{"artifacts":{"doi:10.1016/0040-6031(89)87056-x/p6/text-09":{"artifact":"text_passage","label":"page 6, passage 9","page":6},"doi:10.1016/j.jallcom.2006.05.066/p1/text-06":{"artifact":"text_passage","label":"page 1, passage 6","page":1},"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1":{"artifact":"table","caption":"Au–Si eutectic point","label":"1","page":2},"doi:10.1016/j.jallcom.2006.05.066/p2/text-18":{"artifact":"text_passage","label":"page 2, passage 18","page":2}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["AU","SI"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/bf02666229":{"authors":["R. P. Anantatmula","A. A. Johnson","S. P. Gupta","R. J. Horylev"],"citation":"R. P. Anantatmula, A. A. Johnson, S. P. Gupta, R. J. Horylev, The gold-silicon phase diagram, J. Electron. Mater. 4, 445-463 (1975).","container":"J. Electron. Mater.","doi":"10.1007/bf02666229","doi_url":"https://doi.org/10.1007/bf02666229","id":"doi:10.1007/bf02666229","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The gold-silicon phase diagram","year":1975},"doi:10.1007/bf02884878":{"citation":"H. Okamoto and T.B. Massalski, Bull. Alloy Phase Diagrams, 4 (2) (1983) 190-198.","doi":"10.1007/bf02884878","doi_url":"https://doi.org/10.1007/bf02884878","id":"doi:10.1007/bf02884878","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"]},"doi:10.1016/0022-5088(75)90138-1":{"authors":["Bruno Predel","Hanspeter Bankstahl"],"citation":"Bruno Predel, Hanspeter Bankstahl, Beitrag zur kenntnis der thermodynamischen eigenschaften flüssiger silber-germanium-, silber-silizium-, gold-germanium- und gold-silizium-legierungen, Journal of the Less Common Metals 43, 191-203 (1975).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(75)90138-1","doi_url":"https://doi.org/10.1016/0022-5088(75)90138-1","id":"doi:10.1016/0022-5088(75)90138-1","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Beitrag zur kenntnis der thermodynamischen eigenschaften flüssiger silber-germanium-, silber-silizium-, gold-germanium- und gold-silizium-legierungen","year":1975},"doi:10.1016/0038-1101(67)90140-2":{"authors":["W. Gerlach","B. Goel"],"citation":"W. Gerlach, B. Goel, Gold silicon phase diagram, Solid-State Electronics 10, 589-592 (1967).","container":"Solid-State Electronics","doi":"10.1016/0038-1101(67)90140-2","doi_url":"https://doi.org/10.1016/0038-1101(67)90140-2","id":"doi:10.1016/0038-1101(67)90140-2","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Gold silicon phase diagram","year":1967},"doi:10.1016/0040-6031(89)87056-x":{"authors":["P.-Y. Chevalier"],"citation":"P.-Y. Chevalier, A thermodynamic evaluation of the Au-Ge and Au-Si systems, Thermochimica Acta 141, 217-226 (1989).","container":"Thermochimica Acta","doi":"10.1016/0040-6031(89)87056-x","doi_url":"https://doi.org/10.1016/0040-6031(89)87056-x","id":"doi:10.1016/0040-6031(89)87056-x","kind":"cited_work","metadata_source":"crossref","roles":["cited_source","reporting_paper"],"source_kinds":["cited_work"],"title":"A thermodynamic evaluation of the Au-Ge and Au-Si systems","year":1989},"doi:10.1016/j.jallcom.2006.05.066":{"authors":["F.G. Meng","H.S. Liu","L.B. Liu","Z.P. Jin"],"citation":"F.G. Meng, H.S. Liu, L.B. Liu, Z.P. Jin, Thermodynamic description of the Au–Si–Sn system, Journal of Alloys and Compounds 431, 292-297 (2007).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2006.05.066","doi_url":"https://doi.org/10.1016/j.jallcom.2006.05.066","id":"doi:10.1016/j.jallcom.2006.05.066","kind":"corpus_paper","metadata_source":"crossref","roles":["cited_source","reporting_paper"],"source_kinds":["cited_work","journal_article"],"title":"Thermodynamic description of the Au–Si–Sn system","year":2007},"doi:10.1063/1.1710186":{"authors":["H. S. Chen","D. Turnbull"],"citation":"H. S. Chen, D. Turnbull, Thermal Properties of Gold-Silicon Binary Alloy near the Eutectic Composition, Journal of Applied Physics 38, 3646-3650 (1967).","container":"Journal of Applied Physics","doi":"10.1063/1.1710186","doi_url":"https://doi.org/10.1063/1.1710186","id":"doi:10.1063/1.1710186","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Thermal Properties of Gold-Silicon Binary Alloy near the Eutectic Composition","year":1967},"doi:10.1080/00207216108961472":{"authors":["E.G. HEATH"],"citation":"E.G. HEATH, The Composition of the Gold-Silicon Eutectic †, Journal of Electronics and Control 11, 13-15 (1961).","container":"Journal of Electronics and Control","doi":"10.1080/00207216108961472","doi_url":"https://doi.org/10.1080/00207216108961472","id":"doi:10.1080/00207216108961472","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The Composition of the Gold-Silicon Eutectic †","year":1961},"ref:4221303d1bb00e01":{"citation":"C. Dicapua, Rend. Accad. Nazl. Lincei. 