{"artifacts":{"sha256:9ab7b94380286f62/p10/tab-6":{"artifact":"table","caption":"i","label":"6","page":10}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{"doi:10.1016/j.tca.2021.178913":{"context_id":"context:source-doi-10-1016-j-tca-2021-178913","items":[{"applies_to":"U-(LBE)","extraction_accepted":false,"id":"ORC-UI52I6CSVV","method":"XRD and SEM-EDS","page":1,"quote":"The calorimetric investigations of U-(LBE) followed by XRD and SEM-EDS investigations of the mixtures helped in understanding their interaction behaviour.","second_reader_agrees":true,"type":"measurement"},{"extraction_accepted":false,"id":"ORC-DIOO2HSN3S","instrument":"high-temperature Calvet calorimeter, Setaram HT-1000","page":2,"quote":"The basic features of the high-temperature Calvet calorimeter, Setaram HT-1000, are given elsewhere [22].","second_reader_agrees":true,"type":"measurement"},{"extraction_accepted":false,"has_dropped_fields":true,"id":"ORC-HMQIII22JG","method":"direct reaction calorimetry","page":2,"quote":"The enthalpy of mixing of Bi-U liquid solution and the enthalpy of formation of Bi2U intermetallic compound were measured by direct reaction calorimetry.","second_reader_agrees":true,"type":"measurement"}],"paper":"doi:10.1016/j.tca.2021.178913","reader_tier":"preliminary_flash","readers":["gemini-3.8-flash / exp-context-v2.1-quote","claude-opus-5.5 / exp-context-v2.1-quote (claude broker)"],"section_basis":"own_work_method_cues"}},"elements":["BI","PB","U"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1016/j.tca.2021.178913":{"authors":["Renu Agarwal"],"citation":"Renu Agarwal, Understanding uranium interactions with bismuth and lead-bismuth eutectic: Using calorimetric measurements, Thermochimica Acta 699, 178913 (2021).","container":"Thermochimica Acta","doi":"10.1016/j.tca.2021.178913","doi_url":"https://doi.org/10.1016/j.tca.2021.178913","id":"doi:10.1016/j.tca.2021.178913","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"9ab7b94380286f62","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"Understanding uranium interactions with bismuth and lead-bismuth eutectic: Using calorimetric measurements","year":2021}},"part":1,"parts":1,"records":[{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-EOBMIMFLOP","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":1},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"BI":0.9157},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"(Bi,Pb)liq"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔH^bmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.01435},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-0.287,"value_printed":-287.0,"value_stored":-287.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-7SZ2PK7AZU","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":2},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"BI":0.773},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"(Bi,Pb)liq"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔH^bmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.0366},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-0.732,"value_printed":-732.0,"value_stored":-732.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-IUBDHRKNAW","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":3},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"BI":0.6307},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"(Bi,Pb)liq"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔH^bmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.05015},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-1.003,"value_printed":-1003.0,"value_stored":-1003.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-ASI32TVI7E","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":4},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"BI":0.5502},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"(Bi,Pb)liq"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔH^bmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.05435},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-1.087,"value_printed":-1087.0,"value_stored":-1087.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-X3SEE2B46F.53a0e9","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":5},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0047},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.04315},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-0.863,"value_printed":-863.0,"value_stored":-863.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-X3SEE2B46F.a487ed","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":5},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0047},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":9.2188},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-184.376,"value_printed":-184376.0,"value_stored":-184376.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-X3SEE2B46F.e30d6d","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":5},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0047},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.04025},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-0.805,"value_printed":-805.0,"value_stored":-805.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-2KLHD5XTQF.45c648","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":6},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0275},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.19025},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-3.805,"value_printed":-3805.0,"value_stored":-3805.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-2KLHD5XTQF.4b094f","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":6},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0275},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":7.20225},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-144.045,"value_printed":-144045.0,"value_stored":-144045.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-2KLHD5XTQF.703329","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":6},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0275},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.20725},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-4.145,"value_printed":-4145.0,"value_stored":-4145.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-C7GKIO4O6Q.008a24","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":7},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0489},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.3586},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-7.172,"value_printed":-7172.0,"value_stored":-7172.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-C7GKIO4O6Q.717744","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":7},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0489},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.38875},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-7.775,"value_printed":-7775.0,"value_stored":-7775.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-C7GKIO4O6Q.ea68b0","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":7},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0489},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":8.4997},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-169.994,"value_printed":-169994.0,"value_stored":-169994.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-KLFQKMT7N5.3968e9","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":8},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0785},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.6249},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-12.498,"value_printed":-12498.0,"value_stored":-12498.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-KLFQKMT7N5.ed73b5","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":8},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0785},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":7.9447},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-158.894,"value_printed":-158894.0,"value_stored":-158894.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-KLFQKMT7N5.fe36b0","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":8},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0785},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.5764},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-11.528,"value_printed":-11528.0,"value_stored":-11528.