{"artifacts":{"doi:10.1016/j.calphad.2012.05.004/p2/text-55":{"artifact":"text_passage","label":"page 2, passage 55","page":2},"doi:10.1016/j.calphad.2012.05.004/p4/tab-3":{"artifact":"table","caption":"Invariant reactions in binary Ce–Bi system: comparison between calculation and experimental.","label":"3","page":4},"doi:10.1016/j.calphad.2012.05.004/p6/tab-6":{"artifact":"table","caption":"Comparison of experiment and prediction by Liu et al. [18] models on IMC formation in the diffusion couple Fe-45 at%–Ce/Bi at 773 K.","label":"6","page":6},"doi:10.1016/j.jnucmat.2017.08.016/p3/text-02":{"artifact":"text_passage","label":"page 3, passage 2","page":3},"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3":{"artifact":"table","caption":"Invariant reactions in the Bi-Ce binary system.","label":"3","page":5},"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8":{"artifact":"table","caption":"Enthalpies of formation of the intermetallic compounds in the Bi-Ce system.","label":"8","page":6},"doi:10.1016/j.jnucmat.2017.08.016/p8/tab-11":{"artifact":"table","caption":"Comparison between the calculated activity coefﬁcients and literature values for the Bi-Ce system.","label":"11","page":8},"sha256:414670b8925c12d6/p7/tab-10":{"artifact":"table","caption":"Entropies of formation of intermetallic compounds for the Bi-Pr, Bi-Ce, and Bi-Er systems.","label":"10","page":7}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["BI","CE"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"M4a9cfab6":{"catalog_entry":{"license":"CC BY 4.0","name":"BiCe-12Li.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model (TDB header cites this paper)","model_citation":"Calphad, 38, 133-39(2012).","model_doi":"10.1016/j.calphad.2012.05.004","tdb":"BiCe-12Li.tdb","tdb_path":"databases/sgte-binary/BiCe-12Li.tdb","tdb_sha256":"a261b33b47f12b953e299f768bc804c48f9b28e66d7c2eb6d4212cdfecdd1434"},"M6076368a":{"catalog_entry":{"license":"CC BY 4.0","name":"BiCe-12Li.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"Calphad, 38, 133-39(2012).","model_doi":"10.1016/j.calphad.2012.05.004","reproduced_by_calculation":true,"tdb":"BiCe-12Li.tdb","tdb_path":"databases/sgte-binary/BiCe-12Li.tdb","tdb_sha256":"a261b33b47f12b953e299f768bc804c48f9b28e66d7c2eb6d4212cdfecdd1434"},"M6766fe15":{"catalog_entry":{"license":"CC BY 4.0","name":"BiCe-17Wan.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"Y. Wang, W. Zhou, S. Guo, J. Zhang, J. Nucl. Mater., 495, 181-91(2017).","model_doi":"10.1016/j.jnucmat.2017.08.016","reproduced_by_calculation":false,"tdb":"BiCe-17Wan.tdb","tdb_path":"databases/sgte-binary/BiCe-17Wan.tdb","tdb_sha256":"7b39a0f2a6bf4ab9f62ea2fc41e258ef69c8b61339030b7acdb9dfa90e45a06c"},"Ma528ecd8":{"catalog_entry":{"license":"CC BY 4.0","name":"BiCe-12Li.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"Calphad, 38, 133-39(2012).","model_doi":"10.1016/j.calphad.2012.05.004","reproduced_by_calculation":false,"tdb":"BiCe-12Li.tdb","tdb_path":"databases/sgte-binary/BiCe-12Li.tdb","tdb_sha256":"a261b33b47f12b953e299f768bc804c48f9b28e66d7c2eb6d4212cdfecdd1434"},"Md30dd759":{"catalog_entry":{"license":"CC BY 4.0","name":"BiCe-17Wan.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"Y. Wang, W. Zhou, S. Guo, J. Zhang, J. Nucl. Mater., 495, 181-91(2017).","model_doi":"10.1016/j.jnucmat.2017.08.016","reproduced_by_calculation":true,"tdb":"BiCe-17Wan.tdb","tdb_path":"databases/sgte-binary/BiCe-17Wan.tdb","tdb_sha256":"7b39a0f2a6bf4ab9f62ea2fc41e258ef69c8b61339030b7acdb9dfa90e45a06c"},"Mf6b3e4df":{"catalog_entry":{"license":"CC BY 4.0","name":"BiCe-17Wan.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model (TDB header cites this paper)","model_citation":"Y. Wang, W. Zhou, S. Guo, J. Zhang, J. Nucl. Mater., 495, 181-91(2017).","model_doi":"10.1016/j.jnucmat.2017.08.016","tdb":"BiCe-17Wan.tdb","tdb_path":"databases/sgte-binary/BiCe-17Wan.tdb","tdb_sha256":"7b39a0f2a6bf4ab9f62ea2fc41e258ef69c8b61339030b7acdb9dfa90e45a06c"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1002/zaac.19130840125":{"authors":["Rudolf Vogel"],"citation":"Rudolf Vogel, Über die Legierungen des Cers mit Silicium und Wismut, Z. Anorg. Chem. 84, 323-339 (1913).","container":"Z. Anorg. Chem.","doi":"10.1002/zaac.19130840125","doi_url":"https://doi.org/10.1002/zaac.19130840125","id":"doi:10.1002/zaac.19130840125","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Über die Legierungen des Cers mit Silicium und Wismut","year":1913},"doi:10.1007/bf02882364":{"citation":"K.A. Gschneidner, F.W. Calderwood, Bull. Alloy Phase Diagr. 10 (1989) 427e430.","doi":"10.1007/bf02882364","doi_url":"https://doi.org/10.1007/bf02882364","id":"doi:10.1007/bf02882364","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"]},"doi:10.1016/0022-5088(75)90038-7":{"authors":["K. Yoshihara","J.B. Taylor","L.D. Calvert","J.G. Despault"],"citation":"K. Yoshihara, J.B. Taylor, L.D. Calvert, J.G. Despault, Rare-earth bismuthides, Journal of the Less Common Metals 41, 329-337 (1975).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(75)90038-7","doi_url":"https://doi.org/10.1016/0022-5088(75)90038-7","id":"doi:10.1016/0022-5088(75)90038-7","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Rare-earth bismuthides","year":1975},"doi:10.1016/0022-5088(78)90067-x":{"authors":["G Borzone","A Borsese","A Calabretta","R Ferro"],"citation":"G Borzone, A Borsese, A Calabretta, R Ferro, Heats of formation of cerium-bismuth alloys, Journal of the Less Common Metals 58, 31-36 (1978).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(78)90067-x","doi_url":"https://doi.org/10.1016/0022-5088(78)90067-x","id":"doi:10.1016/0022-5088(78)90067-x","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Heats of formation of cerium-bismuth alloys","year":1978},"doi:10.1016/0022-5088(84)90320-5":{"authors":["C. Colinet","A. Pasturel","A. Percheron-Guégan","J.C. Achard"],"citation":"C. Colinet, A. Pasturel, A. Percheron-Guégan, J.C. Achard, Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements, Journal of the Less Common Metals 102, 239-249 (1984).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(84)90320-5","doi_url":"https://doi.org/10.1016/0022-5088(84)90320-5","id":"doi:10.1016/0022-5088(84)90320-5","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements","year":1984},"doi:10.1016/j.calphad.2012.05.004":{"authors":["Juan Li","Yu Cai","Qiang Chen","Hang Zhang","HuaShan Liu","ZhanPeng Jin"],"citation":"Juan Li, Yu Cai, Qiang Chen, Hang Zhang, HuaShan Liu, ZhanPeng Jin, Thermodynamic modeling of Fe–Ce–Bi system and explanation of interfacial reaction in Fe-45at%–Ce/Bi couple, Calphad 38, 133-139 (2012).","container":"Calphad","doi":"10.1016/j.calphad.2012.05.004","doi_url":"https://doi.org/10.1016/j.calphad.2012.05.004","id":"doi:10.1016/j.calphad.2012.05.004","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"c9f81c1f3ff29521","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic modeling of Fe–Ce–Bi system and explanation of interfacial reaction in Fe-45at%–Ce/Bi couple","year":2012},"doi:10.1016/j.jnucmat.2017.08.016":{"authors":["Yafei Wang","Wentao Zhou","Shaoqiang Guo","Jinsuo Zhang"],"citation":"Yafei Wang, Wentao Zhou, Shaoqiang Guo, Jinsuo Zhang, Thermodynamic properties of fission products (Pr, Ce, Er) in liquid bismuth by thermodynamic assessment, Journal of Nuclear Materials 495, 181-191 (2017).","container":"Journal of Nuclear Materials","doi":"10.1016/j.jnucmat.2017.08.016","doi_url":"https://doi.org/10.1016/j.jnucmat.2017.08.016","id":"doi:10.1016/j.jnucmat.2017.08.016","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"414670b8925c12d6","roles":["cited_source","reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic properties of fission products (Pr, Ce, Er) in liquid bismuth by thermodynamic assessment","year":2017},"doi:10.1557/jmr.2007.0212":{"authors":["Huashan Liu","Hang Wang","Wenjun Zhu","Xiaoma Tao","Zhanpeng Jin"],"citation":"Huashan Liu, Hang Wang, Wenjun Zhu, Xiaoma Tao, Zhanpeng Jin, Prediction of formation of intermetallic compounds in diffusion couples, J. Mater. Res. 22, 1502-1511 (2007).","container":"J. Mater. Res.","doi":"10.1557/jmr.2007.0212","doi_url":"https://doi.org/10.1557/jmr.2007.0212","id":"doi:10.1557/jmr.2007.0212","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Prediction of formation of intermetallic compounds in diffusion couples","year":2007},"ref:5df60dd7aa9694f9":{"citation":"K Yoshihara, J.B Taylor, L.D. Calvert, J.G. Despault, J. Less-Common Met. 41 (1975) 239–245. 139","id":"ref:5df60dd7aa9694f9","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1975},"ref:f81bc59ae70956c6":{"citation":"R.J. Pleasance, J. Inst. Met. 88 (1959) 45–50.","id":"ref:f81bc59ae70956c6","kind":"cited_work","metadata_source":"printed_reference","roles":["cited_source"],"source_kinds":["cited_work"],"year":1959}},"part":1,"parts":1,"records":[{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1557/jmr.2007.0212","first_author":"Liu","kind":"unknown","label":"18","paper":"doi:10.1557/jmr.2007.0212","reference":"H.S. Liu, H. Wang, W.J. Zhu, X.M. Tao, Z.P. Jin, J. Mater. Res. 22 (2007) 1502–1511.","status":"resolved","year":"2007"},{"kind":"unknown","label":"24","status":"unresolved"}],"conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-Z2BJS7WTQE","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p6/tab-6","row":1},"model":"M4a9cfab6","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2012.05.004","own_work_of_paper":true},"overall_composition":{"CE":0.666667},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phases":[{"label":"Ce2Bi"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p6/tab-6/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_MIX","property_group":"mixing / partial","property_printed":"Driving force","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_K":773.0,"temperature_basis":"printed","temperature_printed":"773 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.637736},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/G_MIX_PARTIAL","floor":1.0,"floor_unit":"kJ/mol","n_pairs":94,"value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"G_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"column_header","unit_printed":"J/mol","unit_stored":"J/mol (basis unstated)","value":12.75472,"value_printed":12754.72,"value_stored":12754.72},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1557/jmr.2007.0212","first_author":"Liu","kind":"unknown","label":"18","paper":"doi:10.1557/jmr.2007.0212","reference":"H.S. Liu, H. Wang, W.J. Zhu, X.M. Tao, Z.P. Jin, J. Mater. Res. 22 (2007) 1502–1511.","status":"resolved","year":"2007"},{"kind":"unknown","label":"24","status":"unresolved"}],"conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-6JDZ3YDXPW","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p6/tab-6","row":2},"model":"M4a9cfab6","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2012.05.004","own_work_of_paper":true},"overall_composition":{"CE":0.625},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phases":[{"label":"Ce5Bi3"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p6/tab-6/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_MIX","property_group":"mixing / partial","property_printed":"Driving force","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_K":773.0,"temperature_basis":"printed","temperature_printed":"773 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.044692},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/G_MIX_PARTIAL","floor":1.0,"floor_unit":"kJ/mol","n_pairs":94,"value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"G_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"column_header","unit_printed":"J/mol","unit_stored":"J/mol (basis unstated)","value":20.89384,"value_printed":20893.84,"value_stored":20893.84},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1557/jmr.2007.0212","first_author":"Liu","kind":"unknown","label":"18","paper":"doi:10.1557/jmr.2007.0212","reference":"H.S. Liu, H. Wang, W.J. Zhu, X.M. Tao, Z.P. Jin, J. Mater. Res. 22 (2007) 1502–1511.","status":"resolved","year":"2007"},{"kind":"unknown","label":"24","status":"unresolved"}],"conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-2OALGLPX2I","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p6/tab-6","row":3},"model":"M4a9cfab6","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2012.05.004","own_work_of_paper":true},"overall_composition":{"CE":0.571429},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phases":[{"label":"Ce4Bi3"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p6/tab-6/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_MIX","property_group":"mixing / partial","property_printed":"Driving force","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_K":773.0,"temperature_basis":"printed","temperature_printed":"773 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.4227305},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/G_MIX_PARTIAL","floor":1.0,"floor_unit":"kJ/mol","n_pairs":94,"value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"G_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"column_header","unit_printed":"J/mol","unit_stored":"J/mol (basis unstated)","value":28.45461,"value_printed":28454.61,"value_stored":28454.61},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1557/jmr.2007.0212","first_author":"Liu","kind":"unknown","label":"18","paper":"doi:10.1557/jmr.2007.0212","reference":"H.S. Liu, H. Wang, W.J. Zhu, X.M. Tao, Z.P. Jin, J. Mater. Res. 22 (2007) 1502–1511.","status":"resolved","year":"2007"},{"kind":"unknown","label":"24","status":"unresolved"}],"conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-LKEXL464XT","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p6/tab-6","row":4},"model":"M4a9cfab6","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2012.05.004","own_work_of_paper":true},"overall_composition":{"CE":0.5},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phases":[{"label":"CeBi"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p6/tab-6/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_MIX","property_group":"mixing / partial","property_printed":"Driving force","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_K":773.0,"temperature_basis":"printed","temperature_printed":"773 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.6841085},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/G_MIX_PARTIAL","floor":1.0,"floor_unit":"kJ/mol","n_pairs":94,"value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"G_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"column_header","unit_printed":"J/mol","unit_stored":"J/mol (basis unstated)","value":33.68217,"value_printed":33682.17,"value_stored":33682.17},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1557/jmr.2007.0212","first_author":"Liu","kind":"unknown","label":"18","paper":"doi:10.1557/jmr.2007.0212","reference":"H.S. Liu, H. Wang, W.J. Zhu, X.M. Tao, Z.P. Jin, J. Mater. Res. 22 (2007) 1502–1511.","status":"resolved","year":"2007"},{"kind":"unknown","label":"24","status":"unresolved"}],"conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":1,"fold_lso":3,"id":"ORC-PSNFCMVSKQ","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p6/tab-6","row":5},"model":"M4a9cfab6","observation_type":"equilibrium_property","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2012.05.004","own_work_of_paper":true},"overall_composition":{"CE":0.333333},"overall_composition_basis":"from_formula","paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phases":[{"label":"CeBi2"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p6/tab-6/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"GM_MIX","property_group":"mixing / partial","property_printed":"Driving force","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"confirmed_pro","readers":["claude-opus-5.5","gemini-3.1-pro-preview","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_K":773.0,"temperature_basis":"printed","temperature_printed":"773 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.356164},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/G_MIX_PARTIAL","floor":1.0,"floor_unit":"kJ/mol","n_pairs":94,"value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-06},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"G_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"column_header","unit_printed":"J/mol","unit_stored":"J/mol (basis unstated)","value":7.12328,"value_printed":7123.28,"value_stored":7123.28},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1016/0022-5088(84)90320-5","first_author":"Colinet","kind":"assessment","label":"38","paper":"doi:10.1016/0022-5088(84)90320-5","reference":"C. Colinet, et al., Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements, J. Less Common Metals 102 (2) (1984) 239e249.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":3,"id":"ORC-53QOZFQ4VC.503ac5","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8","row":1},"merged_ids":["ORC-53QOZFQ4VC.67a714"],"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"BI":0.667,"CE":0.333},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"CeBi2"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.2},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-84.0,"value_printed":-84,"value_stored":-84000.0},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1016/0022-5088(78)90067-x","first_author":"Borzone","kind":"unknown","label":"44","paper":"doi:10.1016/0022-5088(78)90067-x","reference":"G. Borzone, et al., Heats of formation of cerium-bismuth alloys, J. Less Common Metals 58 (1) (1978) 31e36.","status":"resolved","year":"1978"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":3,"id":"ORC-JDRVVHMRD6.133e1a","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8","row":2},"merged_ids":["ORC-JDRVVHMRD6.423354"],"observation_type":"equilibrium_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(78)90067-x","own_work_of_paper":false},"overall_composition":{"BI":0.667,"CE":0.333},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"CeBi2"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.875},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-77.5,"value_printed":-77.5,"value_stored":-77500.0},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":3,"id":"ORC-O64SEHJNKM.020da1","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8","row":3},"merged_ids":["ORC-O64SEHJNKM.30dbe2"],"model":"Mf6b3e4df","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"BI":0.667,"CE":0.333},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"CeBi2"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.8789},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-77.578,"value_printed":-77.578,"value_stored":-77578.0},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1016/0022-5088(84)90320-5","first_author":"Colinet","kind":"assessment","label":"38","paper":"doi:10.1016/0022-5088(84)90320-5","reference":"C. Colinet, et al., Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements, J. Less Common Metals 102 (2) (1984) 239e249.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":3,"id":"ORC-RH2DIHJICV.318462","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8","row":4},"merged_ids":["ORC-RH2DIHJICV.974ce9"],"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"BI":0.5,"CE":0.5},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"CeBi"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":5.1},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-102.0,"value_printed":-102,"value_stored":-102000.0},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1016/0022-5088(78)90067-x","first_author":"Borzone","kind":"unknown","label":"44","paper":"doi:10.1016/0022-5088(78)90067-x","reference":"G. Borzone, et al., Heats of formation of cerium-bismuth alloys, J. Less Common Metals 58 (1) (1978) 31e36.","status":"resolved","year":"1978"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":3,"id":"ORC-VVTHY5FPN7.3c6009","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8","row":5},"merged_ids":["ORC-VVTHY5FPN7.b5cfcb"],"observation_type":"equilibrium_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(78)90067-x","own_work_of_paper":false},"overall_composition":{"BI":0.5,"CE":0.5},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"CeBi"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":5.735},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-114.7,"value_printed":-114.7,"value_stored":-114700.0},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":3,"id":"ORC-W3QEECN5RM.28e57c","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8","row":6},"merged_ids":["ORC-W3QEECN5RM.771493"],"model":"Mf6b3e4df","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"BI":0.5,"CE":0.5},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"CeBi"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":5.716},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-114.32,"value_printed":-114.32,"value_stored":-114320.0},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1016/0022-5088(84)90320-5","first_author":"Colinet","kind":"assessment","label":"38","paper":"doi:10.1016/0022-5088(84)90320-5","reference":"C. Colinet, et al., Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements, J. Less Common Metals 102 (2) (1984) 239e249.