{"artifacts":{"doi:10.1016/j.jnucmat.2017.08.016/p2/text-30":{"artifact":"text_passage","label":"page 2, passage 30","page":2},"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1":{"artifact":"table","caption":"Invariant reactions in the Bi-Pr binary system.","label":"1","page":4},"sha256:414670b8925c12d6/p6/tab-7":{"artifact":"table","caption":"Enthalpies of formation of the intermetallic compounds in the Bi-Pr system.","label":"7","page":6},"sha256:414670b8925c12d6/p7/tab-10":{"artifact":"table","caption":"Entropies of formation of intermetallic compounds for the Bi-Pr, Bi-Ce, and Bi-Er systems.","label":"10","page":7}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["BI","PR"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/bf02814890":{"authors":["R. B. Griffin","K. A. Gschneidner"],"citation":"R. B. Griffin, K. A. Gschneidner, Effect of the sixth period elements on the melting and transformation temperatures of praseodymium: Part I. Experimental, Metall Trans 2, 2517-2524 (1971).","container":"Metall Trans","doi":"10.1007/bf02814890","doi_url":"https://doi.org/10.1007/bf02814890","id":"doi:10.1007/bf02814890","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Effect of the sixth period elements on the melting and transformation temperatures of praseodymium: Part I. Experimental","year":1971},"doi:10.1016/0022-5088(84)90320-5":{"authors":["C. Colinet","A. Pasturel","A. Percheron-Guégan","J.C. Achard"],"citation":"C. Colinet, A. Pasturel, A. Percheron-Guégan, J.C. Achard, Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements, Journal of the Less Common Metals 102, 239-249 (1984).","container":"Journal of the Less Common Metals","doi":"10.1016/0022-5088(84)90320-5","doi_url":"https://doi.org/10.1016/0022-5088(84)90320-5","id":"doi:10.1016/0022-5088(84)90320-5","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements","year":1984},"doi:10.1016/0040-6031(75)80024-4":{"authors":["A. Borsese","R. Ferro","R. Capelli","S. Delfino"],"citation":"A. Borsese, R. Ferro, R. Capelli, S. Delfino, Heat of formation of PraseodymiumBismuth alloys, Thermochimica Acta 11, 205-210 (1975).","container":"Thermochimica Acta","doi":"10.1016/0040-6031(75)80024-4","doi_url":"https://doi.org/10.1016/0040-6031(75)80024-4","id":"doi:10.1016/0040-6031(75)80024-4","kind":"cited_work","metadata_source":"crossref","roles":["cited_source"],"source_kinds":["cited_work"],"title":"Heat of formation of PraseodymiumBismuth alloys","year":1975},"doi:10.1016/j.jnucmat.2017.08.016":{"authors":["Yafei Wang","Wentao Zhou","Shaoqiang Guo","Jinsuo Zhang"],"citation":"Yafei Wang, Wentao Zhou, Shaoqiang Guo, Jinsuo Zhang, Thermodynamic properties of fission products (Pr, Ce, Er) in liquid bismuth by thermodynamic assessment, Journal of Nuclear Materials 495, 181-191 (2017).","container":"Journal of Nuclear Materials","doi":"10.1016/j.jnucmat.2017.08.016","doi_url":"https://doi.org/10.1016/j.jnucmat.2017.08.016","id":"doi:10.1016/j.jnucmat.2017.08.016","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"414670b8925c12d6","roles":["cited_source","reporting_paper"],"source_kinds":["journal_article"],"title":"Thermodynamic properties of fission products (Pr, Ce, Er) in liquid bismuth by thermodynamic assessment","year":2017}},"part":1,"parts":1,"records":[{"chemical_system":"BI-PR","cited_sources":[{"doi":"10.1016/0022-5088(84)90320-5","first_author":"Colinet","kind":"assessment","label":"38","paper":"doi:10.1016/0022-5088(84)90320-5","reference":"C. Colinet, et al., Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements, J. Less Common Metals 102 (2) (1984) 239e249.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":4,"id":"ORC-YL7O5PX7HP.45e912","locator":{"ref":"sha256:414670b8925c12d6/p6/tab-7","row":1},"merged_ids":["ORC-YL7O5PX7HP.b971be"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"BI":0.667,"PR":0.333},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"PrBi2"}],"pid":"sha256:414670b8925c12d6/p6/tab-7/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-PR","system":"BI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.95},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-79.0,"value_printed":-79,"value_stored":-79000.0},{"chemical_system":"BI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":4,"id":"ORC-OEEK2YP3NN.21f7c2","locator":{"ref":"sha256:414670b8925c12d6/p6/tab-7","row":2},"merged_ids":["ORC-OEEK2YP3NN.9acb66"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"BI":0.667,"PR":0.333},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"PrBi2"}],"pid":"sha256:414670b8925c12d6/p6/tab-7/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-PR","system":"BI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":3.9349},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-78.698,"value_printed":-78.698,"value_stored":-78698.0},{"chemical_system":"BI-PR","cited_sources":[{"doi":"10.1016/0022-5088(84)90320-5","first_author":"Colinet","kind":"assessment","label":"38","paper":"doi:10.1016/0022-5088(84)90320-5","reference":"C. Colinet, et al., Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements, J. Less Common Metals 102 (2) (1984) 239e249.