{"artifacts":{"sha256:cb38fae1d94c72fa/p2/tab-1":{"artifact":"table","caption":"Crystal structure data on the Ga–X (X ¼ B, Ca, Sr, Ba) systems.","label":"1","page":2},"sha256:cb38fae1d94c72fa/p3/tab-2":{"artifact":"table","caption":"Enthalpies of formation for the compounds in the Ga–X (X ¼Ca, Sr, Ba ) systems according to the first-principles calculations along with available experimental data.","label":"2","page":3}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["BA","GA"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/0925-8388(94)90786-2":{"authors":["M.L. Fornasini","M. Pani"],"citation":"M.L. Fornasini, M. Pani, Ba5Ga6: a phase with octahedral clusters of gallium, Journal of Alloys and Compounds 205, 179-181 (1994).","container":"Journal of Alloys and Compounds","doi":"10.1016/0925-8388(94)90786-2","doi_url":"https://doi.org/10.1016/0925-8388(94)90786-2","id":"doi:10.1016/0925-8388(94)90786-2","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Ba5Ga6: a phase with octahedral clusters of gallium","year":1994},"doi:10.1016/j.calphad.2013.09.002":{"authors":["Xi Li","Kaiming Cheng","Xiaoming Yuan","Dongdong Zhao","Jinghua Xin","Weiwei Wang","Cong Zhang","Yong Du"],"citation":"Xi Li, Kaiming Cheng, Xiaoming Yuan, Dongdong Zhao, Jinghua Xin, Weiwei Wang et al., Thermodynamic assessment of the Ga–X (X=B, Ca, Sr, Ba) systems supported by first-principles calculations, Calphad 43, 52-60 (2013).","container":"Calphad","doi":"10.1016/j.calphad.2013.09.002","doi_url":"https://doi.org/10.1016/j.calphad.2013.09.002","id":"doi:10.1016/j.calphad.2013.09.002","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"cb38fae1d94c72fa","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic assessment of the Ga–X (X=B, Ca, Sr, Ba) systems supported by first-principles calculations","year":2013},"ref:529c7666cdc21a2e":{"citation":"G. Bruzzone, Boll. Sci. Fac. Chim. Ind. Bologna 24 (1966) 113–132.","id":"ref:529c7666cdc21a2e","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1966}},"part":1,"parts":1,"records":[{"chemical_system":"BA-GA","cited_sources":[{"first_author":"Fornasini","kind":"unknown","label":"18","reference":"M.L. Fornasini, F. Merlo, Rev. Chim. Miner. 16 (1979) 458–464.","status":"resolved","year":"1979"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"BA-GA","before":"B-BA-CA-GA-SR","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.909091,"CA":0.0,"GA":0.090909,"SR":0.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"Ba10Ga","label_source":"printed_source_page","pearson_symbol":"cF176","prototype":"VAl10","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"Ba10Ga | VAl10 | cF176 | Fd-3m | 2.0521 [18]","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[20],"table":"1","table_key":"t014"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"single printed row","verdict":"confirmed"}},{"after":{"pearson_symbol":"cF176","phase":"Ba10Ga","prototype":"VAl10","space_group":"Fd-3m"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"Ba10Ga | VAl10 | cF176 | Fd-3m | 2.0521 [18]","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[20],"table":"1","table_key":"t014"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"single printed row","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-XIOCIOP7XP","locator":{"ref":"sha256:cb38fae1d94c72fa/p2/tab-1","row":20},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.909091,"GA":0.090909},"overall_composition_basis":"from_formula","overall_composition_stored":{"BA":0.909091,"CA":0.0,"GA":0.090909,"SR":0.0},"paper":"doi:10.1016/j.calphad.2013.09.002","paper_id":"doi:10.1016/j.calphad.2013.09.002","phases":[{"label":"Ba10Ga","label_source":"printed_source_page","pearson_symbol":"cF176","prototype":"VAl10","structure_basis":"printed_source_page"}],"pid":"sha256:cb38fae1d94c72fa/p2/tab-1/r20#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"B-BA-CA-GA-SR","structure":{"pearson_symbol":"cF176","phase":"Ba10Ga","prototype":"VAl10","space_group":"Fd-3m"},"system":"BA-GA","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04515,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.04515},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":20.521,"value_stored":2.0521},{"chemical_system":"BA-GA","cited_sources":[{"first_author":"Fornasini","kind":"unknown","label":"17","reference":"M. Fornasini, Acta Crystallogr. C39 (1983) 943–946.","status":"resolved","year":"1983"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"BA-GA","before":"B-BA-CA-GA-SR","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.533333,"CA":0.0,"GA":0.466667,"SR":0.