{"artifacts":{"doi:10.1007/bf02880522/p2/tab-1":{"artifact":"table","caption":"Experimental Coordinates of the Si-Bi Liquidus","label":"1","page":2},"doi:10.1007/bf02880522/p2/tab-2":{"artifact":"table","caption":"Estimated Invariant Points of the Si-Bi System","label":"2","page":2},"doi:10.1007/bf02880522/p3/tab-3":{"artifact":"table","caption":"Crystal Structure and Lattice Parameter Data of Si and Bi at 25 ~","label":"3","page":3}},"cite_as":{"also_cite":["the original source of every value you use (paper_citation / paper_doi, and cited_dois for values the paper cites from earlier work)"],"bibtex":"@misc{orchid_literature_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23735569},\n  url       = {https://doi.org/10.5281/zenodo.23735569},\n  note      = {Version 1, machine-extracted}\n}","dataset":"literature","doi":"10.5281/zenodo.23735569","license":"CC-BY-4.0","part_of":{"bibtex":"@misc{orchid_data_2026,\n  author    = {Arr{\\'o}yave, Raymundo and Saal, James and Shin, Dongwon},\n  title     = {{ORCHID data: umbrella record of the ORCHID datasets}},\n  version   = {2026.10},\n  publisher = {Zenodo},\n  year      = {2026},\n  doi       = {10.5281/zenodo.23736065},\n  url       = {https://doi.org/10.5281/zenodo.23736065},\n  note      = {Version 1, machine-extracted}\n}","doi":"10.5281/zenodo.23736065","text":"R. Arróyave, J. Saal, D. Shin, ORCHID data: umbrella record of the ORCHID datasets (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23736065","title":"ORCHID data: umbrella record of the ORCHID datasets","url":"https://doi.org/10.5281/zenodo.23736065"},"release_tag":"v2026.10","status":"Version 1, machine-extracted: values were read by language-model readers constrained to quote their source and checked automatically, and the release was then audited on the printed pages by adversarial audits, an independent second review of fit-facing records and a preliminary human review of a frozen sample. Flags such as accepted and ESPEI-ready record screening results, not certification; known issues are listed in the release notes.","text":"R. Arróyave, J. Saal, D. Shin, ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature (version 2026.10; Version 1, machine-extracted), Zenodo (2026). https://doi.org/10.5281/zenodo.23735569","title":"ORCHID-Values: thermodynamic and phase-equilibrium values read from the literature","url":"https://doi.org/10.5281/zenodo.23735569","version":"2026.10"},"contexts":{},"elements":["BI","SI"],"licence":"CC BY 4.0 (ORCHID data; quotes are short excerpts kept for verification, the publishers' copyright, not relicensed)","models":{"M2b97b6e2":{"catalog_entry":{"license":"CC BY 4.0","name":"BiSi-85Ole-LB.tdb","source_url":"https://doi.org/10.1016/j.calphad.2025.102833","tier":"bundled"},"link_basis":"reporting_paper_own_model","model_citation":"R.W. Olesinski, G.J. Abbaschian, Bull. Alloy Phase Diagrams, 6, 359-61(1985).","model_doi":"10.1007/bf02880522","reproduced_by_calculation":false,"tdb":"BiSi-85Ole-LB.tdb","tdb_path":"databases/sgte-binary/BiSi-85Ole-LB.tdb","tdb_sha256":"7e76c13e3a365e7675a49933b756c8c540d6c1a2896c6bb6e51ba5036bebc121"}},"note":"records[].locator.ref -> artifacts; records[].model -> models (full records: orchid-literature.jsonl.gz)","papers":{"doi:10.1007/bf02880522":{"authors":["R. W. Olesinski","G. J. Abbaschian"],"citation":"R. W. Olesinski, G. J. Abbaschian, The Bi−Si (Bismuth-Silicon) system, Bulletin of Alloy Phase Diagrams 6, 359-361 (1985).","container":"Bulletin of Alloy Phase Diagrams","doi":"10.1007/bf02880522","doi_url":"https://doi.org/10.1007/bf02880522","id":"doi:10.1007/bf02880522","kind":"corpus_paper","metadata_source":"crossref","pdf_sha256_prefix":"ca09b9b606cad6f9","roles":["reporting_paper"],"source_kinds":["journal_article"],"title":"The Bi−Si (Bismuth-Silicon) system","year":1985}},"part":1,"parts":1,"records":[{"chemical_system":"BI-SI","cited_sources":[{"kind":"unknown","label":"60Thu","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":4,"id":"ORC-4FELAX7HOC","locator":{"ref":"doi:10.1007/bf02880522/p2/tab-1","row":1},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/bf02880522","paper_id":"doi:10.1007/bf02880522","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BI":0.9807,"SI":0.0193},"composition_source":"printed","phase":"liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"BI":0.9807,"SI":0.0193},"composition_source":"printed","phase":"L"}],"phases":[{"label":"liquid","model_phase":"LIQUID"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1007/bf02880522/p2/tab-1/r01#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-SI","system":"BI-SI","temperature_K":1548.15,"temperature_basis":"printed","temperature_printed":"1275","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"BI-SI","cited_sources