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Ceram.. 152, 728-738 (1975).","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"B-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":{"C":0.0,"TI":0.333333},"phases":["TiB2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"id":"ORC-DAWGQTW734.abf787","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":28},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"TI":0.333333},"overall_composition_basis":"from_formula","overall_composition_stored":{"C":0.0,"TI":0.333333},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiB2"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r28#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"B-TI","temperature_K":2883.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.006644,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.006644},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":3.02,"value_stored":0.302},{"chemical_system":"B-TI","cited_sources":[{"first_author":"Du","kind":"unknown","label":"93Dus","reference":"H. Du schanek, Thesis, Universitat Wien, Austria (1993).","status":"surname_mismatch","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"B-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":{"C":0.0,"TI":0.5},"phases":["TiB"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"TiB"}],"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"phases","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":{"TI":0.5},"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. 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From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition_basis","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Composition of the TiC1-x phase is not printed (only the overall multiphase alloy composition in the comment column). If the builder cannot clear overall_composition/basis to null, apply the phases patch and drop the stale from_formula composition otherwise.","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-GVXG5BT5IE","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":36},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":null,"overall_composition_basis":null,"overall_composition_stored":{"C":0.0,"TI":0.5},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r36#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"B-TI","temperature_K":1823.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009485,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009485},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.3112,"value_stored":0.43112},{"chemical_system":"B-TI","cited_sources":[{"first_author":"Du","kind":"unknown","label":"93Dus","reference":"H. Du schanek, Thesis, Universitat Wien, Austria (1993).","status":"surname_mismatch","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"B-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":{"C":0.0,"TI":0.5},"phases":["TiB"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"TiB"}],"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"phases","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":{"TI":0.5},"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":"from_formula","evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition_basis","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Composition of the TiC1-x phase is not printed (only the overall multiphase alloy composition in the comment column). If the builder cannot clear overall_composition/basis to null, apply the phases patch and drop the stale from_formula composition otherwise.","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-HSD4NTEVKJ","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":37},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":null,"overall_composition_basis":null,"overall_composition_stored":{"C":0.0,"TI":0.5},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r37#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"B-TI","temperature_K":1823.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009497,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009497},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.3166,"value_stored":0.43166},{"chemical_system":"B-TI","cited_sources":[{"first_author":"Du","kind":"unknown","label":"93Dus","reference":"H. Du schanek, Thesis, Universitat Wien, Austria (1993).","status":"surname_mismatch","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"B-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":{"C":0.0,"TI":0.428571},"phases":["Ti3B4"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"Ti3B4"}],"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"phases","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":{"TI":0.428571},"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":"from_formula","evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition_basis","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Composition of the TiC1-x phase is not printed (only the overall multiphase alloy composition in the comment column). If the builder cannot clear overall_composition/basis to null, apply the phases patch and drop the stale from_formula composition otherwise.","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-AXAKQ2GSJE","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":38},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":null,"overall_composition_basis":null,"overall_composition_stored":{"C":0.0,"TI":0.428571},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r38#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"B-TI","temperature_K":1823.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009502,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009502},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.3192,"value_stored":0.43192},{"chemical_system":"B-TI","cited_sources":[{"first_author":"Du","kind":"unknown","label":"93Dus","reference":"H. Du schanek, Thesis, Universitat Wien, Austria (1993).","status":"surname_mismatch","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"B-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":{"C":0.0,"TI":0.428571},"phases":["Ti3B4"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"Ti3B4"}],"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"phases","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":{"TI":0.428571},"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":"from_formula","evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition_basis","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Composition of the TiC1-x phase is not printed (only the overall multiphase alloy composition in the comment column). If the builder cannot clear overall_composition/basis to null, apply the phases patch and drop the stale from_formula composition otherwise.","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-MJISQX4FWC","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":39},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":null,"overall_composition_basis":null,"overall_composition_stored":{"C":0.0,"TI":0.428571},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r39#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"B-TI","temperature_K":1823.