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"Ba8Ga7","label_source":"printed_source_page","pearson_symbol":"cP60","prototype":"Ba8Ga7","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"Ba8Ga7 | Ba8Ga7 | cP60 | P213 | 1.2990 [17] / 1.3081 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[21,22],"table":"1","table_key":"t014"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}},{"after":{"pearson_symbol":"cP60","phase":"Ba8Ga7","prototype":"Ba8Ga7","space_group":"P213"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"Ba8Ga7 | Ba8Ga7 | cP60 | P213 | 1.2990 [17] / 1.3081 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[21,22],"table":"1","table_key":"t014"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-AZLWUWVVQM","locator":{"ref":"sha256:cb38fae1d94c72fa/p2/tab-1","row":21},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"BA":0.533333,"GA":0.466667},"overall_composition_basis":"from_formula","overall_composition_stored":{"BA":0.533333,"CA":0.0,"GA":0.466667,"SR":0.0},"paper":"doi:10.1016/j.calphad.2013.09.002","paper_id":"doi:10.1016/j.calphad.2013.09.002","phases":[{"label":"Ba8Ga7","label_source":"printed_source_page","pearson_symbol":"cP60","prototype":"Ba8Ga7","structure_basis":"printed_source_page"}],"pid":"sha256:cb38fae1d94c72fa/p2/tab-1/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"B-BA-CA-GA-SR","structure":{"pearson_symbol":"cP60","phase":"Ba8Ga7","prototype":"Ba8Ga7","space_group":"P213"},"system":"BA-GA","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02858,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02858},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":12.99,"value_stored":1.299},{"chemical_system":"BA-GA","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GA","before":"B-BA-CA-GA-SR","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.533333,"CA":0.0,"GA":0.466667,"SR":0.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"Ba8Ga7","label_source":"printed_source_page","pearson_symbol":"cP60","prototype":"Ba8Ga7","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"Ba8Ga7 | Ba8Ga7 | cP60 | P213 | 1.2990 [17] / 1.3081 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[21,22],"table":"1","table_key":"t014"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}},{"after":{"pearson_symbol":"cP60","phase":"Ba8Ga7","prototype":"Ba8Ga7","space_group":"P213"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"Ba8Ga7 | Ba8Ga7 | cP60 | P213 | 1.2990 [17] / 1.3081 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[21,22],"table":"1","table_key":"t014"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-POEIAHOQRB","locator":{"ref":"sha256:cb38fae1d94c72fa/p2/tab-1","row":22},"method":"First-Principles","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2013.09.002","own_work_of_paper":true},"overall_composition":{"BA":0.533333,"GA":0.466667},"overall_composition_basis":"from_formula","overall_composition_stored":{"BA":0.533333,"CA":0.0,"GA":0.466667,"SR":0.0},"paper":"doi:10.1016/j.calphad.2013.09.002","paper_id":"doi:10.1016/j.calphad.2013.09.002","phases":[{"label":"Ba8Ga7","label_source":"printed_source_page","pearson_symbol":"cP60","prototype":"Ba8Ga7","structure_basis":"printed_source_page"}],"pid":"sha256:cb38fae1d94c72fa/p2/tab-1/r22#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"B-BA-CA-GA-SR","structure":{"pearson_symbol":"cP60","phase":"Ba8Ga7","prototype":"Ba8Ga7","space_group":"P213"},"system":"BA-GA","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1308,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1308},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":13.081,"value_stored":1.3081},{"chemical_system":"BA-GA","cited_sources":[{"first_author":"Bruzzone","kind":"unknown","label":"11","reference":"G. Bruzzone, Boll. Sci. Fac. Chim. Ind. Bologna 24 (1966) 113–132.","status":"resolved","year":"1966"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"BA-GA","before":"B-BA-CA-GA-SR","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.333333,"CA":0.0,"GA":0.666667,"SR":0.