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":3,"id":"ORC-43EX2OEKAV.7db9cd","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8","row":7},"merged_ids":["ORC-43EX2OEKAV.ffbd86"],"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"BI":0.429,"CE":0.571},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Ce4Bi3"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.95},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-99.0,"value_printed":-99,"value_stored":-99000.0},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1016/0022-5088(78)90067-x","first_author":"Borzone","kind":"unknown","label":"44","paper":"doi:10.1016/0022-5088(78)90067-x","reference":"G. Borzone, et al., Heats of formation of cerium-bismuth alloys, J. Less Common Metals 58 (1) (1978) 31e36.","status":"resolved","year":"1978"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":3,"id":"ORC-URCD42J6HC.67e42b","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8","row":8},"merged_ids":["ORC-URCD42J6HC.9f76a3"],"observation_type":"equilibrium_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(78)90067-x","own_work_of_paper":false},"overall_composition":{"BI":0.429,"CE":0.571},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Ce4Bi3"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":5.065},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-101.3,"value_printed":-101.3,"value_stored":-101300.0},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":3,"id":"ORC-7BBIXGA67V.9ce24e","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8","row":9},"merged_ids":["ORC-7BBIXGA67V.e35619"],"model":"Mf6b3e4df","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"BI":0.429,"CE":0.571},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Ce4Bi3"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":5.077},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-101.54,"value_printed":-101.54,"value_stored":-101540.0},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1016/0022-5088(84)90320-5","first_author":"Colinet","kind":"assessment","label":"38","paper":"doi:10.1016/0022-5088(84)90320-5","reference":"C. Colinet, et al., Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements, J. Less Common Metals 102 (2) (1984) 239e249.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":3,"id":"ORC-WRTAKMAUKW.79e2a9","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8","row":10},"merged_ids":["ORC-WRTAKMAUKW.ac4d3a"],"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"BI":0.375,"CE":0.625},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Ce5Bi3"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.6},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-92.0,"value_printed":-92,"value_stored":-92000.0},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1016/0022-5088(78)90067-x","first_author":"Borzone","kind":"unknown","label":"44","paper":"doi:10.1016/0022-5088(78)90067-x","reference":"G. Borzone, et al., Heats of formation of cerium-bismuth alloys, J. Less Common Metals 58 (1) (1978) 31e36.","status":"resolved","year":"1978"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":3,"id":"ORC-ZK3NKCG3OO.8dee39","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8","row":11},"merged_ids":["ORC-ZK3NKCG3OO.d97899"],"observation_type":"equilibrium_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(78)90067-x","own_work_of_paper":false},"overall_composition":{"BI":0.375,"CE":0.625},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Ce5Bi3"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.585},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-91.7,"value_printed":-91.7,"value_stored":-91700.0},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":3,"id":"ORC-S2JR46GW3J.213d25","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8","row":12},"merged_ids":["ORC-S2JR46GW3J.31b1ec"],"model":"Mf6b3e4df","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"BI":0.375,"CE":0.625},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Ce5Bi3"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8/r12#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.5881},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-91.762,"value_printed":-91.762,"value_stored":-91762.0},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1016/0022-5088(84)90320-5","first_author":"Colinet","kind":"assessment","label":"38","paper":"doi:10.1016/0022-5088(84)90320-5","reference":"C. Colinet, et al., Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements, J. Less Common Metals 102 (2) (1984) 239e249.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":3,"id":"ORC-37QYNVNWGL.423e87","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8","row":13},"merged_ids":["ORC-37QYNVNWGL.48f6eb"],"model_unlinked_reason":"linked TDB not the reporting paper's own model (link basis: None)","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"BI":0.333,"CE":0.667},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Ce2Bi"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8/r13#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.2},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-84.0,"value_printed":-84,"value_stored":-84000.0},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1016/0022-5088(78)90067-x","first_author":"Borzone","kind":"unknown","label":"44","paper":"doi:10.1016/0022-5088(78)90067-x","reference":"G. Borzone, et al., Heats of formation of cerium-bismuth alloys, J. Less Common Metals 58 (1) (1978) 31e36.","status":"resolved","year":"1978"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":3,"fold_lso":3,"id":"ORC-TBUT4TDDGS.00931e","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8","row":14},"merged_ids":["ORC-TBUT4TDDGS.3c98cb"],"observation_type":"equilibrium_property","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(78)90067-x","own_work_of_paper":false},"overall_composition":{"BI":0.333,"CE":0.667},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Ce2Bi"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8/r14#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_K":298.15,"temperature_basis":"assumed_standard_298K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.08},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.5,"sigma_method":{"basis":"calibrated","ci95":[2.41122,4.298262],"class":"unknown","entry":"value_types/HM_FORM/classes/unknown","floor":3.5,"floor_unit":"kJ/mol-atom","n_pairs":290,"value":3.5},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-81.6,"value_printed":-81.6,"value_stored":-81600.0},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:T_K","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":3,"id":"ORC-WK3XZ5EHJA.69726b","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8","row":15},"merged_ids":["ORC-WK3XZ5EHJA.f4d05e"],"model":"Mf6b3e4df","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"BI":0.333,"CE":0.667},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Ce2Bi"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p6/tab-8/r15#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"fixed_state_variables":{"T":298.15},"phase":"RHOMBOHEDRAL_A7"},"CE":{"fixed_state_variables":{"T":298.15},"phase":"FCC_A1"}},"source_system":"BI-CE","system":"BI-CE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.07105},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-81.421,"value_printed":-81.421,"value_stored":-81421.0},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:component","state:component_standard_state","state:composition","unit read by one reader only"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":3,"id":"ORC-TRRSZATTG7","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p8/tab-11","row":3},"model":"Mf6b3e4df","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"liquid"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p8/tab-11/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"ACTIVITY_COEFFICIENT","property_group":"activity / EMF / Gibbs energy","property_printed":"Log(activity coefficient)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-CE","system":"BI-CE","temperature_K":873.0,"temperature_basis":"printed","temperature_printed":"873 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.54},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property ACTIVITY_COEFFICIENT","sigma_method":{"reason":"no method floor defined for property ACTIVITY_COEFFICIENT","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"unknown","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"unknown","unit_basis":"not_printed","value":-10.8,"value_printed":-10.8},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:component","state:component_standard_state","state:composition","unit read by one reader only"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":3,"id":"ORC-FTQIWFHMMA","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p8/tab-11","row":6},"model":"Mf6b3e4df","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"liquid"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p8/tab-11/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"ACTIVITY_COEFFICIENT","property_group":"activity / EMF / Gibbs energy","property_printed":"Log(activity coefficient)","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-CE","system":"BI-CE","temperature_K":923.0,"temperature_basis":"printed","temperature_printed":"923 K","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.505},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":null,"sigma_effective_reason":"no method floor defined for property ACTIVITY_COEFFICIENT","sigma_method":{"reason":"no method floor defined for property ACTIVITY_COEFFICIENT","value":null},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"unknown","value_type":null}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"unknown","unit_basis":"not_printed","value":-10.1,"value_printed":-10.1},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BI-CE","before":"BI-CE-ER-PR","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"CE":0.333},"phases":["CeBi2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-2PFCKSPRBL","locator":{"ref":"sha256:414670b8925c12d6/p7/tab-10","row":6},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"CE":0.333},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"CeBi2"}],"pid":"sha256:414670b8925c12d6/p7/tab-10/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"CE":{"phase":"printed:none"}},"reference_state_stored":{"BI":{"phase":"printed:none"},"CE":{"phase":"printed:none"},"ER":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-CE-ER-PR","system":"BI-CE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.31},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.9,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"scaled_for_unstated_basis":3,"value":9.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"unstated","unit_printed":"J/mol","value":-6.2,"value_printed":-6.2},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BI-CE","before":"BI-CE-ER-PR","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"CE":0.5},"phases":["CeBi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-QWFVNK6G3P","locator":{"ref":"sha256:414670b8925c12d6/p7/tab-10","row":7},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"CE":0.5},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"CeBi"}],"pid":"sha256:414670b8925c12d6/p7/tab-10/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"CE":{"phase":"printed:none"}},"reference_state_stored":{"BI":{"phase":"printed:none"},"CE":{"phase":"printed:none"},"ER":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-CE-ER-PR","system":"BI-CE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.775},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":6.6,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"scaled_for_unstated_basis":2,"value":6.