{"artifacts":{"doi:10.1007/s11669-019-00714-2/p3/tab-2":{"artifact":"table","caption":"The crystal structure data of the Ba-Ge system","label":"2","page":3},"doi:10.1007/s11669-019-00714-2/p3/text-02":{"artifact":"text_passage","label":"page 3, passage 2","page":3},"doi:10.1007/s11669-019-00714-2/p3/text-04":{"artifact":"text_passage","label":"page 3, passage 4","page":3},"doi:10.1007/s11669-019-00714-2/p9/tab-7":{"artifact":"table","caption":"The invariant reactions in the Ba-Ge system including calculated and experimental results","label":"7","page":9},"sha256:41ca11e56c9eee28/p4/tab-3":{"artifact":"table","caption":"The standard enthalpies and entropies of formation of the intermetallic compounds in the Al-Ba and Ba-Ge systems","label":"3","page":4}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["BA","GE"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"M093d74e5":{"catalog_entry":{"license":"CC BY 4.0","name":"BaGe-19Ben.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"G. Ugur, J. Phase Equilib. Diffus., 40, 195-205(2019).","model_doi":"10.1007/s11669-019-00714-2","reproduced_by_calculation":false,"tdb":"BaGe-19Ben.tdb","tdb_path":"databases/sgte-binary/BaGe-19Ben.tdb","tdb_sha256":"118f846ad4780ff7cddbb8c80cc21554ba196360eac8478ff368429d0c678490"},"Mb3b72003":{"catalog_entry":{"license":"CC BY 4.0","name":"BaGe-19Ben.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"G. Ugur, J. Phase Equilib. Diffus., 40, 195-205(2019).","model_doi":"10.1007/s11669-019-00714-2","reproduced_by_calculation":true,"tdb":"BaGe-19Ben.tdb","tdb_path":"databases/sgte-binary/BaGe-19Ben.tdb","tdb_sha256":"118f846ad4780ff7cddbb8c80cc21554ba196360eac8478ff368429d0c678490"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1002/(sici)1521-3773(19981217)37:23<3314::aid-anie3314>3.0.co;2-l":{"authors":["Fabio Zürcher","Reinhard Nesper"],"citation":"Fabio Zürcher, Reinhard Nesper, Ba3Ge4: Polymerization of Zintl Anions in the Solid and Bond Stretching Isomerism, Angewandte Chemie International Edition 37, 3314-3318 (1998).","container":"Angewandte Chemie International Edition","doi":"10.1002/(sici)1521-3773(19981217)37:23<3314::aid-anie3314>3.0.co;2-l","doi_url":"https://doi.org/10.1002/(sici)1521-3773(19981217)37:23<3314::aid-anie3314>3.0.co;2-l","id":"doi:10.1002/(sici)1521-3773(19981217)37:23<3314::aid-anie3314>3.0.co;2-l","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Ba3Ge4: Polymerization of Zintl Anions in the Solid and Bond Stretching Isomerism","year":1998},"doi:10.1006/jssc.2000.8632":{"authors":["Hiroshi Fukuoka","Kazuhito Iwai","Shoji Yamanaka","Hideki Abe","Kenji Yoza","Ludger Häming"],"citation":"Hiroshi Fukuoka, Kazuhito Iwai, Shoji Yamanaka, Hideki Abe, Kenji Yoza, Ludger Häming, Preparation and Structure of a New Germanium Clathrate, Ba24Ge100, Journal of Solid State Chemistry 151, 117-121 (2000).","container":"Journal of Solid State Chemistry","doi":"10.1006/jssc.2000.8632","doi_url":"https://doi.org/10.1006/jssc.2000.8632","id":"doi:10.1006/jssc.2000.8632","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Preparation and Structure of a New Germanium Clathrate, Ba24Ge100","year":2000},"doi:10.1007/s11669-019-00714-2":{"authors":["R. Benhafid","A. Belgacem Bouzida","Y. Djaballah","A. Candan","A. İyigör","G. Uğur"],"citation":"R. Benhafid, A. Belgacem Bouzida, Y. Djaballah, A. Candan, A. İyigör, G. Uğur, Thermodynamic Modeling of the Al-Ba and Ba-Ge Systems Supported by First-Principles Calculations, J. Phase Equilib. Diffus. 40, 195-205 (2019).","container":"J. Phase Equilib. Diffus.","doi":"10.1007/s11669-019-00714-2","doi_url":"https://doi.org/10.1007/s11669-019-00714-2","id":"doi:10.1007/s11669-019-00714-2","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"41ca11e56c9eee28","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic Modeling of the Al-Ba and Ba-Ge Systems Supported by First-Principles Calculations","year":2019},"doi:10.1016/j.jallcom.2007.08.005":{"authors":["M. Pani","A. Palenzona"],"citation":"M. Pani, A. Palenzona, The phase diagram of the Ba–Ge system, Journal of Alloys and Compounds 462, L9-L11 (2008).","container":"Journal of Alloys and Compounds","doi":"10.1016/j.jallcom.2007.08.005","doi_url":"https://doi.org/10.1016/j.jallcom.2007.08.005","id":"doi:10.1016/j.jallcom.2007.08.005","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"The phase diagram of the Ba–Ge system","year":2008},"doi:10.1016/j.jssc.2004.11.011":{"authors":["Wilder Carrillo-Cabrera","Horst Borrmann","Silke Paschen","Michael Baenitz","Frank Steglich","Yuri Grin"],"citation":"Wilder Carrillo-Cabrera, Horst Borrmann, Silke Paschen, Michael Baenitz, Frank Steglich, Yuri Grin, Ba6Ge25: low-temperature Ge–Ge bond breaking during temperature-induced structure transformation, Journal of Solid State Chemistry 178, 715-728 (2005).","container":"Journal of Solid State Chemistry","doi":"10.1016/j.jssc.2004.11.011","doi_url":"https://doi.org/10.1016/j.jssc.2004.11.011","id":"doi:10.1016/j.jssc.2004.11.011","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Ba6Ge25: low-temperature Ge–Ge bond breaking during temperature-induced structure transformation","year":2005},"doi:10.1021/ja104197c":{"authors":["Umut Aydemir","Lev Akselrud","Wilder Carrillo-Cabrera","Christophe Candolfi","Niels Oeschler","Michael Baitinger","Frank Steglich","Yuri Grin"],"citation":"Umut Aydemir, Lev Akselrud, Wilder Carrillo-Cabrera, Christophe Candolfi, Niels Oeschler, Michael Baitinger et al., BaGe<sub>5</sub>: A New Type of Intermetallic Clathrate, J. Am. Chem. Soc. 132, 10984-10985 (2010).","container":"J. Am. Chem. Soc.","doi":"10.1021/ja104197c","doi_url":"https://doi.org/10.1021/ja104197c","id":"doi:10.1021/ja104197c","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"BaGe<sub>5</sub>: A New Type of Intermetallic Clathrate","year":2010},"doi:10.1107/s0365110x67001793":{"authors":["W. Rieger","E. Parthé"],"citation":"W. Rieger, E. Parthé, Alkaline earth silicides, germanides and stannides with CrB structure type, Acta Cryst 22, 919-922 (1967).","container":"Acta Cryst","doi":"10.1107/s0365110x67001793","doi_url":"https://doi.org/10.1107/s0365110x67001793","id":"doi:10.1107/s0365110x67001793","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Alkaline earth silicides, germanides and stannides with CrB structure type","year":1967},"doi:10.1515/ncrs-2000-0208":{"authors":["W. Carrillo-Cabrera","J. Curda","H. G. von Schnering","S. Paschen","Yu. Grin"],"citation":"W. Carrillo-Cabrera, J. Curda, H. G. von Schnering, S. Paschen, Yu. Grin, Crystal structure of hexabarium pentacosagermanide, Ba6Ge25, Zeitschrift für Kristallographie - New Crystal Structures 215, 207-208 (2000).","container":"Zeitschrift für Kristallographie - New Crystal Structures","doi":"10.1515/ncrs-2000-0208","doi_url":"https://doi.org/10.1515/ncrs-2000-0208","id":"doi:10.1515/ncrs-2000-0208","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Crystal structure of hexabarium pentacosagermanide, Ba6Ge25","year":2000},"doi:10.1515/znb-1973-3-427":{"authors":["K. Turban","Herbert Schäfer"],"citation":"K. Turban, Herbert Schäfer, Notizen: Darstellung und Kristallstruktur des Ba<sub>2</sub>Ge / Preparation and Crystal structure of Ba<sub>2</sub>Ge, Zeitschrift für Naturforschung B 28, 220-222 (1973).","container":"Zeitschrift für Naturforschung B","doi":"10.1515/znb-1973-3-427","doi_url":"https://doi.org/10.1515/znb-1973-3-427","id":"doi:10.1515/znb-1973-3-427","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Notizen: Darstellung und Kristallstruktur des Ba<sub>2</sub>Ge / Preparation and Crystal structure of Ba<sub>2</sub>Ge","year":1973},"doi:10.1515/znb-1977-1128":{"authors":["Jürgen Evers","Gilbert Oehlinger","Armin Weiss"],"citation":"Jürgen Evers, Gilbert Oehlinger, Armin Weiss, Notizen: Kristallstruktur von Bariumdigermanid bei hohen Drücken / Crystal Structure of Bariumdigermanide at High Pressures, Zeitschrift für Naturforschung B 32, 1352-1353 (1977).","container":"Zeitschrift für Naturforschung B","doi":"10.1515/znb-1977-1128","doi_url":"https://doi.org/10.1515/znb-1977-1128","id":"doi:10.1515/znb-1977-1128","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Notizen: Kristallstruktur von Bariumdigermanid bei hohen Drücken / Crystal Structure of Bariumdigermanide at High Pressures","year":1977},"ref:584fdc3ead7675c1":{"citation":"T.B. Massalski, O. Okamoto, ASM International, Binary Alloy Phase Diagrams, 2nd ed., ASM International, Materials Park, Ohio, 1990","id":"ref:584fdc3ead7675c1","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1990},"ref:ce8f62686cee8142":{"citation":"W. Carrillo-Cabrera, S. Budnyk, Y. Prots, and Y. Grin, Ba8Ge43 Revisited: A 2a0 9 2a0 9 2a0 Superstructure of the Clathrate-I, Type with Full Vacancy Ordering, Zeitschrift für Anorganische und Allgemeine Chemie, 2004, 630, p 2267-2276","id":"ref:ce8f62686cee8142","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":2004},"ref:fe0be0e3819a967e":{"citation":"V.G. Andrianov, K.A. Bolshakov, E.B. Sokolov, A.V. Chirkin, and P.I. Fedorov, Thermal Analysis of the Melting Diagram of the Germanium-Barium System, Russ. Inorg. Mater., 1966, 2, p 1784-1786","id":"ref:fe0be0e3819a967e","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1966}},"part":1,"parts":1,"records":[{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1515/znb-1973-3-427","first_author":"Turban","kind":"unknown","label":"31","paper":"doi:10.1515/znb-1973-3-427","reference":"K. Turban and H. Schäfer, Preparation and Crystal Structure of Ba2Ge, Zeitschrift für Naturforschung B, 1973, 28, p 220-222","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-2P43SONXCZ.13578a","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":3},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.667,"GE":0.333},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.667,"GE":0.333},"composition_source":"printed","phase":"Ba2Ge"}],"phases":[{"label":"Ba2Ge","model_phase":"BA2GE_C37"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP12","prototype":"Co2Si","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02209,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02209},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":10.04,"value_stored":1.004},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1515/znb-1973-3-427","first_author":"Turban","kind":"unknown","label":"31","paper":"doi:10.1515/znb-1973-3-427","reference":"K. Turban and H. Schäfer, Preparation and Crystal Structure of Ba2Ge, Zeitschrift für Naturforschung B, 1973, 28, p 220-222","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-2P43SONXCZ.5a8960","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":3},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.667,"GE":0.333},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.667,"GE":0.333},"composition_source":"printed","phase":"Ba2Ge"}],"phases":[{"label":"Ba2Ge","model_phase":"BA2GE_C37"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP12","prototype":"Co2Si","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01844,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01844},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.38,"value_stored":0.838},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1515/znb-1973-3-427","first_author":"Turban","kind":"unknown","label":"31","paper":"doi:10.1515/znb-1973-3-427","reference":"K. Turban and H. Schäfer, Preparation and Crystal Structure of Ba2Ge, Zeitschrift für Naturforschung B, 1973, 28, p 220-222","status":"resolved","year":"1973"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-2P43SONXCZ.687995","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":3},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.667,"GE":0.333},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.667,"GE":0.333},"composition_source":"printed","phase":"Ba2Ge"}],"phases":[{"label":"Ba2Ge","model_phase":"BA2GE_C37"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r03#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP12","prototype":"Co2Si","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01206,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01206},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.48,"value_stored":0.548},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-TB7XB4E44A.002983","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":4},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.667,"GE":0.333},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.667,"GE":0.333},"composition_source":"printed","phase":"Ba2Ge"}],"phases":[{"label":"Ba2Ge","model_phase":"BA2GE_C37"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP12","prototype":"Co2Si","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01198,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01198},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.444,"value_stored":0.5444},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-TB7XB4E44A.0e3295","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":4},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.667,"GE":0.333},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.667,"GE":0.333},"composition_source":"printed","phase":"Ba2Ge"}],"phases":[{"label":"Ba2Ge","model_phase":"BA2GE_C37"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP12","prototype":"Co2Si","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02215,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02215},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":10.068,"value_stored":1.0068},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-TB7XB4E44A.88f5bc","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":4},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.667,"GE":0.333},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.667,"GE":0.333},"composition_source":"printed","phase":"Ba2Ge"}],"phases":[{"label":"Ba2Ge","model_phase":"BA2GE_C37"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r04#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP12","prototype":"Co2Si","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01852,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01852},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.419,"value_stored":0.8419},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-NKXSDF4Q6J.11f97e","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":5},"observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.667,"GE":0.333},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.667,"GE":0.333},"composition_source":"printed","phase":"Ba2Ge"}],"phases":[{"label":"Ba2Ge","model_phase":"BA2GE_C37"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP12","prototype":"Co2Si","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/X_PHASE","floor":0.02,"floor_unit":"mole fraction","value":0.02},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1011,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1011},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":10.11,"value_stored":1.011},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-NKXSDF4Q6J.1541f5","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":5},"observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.667,"GE":0.333},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.667,"GE":0.333},"composition_source":"printed","phase":"Ba2Ge"}],"phases":[{"label":"Ba2Ge","model_phase":"BA2GE_C37"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP12","prototype":"Co2Si","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/X_PHASE","floor":0.02,"floor_unit":"mole fraction","value":0.02},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05495,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.05495},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.495,"value_stored":0.5495},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-NKXSDF4Q6J.766e32","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":5},"observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.667,"GE":0.333},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.667,"GE":0.333},"composition_source":"printed","phase":"Ba2Ge"}],"phases":[{"label":"Ba2Ge","model_phase":"BA2GE_C37"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r05#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP12","prototype":"Co2Si","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/X_PHASE","floor":0.02,"floor_unit":"mole