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"BaGa2","label_source":"printed_source_page","pearson_symbol":"hP3","prototype":"AlB2","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"BaGa2 | AlB2 | hP3 | P6/mmm | 0.4429 0.5076 [11] / 0.4475 0.5145 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[23,24],"table":"1","table_key":"t014"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}},{"after":{"pearson_symbol":"hP3","phase":"BaGa2","prototype":"AlB2","space_group":"P6/mmm"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"BaGa2 | AlB2 | hP3 | P6/mmm | 0.4429 0.5076 [11] / 0.4475 0.5145 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[23,24],"table":"1","table_key":"t014"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-3CVOJPZRGY.3ee524","locator":{"ref":"sha256:cb38fae1d94c72fa/p2/tab-1","row":23},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:529c7666cdc21a2e","own_work_of_paper":false},"overall_composition":{"BA":0.333333,"GA":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"BA":0.333333,"CA":0.0,"GA":0.666667,"SR":0.0},"paper":"doi:10.1016/j.calphad.2013.09.002","paper_id":"doi:10.1016/j.calphad.2013.09.002","phases":[{"label":"BaGa2","label_source":"printed_source_page","pearson_symbol":"hP3","prototype":"AlB2","structure_basis":"printed_source_page"}],"pid":"sha256:cb38fae1d94c72fa/p2/tab-1/r23#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"B-BA-CA-GA-SR","structure":{"pearson_symbol":"hP3","phase":"BaGa2","prototype":"AlB2","space_group":"P6/mmm"},"system":"BA-GA","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01117,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01117},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.076,"value_stored":0.5076},{"chemical_system":"BA-GA","cited_sources":[{"first_author":"Bruzzone","kind":"unknown","label":"11","reference":"G. Bruzzone, Boll. Sci. Fac. Chim. Ind. Bologna 24 (1966) 113–132.","status":"resolved","year":"1966"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"BA-GA","before":"B-BA-CA-GA-SR","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.333333,"CA":0.0,"GA":0.666667,"SR":0.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"BaGa2","label_source":"printed_source_page","pearson_symbol":"hP3","prototype":"AlB2","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"BaGa2 | AlB2 | hP3 | P6/mmm | 0.4429 0.5076 [11] / 0.4475 0.5145 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[23,24],"table":"1","table_key":"t014"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}},{"after":{"pearson_symbol":"hP3","phase":"BaGa2","prototype":"AlB2","space_group":"P6/mmm"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"BaGa2 | AlB2 | hP3 | P6/mmm | 0.4429 0.5076 [11] / 0.4475 0.5145 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[23,24],"table":"1","table_key":"t014"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-3CVOJPZRGY.c6af7d","locator":{"ref":"sha256:cb38fae1d94c72fa/p2/tab-1","row":23},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","measured_in":"ref:529c7666cdc21a2e","own_work_of_paper":false},"overall_composition":{"BA":0.333333,"GA":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"BA":0.333333,"CA":0.0,"GA":0.666667,"SR":0.0},"paper":"doi:10.1016/j.calphad.2013.09.002","paper_id":"doi:10.1016/j.calphad.2013.09.002","phases":[{"label":"BaGa2","label_source":"printed_source_page","pearson_symbol":"hP3","prototype":"AlB2","structure_basis":"printed_source_page"}],"pid":"sha256:cb38fae1d94c72fa/p2/tab-1/r23#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"B-BA-CA-GA-SR","structure":{"pearson_symbol":"hP3","phase":"BaGa2","prototype":"AlB2","space_group":"P6/mmm"},"system":"BA-GA","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009744,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009744},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.429,"value_stored":0.4429},{"chemical_system":"BA-GA","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GA","before":"B-BA-CA-GA-SR","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.333333,"CA":0.0,"GA":0.666667,"SR":0.