":[{"kind":"unknown","label":"60Thu","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":4,"id":"ORC-E4RYVFTHUP","locator":{"ref":"doi:10.1007/bf02880522/p2/tab-1","row":2},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/bf02880522","paper_id":"doi:10.1007/bf02880522","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BI":0.9887,"SI":0.0113},"composition_source":"printed","phase":"liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"BI":0.9887,"SI":0.0113},"composition_source":"printed","phase":"L"}],"phases":[{"label":"liquid","model_phase":"LIQUID"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1007/bf02880522/p2/tab-1/r02#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-SI","system":"BI-SI","temperature_K":1473.15,"temperature_basis":"printed","temperature_printed":"1200","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-05},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"BI-SI","cited_sources":[{"kind":"unknown","label":"60Thu","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":4,"id":"ORC-5OKA4BW2QJ","locator":{"ref":"doi:10.1007/bf02880522/p2/tab-1","row":3},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/bf02880522","paper_id":"doi:10.1007/bf02880522","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BI":0.99168,"SI":0.00832},"composition_source":"printed","phase":"liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"BI":0.99168,"SI":0.00832},"composition_source":"printed","phase":"L"}],"phases":[{"label":"liquid","model_phase":"LIQUID"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1007/bf02880522/p2/tab-1/r03#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-SI","system":"BI-SI","temperature_K":1423.15,"temperature_basis":"printed","temperature_printed":"1150","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-06},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"BI-SI","cited_sources":[{"kind":"unknown","label":"60Thu","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":4,"id":"ORC-BOOJNSQTRG","locator":{"ref":"doi:10.1007/bf02880522/p2/tab-1","row":4},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/bf02880522","paper_id":"doi:10.1007/bf02880522","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BI":0.99456,"SI":0.00544},"composition_source":"printed","phase":"liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"BI":0.99456,"SI":0.00544},"composition_source":"printed","phase":"L"}],"phases":[{"label":"liquid","model_phase":"LIQUID"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1007/bf02880522/p2/tab-1/r04#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-SI","system":"BI-SI","temperature_K":1373.15,"temperature_basis":"printed","temperature_printed":"1100","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-06},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"BI-SI","cited_sources":[{"kind":"unknown","label":"60Thu","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":4,"id":"ORC-EZP43UI3SB","locator":{"ref":"doi:10.1007/bf02880522/p2/tab-1","row":5},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/bf02880522","paper_id":"doi:10.1007/bf02880522","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BI":0.99738,"SI":0.00262},"composition_source":"printed","phase":"liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"BI":0.99738,"SI":0.00262},"composition_source":"printed","phase":"L"}],"phases":[{"label":"liquid","model_phase":"LIQUID"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1007/bf02880522/p2/tab-1/r05#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-SI","system":"BI-SI","temperature_K":1273.15,"temperature_basis":"printed","temperature_printed":"1000","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-06},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"BI-SI","cited_sources":[{"first_author":"Girault","kind":"unknown","label":"77Gir","reference":"B. Girault, \"Liquidus Curves of Various Silicon-Metal Systems,\" C.R. Acad. Sci. Paris B, 284, 1-4 (1977) in French. (Equi Diagram; Experimental) *80Whi: C.W. White, S.R. Wilson, B.R. Appleton, and F.W. Young, Jr., \"Supersaturated Substitutional Alloys Formed by Ion Implantation and Pulsed Laser Annealing of Group-III and Group-V Dopants in Silicon,\" J. Appl. Phys., 51,738-749 (1980). (Meta Phases;","status":"resolved","year":1977,"year_basis":"printed_parenthesised_year","year_read":"1985"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_phase_rule":{"basis":"printed_labels","result":"pass"},"espei_ready":true,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":4,"id":"ORC-DMQZDIJZPG","locator":{"ref":"doi:10.1007/bf02880522/p2/tab-1","row":6},"observation_type":"phase_region_vertex_set","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/bf02880522","paper_id":"doi:10.1007/bf02880522","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BI":0.99938,"SI":0.00062},"composition_source":"printed","phase":"liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"BI":0.99938,"SI":0.00062},"composition_source":"printed","phase":"L"}],"phases":[{"label":"liquid","model_phase":"LIQUID"},{"label":"L","model_phase":"LIQUID"}],"pid":"doi:10.1007/bf02880522/p2/tab-1/r06#phase_region_vertex_set","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"PHASE_COMPOSITION","property_group":"phase