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Ceram.. 152, 728-738 (1975).","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Table 3 (continued), Phase: TiC1-x (first row of the block, 0.43292, TiC0.95, 299 K, [85Vil])","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61],"table":"3","table_key":"t010"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"6001c5d9fbc878d14058bea582e7b5adbbe49aa0b30f95130490012d533340ab","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"TiC1-x block = first 33 rows of the continued table on PDF page 5, ends before B4C","verdict":"confirmed"}},{"after":"C-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["TiC1-x"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-2OIFNYVBWC","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":35},"observation_type":"structural_property","origin":{"basis":"cited_work_before_1980_assumed_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r35#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"C-TI","temperature_K":298.15,"temperature_basis":"assumed_room_temperature","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009511,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009511},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.323,"value_stored":0.4323},{"chemical_system":"C-TI","cited_sources":[{"kind":"unknown","label":"66Rud","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"TI","before":"B-C-TI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"C":0.0,"TI":1.0},"phases":["αTi"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":"C-TI","before":"TI","evidence":{"paper":"doi:10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","rationale":"The value is in the TiC1-x block; alpha-Ti is named only as a coexisting phase. Move the unary filing to C-TI, clear the stale unary composition, and attach the printed nonstoichiometric phase.","report_id":"ORCHID-Y10-20261027-v1","table_key":"t010"},"field":"system","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"2026-10-27; Codex rendered-page recheck at 200 dpi with OCR assistance; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting phases named in the Comment column.","verdict":"confirmed"}},{"after":"C-TI","before":null,"evidence":{"paper":"doi:10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","rationale":"The value is in the TiC1-x block; alpha-Ti is named only as a coexisting phase. Move the unary filing to C-TI, clear the stale unary composition, and attach the printed nonstoichiometric phase.","report_id":"ORCHID-Y10-20261027-v1","table_key":"t010"},"field":"chemical_system","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"2026-10-27; Codex rendered-page recheck at 200 dpi with OCR assistance; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting phases named in the Comment column.","verdict":"confirmed"}},{"after":["C","TI"],"before":["TI"],"evidence":{"paper":"doi:10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","rationale":"The value is in the TiC1-x block; alpha-Ti is named only as a coexisting phase. Move the unary filing to C-TI, clear the stale unary composition, and attach the printed nonstoichiometric phase.","report_id":"ORCHID-Y10-20261027-v1","table_key":"t010"},"field":"elements","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"2026-10-27; Codex rendered-page recheck at 200 dpi with OCR assistance; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting phases named in the Comment column.","verdict":"confirmed"}},{"after":null,"before":{"TI":1.0},"evidence":{"paper":"doi:10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","rationale":"The value is in the TiC1-x block; alpha-Ti is named only as a coexisting phase. Move the unary filing to C-TI, clear the stale unary composition, and attach the printed nonstoichiometric phase.","report_id":"ORCHID-Y10-20261027-v1","table_key":"t010"},"field":"overall_composition","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"2026-10-27; Codex rendered-page recheck at 200 dpi with OCR assistance; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting phases named in the Comment column.","verdict":"confirmed"}},{"after":null,"before":"from_formula","evidence":{"paper":"doi:10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","rationale":"The value is in the TiC1-x block; alpha-Ti is named only as a coexisting phase. Move the unary filing to C-TI, clear the stale unary composition, and attach the printed nonstoichiometric phase.","report_id":"ORCHID-Y10-20261027-v1","table_key":"t010"},"field":"overall_composition_basis","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"2026-10-27; Codex rendered-page recheck at 200 dpi with OCR assistance; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting phases named in the Comment