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"BaGa2","label_source":"printed_source_page","pearson_symbol":"hP3","prototype":"AlB2","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"BaGa2 | AlB2 | hP3 | P6/mmm | 0.4429 0.5076 [11] / 0.4475 0.5145 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[23,24],"table":"1","table_key":"t014"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}},{"after":{"pearson_symbol":"hP3","phase":"BaGa2","prototype":"AlB2","space_group":"P6/mmm"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"BaGa2 | AlB2 | hP3 | P6/mmm | 0.4429 0.5076 [11] / 0.4475 0.5145 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[23,24],"table":"1","table_key":"t014"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-CO5IYTXYQM.0ce2c9","locator":{"ref":"sha256:cb38fae1d94c72fa/p2/tab-1","row":24},"method":"First-Principles","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2013.09.002","own_work_of_paper":true},"overall_composition":{"BA":0.333333,"GA":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"BA":0.333333,"CA":0.0,"GA":0.666667,"SR":0.0},"paper":"doi:10.1016/j.calphad.2013.09.002","paper_id":"doi:10.1016/j.calphad.2013.09.002","phases":[{"label":"BaGa2","label_source":"printed_source_page","pearson_symbol":"hP3","prototype":"AlB2","structure_basis":"printed_source_page"}],"pid":"sha256:cb38fae1d94c72fa/p2/tab-1/r24#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"B-BA-CA-GA-SR","structure":{"pearson_symbol":"hP3","phase":"BaGa2","prototype":"AlB2","space_group":"P6/mmm"},"system":"BA-GA","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05145,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.05145},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.145,"value_stored":0.5145},{"chemical_system":"BA-GA","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GA","before":"B-BA-CA-GA-SR","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.333333,"CA":0.0,"GA":0.666667,"SR":0.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"BaGa2","label_source":"printed_source_page","pearson_symbol":"hP3","prototype":"AlB2","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"BaGa2 | AlB2 | hP3 | P6/mmm | 0.4429 0.5076 [11] / 0.4475 0.5145 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[23,24],"table":"1","table_key":"t014"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}},{"after":{"pearson_symbol":"hP3","phase":"BaGa2","prototype":"AlB2","space_group":"P6/mmm"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"BaGa2 | AlB2 | hP3 | P6/mmm | 0.4429 0.5076 [11] / 0.4475 0.5145 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[23,24],"table":"1","table_key":"t014"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-CO5IYTXYQM.50d0ac","locator":{"ref":"sha256:cb38fae1d94c72fa/p2/tab-1","row":24},"method":"First-Principles","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2013.09.002","own_work_of_paper":true},"overall_composition":{"BA":0.333333,"GA":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"BA":0.333333,"CA":0.0,"GA":0.666667,"SR":0.0},"paper":"doi:10.1016/j.calphad.2013.09.002","paper_id":"doi:10.1016/j.calphad.2013.09.002","phases":[{"label":"BaGa2","label_source":"printed_source_page","pearson_symbol":"hP3","prototype":"AlB2","structure_basis":"printed_source_page"}],"pid":"sha256:cb38fae1d94c72fa/p2/tab-1/r24#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"B-BA-CA-GA-SR","structure":{"pearson_symbol":"hP3","phase":"BaGa2","prototype":"AlB2","space_group":"P6/mmm"},"system":"BA-GA","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04475,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04475},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.475,"value_stored":0.4475},{"chemical_system":"BA-GA","cited_sources":[{"first_author":"Bruzzone","kind":"unknown","label":"11","reference":"G. Bruzzone, Boll. Sci. Fac. Chim. Ind. Bologna 24 (1966) 113–132.","status":"resolved","year":"1966"},{"first_author":"Sun","kind":"unknown","label":"19","reference":"X. Sun, G. Lu, L. Chen, R. Ling, Hangzhou Daxue Xuebao, Ziran Kexueban 18 (1991) 55–59.","status":"resolved","year":"1991"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"BA-GA","before":"B-BA-CA-GA-SR","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.2,"CA":0.0,"GA":0.8,"SR":0.