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"unstated","unit_printed":"J/mol","value":-15.5,"value_printed":-15.5},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BI-CE","before":"BI-CE-ER-PR","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"CE":0.571},"phases":["Ce4Bi3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-ST6GWJWJAV","locator":{"ref":"sha256:414670b8925c12d6/p7/tab-10","row":8},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"CE":0.571},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Ce4Bi3"}],"pid":"sha256:414670b8925c12d6/p7/tab-10/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"CE":{"phase":"printed:none"}},"reference_state_stored":{"BI":{"phase":"printed:none"},"CE":{"phase":"printed:none"},"ER":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-CE-ER-PR","system":"BI-CE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.444},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":23.1,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"scaled_for_unstated_basis":7,"value":23.1},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"unstated","unit_printed":"J/mol","value":-8.88,"value_printed":-8.88},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BI-CE","before":"BI-CE-ER-PR","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"CE":0.625},"phases":["Ce5Bi3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-EWVJHQL7XY","locator":{"ref":"sha256:414670b8925c12d6/p7/tab-10","row":9},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"CE":0.625},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Ce5Bi3"}],"pid":"sha256:414670b8925c12d6/p7/tab-10/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"CE":{"phase":"printed:none"}},"reference_state_stored":{"BI":{"phase":"printed:none"},"CE":{"phase":"printed:none"},"ER":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-CE-ER-PR","system":"BI-CE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.4085},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":26.4,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"scaled_for_unstated_basis":8,"value":26.4},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"unstated","unit_printed":"J/mol","value":-8.17,"value_printed":-8.17},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BI-CE","before":"BI-CE-ER-PR","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"CE":0.667},"phases":["Ce2Bi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-NXYZLYGHWX","locator":{"ref":"sha256:414670b8925c12d6/p7/tab-10","row":10},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"CE":0.667},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Ce2Bi"}],"pid":"sha256:414670b8925c12d6/p7/tab-10/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"CE":{"phase":"printed:none"}},"reference_state_stored":{"BI":{"phase":"printed:none"},"CE":{"phase":"printed:none"},"ER":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-CE-ER-PR","system":"BI-CE","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.318},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.9,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"scaled_for_unstated_basis":3,"value":9.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"unstated","unit_printed":"J/mol","value":-6.36,"value_printed":-6.36},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1016/0022-5088(78)90067-x","first_author":"Borzone","kind":"experimental","label":"10","paper":"doi:10.1016/0022-5088(78)90067-x","reference":"G. Borzone, A. Borsese, A. Calabretta, R. Ferro, J. Less-Common Met. 58 (1978) 31–39.","status":"resolved","year":"1978"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-STA7DOTGSF","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3","row":16},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(78)90067-x","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.3333333333},"composition_source":"stoichiometry","phase":"Bi2Ce"}],"phases":[{"label":"BCC_A2","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"FCC_A1","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Bi2Ce","mapping_confidence":"confirmed","model_phase":"BI2CE","pearson_symbol":"aP*","prototype":"Bi2Ce","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3/r-unplaced-2c085a62#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"BCC_A2 = FCC_A1 + Bi2Ce"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":999,"temperature_printed":"999","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":999},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1002/zaac.19130840125","first_author":"Vogel","kind":"experimental","label":"7","paper":"doi:10.1002/zaac.19130840125","reference":"R. Vogel, Z. Anorg. Allg. Chem. 84 (1913) 323–327.","status":"resolved","year":"1913"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":1.983,"dx":{},"model":"BiCe-12Li.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-UNPRGPY63A","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3","row":6},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1002/zaac.19130840125","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.5714285714},"composition_source":"stoichiometry","phase":"Ce4Bi3"},{"basis":"mole_fraction","composition":{"CE":0.5},"composition_source":"stoichiometry","phase":"CeBi"}],"phases":[{"label":"Liquid","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ce4Bi3","mapping_confidence":"confirmed","model_phase":"BI3CE4_D73","pearson_symbol":"cI28","prototype":"Th3P4","structure_basis":"mapped_model_phase"},{"label":"CeBi","mapping_confidence":"confirmed","model_phase":"BICE_B1","pearson_symbol":"cF8","prototype":"NaCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3/r-unplaced-3a8916b0#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + Ce4Bi3 = CeBi"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1903,"temperature_printed":"1903","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1903},{"chemical_system":"BI-CE","cited_sources":[{"first_author":"Pleasance","kind":"experimental","label":"8","reference":"R.J. Pleasance, J. Inst. Met. 88 (1959) 45–50.","status":"resolved","year":"1959"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-OQPU4H6FVQ","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3","row":2},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:f81bc59ae70956c6","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.3333333333},"composition_source":"stoichiometry","phase":"CeBi2"},{"basis":"mole_fraction","composition":{"CE":0.0},"composition_source":"stoichiometric_model_phase","phase":"Rhombo_A7"}],"phases":[{"label":"Liquid","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CeBi2","mapping_confidence":"confirmed","model_phase":"BI2CE","pearson_symbol":"aP*","prototype":"Bi2Ce","structure_basis":"mapped_model_phase"},{"label":"Rhombo_A7","mapping_confidence":"confirmed","model_phase":"RHOMBOHEDRAL_A7","pearson_symbol":"hR2","prototype":"alpha-As","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3/r-unplaced-5d4022a1#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = CeBi2 + Rhombo_A7"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":544,"temperature_printed":"544","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":544},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1002/zaac.19130840125","first_author":"Vogel","kind":"experimental","label":"7","paper":"doi:10.1002/zaac.19130840125","reference":"R. Vogel, Z. Anorg. Allg. Chem. 84 (1913) 323–327.","status":"resolved","year":"1913"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.006,"dx":{},"model":"BiCe-12Li.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-AENRE4JN2R","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3","row":4},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1002/zaac.19130840125","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.5},"composition_source":"stoichiometry","phase":"CeBi"},{"basis":"mole_fraction","composition":{"CE":0.3333333333},"composition_source":"stoichiometry","phase":"CeBi2"}],"phases":[{"label":"Liquid","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CeBi","mapping_confidence":"confirmed","model_phase":"BICE_B1","pearson_symbol":"cF8","prototype":"NaCl","structure_basis":"mapped_model_phase"},{"label":"CeBi2","mapping_confidence":"confirmed","model_phase":"BI2CE","pearson_symbol":"aP*","prototype":"Bi2Ce","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3/r-unplaced-64c6c7d3#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + CeBi = CeBi2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1183,"temperature_printed":"1183","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1183},{"chemical_system":"BI-CE","cited_sources":[{"kind":"experimental","label":"9","reference":"K Yoshihara, J.B Taylor, L.D. Calvert, J.G. Despault, J. Less-Common Met. 41 (1975) 239–245. 139","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":8.244,"dx":{},"model":"BiCe-12Li.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-66BCKWBEXH","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3","row":10},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:5df60dd7aa9694f9","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.5714285714},"composition_source":"stoichiometry","phase":"Ce4Bi3"},{"basis":"mole_fraction","composition":{"CE":0.625},"composition_source":"stoichiometry","phase":"Ce5Bi3"}],"phases":[{"label":"Liquid","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ce4Bi3","mapping_confidence":"confirmed","model_phase":"BI3CE4_D73","pearson_symbol":"cI28","prototype":"Th3P4","structure_basis":"mapped_model_phase"},{"label":"Ce5Bi3","mapping_confidence":"confirmed","model_phase":"BI3CE5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3/r-unplaced-80c516ce#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + Ce4Bi3 = Ce5Bi3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1670,"temperature_printed":"1670","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1670},{"chemical_system":"BI-CE","cited_sources":[{"kind":"experimental","label":"9","reference":"K Yoshihara, J.B Taylor, L.D. Calvert, J.G. Despault, J. Less-Common Met. 41 (1975) 239–245. 139","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":2.033,"dx":{},"model":"BiCe-12Li.