column.","verdict":"confirmed"}},{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"αTi"}],"evidence":{"paper":"doi:10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","rationale":"The value is in the TiC1-x block; alpha-Ti is named only as a coexisting phase. Move the unary filing to C-TI, clear the stale unary composition, and attach the printed nonstoichiometric phase.","report_id":"ORCHID-Y10-20261027-v1","table_key":"t010"},"field":"phases","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"2026-10-27; Codex rendered-page recheck at 200 dpi with OCR assistance; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting phases named in the Comment column.","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["phase_label_misassigned_on_page","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["independent_check_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"gate_failures":[{"code":"phase_label_misassigned_on_page","detail":"Value printed in the TiC1-x block (αTi only in the comment column); stored as αTi in unary TI. Relabel needs a system move (TI -> C-TI), so not patched; not a pure-Ti lattice parameter.","effect":"not_accepted","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (phase, t010)","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"The TiC1-x phase composition is not printed. The records remain excluded until the 2026.10.1 rebuild explicitly reassesses acceptance.","effect":"not_espei_ready","gate":"CX20261028"}],"id":"ORC-W5V43DNCYM","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":43},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":null,"overall_composition_basis":null,"overall_composition_stored":{"C":0.0,"TI":1.0},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r43#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"C-TI","temperature_K":2733.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009478,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009478},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.308,"value_stored":0.4308},{"chemical_system":"C-TI","cited_sources":[{"kind":"unknown","label":"66Rud","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"TI","before":"B-C-TI","evidence":{"basis":"overall_composition_all_elements","overall_composition":{"C":0.0,"TI":1.0},"phases":["αTi"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":"C-TI","before":"TI","evidence":{"paper":"doi:10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","rationale":"The value is in the TiC1-x block; alpha-Ti is named only as a coexisting phase. Move the unary filing to C-TI, clear the stale unary composition, and attach the printed nonstoichiometric phase.","report_id":"ORCHID-Y10-20261027-v1","table_key":"t010"},"field":"system","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"2026-10-27; Codex rendered-page recheck at 200 dpi with OCR assistance; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting phases named in the Comment column.","verdict":"confirmed"}},{"after":"C-TI","before":null,"evidence":{"paper":"doi:10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","rationale":"The value is in the TiC1-x block; alpha-Ti is named only as a coexisting phase. Move the unary filing to C-TI, clear the stale unary composition, and attach the printed nonstoichiometric phase.","report_id":"ORCHID-Y10-20261027-v1","table_key":"t010"},"field":"chemical_system","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"2026-10-27; Codex rendered-page recheck at 200 dpi with OCR assistance; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting phases named in the Comment column.","verdict":"confirmed"}},{"after":["C","TI"],"before":["TI"],"evidence":{"paper":"doi:10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","rationale":"The value is in the TiC1-x block; alpha-Ti is named only as a coexisting phase. Move the unary filing to C-TI, clear the stale unary composition, and attach the printed nonstoichiometric phase.","report_id":"ORCHID-Y10-20261027-v1","table_key":"t010"},"field":"elements","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"2026-10-27; Codex rendered-page recheck at 200 dpi with OCR assistance; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting phases named in the Comment column.","verdict":"confirmed"}},{"after":null,"before":{"TI":1.0},"evidence":{"paper":"doi:10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","rationale":"The value is in the TiC1-x block; alpha-Ti is named only as a coexisting phase. Move the unary filing to C-TI, clear the stale unary composition, and attach the printed nonstoichiometric phase.","report_id":"ORCHID-Y10-20261027-v1","table_key":"t010"},"field":"overall_composition","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"2026-10-27; Codex rendered-page recheck at 200 dpi with OCR