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"BaGa4","label_source":"printed_source_page","pearson_symbol":"tI10","prototype":"BaAl4","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"BaGa4 | BaAl4 | tI10 | I4/mmm | 0.4566 1.0778 [11,19] / 0.4641 1.0833 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[25,26],"table":"1","table_key":"t014"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}},{"after":{"pearson_symbol":"tI10","phase":"BaGa4","prototype":"BaAl4","space_group":"I4/mmm"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"BaGa4 | BaAl4 | tI10 | I4/mmm | 0.4566 1.0778 [11,19] / 0.4641 1.0833 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[25,26],"table":"1","table_key":"t014"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-P5XPDVBZVV.ba2a93","locator":{"ref":"sha256:cb38fae1d94c72fa/p2/tab-1","row":25},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"ref:529c7666cdc21a2e","own_work_of_paper":false},"overall_composition":{"BA":0.2,"GA":0.8},"overall_composition_basis":"from_formula","overall_composition_stored":{"BA":0.2,"CA":0.0,"GA":0.8,"SR":0.0},"paper":"doi:10.1016/j.calphad.2013.09.002","paper_id":"doi:10.1016/j.calphad.2013.09.002","phases":[{"label":"BaGa4","label_source":"printed_source_page","pearson_symbol":"tI10","prototype":"BaAl4","structure_basis":"printed_source_page"}],"pid":"sha256:cb38fae1d94c72fa/p2/tab-1/r25#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"B-BA-CA-GA-SR","structure":{"pearson_symbol":"tI10","phase":"BaGa4","prototype":"BaAl4","space_group":"I4/mmm"},"system":"BA-GA","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01005,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01005},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.566,"value_stored":0.4566},{"chemical_system":"BA-GA","cited_sources":[{"first_author":"Bruzzone","kind":"unknown","label":"11","reference":"G. Bruzzone, Boll. Sci. Fac. Chim. Ind. Bologna 24 (1966) 113–132.","status":"resolved","year":"1966"},{"first_author":"Sun","kind":"unknown","label":"19","reference":"X. Sun, G. Lu, L. Chen, R. Ling, Hangzhou Daxue Xuebao, Ziran Kexueban 18 (1991) 55–59.","status":"resolved","year":"1991"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"BA-GA","before":"B-BA-CA-GA-SR","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.2,"CA":0.0,"GA":0.8,"SR":0.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"BaGa4","label_source":"printed_source_page","pearson_symbol":"tI10","prototype":"BaAl4","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"BaGa4 | BaAl4 | tI10 | I4/mmm | 0.4566 1.0778 [11,19] / 0.4641 1.0833 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[25,26],"table":"1","table_key":"t014"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}},{"after":{"pearson_symbol":"tI10","phase":"BaGa4","prototype":"BaAl4","space_group":"I4/mmm"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"BaGa4 | BaAl4 | tI10 | I4/mmm | 0.4566 1.0778 [11,19] / 0.4641 1.0833 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[25,26],"table":"1","table_key":"t014"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-P5XPDVBZVV.bcb165","locator":{"ref":"sha256:cb38fae1d94c72fa/p2/tab-1","row":25},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"ref:529c7666cdc21a2e","own_work_of_paper":false},"overall_composition":{"BA":0.2,"GA":0.8},"overall_composition_basis":"from_formula","overall_composition_stored":{"BA":0.2,"CA":0.0,"GA":0.8,"SR":0.0},"paper":"doi:10.1016/j.calphad.2013.09.002","paper_id":"doi:10.1016/j.calphad.2013.09.002","phases":[{"label":"BaGa4","label_source":"printed_source_page","pearson_symbol":"tI10","prototype":"BaAl4","structure_basis":"printed_source_page"}],"pid":"sha256:cb38fae1d94c72fa/p2/tab-1/r25#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"B-BA-CA-GA-SR","structure":{"pearson_symbol":"tI10","phase":"BaGa4","prototype":"BaAl4","space_group":"I4/mmm"},"system":"BA-GA","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02371,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02371},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":10.778,"value_stored":1.0778},{"chemical_system":"BA-GA","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GA","before":"B-BA-CA-GA-SR","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.2,"CA":0.0,"GA":0.8,"SR":0.