fraction","value":0.02},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.08429,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.08429},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.429,"value_stored":0.8429},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-XU5D2DWPIU.40b725","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":6},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.625,"GE":0.375},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.625,"GE":0.375},"composition_source":"printed","phase":"Ba5Ge3"}],"phases":[{"label":"Ba5Ge3","model_phase":"BA5GE3"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"tP32","prototype":"Ba5Si3","space_group":"P4/ncc","space_group_number":130},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01878,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01878},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.538,"value_stored":0.8538},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-XU5D2DWPIU.547e0c","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":6},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.625,"GE":0.375},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.625,"GE":0.375},"composition_source":"printed","phase":"Ba5Ge3"}],"phases":[{"label":"Ba5Ge3","model_phase":"BA5GE3"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"tP32","prototype":"Ba5Si3","space_group":"P4/ncc","space_group_number":130},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01878,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01878},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.538,"value_stored":0.8538},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-XU5D2DWPIU.be9a4a","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":6},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.625,"GE":0.375},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.625,"GE":0.375},"composition_source":"printed","phase":"Ba5Ge3"}],"phases":[{"label":"Ba5Ge3","model_phase":"BA5GE3"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r06#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"tP32","prototype":"Ba5Si3","space_group":"P4/ncc","space_group_number":130},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03629,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03629},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":16.495,"value_stored":1.6495},{"chemical_system":"BA-GE","cited_sources":[{"first_author":"Nesper","kind":"unknown","label":"32","reference":"R. Nesper and F. Zürcher, Crystal structure of pentabarium trigermanide, Ba5Ge3, Z. Kristallogr., 1999, 214, p 22","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-GN7PTUQTSW.49fab1","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":7},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.625,"GE":0.375},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.625,"GE":0.375},"composition_source":"printed","phase":"Ba5Ge3"}],"phases":[{"label":"Ba5Ge3","model_phase":"BA5GE3"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"tP32","prototype":"Ba5Si3","space_group":"P4/ncc","space_group_number":130},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01874,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01874},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.519,"value_stored":0.8519},{"chemical_system":"BA-GE","cited_sources":[{"first_author":"Nesper","kind":"unknown","label":"32","reference":"R. Nesper and F. Zürcher, Crystal structure of pentabarium trigermanide, Ba5Ge3, Z. Kristallogr., 1999, 214, p 22","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-GN7PTUQTSW.5c9cfe","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":7},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.625,"GE":0.375},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.625,"GE":0.375},"composition_source":"printed","phase":"Ba5Ge3"}],"phases":[{"label":"Ba5Ge3","model_phase":"BA5GE3"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"tP32","prototype":"Ba5Si3","space_group":"P4/ncc","space_group_number":130},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03642,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03642},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":16.554,"value_stored":1.6554},{"chemical_system":"BA-GE","cited_sources":[{"first_author":"Nesper","kind":"unknown","label":"32","reference":"R. Nesper and F. Zürcher, Crystal structure of pentabarium trigermanide, Ba5Ge3, Z. Kristallogr., 1999, 214, p 22","status":"resolved","year":"1999"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-GN7PTUQTSW.7a9395","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":7},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.625,"GE":0.375},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.625,"GE":0.375},"composition_source":"printed","phase":"Ba5Ge3"}],"phases":[{"label":"Ba5Ge3","model_phase":"BA5GE3"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r07#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"tP32","prototype":"Ba5Si3","space_group":"P4/ncc","space_group_number":130},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01874,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01874},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.519,"value_stored":0.8519},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-PXU6ZYGTYC.4a9ba2","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":8},"observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.625,"GE":0.375},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.625,"GE":0.375},"composition_source":"printed","phase":"Ba5Ge3"}],"phases":[{"label":"Ba5Ge3","model_phase":"BA5GE3"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"tP32","prototype":"Ba5Si3","space_group":"P4/ncc","space_group_number":130},"system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/X_PHASE","floor":0.02,"floor_unit":"mole fraction","value":0.02},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1656,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1656},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":16.563,"value_stored":1.6563},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-PXU6ZYGTYC.829c47","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":8},"observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.625,"GE":0.375},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.625,"GE":0.375},"composition_source":"printed","phase":"Ba5Ge3"}],"phases":[{"label":"Ba5Ge3","model_phase":"BA5GE3"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"tP32","prototype":"Ba5Si3","space_group":"P4/ncc","space_group_number":130},"system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/X_PHASE","floor":0.02,"floor_unit":"mole fraction","value":0.02},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.08539,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.08539},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.539,"value_stored":0.8539},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-PXU6ZYGTYC.cc8a57","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":8},"observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.625,"GE":0.375},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.625,"GE":0.375},"composition_source":"printed","phase":"Ba5Ge3"}],"phases":[{"label":"Ba5Ge3","model_phase":"BA5GE3"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r08#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"tP32","prototype":"Ba5Si3","space_group":"P4/ncc","space_group_number":130},"system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/X_PHASE","floor":0.02,"floor_unit":"mole fraction","value":0.02},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.08539,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.08539},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.539,"value_stored":0.8539},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1107/s0365110x67001793","first_author":"Rieger","kind":"unknown","label":"33","paper":"doi:10.1107/s0365110x67001793","reference":"W. Rieger and E. Parthé, Alkaline Earth Silicides, Germanides and Stannides with CrB Structure Type, Acta Crystallogr. A, 1967, 22, p 919-922","status":"resolved","year":"1967"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-WTJXTMBUPY.0dfcad","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":9},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.5,"GE":0.5},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.5,"GE":0.5},"composition_source":"printed","phase":"BaGe"}],"phases":[{"label":"BaGe","model_phase":"BAGE_B33"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oC8","prototype":"CrB","space_group":"Cmcm","space_group_number":63},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009458,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009458},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.299,"value_stored":0.4299},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1107/s0365110x67001793","first_author":"Rieger","kind":"unknown","label":"33","paper":"doi:10.1107/s0365110x67001793","reference":"W. Rieger and E. Parthé, Alkaline Earth Silicides, Germanides and Stannides with CrB Structure Type, Acta Crystallogr. A, 1967, 22, p 919-922","status":"resolved","year":"1967"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-WTJXTMBUPY.42412c","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":9},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.5,"GE":0.5},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.5,"GE":0.5},"composition_source":"printed","phase":"BaGe"}],"phases":[{"label":"BaGe","model_phase":"BAGE_B33"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oC8","prototype":"CrB","space_group":"Cmcm","space_group_number":63},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01113,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01113},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.057,"value_stored":0.5057},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1107/s0365110x67001793","first_author":"Rieger","kind":"unknown","label":"33","paper":"doi:10.1107/s0365110x67001793","reference":"W. Rieger and E. Parthé, Alkaline Earth Silicides, Germanides and Stannides with CrB Structure Type, Acta Crystallogr. A, 1967, 22, p 919-922","status":"resolved","year":"1967"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-WTJXTMBUPY.730be2","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":9},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.5,"GE":0.5},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.5,"GE":0.5},"composition_source":"printed","phase":"BaGe"}],"phases":[{"label":"BaGe","model_phase":"BAGE_B33"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r09#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oC8","prototype":"CrB","space_group":"Cmcm","space_group_number":63},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02627,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02627},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":11.942,"value_stored":1.1942},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-PECN3AZ3E3.6b1c46","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":10},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.5,"GE":0.5},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.5,"GE":0.5},"composition_source":"printed","phase":"BaGe"}],"phases":[{"label":"BaGe","model_phase":"BAGE_B33"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oC8","prototype":"CrB","space_group":"Cmcm","space_group_number":63},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0263,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0263},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":11.954,"value_stored":1.1954},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-PECN3AZ3E3.7b5e52","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":10},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.5,"GE":0.5},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.5,"GE":0.5},"composition_source":"printed","phase":"BaGe"}],"phases":[{"label":"BaGe","model_phase":"BAGE_B33"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oC8","prototype":"CrB","space_group":"Cmcm","space_group_number":63},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01114,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01114},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.062,"value_stored":0.5062},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-PECN3AZ3E3.e6d704","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":10},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.5,"GE":0.5},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.5,"GE":0.5},"composition_source":"printed","phase":"BaGe"}],"phases":[{"label":"BaGe","model_phase":"BAGE_B33"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r10#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oC8","prototype":"CrB","space_group":"Cmcm","space_group_number":63},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009462,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009462},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.301,"value_stored":0.4301},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-74F4T2AYW3.57a6ce","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":11},"observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.5,"GE":0.5},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.5,"GE":0.5},"composition_source":"printed","phase":"BaGe"}],"phases":[{"label":"BaGe","model_phase":"BAGE_B33"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oC8","prototype":"CrB","space_group":"Cmcm","space_group_number":63},"system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/X_PHASE","floor":0.02,"floor_unit":"mole fraction","value":0.02},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0431,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.0431},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.31,"value_stored":0.431},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-74F4T2AYW3.b27dcf","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":11},"observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.5,"GE":0.5},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.5,"GE":0.5},"composition_source":"printed","phase":"BaGe"}],"phases":[{"label":"BaGe","model_phase":"BAGE_B33"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oC8","prototype":"CrB","space_group":"Cmcm","space_group_number":63},"system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/X_PHASE","floor":0.02,"floor_unit":"mole fraction","value":0.02},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0507,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.0507},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.07,"value_stored":0.507},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-74F4T2AYW3.d1ccca","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":11},"observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.5,"GE":0.5},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.5,"GE":0.5},"composition_source":"printed","phase":"BaGe"}],"phases":[{"label":"BaGe","model_phase":"BAGE_B33"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r11#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oC8","prototype":"CrB","space_group":"Cmcm","space_group_number":63},"system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/X_PHASE","floor":0.02,"floor_unit":"mole fraction","value":0.02},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.12,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.12},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":11.995,"value_stored":1.1995},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-34LQRJQO3C.5d9fcb","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":12},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.429,"GE":0.571},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.429,"GE":0.571},"composition_source":"printed","phase":"α-Ba3Ge4"}],"phases":[{"label":"α-Ba3Ge4","model_phase":"BA3GE4_ALPHA"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oC56","prototype":"Ba3Ge4","space_group":"Cmmm","space_group_number":65},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0266,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0266},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":12.09,"value_stored":1.209},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-34LQRJQO3C.d799bb","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":12},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.429,"GE":0.571},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.429,"GE":0.571},"composition_source":"printed","phase":"α-Ba3Ge4"}],"phases":[{"label":"α-Ba3Ge4","model_phase":"BA3GE4_ALPHA"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oC56","prototype":"Ba3Ge4","space_group":"Cmmm","space_group_number":65},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02594,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02594},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":11.789,"value_stored":1.1789},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-34LQRJQO3C.e6830d","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":12},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.429,"GE":0.571},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.429,"GE":0.571},"composition_source":"printed","phase":"α-Ba3Ge4"}],"phases":[{"label":"α-Ba3Ge4","model_phase":"BA3GE4_ALPHA"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r12#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oC56","prototype":"Ba3Ge4","space_group":"Cmmm","space_group_number":65},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02683,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02683},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":12.197,"value_stored":1.2197},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1002/(sici)1521-3773(19981217)37:23<3314::aid-anie3314>3.0.co;2-l","first_author":"Zurcher","kind":"unknown","label":"34","paper":"doi:10.1002/(sici)1521-3773(19981217)37:23<3314::aid-anie3314>3.0.co;2-l","reference":"F. Zürcher and R. Nesper, Ba3Ge4: Polymerization of Zintl Anions in the Solid and Bond Stretching Isomerism, Angew. Chem. Int. Ed., 1998, 37, p 