assistance; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting phases named in the Comment column.","verdict":"confirmed"}},{"after":null,"before":"from_formula","evidence":{"paper":"doi:10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","rationale":"The value is in the TiC1-x block; alpha-Ti is named only as a coexisting phase. Move the unary filing to C-TI, clear the stale unary composition, and attach the printed nonstoichiometric phase.","report_id":"ORCHID-Y10-20261027-v1","table_key":"t010"},"field":"overall_composition_basis","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"2026-10-27; Codex rendered-page recheck at 200 dpi with OCR assistance; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting phases named in the Comment column.","verdict":"confirmed"}},{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"αTi"}],"evidence":{"paper":"doi:10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","rationale":"The value is in the TiC1-x block; alpha-Ti is named only as a coexisting phase. Move the unary filing to C-TI, clear the stale unary composition, and attach the printed nonstoichiometric phase.","report_id":"ORCHID-Y10-20261027-v1","table_key":"t010"},"field":"phases","gate":"CX20261028","rule":"source_adjudicated_independent_check","visual_check":{"checked":"2026-10-27; Codex rendered-page recheck at 200 dpi with OCR assistance; AI-assisted, not human re-review; ORCHID-Y10-20261027-v1","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting phases named in the Comment column.","verdict":"confirmed"}}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":false,"gate_failures":["phase_label_misassigned_on_page","human_review_residual_concern"],"review_state":"extracted","specification_gaps":["independent_check_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"gate_failures":[{"code":"phase_label_misassigned_on_page","detail":"Value printed in the TiC1-x block (αTi only in the comment column); stored as αTi in unary TI. Relabel needs a system move (TI -> C-TI), so not patched; not a pure-Ti lattice parameter.","effect":"not_accepted","gate":"page","visual_check":{"checked":"2026-10-28; Claude (Studio sub-agent readers) rendered-page check, AI-assisted, not human re-review; ORCHID-TD-20261028-v1 (phase, t010)","image_sha256":"044e16270a98e924996e1a6761d9a23bae4af9eb15dd3f3d595b5550bac25308","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"All 15 values (r36 0.43112, r37 0.43166, r38 0.43192, r39 0.43209, r40 0.43136, r41 0.43207, r42 0.43226, r43 0.4308, r44 0.4321, r45 0.4310, r46 0.4318, r47 0.4329, r48 0.4309, r52 0.4322, r53 0.4329) are a-column cells of the TiC1-x block (a only, b/c '...'); the stored phases are the coexisting p","verdict":"confirmed"}},{"code":"human_review_residual_concern","detail":"The TiC1-x phase composition is not printed. The records remain excluded until the 2026.10.1 rebuild explicitly reassesses acceptance.","effect":"not_espei_ready","gate":"CX20261028"}],"id":"ORC-YFL4ICUSTO","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":48},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"overall_composition":null,"overall_composition_basis":null,"overall_composition_stored":{"C":0.0,"TI":1.0},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r48#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"C-TI","temperature_K":2646.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.00948,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.00948},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.309,"value_stored":0.4309},{"chemical_system":"C-TI","cited_sources":[{"kind":"unknown","label":"66Rud","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Table 3 (continued), Phase: TiC1-x (first row of the block, 0.43292, TiC0.95, 299 K, [85Vil])","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61],"table":"3","table_key":"t010"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"6001c5d9fbc878d14058bea582e7b5adbbe49aa0b30f95130490012d533340ab","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"TiC1-x block = first 33 rows of the continued table on PDF page 5, ends before B4C","verdict":"confirmed"}},{"after":"C-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["TiC1-x"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-2JNM73ZWQW","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":49},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r49#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"C-TI","temperature_K":3073.