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"BaGa4","label_source":"printed_source_page","pearson_symbol":"tI10","prototype":"BaAl4","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"BaGa4 | BaAl4 | tI10 | I4/mmm | 0.4566 1.0778 [11,19] / 0.4641 1.0833 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[25,26],"table":"1","table_key":"t014"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}},{"after":{"pearson_symbol":"tI10","phase":"BaGa4","prototype":"BaAl4","space_group":"I4/mmm"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"BaGa4 | BaAl4 | tI10 | I4/mmm | 0.4566 1.0778 [11,19] / 0.4641 1.0833 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[25,26],"table":"1","table_key":"t014"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-KT2UYWSJYY.b7bbde","locator":{"ref":"sha256:cb38fae1d94c72fa/p2/tab-1","row":26},"method":"First-Principles","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2013.09.002","own_work_of_paper":true},"overall_composition":{"BA":0.2,"GA":0.8},"overall_composition_basis":"from_formula","overall_composition_stored":{"BA":0.2,"CA":0.0,"GA":0.8,"SR":0.0},"paper":"doi:10.1016/j.calphad.2013.09.002","paper_id":"doi:10.1016/j.calphad.2013.09.002","phases":[{"label":"BaGa4","label_source":"printed_source_page","pearson_symbol":"tI10","prototype":"BaAl4","structure_basis":"printed_source_page"}],"pid":"sha256:cb38fae1d94c72fa/p2/tab-1/r26#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"B-BA-CA-GA-SR","structure":{"pearson_symbol":"tI10","phase":"BaGa4","prototype":"BaAl4","space_group":"I4/mmm"},"system":"BA-GA","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04641,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.04641},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.641,"value_stored":0.4641},{"chemical_system":"BA-GA","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GA","before":"B-BA-CA-GA-SR","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.2,"CA":0.0,"GA":0.8,"SR":0.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"BaGa4","label_source":"printed_source_page","pearson_symbol":"tI10","prototype":"BaAl4","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"BaGa4 | BaAl4 | tI10 | I4/mmm | 0.4566 1.0778 [11,19] / 0.4641 1.0833 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[25,26],"table":"1","table_key":"t014"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}},{"after":{"pearson_symbol":"tI10","phase":"BaGa4","prototype":"BaAl4","space_group":"I4/mmm"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"BaGa4 | BaAl4 | tI10 | I4/mmm | 0.4566 1.0778 [11,19] / 0.4641 1.0833 F.P.","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[25,26],"table":"1","table_key":"t014"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"first row prints phase/prototype/Pearson/space group; F.P. continuation row inherits","verdict":"confirmed"}}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-KT2UYWSJYY.e83470","locator":{"ref":"sha256:cb38fae1d94c72fa/p2/tab-1","row":26},"method":"First-Principles","method_basis":"printed in the table row/column","observation_type":"structural_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2013.09.002","own_work_of_paper":true},"overall_composition":{"BA":0.2,"GA":0.8},"overall_composition_basis":"from_formula","overall_composition_stored":{"BA":0.2,"CA":0.0,"GA":0.8,"SR":0.0},"paper":"doi:10.1016/j.calphad.2013.09.002","paper_id":"doi:10.1016/j.calphad.2013.09.002","phases":[{"label":"BaGa4","label_source":"printed_source_page","pearson_symbol":"tI10","prototype":"BaAl4","structure_basis":"printed_source_page"}],"pid":"sha256:cb38fae1d94c72fa/p2/tab-1/r26#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"B-BA-CA-GA-SR","structure":{"pearson_symbol":"tI10","phase":"BaGa4","prototype":"BaAl4","space_group":"I4/mmm"},"system":"BA-GA","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1083,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1083},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":10.833,"value_stored":1.0833},{"chemical_system":"BA-GA","cited_sources":[{"doi":"10.1016/0925-8388(94)90786-2","first_author":"Fornasini","kind":"unknown","label":"20","paper":"doi:10.1016/0925-8388(94)90786-2","reference":"M.L. Fornasini, M. Pani, J. Alloys Compd. 205 (1994) 179–181.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"BA-GA","before":"B-BA-CA-GA-SR","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.454545,"CA":0.0,"GA":0.545455,"SR":0.