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-WWUY7QUSWH.476868","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":9},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.1075},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.79695},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-15.939,"value_printed":-15939.0,"value_stored":-15939.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-WWUY7QUSWH.5d7c49","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":9},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.1075},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":8.2072},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-164.144,"value_printed":-164144.0,"value_stored":-164144.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-WWUY7QUSWH.60784d","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":9},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.1075},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.86335},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-17.267,"value_printed":-17267.0,"value_stored":-17267.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-LPDJOIFQJX.b000db","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":10},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.1335},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.0782},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-21.564,"value_printed":-21564.0,"value_stored":-21564.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-LPDJOIFQJX.bd1642","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":10},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.1335},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.9957},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-19.914,"value_printed":-19914.0,"value_stored":-19914.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-LPDJOIFQJX.e02b28","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":10},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.1335},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":8.2252},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-164.504,"value_printed":-164504.0,"value_stored":-164504.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-FC6VU2OJDA","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":11},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"BI":0.0984},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"(Bi,Pb)liq"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔH^bmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.0163},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-0.326,"value_printed":-326.0,"value_stored":-326.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-ONXC2COTC3","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":12},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"BI":0.2635},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"(Bi,Pb)liq"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r12#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔH^bmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.04075},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-0.815,"value_printed":-815.0,"value_stored":-815.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-LYE3FXCFYP","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":13},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"BI":0.3716},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"(Bi,Pb)liq"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r13#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔH^bmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.05025},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-1.005,"value_printed":-1005.0,"value_stored":-1005.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-257DHT5FC2","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":14},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"BI":0.4437},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"(Bi,Pb)liq"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r14#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔH^bmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.05345},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-1.069,"value_printed":-1069.0,"value_stored":-1069.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-46TRZ4AVDG","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":15},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"BI":0.5101},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"(Bi,Pb)liq"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r15#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔH^bmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.05465},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-1.093,"value_printed":-1093.0,"value_stored":-1093.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-E7EYR3253U","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":16},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"BI":0.5502},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"(Bi,Pb)liq"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r16#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔH^bmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.05375},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-1.075,"value_printed":-1075.0,"value_stored":-1075.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-62J7W7RMMY.76abac","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":17},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0155},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.1096},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-2.192,"value_printed":-2192.0,"value_stored":-2192.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-62J7W7RMMY.ae6787","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":17},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0155},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":7.66795},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-153.359,"value_printed":-153359.0,"value_stored":-153359.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-62J7W7RMMY.bf5592","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":17},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0155},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r17#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.1192},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-2.384,"value_printed":-2384.0,"value_stored":-2384.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-MBRN5EF6IM.6ec8d6","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":18},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0345},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.28035},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-5.607,"value_printed":-5607.0,"value_stored":-5607.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-MBRN5EF6IM.abd035","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":18},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0345},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":8.5047},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-170.094,"value_printed":-170094.0,"value_stored":-170094.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-MBRN5EF6IM.de9277","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":18},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0345},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r18#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.25905},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-5.181,"value_printed":-5181.0,"value_stored":-5181.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-QSVCPEXXDY.83e20d","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":19},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0512},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r19#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.4122},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-8.244,"value_printed":-8244.0,"value_stored":-8244.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-QSVCPEXXDY.8c4f56","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":19},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0512},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r19#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":7.8901},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-157.802,"value_printed":-157802.0,"value_stored":-157802.