29 (1920) 111.","id":"ref:4221303d1bb00e01","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1920},"ref:49d5c6592e5f8c14":{"citation":"B. Legendre, C. Souleau, C. Hancheng, N. Rodier, J. Chem. Res. (S) 5 (1978) 168.","id":"ref:49d5c6592e5f8c14","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1978},"ref:7c98d6628338921c":{"citation":"R. Castanet, C. Bergman, Ann. Chim. Fr. 4 (1979) 419.","id":"ref:7c98d6628338921c","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1979},"ref:abc77ea121b81025":{"citation":"W. Loskiewicz, J. Inst. Met. 47 (1931) 516.","id":"ref:abc77ea121b81025","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1931}},"part":1,"parts":1,"records":[{"chemical_system":"AU-SI","cited_sources":[{"doi":"10.1007/bf02666229","first_author":"Anantatmula","kind":"experimental","label":"11","paper":"doi:10.1007/bf02666229","reference":"R.P. Anantatmula, A.A. Johnson, S.P. Gupta, R.J. Horylev, J. Electron. Mater. 4 (1975) 445.","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":4,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-K3AJP46EI2","locator":{"ref":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1","row":7},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1007/bf02666229","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.05.066","paper_id":"doi:10.1016/j.jallcom.2006.05.066","pid":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1/r-unplaced-1d6fd36c#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"AU-SI","system":"AU-SI","temperature_K":636,"temperature_printed":"636","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":636},{"chemical_system":"AU-SI","cited_sources":[{"first_author":"Castanet","kind":"experimental","label":"18","reference":"R. Castanet, C. Bergman, Ann. Chim. Fr. 4 (1979) 419.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":4,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-7EVXOD4JYA","locator":{"ref":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1","row":10},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:7c98d6628338921c","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.05.066","paper_id":"doi:10.1016/j.jallcom.2006.05.066","pid":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1/r-unplaced-237671cd#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"AU-SI","system":"AU-SI","temperature_K":621,"temperature_max_K":630,"temperature_printed":"621–630","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":621},{"chemical_system":"AU-SI","cited_sources":[{"doi":"10.1063/1.1710186","first_author":"Chen","kind":"experimental","label":"15","paper":"doi:10.1063/1.1710186","reference":"H.S. Chen, D. Turnbyll, J. Appl. Phys. 38 (1967) 3646.","status":"resolved","year":"1967"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":4,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-Y2YJRT4LAW","locator":{"ref":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1","row":4},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1063/1.1710186","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.05.066","paper_id":"doi:10.1016/j.jallcom.2006.05.066","pid":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1/r-unplaced-32a69ee6#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"AU-SI","system":"AU-SI","temperature_K":636,"temperature_printed":"636","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":636},{"chemical_system":"AU-SI","cited_sources":[{"doi":"10.1080/00207216108961472","first_author":"Heath","kind":"experimental","label":"14","paper":"doi:10.1080/00207216108961472","reference":"E.G. Heath, J. Electron. Control. 11 (1961) 13.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":4,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-GB55IDQTYK","locator":{"ref":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1","row":3},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1080/00207216108961472","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.05.066","paper_id":"doi:10.1016/j.jallcom.2006.05.066","pid":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1/r-unplaced-674ac7b8#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"AU-SI","system":"AU-SI","temperature_K":642,"temperature_printed":"642","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":642},{"chemical_system":"AU-SI","cited_sources":[{"first_author":"Dicapua","kind":"experimental","label":"12","reference":"C. Dicapua, Rend. Accad. Nazl. Lincei. 