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":4,"id":"ORC-SKRJI24TSA.7fcaeb","locator":{"ref":"sha256:414670b8925c12d6/p6/tab-7","row":3},"merged_ids":["ORC-SKRJI24TSA.c878ef"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"BI":0.5,"PR":0.5},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"PrBi"}],"pid":"sha256:414670b8925c12d6/p6/tab-7/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-PR","system":"BI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.85},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-97.0,"value_printed":-97,"value_stored":-97000.0},{"chemical_system":"BI-PR","cited_sources":[{"doi":"10.1016/0040-6031(75)80024-4","first_author":"Borsese","kind":"assessment","label":"40","paper":"doi:10.1016/0040-6031(75)80024-4","reference":"A. Borsese, R. Ferro, R. Capelli, S. Delfino, Thermochim. Acta 11 (1975) 205.","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":4,"id":"ORC-D4ICXWIL6F.98e2f2","locator":{"ref":"sha256:414670b8925c12d6/p6/tab-7","row":4},"merged_ids":["ORC-D4ICXWIL6F.e71cf4"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"BI":0.5,"PR":0.5},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"PrBi"}],"pid":"sha256:414670b8925c12d6/p6/tab-7/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-PR","system":"BI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":5.0},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-100.0,"value_printed":-100,"value_stored":-100000.0},{"chemical_system":"BI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":4,"id":"ORC-M6HLMDXRDA.6f03c3","locator":{"ref":"sha256:414670b8925c12d6/p6/tab-7","row":5},"merged_ids":["ORC-M6HLMDXRDA.9eb05a"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"BI":0.5,"PR":0.5},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"PrBi"}],"pid":"sha256:414670b8925c12d6/p6/tab-7/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-PR","system":"BI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.88245},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-97.649,"value_printed":-97.649,"value_stored":-97649.0},{"chemical_system":"BI-PR","cited_sources":[{"doi":"10.1016/0022-5088(84)90320-5","first_author":"Colinet","kind":"assessment","label":"38","paper":"doi:10.1016/0022-5088(84)90320-5","reference":"C. Colinet, et al., Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements, J. Less Common Metals 102 (2) (1984) 239e249.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":4,"id":"ORC-GTBFCTYUGK.79bcb6","locator":{"ref":"sha256:414670b8925c12d6/p6/tab-7","row":6},"merged_ids":["ORC-GTBFCTYUGK.7c3cf9"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"BI":0.429,"PR":0.571},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Pr4Bi3"}],"pid":"sha256:414670b8925c12d6/p6/tab-7/r06#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-PR","system":"BI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.7},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-94.0,"value_printed":-94,"value_stored":-94000.0},{"chemical_system":"BI-PR","cited_sources":[{"doi":"10.1016/0040-6031(75)80024-4","first_author":"Borsese","kind":"assessment","label":"40","paper":"doi:10.1016/0040-6031(75)80024-4","reference":"A. Borsese, R. Ferro, R. Capelli, S. Delfino, Thermochim. Acta 11 (1975) 205.","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":4,"id":"ORC-5ZXYBMGTJQ.24b63f","locator":{"ref":"sha256:414670b8925c12d6/p6/tab-7","row":7},"merged_ids":["ORC-5ZXYBMGTJQ.91bb29"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"BI":0.429,"PR":0.571},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Pr4Bi3"}],"pid":"sha256:414670b8925c12d6/p6/tab-7/r07#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-PR","system":"BI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.7},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-94.0,"value_printed":-94,"value_stored":-94000.0},{"chemical_system":"BI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":4,"id":"ORC-JKT3WHXMN5.8c3526","locator":{"ref":"sha256:414670b8925c12d6/p6/tab-7","row":8},"merged_ids":["ORC-JKT3WHXMN5.f35af8"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"BI":0.429,"PR":0.571},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Pr4Bi3"}],"pid":"sha256:414670b8925c12d6/p6/tab-7/r08#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-PR","system":"BI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.64385},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-92.877,"value_printed":-92.877,"value_stored":-92877.0},{"chemical_system":"BI-PR","cited_sources":[{"doi":"10.1016/0022-5088(84)90320-5","first_author":"Colinet","kind":"assessment","label":"38","paper":"doi:10.1016/0022-5088(84)90320-5","reference":"C. Colinet, et al., Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements, J. Less Common Metals 102 (2) (1984) 239e249.