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"Ba5Ga6","label_source":"printed_source_page","pearson_symbol":"hP24","prototype":"Ba5Ga6","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"Ba5Ga6 | Ba5Ga6 | hP24 | P-6c2 | 0.7771 1.4376 [20]","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[27],"table":"1","table_key":"t014"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"single printed row","verdict":"confirmed"}},{"after":{"pearson_symbol":"hP24","phase":"Ba5Ga6","prototype":"Ba5Ga6","space_group":"P-6c2"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"Ba5Ga6 | Ba5Ga6 | hP24 | P-6c2 | 0.7771 1.4376 [20]","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[27],"table":"1","table_key":"t014"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"single printed row","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-4MH4PKPQB2.11f4b4","locator":{"ref":"sha256:cb38fae1d94c72fa/p2/tab-1","row":27},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.454545,"GA":0.545455},"overall_composition_basis":"from_formula","overall_composition_stored":{"BA":0.454545,"CA":0.0,"GA":0.545455,"SR":0.0},"paper":"doi:10.1016/j.calphad.2013.09.002","paper_id":"doi:10.1016/j.calphad.2013.09.002","phases":[{"label":"Ba5Ga6","label_source":"printed_source_page","pearson_symbol":"hP24","prototype":"Ba5Ga6","structure_basis":"printed_source_page"}],"pid":"sha256:cb38fae1d94c72fa/p2/tab-1/r27#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"B-BA-CA-GA-SR","structure":{"pearson_symbol":"hP24","phase":"Ba5Ga6","prototype":"Ba5Ga6","space_group":"P-6c2"},"system":"BA-GA","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03163,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03163},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":14.376,"value_stored":1.4376},{"chemical_system":"BA-GA","cited_sources":[{"doi":"10.1016/0925-8388(94)90786-2","first_author":"Fornasini","kind":"unknown","label":"20","paper":"doi:10.1016/0925-8388(94)90786-2","reference":"M.L. Fornasini, M. Pani, J. Alloys Compd. 205 (1994) 179–181.","status":"resolved","year":"1994"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"BA-GA","before":"B-BA-CA-GA-SR","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.454545,"CA":0.0,"GA":0.545455,"SR":0.0},"phases":["UNKNOWN"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":[{"label":"Ba5Ga6","label_source":"printed_source_page","pearson_symbol":"hP24","prototype":"Ba5Ga6","structure_basis":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"Ba5Ga6 | Ba5Ga6 | hP24 | P-6c2 | 0.7771 1.4376 [20]","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[27],"table":"1","table_key":"t014"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"single printed row","verdict":"confirmed"}},{"after":{"pearson_symbol":"hP24","phase":"Ba5Ga6","prototype":"Ba5Ga6","space_group":"P-6c2"},"before":null,"evidence":{"batch":"table_context_batch_01","doi":"10.1016/j.calphad.2013.09.002","pdf_page":2,"pdf_sha256":"cb38fae1d94c72fa4ac095429ad984aa4e1696c34e80e9c6aeff30c89653af2c","printed":"Ba5Ga6 | Ba5Ga6 | hP24 | P-6c2 | 0.7771 1.4376 [20]","rationale":"Printed table context for this group supplies phase, pearson_symbol, prototype, space_group; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[27],"table":"1","table_key":"t014"},"field":"structure","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"4a99cc431d0fd02fdff13b1d9e17501addd1e6db8b82b6fef6c06210926adb3f","page":2,"pdf_sha256_prefix":"cb38fae1d94c72fa","seen":"single printed row","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-4MH4PKPQB2.fc3f3f","locator":{"ref":"sha256:cb38fae1d94c72fa/p2/tab-1","row":27},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.454545,"GA":0.545455},"overall_composition_basis":"from_formula","overall_composition_stored":{"BA":0.454545,"CA":0.0,"GA":0.545455,"SR":0.0},"paper":"doi:10.1016/j.calphad.2013.09.002","paper_id":"doi:10.1016/j.calphad.2013.09.002","phases":[{"label":"Ba5Ga6","label_source":"printed_source_page","pearson_symbol":"hP24","prototype":"Ba5Ga6","structure_basis":"printed_source_page"}],"pid":"sha256:cb38fae1d94c72fa/p2/tab-1/r27#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"single_reader_text_layer","reader_agreement_label":"single reader + PDF text