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009506,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009506},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.3209,"value_stored":0.43209},{"chemical_system":"B-TI","cited_sources":[{"first_author":"Du","kind":"unknown","label":"93Dus","reference":"H. Du schanek, Thesis, Universitat Wien, Austria (1993).","status":"surname_mismatch","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"B-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":{"C":0.0,"TI":0.428571},"phases":["Ti3B4"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"Ti3B4"}],"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"phases","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":{"TI":0.428571},"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":"from_formula","evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition_basis","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Composition of the TiC1-x phase is not printed (only the overall multiphase alloy composition in the comment column). If the builder cannot clear overall_composition/basis to null, apply the phases patch and drop the stale from_formula composition otherwise.","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-3WT5XY4K7U","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":40},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":null,"overall_composition_basis":null,"overall_composition_stored":{"C":0.0,"TI":0.428571},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r40#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"B-TI","temperature_K":1823.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.00949,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.00949},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.3136,"value_stored":0.43136},{"chemical_system":"B-TI","cited_sources":[{"first_author":"Du","kind":"unknown","label":"93Dus","reference":"H. Du schanek, Thesis, Universitat Wien, Austria (1993).","status":"surname_mismatch","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"B-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":{"C":0.0,"TI":0.428571},"phases":["Ti3B4"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"Ti3B4"}],"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"phases","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":{"TI":0.428571},"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":"from_formula","evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition_basis","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Composition of the TiC1-x phase is not printed (only the overall multiphase alloy composition in the comment column). If the builder cannot clear overall_composition/basis to null, apply the phases patch and drop the stale from_formula composition otherwise.","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-F5AX7BB3DQ","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":41},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":null,"overall_composition_basis":null,"overall_composition_stored":{"C":0.0,"TI":0.428571},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r41#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"B-TI","temperature_K":1823.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009506,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009506},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.3207,"value_stored":0.43207},{"chemical_system":"B-TI","cited_sources":[{"first_author":"Du","kind":"unknown","label":"93Dus","reference":"H. Du schanek, Thesis, Universitat Wien, Austria (1993).","status":"surname_mismatch","year":"1993"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"B-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":{"C":0.0,"TI":0.428571},"phases":["Ti3B4"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"Ti3B4"}],"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"phases","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":{"TI":0.428571},"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":"from_formula","evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition_basis","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Composition of the TiC1-x phase is not printed (only the overall multiphase alloy composition in the comment column). If the builder cannot clear overall_composition/basis to null, apply the phases patch and drop the stale from_formula composition otherwise.","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-FD6HKGTDCK","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":42},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":null,"overall_composition_basis":null,"overall_composition_stored":{"C":0.0,"TI":0.428571},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r42#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"B-TI","temperature_K":1823.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.00951,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.00951},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.3226,"value_stored":0.43226},{"chemical_system":"B-TI","cited_sources":[{"kind":"unknown","label":"66Rud","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"B-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":{"C":0.0,"TI":0.333333},"phases":["TiB2"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"TiB2"}],"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"phases","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":{"TI":0.333333},"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":"from_formula","evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition_basis","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Composition of the TiC1-x phase is not printed (only the overall multiphase alloy composition in the comment column). If the builder cannot clear overall_composition/basis to null, apply the phases patch and drop the stale from_formula composition otherwise.","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-JYCTJWURWH","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":44},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":null,"overall_composition_basis":null,"overall_composition_stored":{"C":0.0,"TI":0.333333},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r44#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"B-TI","temperature_K":2915.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009506,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009506},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.321,"value_stored":0.4321},{"chemical_system":"B-TI","cited_sources":[{"kind":"unknown","label":"66Rud","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"B-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":{"C":0.0,"TI":0.5},"phases":["TiB"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"TiB"}],"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"phases","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":{"TI":0.5},"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":"from_formula","evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition_basis","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Composition of the TiC1-x phase is not printed (only the overall multiphase alloy composition in the comment column). If the builder cannot clear overall_composition/basis to null, apply the phases patch and drop the stale from_formula composition otherwise.","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-RFVHAOWHXU","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":45},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":null,"overall_composition_basis":null,"overall_composition_stored":{"C":0.0,"TI":0.5},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r45#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"B-TI","temperature_K":2791.