equilibrium","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-SI","system":"BI-SI","temperature_K":1073.15,"temperature_basis":"printed","temperature_printed":"800","tool_release":"tools-release-v2.1.18","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-06},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"temperature_K":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":5.0,"sigma_method":{"basis":"prior","ci95":null,"class":"unknown","entry":"value_types/T_CONDITION/classes/unknown","floor":5.0,"floor_unit":"K","n_pairs":0,"prior_source":"orchid_assumed","value":5.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.5},"sigma_scatter":null,"unit":"K","value_type":"T_CONDITION"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"}},{"chemical_system":"BI-SI","conditions":{"kind":"own_work_origin_unspecified"},"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted"},"fold_lpo":2,"fold_lso":4,"id":"ORC-6RTWONINIU","locator":{"ref":"doi:10.1007/bf02880522/p3/tab-3","row":1},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","measured_in":"doi:10.1007/bf02880522","own_work_of_paper":true},"paper":"doi:10.1007/bf02880522","paper_id":"doi:10.1007/bf02880522","phase_compositions":[{"basis":"mole_fraction","composition":{"BI":1.8e-05,"SI":0.999982},"composition_source":"printed","phase":"(Si)"}],"phases":[{"label":"(Si)"}],"pid":"doi:10.1007/bf02880522/p3/tab-3/r01#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"BI-SI","structure":{"pearson_symbol":"cF8","prototype":"C (diamond)","strukturbericht":"A4"},"system":"BI-SI","temperature_K":298.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":5e-05},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.011,"sigma_method":{"basis":"calibrated","ci95":[0.010484,0.011532],"class":"unknown","entry":"value_types/X_PHASE/classes/unknown","floor":0.011,"floor_unit":"mole fraction","n_pairs":3014,"value":0.011},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":5e-07},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.01195,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.01195},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":5e-05},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":5.4306,"value_stored":0.54306},{"chemical_system":"BI-SI","conditions":{"kind":"not_applicable_own_calculation"},"corrections":[{"after":["Si-rich liquid","Bi-rich liquid","(Si)"],"before":["Si-rich liquid","Bi-rich liquid"],"evidence":{"added":["(Si)"],"reaction_printed":"Monotectic transformation"},"field":"phases","gate":"G6","rule":"printed_reaction_phase_added_on_page","visual_check":{"checked":"2026-10-24","image_sha256":"a6ffba7de6b7fb5bf613a3fd21c97a344ec3561f6a129e9343ad33cc4880efe1","page":2,"pdf_sha256_prefix":"ca09b9b606cad6f9","seen":"Table 2 Si-Bi: 'Monotectic transformation' Temperature degC 1400 (This work), 1393 [60Thu]; Composition at.% Bi Si-rich liquid 3.3/4.0, Bi-rich liquid 96.7/96.0. Fig. 2: L1 / (Si) + L2.","verdict":"checked"}},{"after":null,"before":"DIAMOND_A4","evidence":{"label":"Si-rich liquid","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"label_not_a_solution_or_structure_name"},{"after":null,"before":"RHOMBOHEDRAL_A7","evidence":{"label":"Bi-rich liquid","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"label_not_a_solution_or_structure_name"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":4,"id":"ORC-SSILTUANW7","locator":{"ref":"doi:10.1007/bf02880522/p2/tab-2","row":1},"model":"M2b97b6e2","observation_type":"invariant_reaction","origin":{"basis":"this_work+caption_names_calc_only","class":"model_value","measured_in":"doi:10.1007/bf02880522","own_work_of_paper":true},"paper":"doi:10.1007/bf02880522","paper_id":"doi:10.1007/bf02880522","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BI":0.033},"composition_source":"printed","phase":"Si-rich liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"BI":0.967},"composition_source":"printed","phase":"Bi-rich liquid"}],"phases":[{"label":"Si-rich liquid","model_phase_rejected":{"model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","reason":"label_not_a_solution_or_structure_name"}},{"label":"Bi-rich liquid","model_phase_rejected":{"model_phase":"RHOMBOHEDRAL_A7","pearson_symbol":"hR2","prototype":"alpha-As","reason":"label_not_a_solution_or_structure_name"}},{"label":"(Si)","label_source":"page_check"}],"phases_stored":["Si-rich