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":4,"id":"ORC-4CMH7Y3H54.d1dc2c","locator":{"ref":"sha256:414670b8925c12d6/p6/tab-7","row":9},"merged_ids":["ORC-4CMH7Y3H54.d33978"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"BI":0.375,"PR":0.625},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Pr5Bi3"}],"pid":"sha256:414670b8925c12d6/p6/tab-7/r09#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-PR","system":"BI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.4},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-88.0,"value_printed":-88,"value_stored":-88000.0},{"chemical_system":"BI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":4,"id":"ORC-HG25SSGH2U.323afa","locator":{"ref":"sha256:414670b8925c12d6/p6/tab-7","row":10},"merged_ids":["ORC-HG25SSGH2U.9abdef"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"BI":0.375,"PR":0.625},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Pr5Bi3"}],"pid":"sha256:414670b8925c12d6/p6/tab-7/r10#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-PR","system":"BI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.4068},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-88.136,"value_printed":-88.136,"value_stored":-88136.0},{"chemical_system":"BI-PR","cited_sources":[{"doi":"10.1016/0022-5088(84)90320-5","first_author":"Colinet","kind":"assessment","label":"38","paper":"doi:10.1016/0022-5088(84)90320-5","reference":"C. Colinet, et al., Enthalpies of formation of liquid and solid binary alloys of lead, antimony and bismuth with rare earth elements, J. Less Common Metals 102 (2) (1984) 239e249.","status":"resolved","year":"1984"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":4,"id":"ORC-OSJNZ5NJFP.b897c6","locator":{"ref":"sha256:414670b8925c12d6/p6/tab-7","row":11},"merged_ids":["ORC-OSJNZ5NJFP.ff502c"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"cited_reference_is_assessment","class":"model_value","own_work_of_paper":false},"overall_composition":{"BI":0.333,"PR":0.667},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Pr2Bi"}],"pid":"sha256:414670b8925c12d6/p6/tab-7/r11#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-PR","system":"BI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-81.0,"value_printed":-81,"value_stored":-81000.0},{"chemical_system":"BI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"basis_inferred_from_magnitude":true,"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false},"fold_lpo":3,"fold_lso":4,"id":"ORC-TXW5NO6YMS.154e5f","locator":{"ref":"sha256:414670b8925c12d6/p6/tab-7","row":12},"merged_ids":["ORC-TXW5NO6YMS.b1c776"],"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"BI":0.333,"PR":0.667},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Pr2Bi"}],"pid":"sha256:414670b8925c12d6/p6/tab-7/r12#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"HM_FORM","property_group":"formation","property_printed":"ΔHf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-PR","system":"BI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":4.07},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":3.9,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.54664],"class":"model_calculated","entry":"model/HM_FORM","floor":3.9,"floor_unit":"kJ/mol-atom","n_pairs":2045,"value":3.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"kJ/mol-atom","value_type":"HM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"kJ/mol-atom","unit_basis":"magnitude_heuristic","unit_printed":"kJ/mol","unit_stored":"J/mol-atom","value":-81.4,"value_printed":-81.4,"value_stored":-81400.0},{"chemical_system":"BI-PR","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BI-PR","before":"BI-CE-ER-PR","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"PR":0.333},"phases":["PrBi2"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-5F7SI7SOXF","locator":{"ref":"sha256:414670b8925c12d6/p7/tab-10","row":1},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"PR":0.333},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"PrBi2"}],"pid":"sha256:414670b8925c12d6/p7/tab-10/r01#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"reference_state_stored":{"BI":{"phase":"printed:none"},"CE":{"phase":"printed:none"},"ER":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-CE-ER-PR","system":"BI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.296},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.9,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"scaled_for_unstated_basis":3,"value":9.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"unstated","unit_printed":"J/mol","value":5.92,"value_printed":5.92},{"chemical_system":"BI-PR","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BI-PR","before":"BI-CE-ER-PR","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"PR":0.5},"phases":["PrBi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-MFRSX2ZWJT","locator":{"ref":"sha256:414670b8925c12d6/p7/tab-10","row":2},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"PR":0.5},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"PrBi"}],"pid":"sha256:414670b8925c12d6/p7/tab-10/r02#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"reference_state_stored":{"BI":{"phase":"printed:none"},"CE":{"phase":"printed:none"},"ER":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-CE-ER-PR","system":"BI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.378},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":6.6,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"scaled_for_unstated_basis":2,"value":6.6},