{"artifacts":{"doi:10.1016/0040-6031(88)87100-4/p2/text-06":{"artifact":"text_passage","label":"page 2, passage 6","page":2},"doi:10.1016/0040-6031(88)87100-4/p5/text-18":{"artifact":"text_passage","label":"page 5, passage 18","page":5}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["BI","GE"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/0040-6031(88)87100-4":{"authors":["P.-Y. Chevalier"],"citation":"P.-Y. Chevalier, Thermodynamic evaluation of the Bi-Ge system, Thermochimica Acta 132, 111-116 (1988).","container":"Thermochimica Acta","doi":"10.1016/0040-6031(88)87100-4","doi_url":"https://doi.org/10.1016/0040-6031(88)87100-4","id":"doi:10.1016/0040-6031(88)87100-4","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"debed1e97b2a40e9","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic evaluation of the Bi-Ge system","year":1988}},"part":1,"parts":1,"records":[{"chemical_system":"BI-GE","citations_printed":["3","4"],"cited_sources":[{"first_author":"Stohr","kind":"unknown","label":"3","reference":"H. Stohr and W. Klemm. Z. Anorg. Chem., 244 (1970) 205.","status":"resolved","year":"1970"},{"first_author":"Ruttewit","kind":"unknown","label":"4","reference":"K. Ruttewit and G. Masing, Z. Metallkd., 32 (1940) 52.","status":"resolved","year":"1940"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:1)","effect":"not_accepted","gate":"R3"}],"id":"ORC-TEX53K23NH","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/0040-6031(88)87100-4/p2/text-06"},"observation_type":"phase_transition","origin":{"class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/0040-6031(88)87100-4","paper_id":"doi:10.1016/0040-6031(88)87100-4","pid":"doi:10.1016/0040-6031(88)87100-4/p2/text-06/s06#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"According to refs. 3 and 4, the eutectic consists of practically pure Bi at T = 544.15 K.","quote_page":2,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-GE","system":"BI-GE","temperature_K":544.15,"temperature_printed":"544.15","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":544.15},{"chemical_system":"BI-GE","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_flags":["NOTE_SELF_FLAG"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":1,"fold_lso":1,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:4)","effect":"not_accepted","gate":"R3"}],"id":"ORC-3VCGOC4IQD","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/0040-6031(88)87100-4/p5/text-18"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"model_value","measured_in":"doi:10.1016/0040-6031(88)87100-4","own_work_of_paper":true},"paper":"doi:10.1016/0040-6031(88)87100-4","paper_id":"doi:10.1016/0040-6031(88)87100-4","pid":"doi:10.1016/0040-6031(88)87100-4/p5/text-18/s04#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"The calculated composition and temperature for the eutectic reaction are xGe = 0.00044 and T = 544.38 K, which can be compared with the calculated values in refs. 0.0002 and 0.0003 and experimental temperature T = 544.15 5and6ofx,,= K.","quote_page":5,"reaction":{"type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more 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