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-3TRMLZWEK3","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3","row":12},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"ref:5df60dd7aa9694f9","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.625},"composition_source":"stoichiometry","phase":"Ce5Bi3"},{"basis":"mole_fraction","composition":{"CE":0.6666666667},"composition_source":"stoichiometry","phase":"Ce2Bi"}],"phases":[{"label":"Liquid","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ce5Bi3","mapping_confidence":"confirmed","model_phase":"BI3CE5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"},{"label":"Ce2Bi","mapping_confidence":"confirmed","model_phase":"BICE2","pearson_symbol":"tI12","prototype":"La2Sb","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3/r-unplaced-a012eea0#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + Ce5Bi3 = Ce2Bi"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1518,"temperature_printed":"1518","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1518},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1016/0022-5088(78)90067-x","first_author":"Borzone","kind":"experimental","label":"10","paper":"doi:10.1016/0022-5088(78)90067-x","reference":"G. Borzone, A. Borsese, A. Calabretta, R. Ferro, J. Less-Common Met. 58 (1978) 31–39.","status":"resolved","year":"1978"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"agrees","espei_certified":true,"espei_certified_basis":"pycalphad_invariant_agreement","espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-23.207,"dx":{},"model":"BiCe-12Li.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-N3VRNZVWHZ","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3","row":14},"observation_type":"invariant_reaction","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1016/0022-5088(78)90067-x","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.6666666667},"composition_source":"stoichiometry","phase":"Ce2Bi"}],"phases":[{"label":"Liquid","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"BCC_A2","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"Ce2Bi","mapping_confidence":"confirmed","model_phase":"BICE2","pearson_symbol":"tI12","prototype":"La2Sb","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3/r-unplaced-a57d0a44#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = BCC_A2 + Ce2Bi"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1032,"temperature_printed":"1032","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1032},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1002/zaac.19130840125","first_author":"Vogel","kind":"experimental","label":"7","paper":"doi:10.1002/zaac.19130840125","reference":"R. Vogel, Z. Anorg. Allg. Chem. 84 (1913) 323–327.","status":"resolved","year":"1913"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-5YCDJ3CGAU","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3","row":8},"observation_type":"phase_transition","origin":{"basis":"printed_source_experimental","class":"experimental","measured_in":"doi:10.1002/zaac.19130840125","measured_in_basis":"cited_work","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.5714285714},"composition_source":"congruent_same_composition","phase":"Liquid"},{"basis":"mole_fraction","composition":{"CE":0.5714285714},"composition_source":"stoichiometry","phase":"Ce4Bi3"}],"phases":[{"label":"Liquid","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ce4Bi3","mapping_confidence":"confirmed","model_phase":"BI3CE4_D73","pearson_symbol":"cI28","prototype":"Th3P4","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3/r-unplaced-a6b149e2#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Liquid = Ce4Bi3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":2013,"temperature_printed":"2013","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-11},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2013},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-IKZCN5BP35","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3","row":1},"model":"Ma528ecd8","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2012.05.004","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.005},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"CE":0.33},"composition_source":"printed","phase":"CeBi2"},{"basis":"mole_fraction","composition":{"CE":0.001},"composition_source":"printed","phase":"Rhombo_A7"}],"phases":[{"label":"Liquid","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CeBi2","mapping_confidence":"confirmed","model_phase":"BI2CE","pearson_symbol":"aP*","prototype":"Bi2Ce","structure_basis":"mapped_model_phase"},{"label":"Rhombo_A7","mapping_confidence":"confirmed","model_phase":"RHOMBOHEDRAL_A7","pearson_symbol":"hR2","prototype":"alpha-As","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3/r01#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = CeBi2 + Rhombo_A7"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":544.5,"temperature_printed":"544.5","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":544.5},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.006,"dx":{"CeBi":0.0,"CeBi2":-0.0033,"Liquid":0.0227},"model":"BiCe-12Li.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-EHJS2GJPHB","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3","row":3},"model":"Ma528ecd8","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2012.05.004","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.21},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"CE":0.5},"composition_source":"printed","phase":"CeBi"},{"basis":"mole_fraction","composition":{"CE":0.33},"composition_source":"printed","phase":"CeBi2"}],"phases":[{"label":"Liquid","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"CeBi","mapping_confidence":"confirmed","model_phase":"BICE_B1","pearson_symbol":"cF8","prototype":"NaCl","structure_basis":"mapped_model_phase"},{"label":"CeBi2","mapping_confidence":"confirmed","model_phase":"BI2CE","pearson_symbol":"aP*","prototype":"Bi2Ce","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3/r02#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + CeBi = CeBi2"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1183,"temperature_printed":"1183","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1183},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":-0.017,"dx":{"Ce4Bi3":-0.0004,"CeBi":0.0,"Liquid":-0.0054},"model":"BiCe-12Li.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-HR7D3HFIXA","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3","row":5},"model":"M6076368a","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2012.05.004","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.465},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"CE":0.571},"composition_source":"printed","phase":"Ce4Bi3"},{"basis":"mole_fraction","composition":{"CE":0.5},"composition_source":"printed","phase":"CeBi"}],"phases":[{"label":"Liquid","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ce4Bi3","mapping_confidence":"confirmed","model_phase":"BI3CE4_D73","pearson_symbol":"cI28","prototype":"Th3P4","structure_basis":"mapped_model_phase"},{"label":"CeBi","mapping_confidence":"confirmed","model_phase":"BICE_B1","pearson_symbol":"cF8","prototype":"NaCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3/r03#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + Ce4Bi3 = CeBi"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1901,"temperature_printed":"1901","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1901},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-76PA7LUS26","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3","row":7},"model":"M6076368a","observation_type":"phase_transition","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2012.05.004","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.571},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"CE":0.571},"composition_source":"printed","phase":"Ce4Bi3"}],"phases":[{"label":"Liquid","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ce4Bi3","mapping_confidence":"confirmed","model_phase":"BI3CE4_D73","pearson_symbol":"cI28","prototype":"Th3P4","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3/r04#transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","reaction":{"printed":"Liquid = Ce4Bi3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":2013,"temperature_printed":"2013","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":10.0,"sigma_method":{"basis":"prior","ci95":null,"class":"model_calculated","entry":"model/T_TRANSITION","floor":10.0,"floor_unit":"K","n_pairs":129,"value":10.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2013},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":6.244,"dx":{"Ce4Bi3":-0.0004,"Ce5Bi3":0.0,"Liquid":0.022},"model":"BiCe-12Li.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-QYH6BOCLAR","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3","row":9},"model":"Ma528ecd8","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2012.05.004","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.78},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"CE":0.571},"composition_source":"printed","phase":"Ce4Bi3"},{"basis":"mole_fraction","composition":{"CE":0.625},"composition_source":"printed","phase":"Ce5Bi3"}],"phases":[{"label":"Liquid","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ce4Bi3","mapping_confidence":"confirmed","model_phase":"BI3CE4_D73","pearson_symbol":"cI28","prototype":"Th3P4","structure_basis":"mapped_model_phase"},{"label":"Ce5Bi3","mapping_confidence":"confirmed","model_phase":"BI3CE5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3/r05#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + Ce4Bi3 = Ce5Bi3"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1668,"temperature_printed":"1668","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1668},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.033,"dx":{"Ce2Bi":0.0033,"Ce5Bi3":0.0,"Liquid":0.0075},"model":"BiCe-12Li.