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"unstated","unit_printed":"J/mol","value":7.56,"value_printed":7.56},{"chemical_system":"BI-PR","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BI-PR","before":"BI-CE-ER-PR","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"PR":0.571},"phases":["Pr4Bi3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-77HJ5NJTA6","locator":{"ref":"sha256:414670b8925c12d6/p7/tab-10","row":3},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"PR":0.571},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Pr4Bi3"}],"pid":"sha256:414670b8925c12d6/p7/tab-10/r03#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"reference_state_stored":{"BI":{"phase":"printed:none"},"CE":{"phase":"printed:none"},"ER":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-CE-ER-PR","system":"BI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.4165},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":23.1,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"scaled_for_unstated_basis":7,"value":23.1},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"unstated","unit_printed":"J/mol","value":8.33,"value_printed":8.33},{"chemical_system":"BI-PR","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BI-PR","before":"BI-CE-ER-PR","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"PR":0.625},"phases":["Pr5Bi3"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-WIY42FFWRC","locator":{"ref":"sha256:414670b8925c12d6/p7/tab-10","row":4},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"PR":0.625},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Pr5Bi3"}],"pid":"sha256:414670b8925c12d6/p7/tab-10/r04#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"reference_state_stored":{"BI":{"phase":"printed:none"},"CE":{"phase":"printed:none"},"ER":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-CE-ER-PR","system":"BI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.232},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":26.4,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"scaled_for_unstated_basis":8,"value":26.4},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"unstated","unit_printed":"J/mol","value":4.64,"value_printed":4.64},{"chemical_system":"BI-PR","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":"BI-PR","before":"BI-CE-ER-PR","evidence":{"basis":"phase_formula_with_partial_overall_composition","overall_composition":{"PR":0.667},"phases":["Pr2Bi"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["reference-dependent quantity without a resolved reference state","state:T_K","state:reference_state","temperature not stated"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-OJMMMWLZU2","locator":{"ref":"sha256:414670b8925c12d6/p7/tab-10","row":5},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"equilibrium_property","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"overall_composition":{"PR":0.667},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phases":[{"label":"Pr2Bi"}],"pid":"sha256:414670b8925c12d6/p7/tab-10/r05#equilibrium_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"SM_FORM","property_group":"formation","property_printed":"ΔSf","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","reference_state":{"BI":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"reference_state_stored":{"BI":{"phase":"printed:none"},"CE":{"phase":"printed:none"},"ER":{"phase":"printed:none"},"PR":{"phase":"printed:none"}},"source_system":"BI-CE-ER-PR","system":"BI-PR","temperature_basis":"not_printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"stated_default","note":"5% default","value":0.141},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":9.9,"sigma_method":{"basis":"calibrated","ci95":[1.937758,4.143867],"class":"model_calculated","entry":"model/SM_FORM","floor":3.3,"floor_unit":"J/K/mol-atom","n_pairs":118,"scaled_for_unstated_basis":3,"value":9.9},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"J/mol (basis unstated)/K","value_type":"SM_FORM"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"J/mol (basis unstated)/K","unit_basis":"unstated","unit_printed":"J/mol","value":2.82,"value_printed":2.82},{"chemical_system":"BI-PR","cited_sources":[{"first_author":"William","kind":"assessment","label":"37","reference":"William G. Moffatt, The Handbook of Binary Phase Diagrams, vol. 1, Genium Pub. Corp., 1976, 11/85.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-KCX752R7UF","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1","row":1},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"PR":0.0},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L"},{"label":"rhombohedral (Bi)"},{"label":"PrBi2"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> rhombohedral (Bi) + PrBi2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-PR","system":"BI-PR","temperature_K":544.0,"temperature_printed":"544","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":544.0},{"chemical_system":"BI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-LBYW7HK5IS","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1","row":2},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"PR":5e-06},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L"},{"label":"rhombohedral (Bi)"},{"label":"PrBi2"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1/r02#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> rhombohedral (Bi) + PrBi2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-PR","system":"BI-PR","temperature_K":544.5,"temperature_printed":"544.5","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":null,"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":544.5},{"chemical_system":"BI-PR","cited_sources":[{"first_author":"William","kind":"assessment","label":"37","reference":"William G. Moffatt, The Handbook of Binary Phase Diagrams, vol. 1, Genium Pub. Corp., 1976, 11/85.