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009502,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009502},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.319,"value_stored":0.4319},{"chemical_system":"C-TI","cited_sources":[{"kind":"unknown","label":"66Rud","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Table 3 (continued), Phase: TiC1-x (first row of the block, 0.43292, TiC0.95, 299 K, [85Vil])","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61],"table":"3","table_key":"t010"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"6001c5d9fbc878d14058bea582e7b5adbbe49aa0b30f95130490012d533340ab","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"TiC1-x block = first 33 rows of the continued table on PDF page 5, ends before B4C","verdict":"confirmed"}},{"after":"C-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["TiC1-x"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-V55DKBUNYN","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":50},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r50#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"C-TI","temperature_K":3133.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009517,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009517},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.326,"value_stored":0.4326},{"chemical_system":"C-TI","cited_sources":[{"kind":"unknown","label":"66Rud","status":"unresolved"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Table 3 (continued), Phase: TiC1-x (first row of the block, 0.43292, TiC0.95, 299 K, [85Vil])","rationale":"Printed table context for this group supplies phase; 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TiCI.,~ , , , 0.2 0.3 ~, , , I 0.18 0.4 0.5 0.6 0.7 0. xB (B12)(C253B0 ~B0a7) Calculated TiC I_t-\"B4C\" isopleth (x ~_0.203).","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Table 3 (continued), Phase: TiC1-x (first row of the block, 0.43292, TiC0.95, 299 K, [85Vil])","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61],"table":"3","table_key":"t010"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"6001c5d9fbc878d14058bea582e7b5adbbe49aa0b30f95130490012d533340ab","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"TiC1-x block = first 33 rows of the continued table on PDF page 5, ends before B4C","verdict":"confirmed"}},{"after":"C-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["TiC1-x"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-5AY5GS7VOQ","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":58},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r58#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"C-TI","temperature_K":1773.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009522,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009522},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.328,"value_stored":0.4328},{"chemical_system":"C-TI","cited_sources":[{"first_author":"Aivazov","kind":"unknown","label":"75Aiv","reference":"M.I. Aivazov and T.A. Stepashina, \"Synthesis of Complex Carbide Phases in the System Ti-B-C and Ti-Si-C by Crystallisation from the Gas Phase,\" Iz~:Akad. Nauk SSSR, Neorg. Mater., 11, 1223-1226 (1975) in Russian; TR: Inorganic Mater., 11, 1044-1046 (1975). TiCI.,~ , , , 0.2 0.3 ~, , , I 0.18 0.4 0.5 0.6 0.7 0. xB (B12)(C253B0 ~B0a7) Calculated TiC I_t-\"B4C\" isopleth (x ~_0.203).","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Table 3 (continued), Phase: TiC1-x (first row of the block, 0.43292, TiC0.95, 299 K, [85Vil])","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61],"table":"3","table_key":"t010"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"6001c5d9fbc878d14058bea582e7b5adbbe49aa0b30f95130490012d533340ab","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"TiC1-x block = first 33 rows of the continued table on PDF page 5, ends before B4C","verdict":"confirmed"}},{"after":"C-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["TiC1-x"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-5IYLEVA7SL","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":59},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r59#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"C-TI","temperature_K":1773.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009533,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009533},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.333,"value_stored":0.4333},{"chemical_system":"C-TI","cited_sources":[{"first_author":"Aivazov","kind":"unknown","label":"75Aiv","reference":"M.I. Aivazov and T.A. Stepashina, \"Synthesis of Complex Carbide Phases in the System Ti-B-C and Ti-Si-C by Crystallisation from the Gas Phase,\" Iz~:Akad. Nauk SSSR, Neorg. Mater., 11, 1223-1226 (1975) in Russian; TR: Inorganic Mater., 11, 1044-1046 (1975). TiCI.,~ , , , 0.2 0.3 ~, , , I 0.18 0.4 0.5 0.6 0.7 0. xB (B12)(C253B0 ~B0a7) Calculated TiC I_t-\"B4C\" isopleth (x ~_0.203).","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Table 3 (continued), Phase: TiC1-x (first row of the block, 0.43292, TiC0.95, 299 