3314-3318","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-V4WCLOT36G.156d3e","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":13},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"BA":0.429,"GE":0.571},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.429,"GE":0.571},"composition_source":"printed","phase":"α-Ba3Ge4"}],"phases":[{"label":"α-Ba3Ge4","model_phase":"BA3GE4_ALPHA"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oC56","prototype":"Ba3Ge4","space_group":"Cmmm","space_group_number":65},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02596,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02596},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":11.799,"value_stored":1.1799},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1002/(sici)1521-3773(19981217)37:23<3314::aid-anie3314>3.0.co;2-l","first_author":"Zurcher","kind":"unknown","label":"34","paper":"doi:10.1002/(sici)1521-3773(19981217)37:23<3314::aid-anie3314>3.0.co;2-l","reference":"F. Zürcher and R. Nesper, Ba3Ge4: Polymerization of Zintl Anions in the Solid and Bond Stretching Isomerism, Angew. Chem. Int. Ed., 1998, 37, p 3314-3318","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-V4WCLOT36G.d0a7a5","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":13},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"BA":0.429,"GE":0.571},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.429,"GE":0.571},"composition_source":"printed","phase":"α-Ba3Ge4"}],"phases":[{"label":"α-Ba3Ge4","model_phase":"BA3GE4_ALPHA"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oC56","prototype":"Ba3Ge4","space_group":"Cmmm","space_group_number":65},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02686,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02686},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":12.21,"value_stored":1.221},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1002/(sici)1521-3773(19981217)37:23<3314::aid-anie3314>3.0.co;2-l","first_author":"Zurcher","kind":"unknown","label":"34","paper":"doi:10.1002/(sici)1521-3773(19981217)37:23<3314::aid-anie3314>3.0.co;2-l","reference":"F. Zürcher and R. Nesper, Ba3Ge4: Polymerization of Zintl Anions in the Solid and Bond Stretching Isomerism, Angew. Chem. Int. Ed., 1998, 37, p 3314-3318","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-V4WCLOT36G.e26f67","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":13},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"BA":0.429,"GE":0.571},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.429,"GE":0.571},"composition_source":"printed","phase":"α-Ba3Ge4"}],"phases":[{"label":"α-Ba3Ge4","model_phase":"BA3GE4_ALPHA"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r13#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oC56","prototype":"Ba3Ge4","space_group":"Cmmm","space_group_number":65},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02661,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02661},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":12.097,"value_stored":1.2097},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1002/(sici)1521-3773(19981217)37:23<3314::aid-anie3314>3.0.co;2-l","first_author":"Zurcher","kind":"unknown","label":"34","paper":"doi:10.1002/(sici)1521-3773(19981217)37:23<3314::aid-anie3314>3.0.co;2-l","reference":"F. Zürcher and R. Nesper, Ba3Ge4: Polymerization of Zintl Anions in the Solid and Bond Stretching Isomerism, Angew. Chem. Int. Ed., 1998, 37, p 3314-3318","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":3,"id":"ORC-HTZFWEJU2V.532a9b","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":14},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"BA":0.429,"GE":0.571},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.429,"GE":0.571},"composition_source":"printed","phase":"β-Ba3Ge4"}],"phases":[{"label":"β-Ba3Ge4","model_phase":"BA3GE4_BETA"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"tP28","prototype":"Ba3Si4","space_group":"P42/mnm","space_group_number":136},"system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01897,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01897},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.621,"value_stored":0.8621},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1002/(sici)1521-3773(19981217)37:23<3314::aid-anie3314>3.0.co;2-l","first_author":"Zurcher","kind":"unknown","label":"34","paper":"doi:10.1002/(sici)1521-3773(19981217)37:23<3314::aid-anie3314>3.0.co;2-l","reference":"F. Zürcher and R. Nesper, Ba3Ge4: Polymerization of Zintl Anions in the Solid and Bond Stretching Isomerism, Angew. Chem. Int. Ed., 1998, 37, p 3314-3318","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":3,"id":"ORC-HTZFWEJU2V.718f07","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":14},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"BA":0.429,"GE":0.571},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.429,"GE":0.571},"composition_source":"printed","phase":"β-Ba3Ge4"}],"phases":[{"label":"β-Ba3Ge4","model_phase":"BA3GE4_BETA"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"tP28","prototype":"Ba3Si4","space_group":"P42/mnm","space_group_number":136},"system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02647,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02647},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":12.031,"value_stored":1.2031},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1002/(sici)1521-3773(19981217)37:23<3314::aid-anie3314>3.0.co;2-l","first_author":"Zurcher","kind":"unknown","label":"34","paper":"doi:10.1002/(sici)1521-3773(19981217)37:23<3314::aid-anie3314>3.0.co;2-l","reference":"F. Zürcher and R. Nesper, Ba3Ge4: Polymerization of Zintl Anions in the Solid and Bond Stretching Isomerism, Angew. Chem. Int. Ed., 1998, 37, p 3314-3318","status":"resolved","year":"1998"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K_explicit","temperature not stated"],"state_fully_specified":false},"fold_lpo":1,"fold_lso":3,"id":"ORC-HTZFWEJU2V.ce7348","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":14},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"BA":0.429,"GE":0.571},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.429,"GE":0.571},"composition_source":"printed","phase":"β-Ba3Ge4"}],"phases":[{"label":"β-Ba3Ge4","model_phase":"BA3GE4_BETA"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r14#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"tP28","prototype":"Ba3Si4","space_group":"P42/mnm","space_group_number":136},"system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01897,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01897},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.621,"value_stored":0.8621},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-5QOADD7IMN.6ad101","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":15},"observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.429,"GE":0.571},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.429,"GE":0.571},"composition_source":"printed","phase":"β-Ba3Ge4"}],"phases":[{"label":"β-Ba3Ge4","model_phase":"BA3GE4_BETA"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"tP28","prototype":"Ba3Si4","space_group":"P42/mnm","space_group_number":136},"system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/X_PHASE","floor":0.02,"floor_unit":"mole fraction","value":0.02},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1214,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1214},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":12.137,"value_stored":1.2137},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-5QOADD7IMN.72027b","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":15},"observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.429,"GE":0.571},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.429,"GE":0.571},"composition_source":"printed","phase":"β-Ba3Ge4"}],"phases":[{"label":"β-Ba3Ge4","model_phase":"BA3GE4_BETA"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"tP28","prototype":"Ba3Si4","space_group":"P42/mnm","space_group_number":136},"system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/X_PHASE","floor":0.02,"floor_unit":"mole fraction","value":0.02},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0855,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.0855},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.55,"value_stored":0.855},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-5QOADD7IMN.ceae58","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":15},"observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.429,"GE":0.571},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.429,"GE":0.571},"composition_source":"printed","phase":"β-Ba3Ge4"}],"phases":[{"label":"β-Ba3Ge4","model_phase":"BA3GE4_BETA"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r15#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"tP28","prototype":"Ba3Si4","space_group":"P42/mnm","space_group_number":136},"system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/X_PHASE","floor":0.02,"floor_unit":"mole fraction","value":0.02},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0855,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.0855},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":8.55,"value_stored":0.855},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1515/znb-1977-1128","first_author":"Evers","kind":"unknown","label":"35","paper":"doi:10.1515/znb-1977-1128","reference":"J. Evers, G. Oehlinger, and A. Weiss, Kristallstruktur von Bariumdigermanid bei hohen Drücken/Crystal Structure of Bariumdigermanide at High Pressures, Zeitschrift für Naturforschung B, 1977, 32, p 1352-1353","status":"resolved","year":"1977"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-CH7PZJ54AN.3c7b04","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":16},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.333,"GE":0.667},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.333,"GE":0.667},"composition_source":"printed","phase":"BaGe2"}],"phases":[{"label":"BaGe2","model_phase":"BAGE2"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP24","prototype":"BaSi2","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01503,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01503},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.83,"value_stored":0.683},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1515/znb-1977-1128","first_author":"Evers","kind":"unknown","label":"35","paper":"doi:10.1515/znb-1977-1128","reference":"J. Evers, G. Oehlinger, and A. Weiss, Kristallstruktur von Bariumdigermanid bei hohen Drücken/Crystal Structure of Bariumdigermanide at High Pressures, Zeitschrift für Naturforschung B, 1977, 32, p 1352-1353","status":"resolved","year":"1977"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-CH7PZJ54AN.55bf02","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":16},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.333,"GE":0.667},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.333,"GE":0.667},"composition_source":"printed","phase":"BaGe2"}],"phases":[{"label":"BaGe2","model_phase":"BAGE2"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP24","prototype":"BaSi2","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01991,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01991},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":9.05,"value_stored":0.905},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1515/znb-1977-1128","first_author":"Evers","kind":"unknown","label":"35","paper":"doi:10.1515/znb-1977-1128","reference":"J. Evers, G. Oehlinger, and A. Weiss, Kristallstruktur von Bariumdigermanid bei hohen Drücken/Crystal Structure of Bariumdigermanide at High Pressures, Zeitschrift für Naturforschung B, 1977, 32, p 1352-1353","status":"resolved","year":"1977"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-CH7PZJ54AN.f0abd0","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":16},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.333,"GE":0.667},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.333,"GE":0.667},"composition_source":"printed","phase":"BaGe2"}],"phases":[{"label":"BaGe2","model_phase":"BAGE2"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r16#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP24","prototype":"BaSi2","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02563,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02563},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":11.65,"value_stored":1.165},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-DBVMVOO6GH.1b230c","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":17},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.333,"GE":0.667},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.333,"GE":0.667},"composition_source":"printed","phase":"BaGe2"}],"phases":[{"label":"BaGe2","model_phase":"BAGE2"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP24","prototype":"BaSi2","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01499,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01499},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.812,"value_stored":0.6812},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-DBVMVOO6GH.3095a1","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":17},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.333,"GE":0.667},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.333,"GE":0.667},"composition_source":"printed","phase":"BaGe2"}],"phases":[{"label":"BaGe2","model_phase":"BAGE2"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP24","prototype":"BaSi2","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02561,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.02561},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":11.642,"value_stored":1.1642},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-DBVMVOO6GH.3869eb","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":17},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.333,"GE":0.667},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.333,"GE":0.667},"composition_source":"printed","phase":"BaGe2"}],"phases":[{"label":"BaGe2","model_phase":"BAGE2"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r17#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP24","prototype":"BaSi2","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01997,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01997},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":9.076,"value_stored":0.9076},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-3GO6RRZAYD.6baf53","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":18},"observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.333,"GE":0.667},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.333,"GE":0.667},"composition_source":"printed","phase":"BaGe2"}],"phases":[{"label":"BaGe2","model_phase":"BAGE2"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r18#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP24","prototype":"BaSi2","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/X_PHASE","floor":0.02,"floor_unit":"mole fraction","value":0.02},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0915,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.0915},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":9.15,"value_stored":0.915},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-3GO6RRZAYD.874cc4","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":18},"observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.333,"GE":0.667},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.333,"GE":0.667},"composition_source":"printed","phase":"BaGe2"}],"phases":[{"label":"BaGe2","model_phase":"BAGE2"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r18#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP24","prototype":"BaSi2","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/X_PHASE","floor":0.02,"floor_unit":"mole fraction","value":0.02},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.1173,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.1173},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":11.73,"value_stored":1.173},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"dft","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-3GO6RRZAYD.9a4de9","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":18},"observation_type":"structural_property","origin":{"basis":"this_work_uncited_beside_cited_rows+title_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.333,"GE":0.667},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.333,"GE":0.667},"composition_source":"printed","phase":"BaGe2"}],"phases":[{"label":"BaGe2","model_phase":"BAGE2"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r18#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP24","prototype":"BaSi2","space_group":"Pnma","space_group_number":62},"system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.02,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/X_PHASE","floor":0.02,"floor_unit":"mole fraction","value":0.02},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0687,"sigma_method":{"basis":"prior","class":"dft","entry":"dft/priors/LATTICE_LENGTH","floor":0.01,"floor_unit":"relative (fraction of the