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009482,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009482},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.31,"value_stored":0.431},{"chemical_system":"B-TI","cited_sources":[{"kind":"unknown","label":"66Rud","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"B-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":{"C":0.0,"TI":0.333333},"phases":["TiB2"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"TiB2"}],"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"phases","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":{"TI":0.333333},"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":"from_formula","evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition_basis","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Composition of the TiC1-x phase is not printed (only the overall multiphase alloy composition in the comment column). If the builder cannot clear overall_composition/basis to null, apply the phases patch and drop the stale from_formula composition otherwise.","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-CZR6MFDMNP","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":46},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":null,"overall_composition_basis":null,"overall_composition_stored":{"C":0.0,"TI":0.333333},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r46#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"B-TI","temperature_K":2903.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0095,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0095},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.318,"value_stored":0.4318},{"chemical_system":"B-TI","cited_sources":[{"kind":"unknown","label":"66Rud","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"B-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":{"C":0.0,"TI":0.333333},"phases":["TiB2"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"TiB2"}],"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"phases","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":{"TI":0.333333},"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":"from_formula","evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition_basis","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Composition of the TiC1-x phase is not printed (only the overall multiphase alloy composition in the comment column). If the builder cannot clear overall_composition/basis to null, apply the phases patch and drop the stale from_formula composition otherwise.","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-YJYLMTOO32","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":47},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":null,"overall_composition_basis":null,"overall_composition_stored":{"C":0.0,"TI":0.333333},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r47#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"B-TI","temperature_K":2934.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009524,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009524},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.329,"value_stored":0.4329},{"chemical_system":"B-TI","cited_sources":[{"kind":"unknown","label":"66Rud","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"B-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":{"C":0.0,"TI":0.333333},"phases":["TiB2"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"TiB2"}],"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"phases","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":{"TI":0.333333},"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":"from_formula","evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition_basis","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Composition of the TiC1-x phase is not printed (only the overall multiphase alloy composition in the comment column). If the builder cannot clear overall_composition/basis to null, apply the phases patch and drop the stale from_formula composition otherwise.","effect":"not_espei_ready","gate":"TD20261028"}],"id":"ORC-PNUPVNTZFW","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":52},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":null,"overall_composition_basis":null,"overall_composition_stored":{"C":0.0,"TI":0.333333},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r52#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"B-TI","temperature_K":2790.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009508,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009508},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.322,"value_stored":0.4322},{"chemical_system":"B-TI","cited_sources":[{"kind":"unknown","label":"66Rud","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"B-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":{"C":0.0,"TI":0.333333},"phases":["TiB2"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"TiB2"}],"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"phases","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":{"TI":0.333333},"evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... 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Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"after":null,"before":"from_formula","evidence":{"class":"phase","decision_file":"phase_t010.json","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Phase: TiC1-x (block head); e.g. '0.43112 ... From alloy Ti49B46C5 annealed at 1550 °C, contained also TiB and Ti3B4 [93Dus]'; '0.4309 ... From alloy Ti63B3C31 quenched from 2373 °C, contained traces (αTi) [66Rud]'","rationale":"The lattice parameter a~0.431-0.433 nm (cubic, a only) is printed under Phase TiC1-x; TiB/Ti3B4/TiB2/αTi are other phases in the same sample. Composition from_formula of the wrong phase is cleared (null) to the sibling convention of the same block (the 17 already-patched TiC1-x rows have no overall_composition key), since TiC1-x has no fixed formula and the printed alloy is multiphase.","report_id":"ORCHID-TD-20261028-v1","table":"3","table_key":"t010"},"field":"overall_composition_basis","gate":"TD20261028","rule":"source_adjudicated_table_defect","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["human_review_residual_concern"],"review_state":"extracted","specification_gaps":["table_defect_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":2,"gate_failures":[{"code":"human_review_residual_concern","detail":"Composition of the TiC1-x phase is not printed (only the overall multiphase alloy composition in the comment column). 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The DTA temperature is hereafter treated as relating to the reaction L + Ti3 B4 ↔ TiB, and the pyrometric temperature seems to be rather overestimated owing to small quantity of liquid and to be close to the next reaction L + TiB2 ↔ Ti3 B4 .","quote_page":5,"reaction":{"printed":"L + Ti3 B4 ↔ TiB"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"B-TI","system":"B-TI","temperature_K":2393.0,"temperature_printed":"2393 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2393.0},{"chemical_system":"B-TI","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":2,"gate_failures":[{"code":"state_phases_missing","detail":"TRANSITION_TEMPERATURE without the phases of its state (not_a_single_phase_transition)","effect":"not_accepted","gate":"R3"}],"id":"ORC-YE6BDSMZXV","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jallcom.2006.10.034/p8/text-07"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/j.jallcom.2006.10.034","own_work_of_paper":true},"paper":"doi:10.1016/j.jallcom.2006.10.034","paper_id":"doi:10.1016/j.jallcom.2006.10.034","pid":"doi:10.1016/j.jallcom.2006.10.034/p8/text-07/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Finally, the calculation of the metastable invariant reaction L + TiB2 ↔ TiB performed using the present description gave the temperature 2400 K and composition of liquid equal to Ti-31.0 at.% B.","quote_page":8,"reaction":{"printed":"L + TiB2 ↔ TiB"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"B-TI","system":"B-TI","temperature_K":2400.0,"temperature_printed":"2400 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2400.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"B-TI"}