K, [85Vil])","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other papers.","report_id":"ORCHID-TC-20261027-v1","source_group_rows":[29,30,31,32,33,34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61],"table":"3","table_key":"t010"},"field":"phases","gate":"TC20261027","rule":"source_adjudicated_table_context","visual_check":{"checked":"2026-10-27; Claude rendered-page inspection, table-context batch 01","image_sha256":"6001c5d9fbc878d14058bea582e7b5adbbe49aa0b30f95130490012d533340ab","page":5,"pdf_sha256_prefix":"c3cce0d3e97b1f77","seen":"TiC1-x block = first 33 rows of the continued table on PDF page 5, ends before B4C","verdict":"confirmed"}},{"after":"C-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["TiC1-x"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"unspecified","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition","table_context_correction_requires_downstream_revalidation"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-7KZPKVXAZM","locator":{"ref":"sha256:c3cce0d3e97b1f77/p4/tab-3","row":60},"observation_type":"structural_property","origin":{"basis":"no_printed_or_resolvable_source_kind","class":"unspecified","own_work_of_paper":false},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x","label_source":"printed_source_page"}],"pid":"sha256:c3cce0d3e97b1f77/p4/tab-3/r60#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"C-TI","temperature_K":1773.15,"temperature_basis":"printed","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009508,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009508},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.322,"value_stored":0.4322},{"chemical_system":"C-TI","cited_sources":[{"first_author":"Aivazov","kind":"unknown","label":"75Aiv","reference":"M.I. Aivazov and T.A. Stepashina, \"Synthesis of Complex Carbide Phases in the System Ti-B-C and Ti-Si-C by Crystallisation from the Gas Phase,\" Iz~:Akad. Nauk SSSR, Neorg. Mater., 11, 1223-1226 (1975) in Russian; TR: Inorganic Mater., 11, 1044-1046 (1975). TiCI.,~ , , , 0.2 0.3 ~, , , I 0.18 0.4 0.5 0.6 0.7 0. xB (B12)(C253B0 ~B0a7) Calculated TiC I_t-\"B4C\" isopleth (x ~_0.203).","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":[{"label":"TiC1-x","label_source":"printed_source_page"}],"before":[{"label":"UNKNOWN"}],"evidence":{"batch":"table_context_batch_01","doi":"10.1007/bf02646248","pdf_page":5,"pdf_sha256":"c3cce0d3e97b1f77db693658a1c3dfe3bf456e1fb88cdbc8579134bf41d4bf5a","printed":"Table 3 (continued), Phase: TiC1-x (first row of the block, 0.43292, TiC0.95, 299 K, [85Vil])","rationale":"Printed table context for this group supplies phase; shared fields only, row values, references, uncertainty, composition and conditions unchanged; no forward fill across groups and no inference from symmetry, composition or other 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TiCI.,~ , , , 0.2 0.3 ~, , , I 0.18 0.4 0.5 0.6 0.7 0. xB (B12)(C253B0 ~B0a7) Calculated TiC I_t-\"B4C\" isopleth (x ~_0.203).","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"C-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["TiC1-x"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-HXRLH5WJKR","locator":{"ref":"sha256:c3cce0d3e97b1f77/p5/tab-3","row":30},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x"}],"pid":"sha256:c3cce0d3e97b1f77/p5/tab-3/r30#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"C-TI","temperature_K":1773.15,"temperature_basis":"printed","temperature_printed":"1500 °C","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009522,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009522},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.328,"value_stored":0.4328},{"chemical_system":"C-TI","cited_sources":[{"first_author":"Aivazov","kind":"unknown","label":"75Aiv","reference":"M.I. Aivazov and T.A. Stepashina, \"Synthesis of Complex Carbide Phases in the System Ti-B-C and Ti-Si-C by Crystallisation from the Gas Phase,\" Iz~:Akad. Nauk SSSR, Neorg. Mater., 11, 1223-1226 (1975) in Russian; TR: Inorganic Mater., 11, 1044-1046 (1975). TiCI.,~ , , , 0.2 0.3 ~, , , I 0.18 0.4 0.5 0.6 0.7 0. xB (B12)(C253B0 ~B0a7) Calculated TiC I_t-\"B4C\" isopleth (x ~_0.203).","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"C-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["TiC1-x"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-7NSLIJ6VRY","locator":{"ref":"sha256:c3cce0d3e97b1f77/p5/tab-3","row":31},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x"}],"pid":"sha256:c3cce0d3e97b1f77/p5/tab-3/r31#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"C-TI","temperature_K":1773.15,"temperature_basis":"printed","temperature_printed":"1500 °C","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009533,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009533},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.333,"value_stored":0.4333},{"chemical_system":"C-TI","cited_sources":[{"first_author":"Aivazov","kind":"unknown","label":"75Aiv","reference":"M.I. Aivazov and T.A. Stepashina, \"Synthesis of Complex Carbide Phases in the System Ti-B-C and Ti-Si-C by Crystallisation from the Gas Phase,\" Iz~:Akad. Nauk SSSR, Neorg. Mater., 11, 1223-1226 (1975) in Russian; TR: Inorganic Mater., 11, 1044-1046 (1975). TiCI.,~ , , , 0.2 0.3 ~, , , I 0.18 0.4 0.5 0.6 0.7 0. xB (B12)(C253B0 ~B0a7) Calculated TiC I_t-\"B4C\" isopleth (x ~_0.203).","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"C-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["TiC1-x"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-WFIUCR6GU6","locator":{"ref":"sha256:c3cce0d3e97b1f77/p5/tab-3","row":32},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x"}],"pid":"sha256:c3cce0d3e97b1f77/p5/tab-3/r32#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"C-TI","temperature_K":1773.15,"temperature_basis":"printed","temperature_printed":"1500 °C","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009508,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009508},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.322,"value_stored":0.4322},{"chemical_system":"C-TI","cited_sources":[{"first_author":"Aivazov","kind":"unknown","label":"75Aiv","reference":"M.I. Aivazov and T.A. Stepashina, \"Synthesis of Complex Carbide Phases in the System Ti-B-C and Ti-Si-C by Crystallisation from the Gas Phase,\" Iz~:Akad. Nauk SSSR, Neorg. Mater., 11, 1223-1226 (1975) in Russian; TR: Inorganic Mater., 11, 1044-1046 (1975). TiCI.,~ , , , 0.2 0.3 ~, , , I 0.18 0.4 0.5 0.6 0.7 0. xB (B12)(C253B0 ~B0a7) Calculated TiC I_t-\"B4C\" isopleth (x ~_0.203).","status":"resolved","year":"1975"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"C-TI","before":"B-C-TI","evidence":{"basis":"phase_formula","overall_composition":null,"phases":["TiC1-x"]},"field":"system","gate":"A1","rule":"system_of_the_state"}],"evidence_class":"experimental","flags":{"calphad_check":"not_available","espei_certified":false,"espei_ready":false,"extraction_accepted":true,"review_state":"extracted","specification_gaps":["state:composition"],"state_fully_specified":false,"system_is_state_subsystem":true},"fold_lpo":2,"fold_lso":0,"id":"ORC-HLVO7L4PXB","locator":{"ref":"sha256:c3cce0d3e97b1f77/p5/tab-3","row":33},"observation_type":"structural_property","origin":{"basis":"printed_source_experimental","class":"experimental","own_work_of_paper":false},"paper":"doi:10.1007/bf02646248","paper_id":"doi:10.1007/bf02646248","phases":[{"label":"TiC1-x"}],"pid":"sha256:c3cce0d3e97b1f77/p5/tab-3/r33#structural_property","pressure_Pa":101325,"pressure_basis":"assumed_default_1_atm_not_printed","pressure_basis_stored":"unstated_assumed","property":"LATTICE_A","property_group":"crystal structure","reader_agreement":"multi_reader","reader_agreement_label":"confirmed (two or more readers)","reader_tier":"preliminary_flash+claude","readers":["claude-opus-5.5","gemini-3.1-pro-preview","gemini-3.8-flash","text_layer"],"record_kind":"general_table","source_system":"B-C-TI","system":"C-TI","temperature_K":1773.15,"temperature_basis":"printed","temperature_printed":"1500 °C","tool_release":"tools-release-v2.1.18","uncertainty":{"basis":"reading_resolution","value":0.0005},"uncertainty_budget":{"calibration":"orchid-uncertainty-calibration 2026-10-24 (audit round 2) sha256 6a2b5a92b0ec","quantities":{"value":{"sigma_composition":null,"sigma_conversion":null,"sigma_effective":0.009513,"sigma_method":{"basis":"calibrated","ci95":[0.001793,0.002549],"class":"unknown","entry":"value_types/LATTICE_LENGTH/classes/unknown","floor":0.0022,"floor_unit":"relative (fraction of the value)","n_pairs":586,"value":0.009513},"sigma_printed":null,"sigma_reading":{"basis":"last_printed_digit","value":0.0005},"sigma_scatter":null,"unit":"Å","value_type":"LATTICE_LENGTH"}},"sigma_rule":"max(sqrt(max(printed, reading, method)^2 + composition^2 + conversion^2), scatter)"},"unit":"Å","unit_stored":"nm","value":4.324,"value_stored":0.4324},{"chemical_system":"C-TI","cited_sources":[{"first_author":"Jonsson","kind":"unknown","label":"92Jon","reference":"S. Jonsson, Thesis, Royal Institute of Technology Stockholm, Sweden (1992).","status":"resolved","year":"1992"}],"conditions":{"kind":"cited_source","note":"conditions in the cited source"},"corrections":[{"after":"C-TI","before":"B-C-TI","evidence":{"basis":"every_phase_determined","overall_composition":null,"phases":["βTi","TiC1-x","αTi"]},"field":"system","gate":"A1","rule":"system_of_the_state"},{"after":"BCC_A2","before":"HCP_A3","evidence":{"label":"βTi","release":"phase-label-check 2026-10-24 (audit round 2, A2 class 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