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-QSVCPEXXDY.b9c58e","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":19},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0512},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r19#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.3806},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-7.612,"value_printed":-7612.0,"value_stored":-7612.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-DQPZEV4K6T.75cb62","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":20},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0617},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r20#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.49245},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-9.849,"value_printed":-9849.0,"value_stored":-9849.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-DQPZEV4K6T.a19145","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":20},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0617},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r20#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":7.6546},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-153.092,"value_printed":-153092.0,"value_stored":-153092.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-DQPZEV4K6T.ee6c60","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":20},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0617},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r20#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.4543},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-9.086,"value_printed":-9086.0,"value_stored":-9086.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-2VIUQAXVRG.3d6907","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":21},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0789},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r21#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":8.0065},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-160.13,"value_printed":-160130.0,"value_stored":-160130.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-2VIUQAXVRG.8870d7","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":21},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0789},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r21#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.5819},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-11.638,"value_printed":-11638.0,"value_stored":-11638.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-2VIUQAXVRG.bde24c","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":21},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0789},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r21#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.6307},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-12.614,"value_printed":-12614.0,"value_stored":-12614.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-AGJUGAIUGU.163392","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":22},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0972},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r22#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.78655},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-15.731,"value_printed":-15731.0,"value_stored":-15731.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-AGJUGAIUGU.1b860a","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":22},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0972},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r22#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":8.48935},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-169.787,"value_printed":-169787.0,"value_stored":-169787.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-AGJUGAIUGU.fa0cbf","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":22},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0972},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r22#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.72645},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-14.529,"value_printed":-14529.0,"value_stored":-14529.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-XUSHVA4NLJ.4a505e","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":23},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.1114},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r23#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":7.88265},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-157.653,"value_printed":-157653.0,"value_stored":-157653.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-XUSHVA4NLJ.8ce065","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":23},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.1114},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r23#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.89775},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-17.955,"value_printed":-17955.0,"value_stored":-17955.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-XUSHVA4NLJ.e0bd4d","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":23},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.1114},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r23#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.82895},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-16.579,"value_printed":-16579.0,"value_stored":-16579.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-FZWUQ4VHXE.229e07","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":24},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.1264},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r24#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.93895},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-18.779,"value_printed":-18779.0,"value_stored":-18779.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-FZWUQ4VHXE.4a04fa","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":24},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.1264},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r24#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":1.01705},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-20.341,"value_printed":-20341.0,"value_stored":-20341.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-FZWUQ4VHXE.5411c7","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":24},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.1264},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r24#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":7.9574},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-159.148,"value_printed":-159148.0,"value_stored":-159148.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-LK3LFXTWLL","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":25},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"BI":0.204},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"(Bi,Pb)liq"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r25#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔH^bmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.0341},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-0.682,"value_printed":-682.0,"value_stored":-682.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-5NUVIYZ2QN","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":26},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"BI":0.3439},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"(Bi,Pb)liq"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r26#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔH^bmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.04875},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-0.975,"value_printed":-975.0,"value_stored":-975.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-ZCVDMCZXO3","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":27},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"BI":0.443},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"(Bi,Pb)liq"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r27#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔH^bmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.0538},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-1.076,"value_printed":-1076.0,"value_stored":-1076.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-MT7XYBA2EF","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":28},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"BI":0.5179},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"(Bi,Pb)liq"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r28#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔH^bmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.0546},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-1.092,"value_printed":-1092.0,"value_stored":-1092.