value)","value":0.0687},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":6.87,"value_stored":0.687},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-ERMS75WMQ4.20d247","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":19},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.194,"GE":0.806},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.194,"GE":0.806},"composition_source":"printed","phase":"Ba6Ge25"}],"phases":[{"label":"Ba6Ge25","model_phase":"BA6GE25"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r19#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"cP124","prototype":"Ba6Ge25","space_group":"P4132","space_group_number":213},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03203,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03203},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":14.56,"value_stored":1.456},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-ERMS75WMQ4.c001ab","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":19},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.194,"GE":0.806},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.194,"GE":0.806},"composition_source":"printed","phase":"Ba6Ge25"}],"phases":[{"label":"Ba6Ge25","model_phase":"BA6GE25"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r19#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"cP124","prototype":"Ba6Ge25","space_group":"P4132","space_group_number":213},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03203,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03203},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":14.56,"value_stored":1.456},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-ERMS75WMQ4.f00fb2","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":19},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.194,"GE":0.806},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.194,"GE":0.806},"composition_source":"printed","phase":"Ba6Ge25"}],"phases":[{"label":"Ba6Ge25","model_phase":"BA6GE25"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r19#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"cP124","prototype":"Ba6Ge25","space_group":"P4132","space_group_number":213},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03203,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03203},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":14.56,"value_stored":1.456},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1006/jssc.2000.8632","first_author":"Fukuoka","kind":"unknown","label":"36","paper":"doi:10.1006/jssc.2000.8632","reference":"H. Fukuoka, K. Iwai, S. Yamanaka, H. Abe, K. Yoza, and L. Häming, Preparation and Structure of a New Germanium Clathrate, Ba24Ge100, J. Solid State Chem., 2000, 151, p 117-121","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-7FAXSNXF5A.9e1473","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":20},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.194,"GE":0.806},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.194,"GE":0.806},"composition_source":"printed","phase":"Ba6Ge25"}],"phases":[{"label":"Ba6Ge25","model_phase":"BA6GE25"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r20#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"cP124","prototype":"Ba6Ge25","space_group":"P4132","space_group_number":213},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03204,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03204},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":14.5635,"value_stored":1.45635},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1006/jssc.2000.8632","first_author":"Fukuoka","kind":"unknown","label":"36","paper":"doi:10.1006/jssc.2000.8632","reference":"H. Fukuoka, K. Iwai, S. Yamanaka, H. Abe, K. Yoza, and L. Häming, Preparation and Structure of a New Germanium Clathrate, Ba24Ge100, J. Solid State Chem., 2000, 151, p 117-121","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-7FAXSNXF5A.c66cf1","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":20},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.194,"GE":0.806},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.194,"GE":0.806},"composition_source":"printed","phase":"Ba6Ge25"}],"phases":[{"label":"Ba6Ge25","model_phase":"BA6GE25"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r20#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"cP124","prototype":"Ba6Ge25","space_group":"P4132","space_group_number":213},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03204,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03204},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":14.5635,"value_stored":1.45635},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1006/jssc.2000.8632","first_author":"Fukuoka","kind":"unknown","label":"36","paper":"doi:10.1006/jssc.2000.8632","reference":"H. Fukuoka, K. Iwai, S. Yamanaka, H. Abe, K. Yoza, and L. Häming, Preparation and Structure of a New Germanium Clathrate, Ba24Ge100, J. Solid State Chem., 2000, 151, p 117-121","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-7FAXSNXF5A.f9378c","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":20},"observation_type":"structural_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"overall_composition":{"BA":0.194,"GE":0.806},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.194,"GE":0.806},"composition_source":"printed","phase":"Ba6Ge25"}],"phases":[{"label":"Ba6Ge25","model_phase":"BA6GE25"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r20#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"cP124","prototype":"Ba6Ge25","space_group":"P4132","space_group_number":213},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03204,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03204},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":14.563,"value_stored":1.4563},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1515/ncrs-2000-0208","first_author":"Carrillo-Cabrera","kind":"unknown","label":"37","paper":"doi:10.1515/ncrs-2000-0208","reference":"W. Carrillo-Cabrera, J. Curda, H. Von Schnering, S. Paschen, and Y. Grin, Crystal Structure of Hexabarium Pentacosagermanide, Ba6Ge25, Zeitschrift für Kristallographie-New Crystal Structures, 2000, 215, p 207-208","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-HEWMM34FX5.39a394","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":21},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","measured_in":"doi:10.1515/ncrs-2000-0208","own_work_of_paper":false},"overall_composition":{"BA":0.194,"GE":0.806},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.194,"GE":0.806},"composition_source":"printed","phase":"Ba6Ge25"}],"phases":[{"label":"Ba6Ge25","model_phase":"BA6GE25"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"cP124","prototype":"Ba6Ge25","space_group":"P4132","space_group_number":213},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03202,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03202},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":14.556,"value_stored":1.4556},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1515/ncrs-2000-0208","first_author":"Carrillo-Cabrera","kind":"unknown","label":"37","paper":"doi:10.1515/ncrs-2000-0208","reference":"W. Carrillo-Cabrera, J. Curda, H. Von Schnering, S. Paschen, and Y. Grin, Crystal Structure of Hexabarium Pentacosagermanide, Ba6Ge25, Zeitschrift für Kristallographie-New Crystal Structures, 2000, 215, p 207-208","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-HEWMM34FX5.9b21ce","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":21},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","measured_in":"doi:10.1515/ncrs-2000-0208","own_work_of_paper":false},"overall_composition":{"BA":0.194,"GE":0.806},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.194,"GE":0.806},"composition_source":"printed","phase":"Ba6Ge25"}],"phases":[{"label":"Ba6Ge25","model_phase":"BA6GE25"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"cP124","prototype":"Ba6Ge25","space_group":"P4132","space_group_number":213},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03202,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03202},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":14.5564,"value_stored":1.45564},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1515/ncrs-2000-0208","first_author":"Carrillo-Cabrera","kind":"unknown","label":"37","paper":"doi:10.1515/ncrs-2000-0208","reference":"W. Carrillo-Cabrera, J. Curda, H. Von Schnering, S. Paschen, and Y. Grin, Crystal Structure of Hexabarium Pentacosagermanide, Ba6Ge25, Zeitschrift für Kristallographie-New Crystal Structures, 2000, 215, p 207-208","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-HEWMM34FX5.f3647d","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":21},"observation_type":"structural_property","origin":{"basis":"cited_work_title_experimental","class":"experimental","measured_in":"doi:10.1515/ncrs-2000-0208","own_work_of_paper":false},"overall_composition":{"BA":0.194,"GE":0.806},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.194,"GE":0.806},"composition_source":"printed","phase":"Ba6Ge25"}],"phases":[{"label":"Ba6Ge25","model_phase":"BA6GE25"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r21#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"cP124","prototype":"Ba6Ge25","space_group":"P4132","space_group_number":213},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03202,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03202},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":14.5564,"value_stored":1.45564},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1021/ja104197c","first_author":"Aydemir","kind":"unknown","label":"38","paper":"doi:10.1021/ja104197c","reference":"U. Aydemir, L. Akselrud, W. Carrillo-Cabrera, C. Candolfi, N. Oeschler, M. Baitinger, F. Steglich, and Y. Grin, BaGe5: A New 205 Type of Intermetallic Clathrate, J. Am. Chem. Soc. , 2010, 132, p 10984-10985","status":"resolved","year":"2010"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-QTMPS6DOSJ.5d58d6","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":22},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"BA":0.167,"GE":0.833},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.167,"GE":0.833},"composition_source":"printed","phase":"BaGe5"}],"phases":[{"label":"BaGe5"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r22#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP60","prototype":"BaGe5","space_group":"Pmna","space_group_number":53},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.2043,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.2043},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":92.844,"value_stored":9.2844},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1021/ja104197c","first_author":"Aydemir","kind":"unknown","label":"38","paper":"doi:10.1021/ja104197c","reference":"U. Aydemir, L. Akselrud, W. Carrillo-Cabrera, C. Candolfi, N. Oeschler, M. Baitinger, F. Steglich, and Y. Grin, BaGe5: A New 205 Type of Intermetallic Clathrate, J. Am. Chem. Soc. , 2010, 132, p 10984-10985","status":"resolved","year":"2010"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-QTMPS6DOSJ.c7c94a","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":22},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"BA":0.167,"GE":0.833},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.167,"GE":0.833},"composition_source":"printed","phase":"BaGe5"}],"phases":[{"label":"BaGe5"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r22#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP60","prototype":"BaGe5","space_group":"Pmna","space_group_number":53},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.0236,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.0236},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":10.727,"value_stored":1.0727},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1021/ja104197c","first_author":"Aydemir","kind":"unknown","label":"38","paper":"doi:10.1021/ja104197c","reference":"U. Aydemir, L. Akselrud, W. Carrillo-Cabrera, C. Candolfi, N. Oeschler, M. Baitinger, F. Steglich, and Y. Grin, BaGe5: A New 205 Type of Intermetallic Clathrate, J. Am. Chem. Soc. , 2010, 132, p 10984-10985","status":"resolved","year":"2010"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-QTMPS6DOSJ.de6eb8","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":22},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":{"BA":0.167,"GE":0.833},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.167,"GE":0.833},"composition_source":"printed","phase":"BaGe5"}],"phases":[{"label":"BaGe5"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r22#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"oP60","prototype":"BaGe5","space_group":"Pmna","space_group_number":53},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.03255,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.03255},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":14.794,"value_stored":1.4794},{"chemical_system":"BA-GE","cited_sources":[{"first_author":"Carrillo-Cabrera","kind":"unknown","label":"26","reference":"W. Carrillo-Cabrera, S. Budnyk, Y. Prots, and Y. Grin, Ba8Ge43 Revisited: A 2a0 9 2a0 9 2a0 Superstructure of the Clathrate-I, Type with Full Vacancy Ordering, Zeitschrift für Anorganische und Allgemeine Chemie, 2004, 630, p 2267-2276","status":"resolved","year":"2004"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-LC4D2HN6J6.08de06","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":23},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","measured_in":"ref:ce8f62686cee8142","own_work_of_paper":false},"overall_composition":{"BA":0.157,"GE":0.843},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.157,"GE":0.843},"composition_source":"printed","phase":"Ba8Ge43"}],"phases":[{"label":"Ba8Ge43","model_phase":"BA8GE43"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r23#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"cI408","prototype":"Ba8Ge43","space_group_number":230},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04689,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.04689},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":21.312,"value_stored":2.1312},{"chemical_system":"BA-GE","cited_sources":[{"first_author":"Carrillo-Cabrera","kind":"unknown","label":"26","reference":"W. Carrillo-Cabrera, S. Budnyk, Y. Prots, and Y. Grin, Ba8Ge43 Revisited: A 2a0 9 2a0 9 2a0 Superstructure of the Clathrate-I, Type with Full Vacancy Ordering, Zeitschrift für Anorganische und Allgemeine Chemie, 2004, 630, p 2267-2276","status":"resolved","year":"2004"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-LC4D2HN6J6.46035a","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":23},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","measured_in":"ref:ce8f62686cee8142","own_work_of_paper":false},"overall_composition":{"BA":0.157,"GE":0.843},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.157,"GE":0.843},"composition_source":"printed","phase":"Ba8Ge43"}],"phases":[{"label":"Ba8Ge43","model_phase":"BA8GE43"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r23#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"cI408","prototype":"Ba8Ge43","space_group_number":230},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04689,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.04689},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":21.312,"value_stored":2.1312},{"chemical_system":"BA-GE","cited_sources":[{"first_author":"Carrillo-Cabrera","kind":"unknown","label":"26","reference":"W. Carrillo-Cabrera, S. Budnyk, Y. Prots, and Y. Grin, Ba8Ge43 Revisited: A 2a0 9 2a0 9 2a0 Superstructure of the Clathrate-I, Type with Full Vacancy Ordering, Zeitschrift für Anorganische und Allgemeine Chemie, 2004, 630, p 