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-42JJAVZ7VC","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1","row":3},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"PR":0.3},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L"},{"label":"PrBi"},{"label":"PrBi2"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + PrBi -> PrBi2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-PR","system":"BI-PR","temperature_K":1773.0,"temperature_printed":"1773","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.05,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1773.0},{"chemical_system":"BI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-Q2CNUDX4BW","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1","row":4},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"PR":0.3031},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L"},{"label":"PrBi"},{"label":"PrBi2"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1/r04#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + PrBi -> PrBi2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-PR","system":"BI-PR","temperature_K":1771.0,"temperature_printed":"1771","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1771.0},{"chemical_system":"BI-PR","cited_sources":[{"first_author":"William","kind":"assessment","label":"37","reference":"William G. Moffatt, The Handbook of Binary Phase Diagrams, vol. 1, Genium Pub. Corp., 1976, 11/85.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-A2ZBRJRMSF","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1","row":5},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"PR":0.61},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L"},{"label":"PrBi"},{"label":"Pr4Bi3"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1/r05#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + PrBi -> Pr4Bi3","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-PR","system":"BI-PR","temperature_K":1923.0,"temperature_printed":"1923","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1923.0},{"chemical_system":"BI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-FG6PKOTNX6","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1","row":6},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"PR":0.6137},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L"},{"label":"PrBi"},{"label":"Pr4Bi3"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1/r06#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + PrBi -> Pr4Bi3","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-PR","system":"BI-PR","temperature_K":1922.0,"temperature_printed":"1922","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1922.0},{"chemical_system":"BI-PR","cited_sources":[{"first_author":"William","kind":"assessment","label":"37","reference":"William G. Moffatt, The Handbook of Binary Phase Diagrams, vol. 1, Genium Pub. Corp., 1976, 11/85.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-M3CZGMHCFZ","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1","row":7},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"PR":0.78},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L"},{"label":"Pr4Bi3"},{"label":"Pr5Bi3"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1/r07#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Pr4Bi3 -> Pr5Bi3","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-PR","system":"BI-PR","temperature_K":1498.0,"temperature_printed":"1498","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1498.0},{"chemical_system":"BI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-ZLDPLL77VF","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1","row":8},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"PR":0.7851},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L"},{"label":"Pr4Bi3"},{"label":"Pr5Bi3"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1/r08#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Pr4Bi3 -> Pr5Bi3","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-PR","system":"BI-PR","temperature_K":1499.0,"temperature_printed":"1499","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1499.0},{"chemical_system":"BI-PR","cited_sources":[{"first_author":"William","kind":"assessment","label":"37","reference":"William G. Moffatt, The Handbook of Binary Phase Diagrams, vol. 1, Genium Pub. Corp., 1976, 11/85.