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-YJ4RHTZQDD","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3","row":11},"model":"M6076368a","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2012.05.004","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.818},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"CE":0.625},"composition_source":"printed","phase":"Ce5Bi3"},{"basis":"mole_fraction","composition":{"CE":0.67},"composition_source":"printed","phase":"Ce2Bi"}],"phases":[{"label":"Liquid","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"Ce5Bi3","mapping_confidence":"confirmed","model_phase":"BI3CE5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"},{"label":"Ce2Bi","mapping_confidence":"confirmed","model_phase":"BICE2","pearson_symbol":"tI12","prototype":"La2Sb","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3/r06#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid + Ce5Bi3 = Ce2Bi"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1516,"temperature_printed":"1516","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1516},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"agrees","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"plausibility":{"calculation":"pycalphad binary topology (computed invariant)","dT_K":0.793,"dx":{"BCC_A2":-0.0043,"Ce2Bi":0.0033,"Liquid":-0.0432},"model":"BiCe-12Li.tdb","result":"pass","tolerance":{"dT_K":25.0,"dx":0.05}},"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"id":"ORC-XZJD7YCHUZ","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3","row":13},"model":"Ma528ecd8","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2012.05.004","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.93},"composition_source":"printed","phase":"Liquid"},{"basis":"mole_fraction","composition":{"CE":0.982},"composition_source":"printed","phase":"BCC_A2"},{"basis":"mole_fraction","composition":{"CE":0.67},"composition_source":"printed","phase":"Ce2Bi"}],"phases":[{"label":"Liquid","mapping_confidence":"confirmed","model_phase":"LIQUID"},{"label":"BCC_A2","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"Ce2Bi","mapping_confidence":"confirmed","model_phase":"BICE2","pearson_symbol":"tI12","prototype":"La2Sb","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3/r07#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Liquid = BCC_A2 + Ce2Bi"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1056,"temperature_printed":"1056","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1056},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":null,"before":"BI2CE","evidence":{"label":"Bi2Ce","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"composition_outside_model_phase_range"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"gate_failures":["label_conflicts_composition"],"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"label_conflicts_composition","detail":"Bi2Ce printed x(CE)=0.67, formula 0.3333","effect":"not_espei_ready","gate":"A1"}],"id":"ORC-M2FYFMN3JK","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3","row":15},"model":"Ma528ecd8","observation_type":"invariant_reaction","origin":{"basis":"this_work+label_names_calculation","class":"model_value","measured_in":"doi:10.1016/j.calphad.2012.05.004","measured_in_basis":"reporting_paper_own_value","own_work_of_paper":true},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.99},"composition_source":"printed","phase":"BCC_A2"},{"basis":"mole_fraction","composition":{"CE":0.995},"composition_source":"printed","phase":"FCC_A1"},{"basis":"mole_fraction","composition":{"CE":0.67},"composition_source":"printed","phase":"Bi2Ce"}],"phases":[{"label":"BCC_A2","mapping_confidence":"confirmed","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"},{"label":"FCC_A1","mapping_confidence":"confirmed","model_phase":"FCC_A1","pearson_symbol":"cF4","prototype":"Cu","structure_basis":"mapped_model_phase"},{"label":"Bi2Ce","model_phase_rejected":{"mapping_confidence":"confirmed","model_phase":"BI2CE","pearson_symbol":"aP*","prototype":"Bi2Ce","reason":"composition_outside_model_phase_range"}}],"pid":"doi:10.1016/j.calphad.2012.05.004/p4/tab-3/r08#invariant","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"BCC_A2 = FCC_A1 + Bi2Ce"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":976.4,"temperature_printed":"976.4","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":976.4},{"chemical_system":"BI-CE","cited_sources":[{"first_author":"Pleasance","kind":"unknown","label":"42","reference":"R.J. Pleasance, J. Inst. Met. 88 (1959) 45e50.","status":"resolved","year":"1959"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-RZ6KLONSMB","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3","row":1},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.0},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"BI":0.666667,"CE":0.333333},"composition_source":"stoichiometric_model_phase","phase":"CeBi2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"rhombohedral (Bi)","model_phase":"RHOMBOHEDRAL_A7","pearson_symbol":"hR2","prototype":"alpha-As","structure_basis":"mapped_model_phase"},{"label":"CeBi2","model_phase":"BI2CE","pearson_symbol":"aP*","prototype":"Bi2Ce","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> rhombohedral (Bi) + CeBi2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":544.0,"temperature_printed":"544","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":544.0},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-NTOX3T3SXD","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3","row":2},"model":"M6766fe15","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":7.5e-05},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"BI":0.666667,"CE":0.333333},"composition_source":"stoichiometric_model_phase","phase":"CeBi2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"rhombohedral (Bi)","model_phase":"RHOMBOHEDRAL_A7","pearson_symbol":"hR2","prototype":"alpha-As","structure_basis":"mapped_model_phase"},{"label":"CeBi2","model_phase":"BI2CE","pearson_symbol":"aP*","prototype":"Bi2Ce","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> rhombohedral (Bi) + CeBi2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":544.5,"temperature_printed":"544.5","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":544.5},{"chemical_system":"BI-CE","cited_sources":[{"first_author":"Rudolf","kind":"unknown","label":"41","reference":"Rudolf Vogel, Über die Legierungen des Cers mit Silicium und Wismut, Z. für Anorg. Chem. 84 (1) (1913) 323e339.","status":"resolved","year":"1913"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-SIDSMVZGOS","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3","row":3},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.21},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"BI":0.5,"CE":0.5},"composition_source":"stoichiometric_model_phase","phase":"CeBi"},{"basis":"mole_fraction","composition":{"BI":0.666667,"CE":0.333333},"composition_source":"stoichiometric_model_phase","phase":"CeBi2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"CeBi","model_phase":"BICE_B1","pearson_symbol":"cF8","prototype":"NaCl","structure_basis":"mapped_model_phase"},{"label":"CeBi2","model_phase":"BI2CE","pearson_symbol":"aP*","prototype":"Bi2Ce","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + CeBi -> CeBi2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1183.0,"temperature_printed":"1183","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1183.0},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-GN6G35XUA2","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3","row":4},"model":"Md30dd759","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.1815},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"BI":0.5,"CE":0.5},"composition_source":"stoichiometric_model_phase","phase":"CeBi"},{"basis":"mole_fraction","composition":{"BI":0.666667,"CE":0.333333},"composition_source":"stoichiometric_model_phase","phase":"CeBi2"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"CeBi","model_phase":"BICE_B1","pearson_symbol":"cF8","prototype":"NaCl","structure_basis":"mapped_model_phase"},{"label":"CeBi2","model_phase":"BI2CE","pearson_symbol":"aP*","prototype":"Bi2Ce","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + CeBi -> CeBi2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1186.0,"temperature_printed":"1186","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1186.0},{"chemical_system":"BI-CE","cited_sources":[{"first_author":"Rudolf","kind":"unknown","label":"41","reference":"Rudolf Vogel, Über die Legierungen des Cers mit Silicium und Wismut, Z. für Anorg. Chem. 84 (1) (1913) 323e339.","status":"resolved","year":"1913"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-E43YZZUUSD","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3","row":5},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.465},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"BI":0.428571,"CE":0.571429},"composition_source":"stoichiometric_model_phase","phase":"Ce4Bi3"},{"basis":"mole_fraction","composition":{"BI":0.5,"CE":0.5},"composition_source":"stoichiometric_model_phase","phase":"CeBi"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ce4Bi3","model_phase":"BI3CE4_D73","pearson_symbol":"cI28","prototype":"Th3P4","structure_basis":"mapped_model_phase"},{"label":"CeBi","model_phase":"BICE_B1","pearson_symbol":"cF8","prototype":"NaCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ce4Bi3 -> CeBi","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1903.0,"temperature_printed":"1903","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1903.0},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-IBYNQCCIYS","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3","row":6},"model":"Md30dd759","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.4721},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"BI":0.428571,"CE":0.571429},"composition_source":"stoichiometric_model_phase","phase":"Ce4Bi3"},{"basis":"mole_fraction","composition":{"BI":0.5,"CE":0.5},"composition_source":"stoichiometric_model_phase","phase":"CeBi"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ce4Bi3","model_phase":"BI3CE4_D73","pearson_symbol":"cI28","prototype":"Th3P4","structure_basis":"mapped_model_phase"},{"label":"CeBi","model_phase":"BICE_B1","pearson_symbol":"cF8","prototype":"NaCl","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ce4Bi3 -> CeBi","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1899.0,"temperature_printed":"1899","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1899.0},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1016/0022-5088(75)90038-7","first_author":"Yoshihara","kind":"unknown","label":"34","paper":"doi:10.1016/0022-5088(75)90038-7","reference":"K. Yoshihara, J.B. Taylor, L.D. Calvert, J.G. Despault, J. Less-Common Met. 41 Y. Wang et al. / Journal of Nuclear Materials 495 (2017) 181e191 (1975) 239e245.","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-B5GUZRYPDD","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3","row":7},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.78},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"BI":0.428571,"CE":0.571429},"composition_source":"stoichiometric_model_phase","phase":"Ce4Bi3"},{"basis":"mole_fraction","composition":{"BI":0.375,"CE":0.625},"composition_source":"stoichiometric_model_phase","phase":"Ce5Bi3"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ce4Bi3","model_phase":"BI3CE4_D73","pearson_symbol":"cI28","prototype":"Th3P4","structure_basis":"mapped_model_phase"},{"label":"Ce5Bi3","model_phase":"BI3CE5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ce4Bi3 -> Ce5Bi3","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1670.0,"temperature_printed":"1670","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1670.0},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-NZCM4BCUON","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3","row":8},"model":"Md30dd759","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.7537},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"BI":0.428571,"CE":0.571429},"composition_source":"stoichiometric_model_phase","phase":"Ce4Bi3"},{"basis":"mole_fraction","composition":{"BI":0.375,"CE":0.625},"composition_source":"stoichiometric_model_phase","phase":"Ce5Bi3"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ce4Bi3","model_phase":"BI3CE4_D73","pearson_symbol":"cI28","prototype":"Th3P4","structure_basis":"mapped_model_phase"},{"label":"Ce5Bi3","model_phase":"BI3CE5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ce4Bi3 -> Ce5Bi3","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1674.0,"temperature_printed":"1674","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1674.0},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1016/0022-5088(75)90038-7","first_author":"Yoshihara","kind":"unknown","label":"34","paper":"doi:10.1016/0022-5088(75)90038-7","reference":"K. Yoshihara, J.B. Taylor, L.D. Calvert, J.G. Despault, J. Less-Common Met. 41 Y. Wang et al. / Journal of Nuclear Materials 495 (2017) 181e191 (1975) 239e245.","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-XN6HGLVLRP","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3","row":9},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_abstract_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.818},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"BI":0.375,"CE":0.625},"composition_source":"stoichiometric_model_phase","phase":"Ce5Bi3"},{"basis":"mole_fraction","composition":{"BI":0.333333,"CE":0.666667},"composition_source":"stoichiometric_model_phase","phase":"Ce2Bi"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ce5Bi3","model_phase":"BI3CE5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"},{"label":"Ce2Bi","model_phase":"BICE2","pearson_symbol":"tI12","prototype":"La2Sb","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3/r09#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ce5Bi3 -> Ce2Bi","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1518.0,"temperature_printed":"1518","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1518.0},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-IP6S3YCLZD","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3","row":10},"model":"Md30dd759","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.8072},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"BI":0.375,"CE":0.625},"composition_source":"stoichiometric_model_phase","phase":"Ce5Bi3"},{"basis":"mole_fraction","composition":{"BI":0.333333,"CE":0.666667},"composition_source":"stoichiometric_model_phase","phase":"Ce2Bi"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ce5Bi3","model_phase":"BI3CE5_D88","pearson_symbol":"hP16","prototype":"Mn5Si3","structure_basis":"mapped_model_phase"},{"label":"Ce2Bi","model_phase":"BICE2","pearson_symbol":"tI12","prototype":"La2Sb","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Ce5Bi3 -> Ce2Bi","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1521.0,"temperature_printed":"1521","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1521.0},{"chemical_system":"BI-CE","cited_sources":[{"doi":"10.1007/bf02882364","first_author":"Gschneidner","kind":"assessment","label":"43","paper":"doi:10.1007/bf02882364","reference":"K.A. Gschneidner, F.W. Calderwood, Bull. Alloy Phase Diagr. 10 (1989) 427e430.","status":"resolved","year":"1989"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-3LMN7JVMSX","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3","row":11},"observation_type":"invariant_reaction","origin":{"basis":"cited_reference_is_assessment_unconfirmed","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.93},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"BI":0.333333,"CE":0.666667},"composition_source":"stoichiometric_model_phase","phase":"Ce2Bi"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ce2Bi","model_phase":"BICE2","pearson_symbol":"tI12","prototype":"La2Sb","structure_basis":"mapped_model_phase"},{"label":"BCC_A2 (Ce)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3/r11#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> Ce2Bi + BCC_A2 (Ce)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1023.0,"temperature_printed":"1023","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1023.0},{"chemical_system":"BI-CE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-QZX5TWAEQA","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3","row":12},"model":"Md30dd759","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"CE":0.9659},"composition_source":"printed","phase":"L"},{"basis":"mole_fraction","composition":{"BI":0.333333,"CE":0.666667},"composition_source":"stoichiometric_model_phase","phase":"Ce2Bi"}],"phases":[{"label":"L","model_phase":"LIQUID"},{"label":"Ce2Bi","model_phase":"BICE2","pearson_symbol":"tI12","prototype":"La2Sb","structure_basis":"mapped_model_phase"},{"label":"BCC_A2 (Ce)","model_phase":"BCC_A2","pearson_symbol":"cI2","prototype":"W","structure_basis":"mapped_model_phase"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p5/tab-3/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> Ce2Bi + BCC_A2 (Ce)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-CE","system":"BI-CE","temperature_K":1019.0,"temperature_printed":"1019","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19p","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1019.0},{"chemical_system":"BI-CE","citations_printed":["[10]"],"cited_sources":[{"doi":"10.1016/0022-5088(78)90067-x","first_author":"Borzone","kind":"unknown","label":"10","paper":"doi:10.1016/0022-5088(78)90067-x","reference":"G. Borzone, A. Borsese, A. Calabretta, R. Ferro, J. Less-Common Met. 58 (1978) 31–39.","status":"resolved","year":"1978"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"proposed","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"HM_FORM without the phases of its state (compounds_in_quote:5)","effect":"not_accepted","gate":"R3"}],"id":"ORC-5ZTLRVCBQI.1bf5c9","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p2/text-55"},"method":"isoperibol direct calorimeter","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"equilibrium_property","origin":{"class":"experimental","measured_in":"doi:10.1016/0022-5088(78)90067-x","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","pid":"doi:10.1016/j.calphad.2012.05.004/p2/text-55/s03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_FORM","property_group":"formation","property_printed":"heats of formation","quote":"The heats of formation of intermetallic compounds in the Ce-Bi system were measured at 300 K by Borzone et al. [10] using an isoperibol direct calorimeter. The following values were measured for the various compounds: Ce2Bi,   81.6 kJ/mol; Ce5Bi3,   91.7 kJ/mol; Ce4Bi3,   101.3 kJ/mol; CeBi,   114.7 kJ/mol and CeBi2,   77.5 kJ/mol.","quote_page":2,"reader_agreement":"single_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-CE","system":"BI-CE","temperature_K":300.0,"temperature_printed":"300 K","tool_release":"release v2 + tools dev copy record build","uncertainty":{"basis":"stated_default","note":"10% placeholder; none printed","value":10.13},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.2,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"value":3.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_stored":"kJ/mol","value":101.3,"value_stored":101.3},{"chemical_system":"BI-CE","citations_printed":["[10]"],"cited_sources":[{"doi":"10.1016/0022-5088(78)90067-x","first_author":"Borzone","kind":"unknown","label":"10","paper":"doi:10.1016/0022-5088(78)90067-x","reference":"G. Borzone, A. Borsese, A. Calabretta, R. Ferro, J. Less-Common Met. 58 (1978) 31–39.","status":"resolved","year":"1978"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"proposed","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"HM_FORM without the phases of its state (compounds_in_quote:5)","effect":"not_accepted","gate":"R3"}],"id":"ORC-5ZTLRVCBQI.43a9b4","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p2/text-55"},"method":"isoperibol direct calorimeter","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"equilibrium_property","origin":{"class":"experimental","measured_in":"doi:10.1016/0022-5088(78)90067-x","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","pid":"doi:10.1016/j.calphad.2012.05.004/p2/text-55/s03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_FORM","property_group":"formation","property_printed":"heats of formation","quote":"The heats of formation of intermetallic compounds in the Ce-Bi system were measured at 300 K by Borzone et al. [10] using an isoperibol direct calorimeter. The following values were measured for the various compounds: Ce2Bi,   81.6 kJ/mol; Ce5Bi3,   91.7 kJ/mol; Ce4Bi3,   101.3 kJ/mol; CeBi,   114.7 kJ/mol and CeBi2,   77.5 kJ/mol.","quote_page":2,"reader_agreement":"single_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-CE","system":"BI-CE","temperature_K":300.0,"temperature_printed":"300 K","tool_release":"release v2 + tools dev copy record build","uncertainty":{"basis":"stated_default","note":"10% placeholder; none printed","value":9.17},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.2,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"value":3.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_stored":"kJ/mol","value":91.7,"value_stored":91.7},{"chemical_system":"BI-CE","citations_printed":["[10]"],"cited_sources":[{"doi":"10.1016/0022-5088(78)90067-x","first_author":"Borzone","kind":"unknown","label":"10","paper":"doi:10.1016/0022-5088(78)90067-x","reference":"G. Borzone, A. Borsese, A. Calabretta, R. Ferro, J. Less-Common Met. 58 (1978) 31–39.","status":"resolved","year":"1978"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"proposed","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"HM_FORM without the phases of its state (compounds_in_quote:5)","effect":"not_accepted","gate":"R3"}],"id":"ORC-5ZTLRVCBQI.905b8f","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p2/text-55"},"method":"isoperibol direct calorimeter","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"equilibrium_property","origin":{"class":"experimental","measured_in":"doi:10.1016/0022-5088(78)90067-x","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","pid":"doi:10.1016/j.calphad.2012.05.004/p2/text-55/s03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_FORM","property_group":"formation","property_printed":"heats of formation","quote":"The heats of formation of intermetallic compounds in the Ce-Bi system were measured at 300 K by Borzone et al. [10] using an isoperibol direct calorimeter. The following values were measured for the various compounds: Ce2Bi,   81.6 kJ/mol; Ce5Bi3,   91.7 kJ/mol; Ce4Bi3,   101.3 kJ/mol; CeBi,   114.7 kJ/mol and CeBi2,   77.5 kJ/mol.","quote_page":2,"reader_agreement":"single_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-CE","system":"BI-CE","temperature_K":300.0,"temperature_printed":"300 K","tool_release":"release v2 + tools dev copy record build","uncertainty":{"basis":"stated_default","note":"10% placeholder; none printed","value":8.16},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.2,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"value":3.