI":0.135},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Au)"},{"label":"(Si)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r31#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L <-> (Au) + (Si) + AuSb2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":604.0,"temperature_printed":"604","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":604.0},{"chemical_system":"AU-SB-SI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-WYP5X44GYB","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1","row":32},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2010.11.199","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phase_compositions":[{"basis":"mole_fraction","composition":{"SB":0.133,"SI":0.135},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"(Au)"},{"label":"(Si)"},{"label":"AuSb2","model_phase":"AUSB2_C2","pearson_symbol":"cP12","prototype":"beta-FeS2","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p2/tab-1/r32#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L <-> (Au) + (Si) + AuSb2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":608.0,"temperature_printed":"608","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"E","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":608.0},{"chemical_system":"AU-SB-SI","citations_printed":["60"],"cited_sources":[{"first_author":"Legendre","kind":"unknown","label":"60","reference":"B. Legendre, C. Hancheng, Bull. Soc. Chim. France 2 (1986) 138.","status":"resolved","year":"1986"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":3,"id":"ORC-5I6H7J7TME","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2010.11.199/p3/text-17"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2010.11.199","paper_id":"doi:10.1016/j.jallcom.2010.11.199","phases":[{"label":"L"},{"label":"rhombohedral A7(Sb)"},{"label":"diamond A4(Si)"},{"label":"AuSb2"}],"pid":"doi:10.1016/j.jallcom.2010.11.199/p3/text-17/s12#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Experimental results obtained by Legendre and Hancheng [60] show that the Au-Sb-Si ternary system contains two invariant reactions: a transition reaction (U) at 730 K, L + rhombohedral A7(Sb) ↔ diamond A4(Si) + AuSb2 and a eutectic reaction (E) at 605 K, L ↔ fcc A1(Au) + diamond A4(Si) + AuSb2 .","quote_page":3,"reaction":{"printed":"L + rhombohedral A7(Sb) ↔ diamond A4(Si) + AuSb2","type":"other"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AU-SB-SI","system":"AU-SB-SI","temperature_K":730.0,"temperature_printed":"730 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"other","transition_kind_printed":"other","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":730.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"AU-SB-SI"}