2267-2276","status":"resolved","year":"2004"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-LC4D2HN6J6.d84a06","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":23},"observation_type":"structural_property","origin":{"basis":"cited_work_fulltext_experimental","class":"experimental","measured_in":"ref:ce8f62686cee8142","own_work_of_paper":false},"overall_composition":{"BA":0.157,"GE":0.843},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.157,"GE":0.843},"composition_source":"printed","phase":"Ba8Ge43"}],"phases":[{"label":"Ba8Ge43","model_phase":"BA8GE43"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r23#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"cI408","prototype":"Ba8Ge43","space_group_number":230},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04689,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.04689},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":21.312,"value_stored":2.1312},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-VKC4OU263U.06ff7b","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":24},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.157,"GE":0.843},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.157,"GE":0.843},"composition_source":"printed","phase":"Ba8Ge43"}],"phases":[{"label":"Ba8Ge43","model_phase":"BA8GE43"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r24#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_C","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"cI408","prototype":"Ba8Ge43","space_group_number":230},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04687,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.04687},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":21.303,"value_stored":2.1303},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-VKC4OU263U.bad0a5","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":24},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.157,"GE":0.843},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.157,"GE":0.843},"composition_source":"printed","phase":"Ba8Ge43"}],"phases":[{"label":"Ba8Ge43","model_phase":"BA8GE43"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r24#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"cI408","prototype":"Ba8Ge43","space_group_number":230},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04687,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.04687},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":21.303,"value_stored":2.1303},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"unknown","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-VKC4OU263U.bde161","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/tab-2","row":24},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1016/j.jallcom.2007.08.005","own_work_of_paper":false},"overall_composition":{"BA":0.157,"GE":0.843},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BA":0.157,"GE":0.843},"composition_source":"printed","phase":"Ba8Ge43"}],"phases":[{"label":"Ba8Ge43","model_phase":"BA8GE43"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/tab-2/r24#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_B","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BA-GE","structure":{"pearson_symbol":"cI408","prototype":"Ba8Ge43","space_group_number":230},"system":"BA-GE","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.04687,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.04687},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":21.303,"value_stored":2.1303},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.666667,"GE":0.333333},"phases":["Ba2Ge"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-E4PRNYQU4G.0ba88b","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":19},"merged_ids":["ORC-E4PRNYQU4G.626944"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.666667,"GE":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"Ba2Ge"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r19#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.50645},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-50.129,"value_printed":-50.129,"value_stored":-50129.0},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.666667,"GE":0.333333},"phases":["Ba2Ge"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-AD7FKKDWDQ.2cb5ae","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":20},"merged_ids":["ORC-AD7FKKDWDQ.cc16ef"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.666667,"GE":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"Ba2Ge"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r20#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.5565},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-51.13,"value_printed":-51.13,"value_stored":-51130.0},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.666667,"GE":0.333333},"phases":["Ba2Ge"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-AD7FKKDWDQ.95ee60","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":20},"merged_ids":["ORC-AD7FKKDWDQ.86d53e"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.666667,"GE":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"Ba2Ge"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r20#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔfS","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.0681},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J/K mol","value":-1.362,"value_printed":-1.362},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.625,"GE":0.375},"phases":["Ba5Ge3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-3FKAOF775C.2d17d3","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":21},"merged_ids":["ORC-3FKAOF775C.da8c7d"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.625,"GE":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"Ba5Ge3"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r21#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.844},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-56.88,"value_printed":-56.88,"value_stored":-56880.0},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.625,"GE":0.375},"phases":["Ba5Ge3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-6L3XPUMAAO.5ffb03","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":22},"merged_ids":["ORC-6L3XPUMAAO.88de10"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.625,"GE":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"Ba5Ge3"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r22#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔfS","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.21595},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J/K mol","value":-4.319,"value_printed":-4.319},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.625,"GE":0.375},"phases":["Ba5Ge3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-6L3XPUMAAO.a223b2","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":22},"merged_ids":["ORC-6L3XPUMAAO.22c649"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.625,"GE":0.375},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"Ba5Ge3"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r22#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.844},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-56.88,"value_printed":-56.88,"value_stored":-56880.0},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.5,"GE":0.5},"phases":["BaGe"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-XXNRUIHWKM.c5e50b","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":23},"merged_ids":["ORC-XXNRUIHWKM.2e4f50"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.5,"GE":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"BaGe"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r23#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.0157},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-60.314,"value_printed":-60.314,"value_stored":-60314.0},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.5,"GE":0.5},"phases":["BaGe"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-KIC7HKFFM3.954d25","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":24},"merged_ids":["ORC-KIC7HKFFM3.042449"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.5,"GE":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"BaGe"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r24#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.0031},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-60.062,"value_printed":-60.062,"value_stored":-60062.0},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.5,"GE":0.5},"phases":["BaGe"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-KIC7HKFFM3.a1d326","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":24},"merged_ids":["ORC-KIC7HKFFM3.297b4c"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.5,"GE":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"BaGe"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r24#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔfS","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.1303},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J/K mol","value":-2.606,"value_printed":-2.606},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.428571,"GE":0.571429},"phases":["α- Ba3Ge4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-K5N5YTUW44.3bce1e","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":25},"merged_ids":["ORC-K5N5YTUW44.7da5e5"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.428571,"GE":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"α- Ba3Ge4"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r25#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.9545},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-59.09,"value_printed":-59.09,"value_stored":-59090.0},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.428571,"GE":0.571429},"phases":["α- Ba3Ge4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-K5N5YTUW44.7e1acb","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":25},"merged_ids":["ORC-K5N5YTUW44.780262"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.428571,"GE":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"α- Ba3Ge4"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r25#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔfS","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.192095},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J/K mol","value":-3.8419,"value_printed":-3.8419},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.428571,"GE":0.571429},"phases":["β- Ba3Ge4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-UF4U7QDZNF.fb4051","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":26},"merged_ids":["ORC-UF4U7QDZNF.054e3c"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.428571,"GE":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"β- Ba3Ge4"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r26#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.91585},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-58.317,"value_printed":-58.317,"value_stored":-58317.0},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.428571,"GE":0.571429},"phases":["β- Ba3Ge4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-72LFN7QHIT.701dea","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":27},"merged_ids":["ORC-72LFN7QHIT.3e931b"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.428571,"GE":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"β- Ba3Ge4"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r27#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.92995},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-58.599,"value_printed":-58.599,"value_stored":-58599.0},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.428571,"GE":0.571429},"phases":["β- Ba3Ge4"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-72LFN7QHIT.e2217e","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":27},"merged_ids":["ORC-72LFN7QHIT.8f1076"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.428571,"GE":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"β- Ba3Ge4"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r27#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔfS","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.15205},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J/K mol","value":-3.041,"value_printed":-3.041},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.333333,"GE":0.666667},"phases":["BaGe2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"dft","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-CZAAGGQUO7.52f124","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":28},"merged_ids":["ORC-CZAAGGQUO7.e89efe"],"method":"Ab-initio","method_basis":"printed in the table row/column","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_first_principles","class":"computed","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.333333,"GE":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"BaGe2"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r28#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_K":0.0,"temperature_basis":"printed","temperature_printed":"0 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.70075},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":8.395,"sigma_method":{"basis":"calibrated","ci95":[6.672,9.877],"class":"dft","entry":"dft/literature/strata/metal","floor":8.395,"floor_unit":"kJ/mol-atom","n_pairs":230,"stratum":"literature/metal","value":8.395},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-54.015,"value_printed":-54.015,"value_stored":-54015.0},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.333333,"GE":0.666667},"phases":["BaGe2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-QED7ELYR7R.9a7453","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":29},"merged_ids":["ORC-QED7ELYR7R.606278"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.333333,"GE":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"BaGe2"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r29#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":2.70075},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-54.015,"value_printed":-54.015,"value_stored":-54015.0},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.333333,"GE":0.666667},"phases":["BaGe2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-QED7ELYR7R.b6ac3d","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":29},"merged_ids":["ORC-QED7ELYR7R.708a75"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.333333,"GE":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"BaGe2"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r29#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔfS","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.0813},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J/K mol","value":-1.626,"value_printed":-1.626},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.193548,"GE":0.806452},"phases":["Ba6Ge25"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-LA3ZLBCVUE.873a10","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":30},"merged_ids":["ORC-LA3ZLBCVUE.2bea9b"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.193548,"GE":0.806452},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"Ba6Ge25"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r30#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔfS","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.04695},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J/K mol","value":-0.939,"value_printed":-0.939},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.193548,"GE":0.806452},"phases":["Ba6Ge25"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-LA3ZLBCVUE.d6fe91","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":30},"merged_ids":["ORC-LA3ZLBCVUE.e82624"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.193548,"GE":0.806452},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"Ba6Ge25"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r30#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.59095},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-31.819,"value_printed":-31.819,"value_stored":-31819.0},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.156863,"GE":0.843137},"phases":["Ba8Ge43"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-TKN3H7ZIST.72dabb","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":31},"merged_ids":["ORC-TKN3H7ZIST.9886d4"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.156863,"GE":0.843137},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"Ba8Ge43"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r31#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔfS","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.17765},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.3,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"value":3.3},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"J/mol-atom/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol-atom/K","unit_basis":"magnitude_heuristic","unit_printed":"J/K mol","value":3.553,"value_printed":3.553},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BA-GE","before":"AL-BA-GE","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"BA":0.156863,"GE":0.843137},"phases":["Ba8Ge43"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-TKN3H7ZIST.91cea5","locator":{"ref":"sha256:41ca11e56c9eee28/p4/tab-3","row":31},"merged_ids":["ORC-TKN3H7ZIST.145926"],"method":"CALPHAD","method_basis":"printed in the table row/column","model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"overall_composition":{"BA":0.156863,"GE":0.843137},"overall_composition_basis":"from_formula","paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"Ba8Ge43"}],"pid":"sha256:41ca11e56c9eee28/p4/tab-3/r31#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔfH","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"reference_state_stored":{"AL":{"phase":"printed:none"},"BA":{"phase":"printed:none"},"GE":{"phase":"printed:none"}},"source_system":"AL-BA-GE","system":"BA-GE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.0599},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-21.198,"value_printed":-21.198,"value_stored":-21198.0},{"chemical_system":"BA-GE","cited_sources":[{"first_author":"Carrillo-Cabrera","kind":"experimental","label":"26","reference":"W. Carrillo-Cabrera, S. Budnyk, Y. Prots, and Y. Grin, Ba8Ge43 Revisited: A 2a0 9 2a0 9 2a0 Superstructure of the Clathrate-I, Type with Full Vacancy Ordering, Zeitschrift für Anorganische und Allgemeine Chemie, 2004, 630, p 2267-2276","status":"resolved","year":"2004"},{"doi":"10.1016/j.jssc.2004.11.011","first_author":"Carrillo-Cabrera","kind":"experimental","label":"27","paper":"doi:10.1016/j.jssc.2004.11.011","reference":"W. Carrillo-Cabrera, H. Borrmann, S. Paschen, M. Baenitz, F. Steglich, and Y. Grin, Ba6Ge25: Low-Temperature Ge-Ge Bond Breaking During Temperature-Induced Structure Transformation, J. Solid State Chem., 2005, 178, p 715-728","status":"resolved","year":"2005"},{"doi":"10.1515/ncrs-2000-0208","first_author":"Carrillo-Cabrera","kind":"unknown","label":"37","paper":"doi:10.1515/ncrs-2000-0208","reference":"W. Carrillo-Cabrera, J. Curda, H. Von Schnering, S. Paschen, and Y. Grin, Crystal Structure of Hexabarium Pentacosagermanide, Ba6Ge25, Zeitschrift für Kristallographie-New Crystal Structures, 2000, 215, p 207-208","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"GE":0.815},"before":{"GE":0.185},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.667},"before":{"GE":0.333},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[BaGe2]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.806},"before":{"GE":0.194},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba6Ge25]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"axis_header_contradicted":true,"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":1.302,"dx":{"Ba6Ge25":-0.6125,"BaGe2":-0.3337,"Liq":-0.6344},"fail_reason":"composition","model":"BaGe-19Ben.