liquid","Bi-rich liquid"],"pid":"doi:10.1007/bf02880522/p2/tab-2/r01#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Monotectic transformation","type":"monotectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-SI","system":"BI-SI","temperature_K":1673.15,"temperature_printed":"1400","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"monotectic","transition_kind_printed":"monotectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.0005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1673.15},{"chemical_system":"BI-SI","cited_sources":[{"kind":"unknown","label":"60Thu","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":["Si-rich liquid","Bi-rich liquid","(Si)"],"before":["Si-rich liquid","Bi-rich liquid"],"evidence":{"added":["(Si)"],"reaction_printed":"Monotectic transformation"},"field":"phases","gate":"G6","rule":"printed_reaction_phase_added_on_page","visual_check":{"checked":"2026-10-24","image_sha256":"a6ffba7de6b7fb5bf613a3fd21c97a344ec3561f6a129e9343ad33cc4880efe1","page":2,"pdf_sha256_prefix":"ca09b9b606cad6f9","seen":"Table 2 Si-Bi: 'Monotectic transformation' Temperature degC 1400 (This work), 1393 [60Thu]; Composition at.% Bi Si-rich liquid 3.3/4.0, Bi-rich liquid 96.7/96.0. Fig. 2: L1 / (Si) + L2.","verdict":"checked"}},{"after":null,"before":"DIAMOND_A4","evidence":{"label":"Si-rich liquid","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"label_not_a_solution_or_structure_name"},{"after":null,"before":"RHOMBOHEDRAL_A7","evidence":{"label":"Bi-rich liquid","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 1)"},"field":"phases.model_phase","gate":"PL","rule":"label_not_a_solution_or_structure_name"}],"evidence_class":"model","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","row_state":"settled","state_fully_specified":true},"fold_lpo":2,"fold_lso":4,"id":"ORC-6VMKGH6ZMP","locator":{"ref":"doi:10.1007/bf02880522/p2/tab-2","row":3},"model_unlinked_reason":"cited calculation whose model is not a corpus TDB","observation_type":"invariant_reaction","origin":{"basis":"printed_source_other_calculation","class":"model_value","own_work_of_paper":false},"paper":"doi:10.1007/bf02880522","paper_id":"doi:10.1007/bf02880522","phase_compositions":[{"basis":"mole_fraction (converted from atomic percent)","composition":{"BI":0.04},"composition_source":"printed","phase":"Si-rich liquid"},{"basis":"mole_fraction (converted from atomic percent)","composition":{"BI":0.96},"composition_source":"printed","phase":"Bi-rich liquid"}],"phases":[{"label":"Si-rich liquid","model_phase_rejected":{"model_phase":"DIAMOND_A4","pearson_symbol":"cF8","prototype":"C(diamond)","reason":"label_not_a_solution_or_structure_name"}},{"label":"Bi-rich liquid","model_phase_rejected":{"model_phase":"RHOMBOHEDRAL_A7","pearson_symbol":"hR2","prototype":"alpha-As","reason":"label_not_a_solution_or_structure_name"}},{"label":"(Si)","label_source":"page_check"}],"phases_stored":["Si-rich liquid","Bi-rich liquid"],"pid":"doi:10.1007/bf02880522/p2/tab-2/r03#invariant_reaction","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"stated_default_1_atm","property":"INVARIANT_TEMPERATURE","property_group":"invariant reaction","reaction":{"printed":"Monotectic transformation","type":"monotectic"},"reader_agreement":"multi_reader","reader_agreement_basis":"derived_from_readers","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"invariant_table","source_system":"BI-SI","system":"BI-SI","temperature_K":1666.15,"temperature_printed":"1393","temperature_uncertainty":{"basis":"stated_default","value":2.0},"tool_release":"v2.1.19n","transition_kind":"monotectic","transition_kind_printed":"monotectic","uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"composition":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.005,"sigma_method":{"basis":"calibrated","ci95":[0.004448,0.004448],"class":"model_calculated","entry":"model/X_PHASE","floor":0.005,"floor_unit":"mole fraction","n_pairs":16730,"value":0.005},"sigma_printed":null,"sigma_reading":{"basis":"last_stored_digit","value":0.005},"sigma_scatter":null,"unit":"mole fraction","value_type":"X_PHASE"},"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":4.0,"sigma_method":{"basis":"calibrated","ci95":[3.11346,4.29954],"class":"model_calculated","entry":"model/T_INVARIANT","floor":4.0,"floor_unit":"K","n_pairs":14146,"value":4.0},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.005},"sigma_scatter":null,"unit":"K","value_type":"T_INVARIANT"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"K","value":1666.15}],"release":"orchid-literature 2026-10-23 (record store db-v2.1: invariant/general v2.1.19r, text+context fixup-20261022)","system":"BI-SI"}