29 (1920) 111.","status":"resolved","year":"1920"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":4,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-CLOLHE2LYQ","locator":{"ref":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1","row":1},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:4221303d1bb00e01","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.05.066","paper_id":"doi:10.1016/j.jallcom.2006.05.066","pid":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1/r-unplaced-ada50296#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"AU-SI","system":"AU-SI","temperature_K":643,"temperature_printed":"643","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":643},{"chemical_system":"AU-SI","cited_sources":[{"first_author":"Loskiewicz","kind":"experimental","label":"13","reference":"W. Loskiewicz, J. Inst. Met. 47 (1931) 516.","status":"resolved","year":"1931"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":4,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-FAHESXWH4L","locator":{"ref":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1","row":2},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:abc77ea121b81025","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.05.066","paper_id":"doi:10.1016/j.jallcom.2006.05.066","pid":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1/r-unplaced-ba8c4290#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"AU-SI","system":"AU-SI","temperature_K":623,"temperature_printed":"623","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":623},{"chemical_system":"AU-SI","cited_sources":[{"doi":"10.1016/0038-1101(67)90140-2","first_author":"Gerlach","kind":"unknown","label":"8","paper":"doi:10.1016/0038-1101(67)90140-2","reference":"W. Gerlach, B. Goel, Solid-State Electron. 10 (1967) 589.","status":"resolved","year":"1967"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":4,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-FWJOWYIKFA","locator":{"ref":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1","row":5},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0038-1101(67)90140-2","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.05.066","paper_id":"doi:10.1016/j.jallcom.2006.05.066","pid":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1/r-unplaced-bf63dcc9#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"AU-SI","system":"AU-SI","temperature_K":643,"temperature_printed":"643","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":643},{"chemical_system":"AU-SI","cited_sources":[{"doi":"10.1016/0022-5088(75)90138-1","first_author":"Predel","kind":"experimental","label":"9","paper":"doi:10.1016/0022-5088(75)90138-1","reference":"B. Predel, H. Bankstahl, J. Less-Common Met. 43 (1975) 191.","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":4,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-3LXTUM66AK","locator":{"ref":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1","row":8},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(75)90138-1","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.05.066","paper_id":"doi:10.1016/j.jallcom.2006.05.066","pid":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1/r-unplaced-cbdd3792#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"AU-SI","system":"AU-SI","temperature_K":618,"temperature_printed":"618","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":618},{"chemical_system":"AU-SI","cited_sources":[{"first_author":"Legendre","kind":"experimental","label":"17","reference":"B. Legendre, C. Souleau, C. Hancheng, N. Rodier, J. Chem. Res. (S) 5 (1978) 168.","status":"resolved","year":"1978"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","row_state":"settled","state_fully_specified":false},"fold_lpo":4,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (no phases extracted)","effect":"not_accepted","gate":"R3"}],"id":"ORC-DE6JLBRBMC","locator":{"ref":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1","row":9},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:49d5c6592e5f8c14","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.05.066","paper_id":"doi:10.1016/j.jallcom.2006.05.066","pid":"doi:10.1016/j.jallcom.2006.05.066/p2/tab-1/r-unplaced-d76850aa#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"AU-SI","system":"AU-SI","temperature_K":637,"temperature_printed":"637","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":637},{"chemical_system":"AU-SI","citations_printed":["21"],"cited_sources":[{"first_author":"Heath","kind":"unknown","label":"21","reference":"E.G. Heath, J. Electron. Control., 