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-Z7G3C2KN7J","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":19},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:ce8f62686cee8142","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.815},"composition_source":"printed","composition_stored":{"GE":0.185},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.667},"composition_source":"printed","composition_stored":{"GE":0.333},"phase":"BaGe2"},{"basis":"mole_fraction","composition":{"GE":0.806},"composition_source":"printed","composition_stored":{"GE":0.194},"phase":"Ba6Ge25"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"BaGe2","mapping_confidence":"confirmed","model_phase":"BAGE2"},{"label":"Ba6Ge25","mapping_confidence":"confirmed","model_phase":"BA6GE25","pearson_symbol":"cP124","prototype":"K6Sn25","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r-unplaced-2c3b8b66#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + BaGe2 -> Ba6Ge25","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1088,"temperature_printed":"1088","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1088},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"experimental","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-A6RC3TNR6I","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":11},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2007.08.005","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.5},"composition_source":"printed","phase":"BaGe"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"BaGe","mapping_confidence":"confirmed","model_phase":"BAGE_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r-unplaced-4996ecd4#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Liq -> BaGe","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1253,"temperature_printed":"1253","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1253},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"experimental","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"GE":0.667},"before":{"GE":0.333},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.667},"before":{"GE":0.333},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[BaGe2]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"axis_header_contradicted":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-4BLCJL6M5D","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":17},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2007.08.005","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.667},"composition_source":"printed","composition_stored":{"GE":0.333},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.667},"composition_source":"printed","composition_stored":{"GE":0.333},"phase":"BaGe2"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"BaGe2","mapping_confidence":"confirmed","model_phase":"BAGE2"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r-unplaced-5672d155#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Liq -> BaGe2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1378,"temperature_printed":"1378","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1378},{"chemical_system":"BA-GE","cited_sources":[{"first_author":"Carrillo-Cabrera","kind":"experimental","label":"26","reference":"W. Carrillo-Cabrera, S. Budnyk, Y. Prots, and Y. Grin, Ba8Ge43 Revisited: A 2a0 9 2a0 9 2a0 Superstructure of the Clathrate-I, Type with Full Vacancy Ordering, Zeitschrift für Anorganische und Allgemeine Chemie, 2004, 630, p 2267-2276","status":"resolved","year":"2004"},{"doi":"10.1016/j.jssc.2004.11.011","first_author":"Carrillo-Cabrera","kind":"experimental","label":"27","paper":"doi:10.1016/j.jssc.2004.11.011","reference":"W. Carrillo-Cabrera, H. Borrmann, S. Paschen, M. Baenitz, F. Steglich, and Y. Grin, Ba6Ge25: Low-Temperature Ge-Ge Bond Breaking During Temperature-Induced Structure Transformation, J. Solid State Chem., 2005, 178, p 715-728","status":"resolved","year":"2005"},{"doi":"10.1515/ncrs-2000-0208","first_author":"Carrillo-Cabrera","kind":"unknown","label":"37","paper":"doi:10.1515/ncrs-2000-0208","reference":"W. Carrillo-Cabrera, J. Curda, H. Von Schnering, S. Paschen, and Y. Grin, Crystal Structure of Hexabarium Pentacosagermanide, Ba6Ge25, Zeitschrift für Kristallographie-New Crystal Structures, 2000, 215, p 207-208","status":"resolved","year":"2000"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"GE":0.826},"before":{"GE":0.174},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.806},"before":{"GE":0.194},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba6Ge25]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.843},"before":{"GE":0.157},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba8Ge43]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"axis_header_contradicted":true,"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-2.928,"dx":{"Ba6Ge25":-0.6125,"Ba8Ge43":-0.6861,"Liq":-0.6547},"fail_reason":"composition","model":"BaGe-19Ben.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-4VEHYMEQJH","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":21},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:ce8f62686cee8142","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.826},"composition_source":"printed","composition_stored":{"GE":0.174},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.806},"composition_source":"printed","composition_stored":{"GE":0.194},"phase":"Ba6Ge25"},{"basis":"mole_fraction","composition":{"GE":0.843},"composition_source":"printed","composition_stored":{"GE":0.157},"phase":"Ba8Ge43"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ba6Ge25","mapping_confidence":"confirmed","model_phase":"BA6GE25","pearson_symbol":"cP124","prototype":"K6Sn25","structure_basis":"mapped_model_phase"},{"label":"Ba8Ge43","mapping_confidence":"confirmed","model_phase":"BA8GE43","pearson_symbol":"cP54","prototype":"Na4Si23","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r-unplaced-761c2687#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> Ba6Ge25 + Ba8Ge43","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1081,"temperature_printed":"1081","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1081},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"experimental","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"GE":0.425},"before":{"GE":0.575},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.375},"before":{"GE":0.625},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba5Ge3]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"axis_header_contradicted":true,"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.405,"dx":{"Ba5Ge3":0.25,"BaGe":0.0,"Liq":0.1481},"fail_reason":"composition","model":"BaGe-19Ben.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-DU35YVQKNS","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":8},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2007.08.005","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.425},"composition_source":"printed","composition_stored":{"GE":0.575},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.375},"composition_source":"printed","composition_stored":{"GE":0.625},"phase":"Ba5Ge3"},{"basis":"mole_fraction","composition":{"GE":0.5},"composition_source":"printed","phase":"BaGe"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ba5Ge3","mapping_confidence":"confirmed","model_phase":"BA5GE3","pearson_symbol":"tP32","prototype":"Ba5Si3","structure_basis":"mapped_model_phase"},{"label":"BaGe","mapping_confidence":"confirmed","model_phase":"BAGE_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r-unplaced-a52da43a#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> Ba5Ge3 + BaGe","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1167,"temperature_printed":"1167","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1167},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"experimental","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"GE":0.569},"before":{"GE":0.431},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.667},"before":{"GE":0.333},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[BaGe2]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.571},"before":{"GE":0.429},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba3Ge4]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"axis_header_contradicted":true,"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-14.1,"dx":{"Ba3Ge4":-0.1424,"BaGe2":-0.3337,"Liq":-0.1305},"model":"BaGe-19Ben.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-DIJSZOOBJJ","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":15},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2007.08.005","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.569},"composition_source":"printed","composition_stored":{"GE":0.431},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.667},"composition_source":"printed","composition_stored":{"GE":0.333},"phase":"BaGe2"},{"basis":"mole_fraction","composition":{"GE":0.571},"composition_source":"printed","composition_stored":{"GE":0.429},"phase":"Ba3Ge4"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"BaGe2","mapping_confidence":"confirmed","model_phase":"BAGE2"},{"label":"Ba3Ge4","mapping_confidence":"proposed","model_phase":"BA3GE4_BETA"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r-unplaced-ab056dad#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + BaGe2 -> Ba3Ge4","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1188,"temperature_printed":"1188","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1188},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"experimental","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"GE":0.56},"before":{"GE":0.44},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.571},"before":{"GE":0.429},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[βBa3Ge4]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"axis_header_contradicted":true,"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-22.301,"dx":{"BaGe":0.0,"Liq":-0.1169,"βBa3Ge4":-0.1424},"model":"BaGe-19Ben.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-RRZ6QFN6R5","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":13},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2007.08.005","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.56},"composition_source":"printed","composition_stored":{"GE":0.44},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.571},"composition_source":"printed","composition_stored":{"GE":0.429},"phase":"βBa3Ge4"},{"basis":"mole_fraction","composition":{"GE":0.5},"composition_source":"printed","phase":"BaGe"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"βBa3Ge4","mapping_confidence":"confirmed","model_phase":"BA3GE4_BETA"},{"label":"BaGe","mapping_confidence":"confirmed","model_phase":"BAGE_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r-unplaced-cd294426#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> βBa3Ge4 + BaGe","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1178,"temperature_printed":"1178","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1178},{"chemical_system":"BA-GE","cited_sources":[{"first_author":"Andrianov","kind":"experimental","label":"24","reference":"V.G. Andrianov, K.A. Bolshakov, E.B. Sokolov, A.V. Chirkin, and P.I. Fedorov, Thermal Analysis of the Melting Diagram of the Germanium-Barium System, Russ. Inorg. Mater., 1966, 2, p 1784-1786","status":"resolved","year":"1966"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"GE":0.04},"before":{"GE":0.96},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.0},"before":{"GE":1.0},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.333},"before":{"GE":0.667},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba2Ge]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"axis_header_contradicted":true,"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-115.523,"dx":{"Ba2Ge":0.3337,"Liq":0.8438},"model":"BaGe-19Ben.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-LP4FZLQILO","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":1},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:fe0be0e3819a967e","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.04},"composition_source":"printed","composition_stored":{"GE":0.96},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.0},"composition_source":"printed","composition_stored":{"GE":1.0},"phase":"Ba"},{"basis":"mole_fraction","composition":{"GE":0.333},"composition_source":"printed","composition_stored":{"GE":0.667},"phase":"Ba2Ge"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ba","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"Ba2Ge","mapping_confidence":"confirmed","model_phase":"BA2GE_C37","pearson_symbol":"oP12","prototype":"Co2Si","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r-unplaced-d552abc9#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> Ba + Ba2Ge","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":818,"temperature_printed":"818","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":818},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"experimental","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"GE":0.333},"before":{"GE":0.667},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.333},"before":{"GE":0.667},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba2Ge]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"axis_header_contradicted":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-5EXF32IXPC","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":4},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2007.08.005","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.333},"composition_source":"printed","composition_stored":{"GE":0.667},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.333},"composition_source":"printed","composition_stored":{"GE":0.667},"phase":"Ba2Ge"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ba2Ge","mapping_confidence":"confirmed","model_phase":"BA2GE_C37","pearson_symbol":"oP12","prototype":"Co2Si","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r-unplaced-eb59a95c#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Liq -> Ba2Ge","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1273,"temperature_printed":"1273","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1273},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"experimental","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"GE":0.075},"before":{"GE":0.925},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.0},"before":{"GE":1.0},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.333},"before":{"GE":0.667},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba2Ge]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"axis_header_contradicted":true,"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-20.523,"dx":{"Ba2Ge":0.3337,"Liq":0.8088},"model":"BaGe-19Ben.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-5XGJHQLEHE","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":2},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2007.08.005","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.075},"composition_source":"printed","composition_stored":{"GE":0.925},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.0},"composition_source":"printed","composition_stored":{"GE":1.0},"phase":"Ba"},{"basis":"mole_fraction","composition":{"GE":0.333},"composition_source":"printed","composition_stored":{"GE":0.667},"phase":"Ba2Ge"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ba","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"Ba2Ge","mapping_confidence":"confirmed","model_phase":"BA2GE_C37","pearson_symbol":"oP12","prototype":"Co2Si","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r-unplaced-f0354ba3#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> Ba + Ba2Ge","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":913,"temperature_printed":"913","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":913},{"chemical_system":"BA-GE","cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"10","reference":"T.B. Massalski, O. Okamoto, ASM International, Binary Alloy Phase Diagrams, 2nd ed., ASM International, Materials Park, Ohio, 1990","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-HE6NROFXJE","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":10},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental_via_assessment","class":"experimental","measured_in":"ref:584fdc3ead7675c1","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.5},"composition_source":"printed","phase":"BaGe"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"BaGe","mapping_confidence":"confirmed","model_phase":"BAGE_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r-unplaced-f32ef892#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Liq -> BaGe","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1428,"temperature_printed":"1428","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1428},{"chemical_system":"BA-GE","cited_sources":[{"doi":"10.1016/j.jallcom.2007.08.005","first_author":"Pani","kind":"experimental","label":"29","paper":"doi:10.1016/j.jallcom.2007.08.005","reference":"M. Pani and A. Palenzona, The Phase Diagram of the Ba-Ge System, J. Alloys Compd., 2008, 462, p L9-L11","status":"resolved","year":"2008"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":{"GE":0.4},"before":{"GE":0.6},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.333},"before":{"GE":0.667},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba2Ge]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.375},"before":{"GE":0.625},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba5Ge3]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"experimental","flags":{"axis_header_contradicted":true,"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":19.485,"dx":{"Ba2Ge":0.3337,"Ba5Ge3":0.25,"Liq":0.1965},"model":"BaGe-19Ben.