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_stored":"kJ/mol","value":81.6,"value_stored":81.6},{"chemical_system":"BI-CE","citations_printed":["[10]"],"cited_sources":[{"doi":"10.1016/0022-5088(78)90067-x","first_author":"Borzone","kind":"unknown","label":"10","paper":"doi:10.1016/0022-5088(78)90067-x","reference":"G. Borzone, A. Borsese, A. Calabretta, R. Ferro, J. Less-Common Met. 58 (1978) 31–39.","status":"resolved","year":"1978"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"proposed","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"HM_FORM without the phases of its state (compounds_in_quote:5)","effect":"not_accepted","gate":"R3"}],"id":"ORC-5ZTLRVCBQI.d16f4c","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p2/text-55"},"method":"isoperibol direct calorimeter","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"equilibrium_property","origin":{"class":"experimental","measured_in":"doi:10.1016/0022-5088(78)90067-x","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","pid":"doi:10.1016/j.calphad.2012.05.004/p2/text-55/s03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_FORM","property_group":"formation","property_printed":"heats of formation","quote":"The heats of formation of intermetallic compounds in the Ce-Bi system were measured at 300 K by Borzone et al. [10] using an isoperibol direct calorimeter. The following values were measured for the various compounds: Ce2Bi,   81.6 kJ/mol; Ce5Bi3,   91.7 kJ/mol; Ce4Bi3,   101.3 kJ/mol; CeBi,   114.7 kJ/mol and CeBi2,   77.5 kJ/mol.","quote_page":2,"reader_agreement":"single_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-CE","system":"BI-CE","temperature_K":300.0,"temperature_printed":"300 K","tool_release":"release v2 + tools dev copy record build","uncertainty":{"basis":"stated_default","note":"10% placeholder; none printed","value":7.75},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.2,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"value":3.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_stored":"kJ/mol","value":77.5,"value_stored":77.5},{"chemical_system":"BI-CE","citations_printed":["[10]"],"cited_sources":[{"doi":"10.1016/0022-5088(78)90067-x","first_author":"Borzone","kind":"unknown","label":"10","paper":"doi:10.1016/0022-5088(78)90067-x","reference":"G. Borzone, A. Borsese, A. Calabretta, R. Ferro, J. Less-Common Met. 58 (1978) 31–39.","status":"resolved","year":"1978"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"proposed","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"HM_FORM without the phases of its state (compounds_in_quote:5)","effect":"not_accepted","gate":"R3"}],"id":"ORC-5ZTLRVCBQI.d66e7d","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.calphad.2012.05.004/p2/text-55"},"method":"isoperibol direct calorimeter","method_basis":"printed in the quoted sentence (fix-up 2026-10-22 gate)","observation_type":"equilibrium_property","origin":{"class":"experimental","measured_in":"doi:10.1016/0022-5088(78)90067-x","own_work_of_paper":false},"paper":"doi:10.1016/j.calphad.2012.05.004","paper_id":"doi:10.1016/j.calphad.2012.05.004","pid":"doi:10.1016/j.calphad.2012.05.004/p2/text-55/s03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"HM_FORM","property_group":"formation","property_printed":"heats of formation","quote":"The heats of formation of intermetallic compounds in the Ce-Bi system were measured at 300 K by Borzone et al. [10] using an isoperibol direct calorimeter. The following values were measured for the various compounds: Ce2Bi,   81.6 kJ/mol; Ce5Bi3,   91.7 kJ/mol; Ce4Bi3,   101.3 kJ/mol; CeBi,   114.7 kJ/mol and CeBi2,   77.5 kJ/mol.","quote_page":2,"reader_agreement":"single_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"unconfirmed (single reader)","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-CE","system":"BI-CE","temperature_K":300.0,"temperature_printed":"300 K","tool_release":"release v2 + tools dev copy record build","uncertainty":{"basis":"stated_default","note":"10% placeholder; none printed","value":11.47},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.2,"sigma_method":{"basis":"calibrated","ci95":[2.201549,4.602285],"class":"solution_reaction_calorimetry","entry":"value_types/HM_FORM/classes/solution_reaction_calorimetry","floor":3.2,"floor_unit":"kJ/mol-atom","n_pairs":80,"value":3.2},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"unstated","unit_stored":"kJ/mol","value":114.7,"value_stored":114.7},{"chemical_system":"BI-CE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1016/j.jnucmat.2017.08.016"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-2SOJTPSC7M.04de1c","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p3/text-02"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","pid":"doi:10.1016/j.jnucmat.2017.08.016/p3/text-02/s19#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Except for Ce4Bi3, which melts congruently at 2013 K, all other four stable compounds are formed through peritectic reactions: L þ CeBi 4 CeBi2 at 1183 K, L þ Ce4Bi3 4 CeBi at 1903 K, L þ Ce4Bi3 4 Ce5Bi3 at 1670 K, and L þ Ce5Bi3 4 Ce2Bi at 1518 K.","quote_page":3,"reaction":{"printed":"L + Ce4Bi3 -> CeBi","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-CE","system":"BI-CE","temperature_K":1903.0,"temperature_printed":"1903 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1903.0},{"chemical_system":"BI-CE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1016/j.jnucmat.2017.08.016"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":true,"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"id":"ORC-2SOJTPSC7M.331159","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p3/text-02"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Ce4Bi3"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p3/text-02/s19#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"TRANSITION_TEMPERATURE","property_group":"phase transition","quote":"Except for Ce4Bi3, which melts congruently at 2013 K, all other four stable compounds are formed through peritectic reactions: L þ CeBi 4 CeBi2 at 1183 K, L þ Ce4Bi3 4 CeBi at 1903 K, L þ Ce4Bi3 4 Ce5Bi3 at 1670 K, and L þ Ce5Bi3 4 Ce2Bi at 1518 K.","quote_page":3,"reaction":{"type":"congruent transformation"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-CE","system":"BI-CE","temperature_K":2013.0,"temperature_printed":"2013 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"congruent transformation","transition_kind_printed":"congruent","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":16.0,"sigma_method":{"basis":"calibrated","ci95":[10.483565,26.208913],"class":"unknown","entry":"value_types/T_TRANSITION/classes/unknown","floor":16.0,"floor_unit":"K","n_pairs":274,"value":16.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_TRANSITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":2013.0},{"chemical_system":"BI-CE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1016/j.jnucmat.2017.08.016"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-2SOJTPSC7M.4c290a","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p3/text-02"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","pid":"doi:10.1016/j.jnucmat.2017.08.016/p3/text-02/s19#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Except for Ce4Bi3, which melts congruently at 2013 K, all other four stable compounds are formed through peritectic reactions: L þ CeBi 4 CeBi2 at 1183 K, L þ Ce4Bi3 4 CeBi at 1903 K, L þ Ce4Bi3 4 Ce5Bi3 at 1670 K, and L þ Ce5Bi3 4 Ce2Bi at 1518 K.","quote_page":3,"reaction":{"printed":"L + Ce4Bi3 -> Ce5Bi3","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-CE","system":"BI-CE","temperature_K":1670.0,"temperature_printed":"1670 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1670.0},{"chemical_system":"BI-CE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1016/j.jnucmat.2017.08.016"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-2SOJTPSC7M.d4b689","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p3/text-02"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","pid":"doi:10.1016/j.jnucmat.2017.08.016/p3/text-02/s19#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Except for Ce4Bi3, which melts congruently at 2013 K, all other four stable compounds are formed through peritectic reactions: L þ CeBi 4 CeBi2 at 1183 K, L þ Ce4Bi3 4 CeBi at 1903 K, L þ Ce4Bi3 4 Ce5Bi3 at 1670 K, and L þ Ce5Bi3 4 Ce2Bi at 1518 K.","quote_page":3,"reaction":{"printed":"L + Ce5Bi3 -> Ce2Bi","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-CE","system":"BI-CE","temperature_K":1518.0,"temperature_printed":"1518 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1518.0},{"chemical_system":"BI-CE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1016/j.jnucmat.2017.08.016"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-2SOJTPSC7M.f112ac","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p3/text-02"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","pid":"doi:10.1016/j.jnucmat.2017.08.016/p3/text-02/s19#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Except for Ce4Bi3, which melts congruently at 2013 K, all other four stable compounds are formed through peritectic reactions: L þ CeBi 4 CeBi2 at 1183 K, L þ Ce4Bi3 4 CeBi at 1903 K, L þ Ce4Bi3 4 Ce5Bi3 at 1670 K, and L þ Ce5Bi3 4 Ce2Bi at 1518 K.","quote_page":3,"reaction":{"printed":"L + CeBi -> CeBi2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-CE","system":"BI-CE","temperature_K":1183.0,"temperature_printed":"1183 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1183.0},{"chemical_system":"BI-CE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1016/j.jnucmat.2017.08.016"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-T4SRKGJNCL.085f76","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p3/text-02"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","pid":"doi:10.1016/j.jnucmat.2017.08.016/p3/text-02/s20#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"There are also two eutectic reactions: L 4 rhombohedral (Bi) þ CeBi2 and L 4 Ce2Bi þ BCC_A2 (Ce) reported at the temperature of 544 K and 1023 K, respectively.","quote_page":3,"reaction":{"printed":"L -> Ce2Bi + BCC_A2 (Ce)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-CE","system":"BI-CE","temperature_K":1023.0,"temperature_printed":"1023 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1023.0},{"chemical_system":"BI-CE","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1016/j.jnucmat.2017.08.016"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":3,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-T4SRKGJNCL.8917b8","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p3/text-02"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","pid":"doi:10.1016/j.jnucmat.2017.08.016/p3/text-02/s20#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"There are also two eutectic reactions: L 4 rhombohedral (Bi) þ CeBi2 and L 4 Ce2Bi þ BCC_A2 (Ce) reported at the temperature of 544 K and 1023 K, respectively.","quote_page":3,"reaction":{"printed":"L -> rhombohedral (Bi) + CeBi2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-CE","system":"BI-CE","temperature_K":544.0,"temperature_printed":"544 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":544.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"BI-CE"}