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-F6SNIQB5N2","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1","row":9},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"PR":0.83},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L"},{"label":"Pr5Bi3"},{"label":"Pr2Bi"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1/r09#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Pr5Bi3 -> Pr2Bi","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-PR","system":"BI-PR","temperature_K":1373.0,"temperature_printed":"1373","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1373.0},{"chemical_system":"BI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-4C5QQPBXGM","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1","row":10},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"PR":0.841},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L"},{"label":"Pr5Bi3"},{"label":"Pr2Bi"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1/r10#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L + Pr5Bi3 -> Pr2Bi","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-PR","system":"BI-PR","temperature_K":1375.0,"temperature_printed":"1375","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"peritectic","transition_kind_printed":"Peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1375.0},{"chemical_system":"BI-PR","cited_sources":[{"doi":"10.1007/bf02814890","first_author":"Griffin","kind":"unknown","label":"33","paper":"doi:10.1007/bf02814890","reference":"R.B. Griffin, K.A. Gschneidner Jr., Metall. Trans. 2 (1971) 2517.","status":"resolved","year":"1971"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-V3TGCPGL6L","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1","row":11},"observation_type":"invariant_reaction","origin":{"basis":"cited_work_title_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"PR":0.97},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L"},{"label":"Pr2Bi"},{"label":"BCC_A2 (Pr)"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1/r11#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> Pr2Bi + BCC_A2 (Pr)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-PR","system":"BI-PR","temperature_K":1167.0,"temperature_printed":"1167","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1167.0},{"chemical_system":"BI-PR","conditions":{"kind":"not_applicable_own_calculation"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":3,"fold_lso":4,"id":"ORC-YW4P6PMD7Q","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1","row":12},"model_unlinked_reason":"reporting paper's own calculation, but no TDB linked to the table","observation_type":"invariant_reaction","origin":{"basis":"this_work+paper_text_states_calculated","class":"model_value","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","phase_compositions":[{"basis":"mole_fraction","composition":{"PR":0.973},"composition_source":"printed","phase":"L"}],"phases":[{"label":"L"},{"label":"Pr2Bi"},{"label":"BCC_A2 (Pr)"}],"pid":"doi:10.1016/j.jnucmat.2017.08.016/p4/tab-1/r12#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"L -> Pr2Bi + BCC_A2 (Pr)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-PR","system":"BI-PR","temperature_K":1168.0,"temperature_printed":"1168","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"eutectic","transition_kind_printed":"Eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1168.0},{"chemical_system":"BI-PR","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1016/j.jnucmat.2017.08.016"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-GRFHBAKUFR.94d057","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p2/text-30"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","pid":"doi:10.1016/j.jnucmat.2017.08.016/p2/text-30/s14#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"There are two eutectic reactions of the L 4 rhombohedral (Bi) þ PrBi2 at 544 K and L 4 Pr2Bi þ BCC_A2 (Pr) at 1167 K.","quote_page":2,"reaction":{"printed":"L -> rhombohedral (Bi) + PrBi2","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-PR","system":"BI-PR","temperature_K":544.0,"temperature_printed":"544 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":544.0},{"chemical_system":"BI-PR","conditions":{"kind":"paper_context_not_extracted","paper":"doi:10.1016/j.jnucmat.2017.08.016"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","dropped_field_count":1,"espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"has_dropped_fields":true,"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-GRFHBAKUFR.9c988f","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p2/text-30"},"observation_type":"phase_transition","origin":{"attribution_note":"no printed citation: the paper's own statement","class":"experimental","measured_in":"doi:10.1016/j.jnucmat.2017.08.016","own_work_of_paper":true},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","pid":"doi:10.1016/j.jnucmat.2017.08.016/p2/text-30/s14#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"There are two eutectic reactions of the L 4 rhombohedral (Bi) þ PrBi2 at 544 K and L 4 Pr2Bi þ BCC_A2 (Pr) at 1167 K.","quote_page":2,"reaction":{"printed":"L -> Pr2Bi + BCC_A2 (Pr)","type":"eutectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-PR","system":"BI-PR","temperature_K":1167.0,"temperature_printed":"1167 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"eutectic","transition_kind_printed":"eutectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":11.0,"sigma_method":{"basis":"calibrated","ci95":[9.435209,10.483565],"class":"unknown","entry":"value_types/T_INVARIANT/classes/unknown","floor":11.0,"floor_unit":"K","n_pairs":4912,"value":11.