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-U7BGHSJE3U","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":6},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/j.jallcom.2007.08.005","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.4},"composition_source":"printed","composition_stored":{"GE":0.6},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.333},"composition_source":"printed","composition_stored":{"GE":0.667},"phase":"Ba2Ge"},{"basis":"mole_fraction","composition":{"GE":0.375},"composition_source":"printed","composition_stored":{"GE":0.625},"phase":"Ba5Ge3"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ba2Ge","mapping_confidence":"confirmed","model_phase":"BA2GE_C37","pearson_symbol":"oP12","prototype":"Co2Si","structure_basis":"mapped_model_phase"},{"label":"Ba5Ge3","mapping_confidence":"confirmed","model_phase":"BA5GE3","pearson_symbol":"tP32","prototype":"Ba5Si3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r-unplaced-fe40cf1a#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + Ba2Ge -> Ba5Ge3","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1213,"temperature_printed":"1213","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1213},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GE":0.115},"before":{"GE":0.885},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.0},"before":{"GE":1.0},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.333},"before":{"GE":0.667},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba2Ge]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"axis_header_contradicted":true,"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":1.267,"dx":{"Ba2Ge":0.3337,"Liq":0.7688},"fail_reason":"composition","model":"BaGe-19Ben.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-JYUBNXMAFZ","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":3},"model":"M093d74e5","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.115},"composition_source":"printed","composition_stored":{"GE":0.885},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.0},"composition_source":"printed","composition_stored":{"GE":1.0},"phase":"Ba"},{"basis":"mole_fraction","composition":{"GE":0.333},"composition_source":"printed","composition_stored":{"GE":0.667},"phase":"Ba2Ge"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ba","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"Ba2Ge","mapping_confidence":"confirmed","model_phase":"BA2GE_C37","pearson_symbol":"oP12","prototype":"Co2Si","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r03#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> Ba + Ba2Ge","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":934.79,"temperature_printed":"934.79","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":934.79},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GE":0.333},"before":{"GE":0.667},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.333},"before":{"GE":0.667},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba2Ge]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"axis_header_contradicted":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-YQZTENSMF6","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":5},"model":"M093d74e5","observation_type":"phase_transition","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.333},"composition_source":"printed","composition_stored":{"GE":0.667},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.333},"composition_source":"printed","composition_stored":{"GE":0.667},"phase":"Ba2Ge"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ba2Ge","mapping_confidence":"confirmed","model_phase":"BA2GE_C37","pearson_symbol":"oP12","prototype":"Co2Si","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r05#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Liq -> Ba2Ge","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1273.2,"temperature_printed":"1273.20","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1273.2},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GE":0.4042},"before":{"GE":0.5958},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.333},"before":{"GE":0.667},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba2Ge]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.375},"before":{"GE":0.625},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba5Ge3]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"axis_header_contradicted":true,"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.605,"dx":{"Ba2Ge":0.3337,"Ba5Ge3":0.25,"Liq":0.1923},"fail_reason":"composition","model":"BaGe-19Ben.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-FHFNUSWTFZ","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":7},"model":"M093d74e5","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.4042},"composition_source":"printed","composition_stored":{"GE":0.5958},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.333},"composition_source":"printed","composition_stored":{"GE":0.667},"phase":"Ba2Ge"},{"basis":"mole_fraction","composition":{"GE":0.375},"composition_source":"printed","composition_stored":{"GE":0.625},"phase":"Ba5Ge3"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ba2Ge","mapping_confidence":"confirmed","model_phase":"BA2GE_C37","pearson_symbol":"oP12","prototype":"Co2Si","structure_basis":"mapped_model_phase"},{"label":"Ba5Ge3","mapping_confidence":"confirmed","model_phase":"BA5GE3","pearson_symbol":"tP32","prototype":"Ba5Si3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r07#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + Ba2Ge -> Ba5Ge3","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1192.91,"temperature_printed":"1192.91","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1192.91},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GE":0.427},"before":{"GE":0.573},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.375},"before":{"GE":0.625},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba5Ge3]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"axis_header_contradicted":true,"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.595,"dx":{"Ba5Ge3":0.25,"BaGe":0.0,"Liq":0.1461},"fail_reason":"composition","model":"BaGe-19Ben.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-NJVNZIL3L6","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":9},"model":"M093d74e5","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.427},"composition_source":"printed","composition_stored":{"GE":0.573},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.375},"composition_source":"printed","composition_stored":{"GE":0.625},"phase":"Ba5Ge3"},{"basis":"mole_fraction","composition":{"GE":0.5},"composition_source":"printed","phase":"BaGe"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ba5Ge3","mapping_confidence":"confirmed","model_phase":"BA5GE3","pearson_symbol":"tP32","prototype":"Ba5Si3","structure_basis":"mapped_model_phase"},{"label":"BaGe","mapping_confidence":"confirmed","model_phase":"BAGE_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r09#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> Ba5Ge3 + BaGe","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1168,"temperature_printed":"1168","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1168},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-RGXOMOPKE7","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":12},"model":"M093d74e5","observation_type":"phase_transition","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5},"composition_source":"printed","phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.5},"composition_source":"printed","phase":"BaGe"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"BaGe","mapping_confidence":"confirmed","model_phase":"BAGE_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r11#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Liq -> BaGe","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1253,"temperature_printed":"1253","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1253},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GE":0.5569},"before":{"GE":0.4431},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.571},"before":{"GE":0.429},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[βBa3Ge4]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"axis_header_contradicted":true,"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-1.301,"dx":{"BaGe":0.0,"Liq":-0.1138,"βBa3Ge4":-0.1424},"fail_reason":"composition","model":"BaGe-19Ben.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-BZ5SGU6D2Y","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":14},"model":"M093d74e5","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5569},"composition_source":"printed","composition_stored":{"GE":0.4431},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.571},"composition_source":"printed","composition_stored":{"GE":0.429},"phase":"βBa3Ge4"},{"basis":"mole_fraction","composition":{"GE":0.5},"composition_source":"printed","phase":"BaGe"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"βBa3Ge4","mapping_confidence":"confirmed","model_phase":"BA3GE4_BETA"},{"label":"BaGe","mapping_confidence":"confirmed","model_phase":"BAGE_B33","pearson_symbol":"oC8","prototype":"CrB","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r14#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> βBa3Ge4 + BaGe","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1199,"temperature_printed":"1199","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1199},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GE":0.5611},"before":{"GE":0.4389},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.667},"before":{"GE":0.333},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[BaGe2]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.571},"before":{"GE":0.429},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba3Ge4]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"axis_header_contradicted":true,"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-1.1,"dx":{"Ba3Ge4":-0.1424,"BaGe2":-0.3337,"Liq":-0.1226},"fail_reason":"composition","model":"BaGe-19Ben.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-K4MYMX57MV","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":16},"model":"M093d74e5","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.5611},"composition_source":"printed","composition_stored":{"GE":0.4389},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.667},"composition_source":"printed","composition_stored":{"GE":0.333},"phase":"BaGe2"},{"basis":"mole_fraction","composition":{"GE":0.571},"composition_source":"printed","composition_stored":{"GE":0.429},"phase":"Ba3Ge4"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"BaGe2","mapping_confidence":"confirmed","model_phase":"BAGE2"},{"label":"Ba3Ge4","mapping_confidence":"proposed","model_phase":"BA3GE4_BETA"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r16#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + BaGe2 -> Ba3Ge4","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1201,"temperature_printed":"1201","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1201},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GE":0.667},"before":{"GE":0.333},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.667},"before":{"GE":0.333},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[BaGe2]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"axis_header_contradicted":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-IOZ35MB44R","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":18},"model":"Mb3b72003","observation_type":"phase_transition","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.667},"composition_source":"printed","composition_stored":{"GE":0.333},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.667},"composition_source":"printed","composition_stored":{"GE":0.333},"phase":"BaGe2"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"BaGe2","mapping_confidence":"confirmed","model_phase":"BAGE2"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r18#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Liq -> BaGe2","type":"congruent melting"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1378.69,"temperature_printed":"1378.69","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"congruent melting","transition_kind_printed":"Congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1378.69},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GE":0.821},"before":{"GE":0.179},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.667},"before":{"GE":0.333},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[BaGe2]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.806},"before":{"GE":0.194},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba6Ge25]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"axis_header_contradicted":true,"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-3.918,"dx":{"Ba6Ge25":-0.6125,"BaGe2":-0.3337,"Liq":-0.6404},"fail_reason":"composition","model":"BaGe-19Ben.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-WRACHZHTYB","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":20},"model":"M093d74e5","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.821},"composition_source":"printed","composition_stored":{"GE":0.179},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.667},"composition_source":"printed","composition_stored":{"GE":0.333},"phase":"BaGe2"},{"basis":"mole_fraction","composition":{"GE":0.806},"composition_source":"printed","composition_stored":{"GE":0.194},"phase":"Ba6Ge25"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"BaGe2","mapping_confidence":"confirmed","model_phase":"BAGE2"},{"label":"Ba6Ge25","mapping_confidence":"confirmed","model_phase":"BA6GE25","pearson_symbol":"cP124","prototype":"K6Sn25","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r20#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq + BaGe2 -> Ba6Ge25","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1082.78,"temperature_printed":"1082.78","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1082.78},{"chemical_system":"BA-GE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":{"GE":0.8252},"before":{"GE":0.1748},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Liq]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.806},"before":{"GE":0.194},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba6Ge25]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}},{"after":{"GE":0.843},"before":{"GE":0.157},"evidence":{"fits":{"rev":30},"printed_header_element":"Ge"},"field":"phase_compositions[Ba8Ge43]","gate":"A1","rule":"composition_axis_from_terminal_and_stoichiometric_phases","visual_check":{"checked":"2026-10-24","image_sha256":"0baa3a4e5c3585f61bb69ebd8aa6cca32542065a4d126f6db5171d9751f2990d","page":9,"pdf_sha256_prefix":"41ca11e56c9eee28","seen":"p9 (printed 203) Table 7 Ba-Ge header 'Compositions of the respective phases, at.% Ba' but Ba is printed at 0, Ba2Ge at 33.3, BaGe2 66.7, Ba8Ge43 84.3: the values are at.