11 (1961) 13-15.","status":"resolved","year":"1961"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:10)","effect":"not_accepted","gate":"R3"}],"id":"ORC-3O7XNRY44M.06657b","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/0040-6031(89)87056-x/p6/text-09"},"merged_ids":["ORC-3O7XNRY44M.e873f5"],"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/0040-6031(89)87056-x","paper_id":"doi:10.1016/0040-6031(89)87056-x","pid":"doi:10.1016/0040-6031(89)87056-x/p6/text-09/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The eutectic point has been located at x&k-'= 0.17, T = 643 K [22], xi;) = O.l86,T= 643 K [21], x&k'= 0.195, T= 618 K [23], xi:) = 0.19, T= 636 K [24] and x$-j = 0.186, T = 636 K [20].","quote_page":6,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AU-SI","system":"AU-SI","temperature_K":643.0,"temperature_printed":"643 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":643.0},{"chemical_system":"AU-SI","citations_printed":["20"],"cited_sources":[{"doi":"10.1007/bf02884878","first_author":"Okamoto","kind":"assessment","label":"20","paper":"doi:10.1007/bf02884878","reference":"H. Okamoto and T.B. Massalski, Bull. Alloy Phase Diagrams, 4 (2) (1983) 190-198.","status":"resolved","year":"1983"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:10)","effect":"not_accepted","gate":"R3"}],"id":"ORC-3O7XNRY44M.88ec21","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/0040-6031(89)87056-x/p6/text-09"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/0040-6031(89)87056-x","paper_id":"doi:10.1016/0040-6031(89)87056-x","pid":"doi:10.1016/0040-6031(89)87056-x/p6/text-09/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The eutectic point has been located at x&k-'= 0.17, T = 643 K [22], xi;) = O.l86,T= 643 K [21], x&k'= 0.195, T= 618 K [23], xi:) = 0.19, T= 636 K [24] and x$-j = 0.186, T = 636 K [20].","quote_page":6,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AU-SI","system":"AU-SI","temperature_K":636.0,"temperature_printed":"636 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":636.0},{"chemical_system":"AU-SI","citations_printed":["24"],"cited_sources":[{"doi":"10.1007/bf02666229","first_author":"Anantatmula","kind":"unknown","label":"24","paper":"doi:10.1007/bf02666229","reference":"R.P. Anantatmula, A.A. Johnson, S.P. Gupta and R.J. Horylov, J. Electron. Mater., 4 (3) (1975) 445-463.","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:10)","effect":"not_accepted","gate":"R3"}],"id":"ORC-3O7XNRY44M.91aeab","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/0040-6031(89)87056-x/p6/text-09"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1007/bf02666229","own_work_of_paper":false},"paper":"doi:10.1016/0040-6031(89)87056-x","paper_id":"doi:10.1016/0040-6031(89)87056-x","pid":"doi:10.1016/0040-6031(89)87056-x/p6/text-09/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The eutectic point has been located at x&k-'= 0.17, T = 643 K [22], xi;) = O.l86,T= 643 K [21], x&k'= 0.195, T= 618 K [23], xi:) = 0.19, T= 636 K [24] and x$-j = 0.186, T = 636 K [20].","quote_page":6,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AU-SI","system":"AU-SI","temperature_K":636.0,"temperature_printed":"636 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":636.0},{"chemical_system":"AU-SI","citations_printed":["23"],"cited_sources":[{"doi":"10.1016/0022-5088(75)90138-1","first_author":"Predel","kind":"unknown","label":"23","paper":"doi:10.1016/0022-5088(75)90138-1","reference":"B. Predel and H. Bankstahl, J. Less-Common Met.,43 (1975) 191-203.","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:10)","effect":"not_accepted","gate":"R3"}],"id":"ORC-3O7XNRY44M.9a555e","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/0040-6031(89)87056-x/p6/text-09"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"doi:10.1016/0022-5088(75)90138-1","own_work_of_paper":false},"paper":"doi:10.1016/0040-6031(89)87056-x","paper_id":"doi:10.1016/0040-6031(89)87056-x","pid":"doi:10.1016/0040-6031(89)87056-x/p6/text-09/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The eutectic point has been located at x&k-'= 0.17, T = 643 