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-GD3MD76ONA","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":29},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"BI":0.5502},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"(Bi,Pb)liq"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r29#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"ΔH^bmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.05395},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-1.079,"value_printed":-1079.0,"value_stored":-1079.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-S2FJR2ITVL.314699","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":30},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0128},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r30#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.08555},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-1.711,"value_printed":-1711.0,"value_stored":-1711.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-S2FJR2ITVL.822252","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":30},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0128},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r30#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.09345},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-1.869,"value_printed":-1869.0,"value_stored":-1869.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-S2FJR2ITVL.8bfe4d","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":30},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0128},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r30#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":7.28265},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-145.653,"value_printed":-145653.0,"value_stored":-145653.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-I3GP566CXU.18050f","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":31},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.027},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r31#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.19},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-3.8,"value_printed":-3800.0,"value_stored":-3800.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-I3GP566CXU.7b8e0c","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":31},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.027},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r31#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.2067},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-4.134,"value_printed":-4134.0,"value_stored":-4134.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-I3GP566CXU.e74733","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":31},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.027},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r31#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":8.00125},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-160.025,"value_printed":-160025.0,"value_stored":-160025.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-47YSDMAPXR.4c34aa","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":32},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0422},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r32#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.3392},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-6.784,"value_printed":-6784.0,"value_stored":-6784.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-47YSDMAPXR.b1f489","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":32},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0422},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r32#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.3131},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-6.262,"value_printed":-6262.0,"value_stored":-6262.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-47YSDMAPXR.ccfb25","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":32},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0422},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r32#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":8.663},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-173.26,"value_printed":-173260.0,"value_stored":-173260.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-XHNYTVSHE2.13d4fd","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":33},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0636},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r33#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.50615},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-10.123,"value_printed":-10123.0,"value_stored":-10123.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-XHNYTVSHE2.20bc58","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":33},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0636},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r33#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":7.81535},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-156.307,"value_printed":-156307.0,"value_stored":-156307.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-XHNYTVSHE2.e668a8","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":33},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0636},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r33#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.46685},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-9.337,"value_printed":-9337.0,"value_stored":-9337.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-SXNR3XVTU2.08df2c","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":34},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0886},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r34#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ1H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.65325},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-13.065,"value_printed":-13065.0,"value_stored":-13065.0},{"chemical_system":"BI-PB-U","component":"U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-SXNR3XVTU2.a3afa0","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":34},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0886},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r34#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PARTIAL_ENTHALPY","property_group":"mixing / partial","property_printed":"ΔiHU^mix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":8.06235},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"column_header","unit_printed":"J.at-mol−1","unit_stored":"J.at-mol−1","value":-161.247,"value_printed":-161247.0,"value_stored":-161247.0},{"chemical_system":"BI-PB-U","conditions":{"kind":"paper_context","paper":"doi:10.1016/j.tca.2021.178913"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:reference_state"],"state_fully_specified":false},"fold_lpo":2,"fold_lso":4,"id":"ORC-SXNR3XVTU2.cf0fc4","locator":{"ref":"sha256:9ab7b94380286f62/p10/tab-6","row":34},"observation_type":"equilibrium_property","origin":{"basis":"reviewer_table_origin:experimental","class":"experimental","measured_in":"doi:10.1016/j.tca.2021.178913","own_work_of_paper":true},"overall_composition":{"U":0.0886},"paper":"doi:10.1016/j.tca.2021.178913","paper_id":"doi:10.1016/j.tca.2021.178913","phases":[{"label":"LBE(l)"}],"pid":"sha256:9ab7b94380286f62/p10/tab-6/r34#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_MIX","property_group":"mixing / partial","property_printed":"Δ2H^Pbmix","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PB":{"phase":"printed:none"},"U":{"phase":"printed:none"}},"source_system":"BI-PB-U","system":"BI-PB-U","temperature_K":843.0,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.708},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":1.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/H_MIX_PARTIAL/classes/unknown","floor":1.0,"floor_unit":"kJ/mol","n_pairs":1,"prior_source":"kubaschewski","value":1.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"kJ/mol (basis unstated)","value_type":"H_MIX_PARTIAL"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol (basis unstated)","unit_basis":"assumed_per_mole_of_atoms","unit_printed":"J.at-mol−1","unit_stored":"J/mol (basis unstated)","value":-14.16,"value_printed":-14160.0,"value_stored":-14160.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"BI-PB-U"}