layer","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","text_layer"],"record_kind":"general_table","source_system":"B-BA-CA-GA-SR","structure":{"pearson_symbol":"hP24","phase":"Ba5Ga6","prototype":"Ba5Ga6","space_group":"P-6c2"},"system":"BA-GA","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0171,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0171},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":7.771,"value_stored":0.7771},{"chemical_system":"BA-GA","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GA","before":"BA-CA-GA-SR","evidence":{"basis":"phase_formula","overall_composition":{"CA":0.0,"GA":0.466667,"SR":0.0},"phases":["Ba8Ga7"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-HA3FJJL4JJ","locator":{"ref":"sha256:cb38fae1d94c72fa/p3/tab-2","row":16},"method":"first-principles calculations","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2013.09.002","own_work_of_paper":true},"overall_composition":{"GA":0.466667},"overall_composition_basis":"from_formula","overall_composition_stored":{"CA":0.0,"GA":0.466667,"SR":0.0},"paper":"doi:10.1016/j.calphad.2013.09.002","paper_id":"doi:10.1016/j.calphad.2013.09.002","phases":[{"label":"Ba8Ga7"}],"pid":"sha256:cb38fae1d94c72fa/p3/tab-2/r16#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GA":{"phase":"printed:none"}},"reference_state_stored":{"BA":{"phase":"printed:none"},"CA":{"phase":"printed:none"},"GA":{"phase":"printed:none"},"SR":{"phase":"printed:none"}},"source_system":"BA-CA-GA-SR","system":"BA-GA","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.74695},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"J/mol-atom","unit_stored":"J/mol-atom","value":-34.939,"value_printed":-34939,"value_stored":-34939.0},{"chemical_system":"BA-GA","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GA","before":"BA-CA-GA-SR","evidence":{"basis":"phase_formula","overall_composition":{"CA":0.0,"GA":0.666667,"SR":0.0},"phases":["BaGa2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-PIIARY7TF2","locator":{"ref":"sha256:cb38fae1d94c72fa/p3/tab-2","row":17},"method":"first-principles calculations","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2013.09.002","own_work_of_paper":true},"overall_composition":{"GA":0.666667},"overall_composition_basis":"from_formula","overall_composition_stored":{"CA":0.0,"GA":0.666667,"SR":0.0},"paper":"doi:10.1016/j.calphad.2013.09.002","paper_id":"doi:10.1016/j.calphad.2013.09.002","phases":[{"label":"BaGa2"}],"pid":"sha256:cb38fae1d94c72fa/p3/tab-2/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GA":{"phase":"printed:none"}},"reference_state_stored":{"BA":{"phase":"printed:none"},"CA":{"phase":"printed:none"},"GA":{"phase":"printed:none"},"SR":{"phase":"printed:none"}},"source_system":"BA-CA-GA-SR","system":"BA-GA","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.2294},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"J/mol-atom","unit_stored":"J/mol-atom","value":-44.588,"value_printed":-44588,"value_stored":-44588.0},{"chemical_system":"BA-GA","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GA","before":"BA-CA-GA-SR","evidence":{"basis":"phase_formula","overall_composition":{"CA":0.0,"GA":0.8,"SR":0.0},"phases":["BaGa4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":1,"id":"ORC-B3ISYVNRGF","locator":{"ref":"sha256:cb38fae1d94c72fa/p3/tab-2","row":18},"method":"first-principles calculations","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1016/j.calphad.2013.09.002","own_work_of_paper":true},"overall_composition":{"GA":0.8},"overall_composition_basis":"from_formula","overall_composition_stored":{"CA":0.0,"GA":0.8,"SR":0.0},"paper":"doi:10.1016/j.calphad.2013.09.002","paper_id":"doi:10.1016/j.calphad.2013.09.002","phases":[{"label":"BaGa4"}],"pid":"sha256:cb38fae1d94c72fa/p3/tab-2/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GA":{"phase":"printed:none"}},"reference_state_stored":{"BA":{"phase":"printed:none"},"CA":{"phase":"printed:none"},"GA":{"phase":"printed:none"},"SR":{"phase":"printed:none"}},"source_system":"BA-CA-GA-SR","system":"BA-GA","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.10675},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"printed_unit","unit_printed":"J/mol-atom","unit_stored":"J/mol-atom","value":-42.135,"value_printed":-42135,"value_stored":-42135.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"BA-GA"}