K [22], xi;) = O.l86,T= 643 K [21], x&k'= 0.195, T= 618 K [23], xi:) = 0.19, T= 636 K [24] and x$-j = 0.186, T = 636 K [20].","quote_page":6,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AU-SI","system":"AU-SI","temperature_K":618.0,"temperature_printed":"618 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":618.0},{"chemical_system":"AU-SI","citations_printed":["19"],"cited_sources":[{"doi":"10.1007/bf02884878","first_author":"Okamoto","kind":"assessment","label":"19","paper":"doi:10.1007/bf02884878","reference":"H. Okamoto, T.B. Massalski, Bull. Alloy Phase Diagrams 4 (1983) 190.","status":"resolved","year":"1983"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-VFYKLGME4X","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2006.05.066/p1/text-06"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.jallcom.2006.05.066","paper_id":"doi:10.1016/j.jallcom.2006.05.066","pid":"doi:10.1016/j.jallcom.2006.05.066/p1/text-06/s11#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Fortunately, Okamoto and Massalski [19] recommend the eutectic temperature of 636 ± 3 K which is accepted in the present optimization.","quote_page":1,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AU-SI","system":"AU-SI","temperature_K":636.0,"temperature_printed":"636 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":636.0},{"chemical_system":"AU-SI","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1016/j.jallcom.2006.05.066"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-SVP6BO56NF.4fd2c2","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2006.05.066/p2/text-18"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2006.05.066","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.05.066","paper_id":"doi:10.1016/j.jallcom.2006.05.066","pid":"doi:10.1016/j.jallcom.2006.05.066/p2/text-18/s05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"For the partial system Au-Si-AuSn, three invariant reactions involving the liquid phase were detected: L + ␤ → (Au) + ␨ at 763 K, L + (Au) → (Si) + ␨ at 629.7 K and L → (Si) + ␨ + AuSn at 546.5 K.","quote_page":2,"reaction":{"printed":"L + (Au) → (Si) + ␨"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AU-SI","system":"AU-SI","temperature_K":629.7,"temperature_printed":"629.7 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":629.7},{"chemical_system":"AU-SI","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1016/j.jallcom.2006.05.066"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-SVP6BO56NF.95b9cf","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2006.05.066/p2/text-18"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2006.05.066","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.05.066","paper_id":"doi:10.1016/j.jallcom.2006.05.066","pid":"doi:10.1016/j.jallcom.2006.05.066/p2/text-18/s05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"For the partial system Au-Si-AuSn, three invariant reactions involving the liquid phase were detected: L + ␤ → (Au) + ␨ at 763 K, L + (Au) → (Si) + ␨ at 629.7 K and L → (Si) + ␨ + AuSn at 546.5 K.","quote_page":2,"reaction":{"printed":"L + ␤ → (Au) + ␨"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AU-SI","system":"AU-SI","temperature_K":763.0,"temperature_printed":"763 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":763.0},{"chemical_system":"AU-SI","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1016/j.jallcom.2006.05.066"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":4,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":4,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-SVP6BO56NF.e10054","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2006.05.066/p2/text-18"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2006.05.066","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.05.066","paper_id":"doi:10.1016/j.jallcom.2006.05.066","pid":"doi:10.1016/j.jallcom.2006.05.066/p2/text-18/s05#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"For the partial system Au-Si-AuSn, three invariant reactions involving the liquid phase were detected: L + ␤ → (Au) + ␨ at 763 K, L + (Au) → (Si) + ␨ at 629.7 K and L → (Si) + ␨ + AuSn at 546.5 K.","quote_page":2,"reaction":{"printed":"L → (Si) + ␨ + AuSn"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"AU-SI","system":"AU-SI","temperature_K":546.5,"temperature_printed":"546.5 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":546.5}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"AU-SI"}