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1167.0},{"chemical_system":"BI-PR","citations_printed":["37"],"cited_sources":[{"first_author":"William","kind":"assessment","label":"37","reference":"William G. Moffatt, The Handbook of Binary Phase Diagrams, vol. 1, Genium Pub. Corp., 1976, 11/85.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-R6OBXXNUBH.2bf456","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p2/text-30"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","pid":"doi:10.1016/j.jnucmat.2017.08.016/p2/text-30/s15#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Also, four peritectic reactions of the L þ PrBi 4 PrBi2 at 1773 K, L þ PrBi 4 Pr4Bi3 at 1923 K, L þ Pr4Bi3 4 Pr5Bi3 at 1498 K, and L þ Pr5Bi3 4 Pr2Bi at 1373 K exist.","quote_page":2,"reaction":{"printed":"L + Pr4Bi3 -> Pr5Bi3","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-PR","system":"BI-PR","temperature_K":1498.0,"temperature_printed":"1498 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1498.0},{"chemical_system":"BI-PR","citations_printed":["37"],"cited_sources":[{"first_author":"William","kind":"assessment","label":"37","reference":"William G. Moffatt, The Handbook of Binary Phase Diagrams, vol. 1, Genium Pub. Corp., 1976, 11/85.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-R6OBXXNUBH.4b94be","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p2/text-30"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","pid":"doi:10.1016/j.jnucmat.2017.08.016/p2/text-30/s15#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Also, four peritectic reactions of the L þ PrBi 4 PrBi2 at 1773 K, L þ PrBi 4 Pr4Bi3 at 1923 K, L þ Pr4Bi3 4 Pr5Bi3 at 1498 K, and L þ Pr5Bi3 4 Pr2Bi at 1373 K exist.","quote_page":2,"reaction":{"printed":"L + PrBi -> Pr4Bi3","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-PR","system":"BI-PR","temperature_K":1923.0,"temperature_printed":"1923 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1923.0},{"chemical_system":"BI-PR","citations_printed":["37"],"cited_sources":[{"first_author":"William","kind":"assessment","label":"37","reference":"William G. Moffatt, The Handbook of Binary Phase Diagrams, vol. 1, Genium Pub. Corp., 1976, 11/85.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-R6OBXXNUBH.5b126d","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p2/text-30"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","pid":"doi:10.1016/j.jnucmat.2017.08.016/p2/text-30/s15#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Also, four peritectic reactions of the L þ PrBi 4 PrBi2 at 1773 K, L þ PrBi 4 Pr4Bi3 at 1923 K, L þ Pr4Bi3 4 Pr5Bi3 at 1498 K, and L þ Pr5Bi3 4 Pr2Bi at 1373 K exist.","quote_page":2,"reaction":{"printed":"L + Pr5Bi3 -> Pr2Bi","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-PR","system":"BI-PR","temperature_K":1373.0,"temperature_printed":"1373 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1373.0},{"chemical_system":"BI-PR","citations_printed":["37"],"cited_sources":[{"first_author":"William","kind":"assessment","label":"37","reference":"William G. Moffatt, The Handbook of Binary Phase Diagrams, vol. 1, Genium Pub. Corp., 1976, 11/85.","status":"resolved","year":"1976"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["state_phases_missing"],"review_state":"extracted","second_reader":"done","value_in_quote":true},"fold_lpo":3,"fold_lso":4,"gate_failures":[{"code":"state_phases_missing","detail":"INVARIANT_TEMPERATURE without the phases of its state (reactions_in_quote:0)","effect":"not_accepted","gate":"R3"}],"id":"ORC-R6OBXXNUBH.8c5810","link_rule":"quote verbatim on one page/passage + printed value inside quote","locator":{"ref":"doi:10.1016/j.jnucmat.2017.08.016/p2/text-30"},"observation_type":"phase_transition","origin":{"class":"model_value","own_work_of_paper":false},"paper":"doi:10.1016/j.jnucmat.2017.08.016","paper_id":"doi:10.1016/j.jnucmat.2017.08.016","pid":"doi:10.1016/j.jnucmat.2017.08.016/p2/text-30/s15#phase_transition","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","quote":"Also, four peritectic reactions of the L þ PrBi 4 PrBi2 at 1773 K, L þ PrBi 4 Pr4Bi3 at 1923 K, L þ Pr4Bi3 4 Pr5Bi3 at 1498 K, and L þ Pr5Bi3 4 Pr2Bi at 1373 K exist.","quote_page":2,"reaction":{"printed":"L + PrBi -> PrBi2","type":"peritectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash","readers":["claude-opus-5.5","gemini-3.8-flash"],"record_kind":"running_text","source_system":"BI-PR","system":"BI-PR","temperature_K":1773.0,"temperature_printed":"1773 K","tool_release":"release v2 + tools dev copy record build","transition_kind":"peritectic","transition_kind_printed":"peritectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.05},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1773.0}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"BI-PR"}