% Ge; the header names the wrong element.","verdict":"confirmed"}}],"evidence_class":"model","flags":{"axis_header_contradicted":true,"calphad_check":"disagrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-2.298,"dx":{"Ba6Ge25":-0.6125,"Ba8Ge43":-0.6861,"Liq":-0.6539},"fail_reason":"composition","model":"BaGe-19Ben.tdb","result":"fail","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-A2DJR6I2FH","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p9/tab-7","row":22},"model":"M093d74e5","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1007/s11669-019-00714-2","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phase_compositions":[{"basis":"mole_fraction","composition":{"GE":0.8252},"composition_source":"printed","composition_stored":{"GE":0.1748},"phase":"Liq"},{"basis":"mole_fraction","composition":{"GE":0.806},"composition_source":"printed","composition_stored":{"GE":0.194},"phase":"Ba6Ge25"},{"basis":"mole_fraction","composition":{"GE":0.843},"composition_source":"printed","composition_stored":{"GE":0.157},"phase":"Ba8Ge43"}],"phases":[{"label":"Liq","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ba6Ge25","mapping_confidence":"confirmed","model_phase":"BA6GE25","pearson_symbol":"cP124","prototype":"K6Sn25","structure_basis":"mapped_model_phase"},{"label":"Ba8Ge43","mapping_confidence":"confirmed","model_phase":"BA8GE43","pearson_symbol":"cP54","prototype":"Na4Si23","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1007/s11669-019-00714-2/p9/tab-7/r22#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liq -> Ba6Ge25 + Ba8Ge43","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BA-GE","system":"BA-GE","temperature_K":1081.63,"temperature_printed":"1081.63","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1081.63},{"chemical_system":"BA-GE","citations_printed":["10"],"cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"10","reference":"T.B. Massalski, O. Okamoto, ASM International, Binary Alloy Phase Diagrams, 2nd ed., ASM International, Materials Park, Ohio, 1990","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_rule_count_mismatch"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"phase_rule_count_mismatch","detail":"peritectic with 1 phase(s) recorded","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-DNTZV6OYGL.514e50","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-02"},"observation_type":"phase_transition","origin":{"class":"model_value","measured_in":"ref:584fdc3ead7675c1","own_work_of_paper":false},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"BaGe4"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/text-02/s01#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"This diagram presents four intermetallic compounds: BaGe melting congruently at 1428 K, while the Ba2Ge, BaGe2 and BaGe4 are formed by peritectic reactions at 1228, 1323 and 1088 K successively.","quote_page":3,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":1088.0,"temperature_printed":"1088 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1088.0},{"chemical_system":"BA-GE","citations_printed":["10"],"cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"10","reference":"T.B. Massalski, O. Okamoto, ASM International, Binary Alloy Phase Diagrams, 2nd ed., ASM International, Materials Park, Ohio, 1990","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-DNTZV6OYGL.627cdf","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-02"},"observation_type":"phase_transition","origin":{"class":"model_value","measured_in":"ref:584fdc3ead7675c1","own_work_of_paper":false},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"BaGe"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/text-02/s01#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"This diagram presents four intermetallic compounds: BaGe melting congruently at 1428 K, while the Ba2Ge, BaGe2 and BaGe4 are formed by peritectic reactions at 1228, 1323 and 1088 K successively.","quote_page":3,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":1428.0,"temperature_printed":"1428 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1428.0},{"chemical_system":"BA-GE","citations_printed":["10"],"cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"10","reference":"T.B. Massalski, O. Okamoto, ASM International, Binary Alloy Phase Diagrams, 2nd ed., ASM International, Materials Park, Ohio, 1990","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_rule_count_mismatch"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"phase_rule_count_mismatch","detail":"peritectic with 1 phase(s) recorded","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-DNTZV6OYGL.8f65c8","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-02"},"observation_type":"phase_transition","origin":{"class":"model_value","measured_in":"ref:584fdc3ead7675c1","own_work_of_paper":false},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"Ba2Ge"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/text-02/s01#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"This diagram presents four intermetallic compounds: BaGe melting congruently at 1428 K, while the Ba2Ge, BaGe2 and BaGe4 are formed by peritectic reactions at 1228, 1323 and 1088 K successively.","quote_page":3,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":1228.0,"temperature_printed":"1228 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1228.0},{"chemical_system":"BA-GE","citations_printed":["10"],"cited_sources":[{"first_author":"Massalski","kind":"assessment","label":"10","reference":"T.B. Massalski, O. Okamoto, ASM International, Binary Alloy Phase Diagrams, 2nd ed., ASM International, Materials Park, Ohio, 1990","status":"resolved","year":"1990"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_rule_count_mismatch"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"phase_rule_count_mismatch","detail":"peritectic with 1 phase(s) recorded","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-DNTZV6OYGL.92ddfc","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-02"},"observation_type":"phase_transition","origin":{"class":"model_value","measured_in":"ref:584fdc3ead7675c1","own_work_of_paper":false},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"BaGe2"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/text-02/s01#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"This diagram presents four intermetallic compounds: BaGe melting congruently at 1428 K, while the Ba2Ge, BaGe2 and BaGe4 are formed by peritectic reactions at 1228, 1323 and 1088 K successively.","quote_page":3,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":1323.0,"temperature_printed":"1323 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1323.0},{"chemical_system":"BA-GE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-019-00714-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-53CX2X3IRL.342740","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-02"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","pid":"doi:10.1007/s11669-019-00714-2/p3/text-02/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Two eutectic reactions occur at the compositions of 4 at.% Ge at 838 K and 84 at.% Ge at 1043 K.","quote_page":3,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":1043.0,"temperature_printed":"1043 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1043.0},{"chemical_system":"BA-GE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-019-00714-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":3,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-53CX2X3IRL.9b2210","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-02"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","pid":"doi:10.1007/s11669-019-00714-2/p3/text-02/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Two eutectic reactions occur at the compositions of 4 at.% Ge at 838 K and 84 at.% Ge at 1043 K.","quote_page":3,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":838.0,"temperature_printed":"838 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":838.0},{"chemical_system":"BA-GE","citations_printed":["26","27"],"cited_sources":[{"first_author":"Carrillo-Cabrera","kind":"unknown","label":"26","reference":"W. Carrillo-Cabrera, S. Budnyk, Y. Prots, and Y. Grin, Ba8Ge43 Revisited: A 2a0 9 2a0 9 2a0 Superstructure of the Clathrate-I, Type with Full Vacancy Ordering, Zeitschrift für Anorganische und Allgemeine Chemie, 2004, 630, p 2267-2276","status":"resolved","year":"2004"},{"doi":"10.1016/j.jssc.2004.11.011","first_author":"Carrillo-Cabrera","kind":"unknown","label":"27","paper":"doi:10.1016/j.jssc.2004.11.011","reference":"W. Carrillo-Cabrera, H. Borrmann, S. Paschen, M. Baenitz, F. Steglich, and Y. Grin, Ba6Ge25: Low-Temperature Ge-Ge Bond Breaking During Temperature-Induced Structure Transformation, J. Solid State Chem., 2005, 178, p 715-728","status":"resolved","year":"2005"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"review_state":"proposed","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-UYQNPESSI4","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-02"},"observation_type":"phase_transition","origin":{"class":"experimental","measured_in":"ref:ce8f62686cee8142","own_work_of_paper":false},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"Ba8Ge43"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/text-02/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Later Carrillo-Cabrera et al.[26,27] determined the partial phase diagram between 75 and 100 at.% Ge and confirmed the existence of two new compounds in the germaniumrich part: Ba8Ge43 which is stable only between 1043 and 1083 K, where it formed peritectically, and BaGe5 stable in the temperature range of 881 and 723 K.","quote_page":3,"reaction":{"type":"peritectic"},"reader_agreement":"single_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":1083.0,"temperature_printed":"1083 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1083.0},{"chemical_system":"BA-GE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-019-00714-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-OCSB4T3G3A","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-02"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","pid":"doi:10.1007/s11669-019-00714-2/p3/text-02/s04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"According to this study, there is an eutectic reaction at 1081 K and 82.5 at.% Ge and the compound BaGe4 is designed as Ba6Ge25.","quote_page":3,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":1081.0,"temperature_printed":"1081 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1081.0},{"chemical_system":"BA-GE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-019-00714-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_rule_count_mismatch"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"phase_rule_count_mismatch","detail":"peritectic with 1 phase(s) recorded","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-FY7TE3CJZJ.298030","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-04"},"method":"DTA","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"Ba5Ge3"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/text-04/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Two new compounds were observed: Ba5Ge3, peritectically formed at 1213 K and dimorphic Ba3Ge4, melting by peritectic reaction at 1188 K and transformed to low temperature form at about 613 K.","quote_page":3,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":1213.0,"temperature_printed":"1213 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"thermal_analysis","entry":"value_types/T_INVARIANT/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1213.0},{"chemical_system":"BA-GE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-019-00714-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["phase_rule_count_mismatch"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"phase_rule_count_mismatch","detail":"peritectic with 1 phase(s) recorded","effect":"not_espei_ready","gate":"R3I"}],"id":"ORC-FY7TE3CJZJ.d23afc","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-04"},"method":"DTA","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"Ba3Ge4"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/text-04/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Two new compounds were observed: Ba5Ge3, peritectically formed at 1213 K and dimorphic Ba3Ge4, melting by peritectic reaction at 1188 K and transformed to low temperature form at about 613 K.","quote_page":3,"reaction":{"type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":1188.0,"temperature_printed":"1188 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"thermal_analysis","entry":"value_types/T_INVARIANT/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1188.0},{"chemical_system":"BA-GE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-019-00714-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":4,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-FY7TE3CJZJ.fe167b","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-04"},"method":"DTA","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"Ba3Ge4"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/text-04/s02#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Two new compounds were observed: Ba5Ge3, peritectically formed at 1213 K and dimorphic Ba3Ge4, melting by peritectic reaction at 1188 K and transformed to low temperature form at about 613 K.","quote_page":3,"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":613.0,"temperature_printed":"613 K","tool_release":"release v2 + tools dev copy record build","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"cleaned_below_threshold","ci95":[2.096713,58.183787],"class":"thermal_analysis","entry":"value_types/T_TRANSITION/classes/thermal_analysis","floor":5.0,"floor_unit":"K","n_pairs":9,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":613.0},{"chemical_system":"BA-GE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-019-00714-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-A3F7OBH4FA.05f840","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-04"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"Ba2Ge"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/text-04/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Three congruently melting points were determined at 1273 K for Ba2Ge, 1253 K for BaGe and 1378 K for BaGe2.","quote_page":3,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":1273.0,"temperature_printed":"1273 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1273.0},{"chemical_system":"BA-GE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-019-00714-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-A3F7OBH4FA.2e9df3","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-04"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"BaGe2"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/text-04/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Three congruently melting points were determined at 1273 K for Ba2Ge, 1253 K for BaGe and 1378 K for BaGe2.","quote_page":3,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":1378.0,"temperature_printed":"1378 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1378.0},{"chemical_system":"BA-GE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-019-00714-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-A3F7OBH4FA.60c483","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-04"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","phases":[{"label":"BaGe"}],"pid":"doi:10.1007/s11669-019-00714-2/p3/text-04/s03#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Three congruently melting points were determined at 1273 K for Ba2Ge, 1253 K for BaGe and 1378 K for BaGe2.","quote_page":3,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":1253.0,"temperature_printed":"1253 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1253.0},{"chemical_system":"BA-GE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-019-00714-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-WGCA4QD3KF.47220c","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-04"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","pid":"doi:10.1007/s11669-019-00714-2/p3/text-04/s04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Four eutectics points occur at the compositions of about 7.5, 42.5, 56, 82.5 at.% Ge and temperatures of 913, 1168, 1178 and 1081 K respectively.","quote_page":3,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":1178.0,"temperature_printed":"1178 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1178.0},{"chemical_system":"BA-GE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-019-00714-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-WGCA4QD3KF.5c7ee4","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-04"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","pid":"doi:10.1007/s11669-019-00714-2/p3/text-04/s04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Four eutectics points occur at the compositions of about 7.5, 42.5, 56, 82.5 at.% Ge and temperatures of 913, 1168, 1178 and 1081 K respectively.","quote_page":3,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":1081.0,"temperature_printed":"1081 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1081.0},{"chemical_system":"BA-GE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-019-00714-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-WGCA4QD3KF.d0e9c9","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-04"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","pid":"doi:10.1007/s11669-019-00714-2/p3/text-04/s04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Four eutectics points occur at the compositions of about 7.5, 42.5, 56, 82.5 at.% Ge and temperatures of 913, 1168, 1178 and 1081 K respectively.","quote_page":3,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":1168.0,"temperature_printed":"1168 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1168.0},{"chemical_system":"BA-GE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1007/s11669-019-00714-2"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":2,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-WGCA4QD3KF.f191dd","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1007/s11669-019-00714-2/p3/text-04"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1007/s11669-019-00714-2","own_work_of_paper":true},"paper":"doi:10.1007/s11669-019-00714-2","paper_id":"doi:10.1007/s11669-019-00714-2","pid":"doi:10.1007/s11669-019-00714-2/p3/text-04/s04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Four eutectics points occur at the compositions of about 7.5, 42.5, 56, 82.5 at.% Ge and temperatures of 913, 1168, 1178 and 1081 K respectively.","quote_page":3,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BA-GE","system":"BA-GE","temperature_K":913.0,"temperature_printed":"913 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":913.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"BA-GE"}